CN110582873A - 作为电池活性材料的硫族物聚合物-碳复合物 - Google Patents

作为电池活性材料的硫族物聚合物-碳复合物 Download PDF

Info

Publication number
CN110582873A
CN110582873A CN201880028392.9A CN201880028392A CN110582873A CN 110582873 A CN110582873 A CN 110582873A CN 201880028392 A CN201880028392 A CN 201880028392A CN 110582873 A CN110582873 A CN 110582873A
Authority
CN
China
Prior art keywords
carbon
sulfur
chalcogenide
monomers
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201880028392.9A
Other languages
English (en)
Chinese (zh)
Inventor
L·M·弗拉加·特里略
J·尼古拉斯·阿瓜多
R·帕里斯·艾斯库里巴诺
J·A·布拉兹奎兹·马丁
O·里昂奈特·博贝塔
E·阿萨塞塔·穆尼奥斯
I·乌丹皮列塔·冈萨雷斯
O·米格尔
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Repsol SA
Original Assignee
Repsol YPF SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Repsol YPF SA filed Critical Repsol YPF SA
Publication of CN110582873A publication Critical patent/CN110582873A/zh
Pending legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/362—Composites
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/136—Electrodes based on inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/054—Accumulators with insertion or intercalation of metals other than lithium, e.g. with magnesium or aluminium
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/04—Processes of manufacture in general
    • H01M4/049—Manufacturing of an active layer by chemical means
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/38—Selection of substances as active materials, active masses, active liquids of elements or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/581—Chalcogenides or intercalation compounds thereof
    • H01M4/5815—Sulfides
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/621—Binders
    • H01M4/622—Binders being polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
    • H01M4/624—Electric conductive fillers
    • H01M4/625—Carbon or graphite
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2309/00—Characterised by the use of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08J2309/06—Copolymers with styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
    • C08J2323/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
    • C08J2323/22—Copolymers of isobutene; butyl rubber
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/16—Homopolymers or copolymers of alkyl-substituted styrenes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/18—Homopolymers or copolymers of aromatic monomers containing elements other than carbon and hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/06—Sulfur
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M2004/026—Electrodes composed of, or comprising, active material characterised by the polarity
    • H01M2004/028—Positive electrodes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Medicinal Chemistry (AREA)
  • Composite Materials (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Secondary Cells (AREA)
CN201880028392.9A 2017-05-03 2018-05-02 作为电池活性材料的硫族物聚合物-碳复合物 Pending CN110582873A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP17382241 2017-05-03
EP17382241.2 2017-05-03
PCT/EP2018/061210 WO2018202716A1 (en) 2017-05-03 2018-05-02 Chalcogenide polymer-carbon composites as active materials for batteries

Publications (1)

Publication Number Publication Date
CN110582873A true CN110582873A (zh) 2019-12-17

Family

ID=58707449

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880028392.9A Pending CN110582873A (zh) 2017-05-03 2018-05-02 作为电池活性材料的硫族物聚合物-碳复合物

Country Status (6)

Country Link
US (1) US20200176767A1 (https=)
EP (1) EP3619758A1 (https=)
JP (1) JP2020518536A (https=)
KR (1) KR20190139936A (https=)
CN (1) CN110582873A (https=)
WO (1) WO2018202716A1 (https=)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110247034B (zh) * 2019-05-29 2020-12-22 嘉兴学院 一种有机硫电极材料及其制备方法
CN110890532A (zh) * 2019-11-19 2020-03-17 嘉兴学院 一种锂硫电池正极材料及其制备方法
CN113651311A (zh) * 2021-07-16 2021-11-16 西安理工大学 一种炔基碳材料及其制备方法及复合电极
US20250286141A1 (en) 2024-03-06 2025-09-11 Lyten, Inc. Electrolyte systems including performance-enhancing additives, and electrochemical cells including the same
CN119490656B (zh) * 2024-11-14 2025-08-15 暨南大学 一种导电有机硫聚合物微米笼的制备方法及其应用

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4049616A (en) * 1974-11-18 1977-09-20 The Goodyear Tire & Rubber Company Preparation of graft, block and crosslinked unsaturated polymers and copolymers by olefin metathesis
US20040043291A1 (en) * 2002-09-04 2004-03-04 Kim Nam In Cathode containing muticomponent binder mixture and lithium-sulfur battery using the same
JP2012133918A (ja) * 2010-12-20 2012-07-12 Toyota Central R&D Labs Inc 蓄電デバイス及び電極活物質の製造方法
CN104241612A (zh) * 2013-06-14 2014-12-24 中国科学院大连化学物理研究所 一种硫化聚合物包覆的硫/碳复合材料及其制备方法
WO2015123552A1 (en) * 2014-02-14 2015-08-20 The Arizona Board Of Regents On Behalf Of The University Of Arizona Sulfur composites and polymeric materials from elemental sulfur
FR3030890A1 (fr) * 2014-12-22 2016-06-24 Arkema France Matiere active d'electrode pour batterie li/s
US20160248087A1 (en) * 2013-10-18 2016-08-25 Lg Chem, Ltd. Carbon nanotube-sulfur composite comprising carbon nanotube aggregates, and method for preparing same
WO2017011533A1 (en) * 2015-07-13 2017-01-19 The Arizona Board Of Regents On Behalf Of The University Of Arizona Copolymerization of elemental sulfur to synthesize high sulfur content polymeric materials
WO2017027739A1 (en) * 2015-08-11 2017-02-16 The Arizona Board Of Regents On Behalf Of The University Of Arizona Copolymerization of elemental sulfur and thiocarbonyl-containing compounds
CN106463704A (zh) * 2014-04-18 2017-02-22 西奥公司 长循环寿命的锂硫固态电化学电池

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9005808B2 (en) 2011-03-01 2015-04-14 Uchicago Argonne, Llc Electrode materials for rechargeable batteries
US10243237B2 (en) * 2012-04-13 2019-03-26 Arkema Inc. Battery based on organosulfur species
US9774058B2 (en) * 2014-04-18 2017-09-26 Seeo, Inc. Polymer composition with electrophilic groups for stabilization of lithium sulfur batteries

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4049616A (en) * 1974-11-18 1977-09-20 The Goodyear Tire & Rubber Company Preparation of graft, block and crosslinked unsaturated polymers and copolymers by olefin metathesis
US20040043291A1 (en) * 2002-09-04 2004-03-04 Kim Nam In Cathode containing muticomponent binder mixture and lithium-sulfur battery using the same
JP2012133918A (ja) * 2010-12-20 2012-07-12 Toyota Central R&D Labs Inc 蓄電デバイス及び電極活物質の製造方法
CN104241612A (zh) * 2013-06-14 2014-12-24 中国科学院大连化学物理研究所 一种硫化聚合物包覆的硫/碳复合材料及其制备方法
US20160248087A1 (en) * 2013-10-18 2016-08-25 Lg Chem, Ltd. Carbon nanotube-sulfur composite comprising carbon nanotube aggregates, and method for preparing same
WO2015123552A1 (en) * 2014-02-14 2015-08-20 The Arizona Board Of Regents On Behalf Of The University Of Arizona Sulfur composites and polymeric materials from elemental sulfur
CN106463704A (zh) * 2014-04-18 2017-02-22 西奥公司 长循环寿命的锂硫固态电化学电池
FR3030890A1 (fr) * 2014-12-22 2016-06-24 Arkema France Matiere active d'electrode pour batterie li/s
WO2017011533A1 (en) * 2015-07-13 2017-01-19 The Arizona Board Of Regents On Behalf Of The University Of Arizona Copolymerization of elemental sulfur to synthesize high sulfur content polymeric materials
WO2017027739A1 (en) * 2015-08-11 2017-02-16 The Arizona Board Of Regents On Behalf Of The University Of Arizona Copolymerization of elemental sulfur and thiocarbonyl-containing compounds

Also Published As

Publication number Publication date
KR20190139936A (ko) 2019-12-18
US20200176767A1 (en) 2020-06-04
WO2018202716A1 (en) 2018-11-08
EP3619758A1 (en) 2020-03-11
JP2020518536A (ja) 2020-06-25

Similar Documents

Publication Publication Date Title
JP7382231B2 (ja) リチウム金属二次バッテリーのためのリチウムアノード保護ポリマー層及び製造方法
US6201100B1 (en) Electroactive, energy-storing, highly crosslinked, polysulfide-containing organic polymers and methods for making same
CN110582872B (zh) 锂电池阴极以及制造方法
Mukkabla et al. Cathode materials for lithium–sulfur batteries based on sulfur covalently bound to a polymeric backbone
CN104334613B (zh) 制备聚丙烯腈-硫-复合材料的方法
CN1323445C (zh) 阴极及其制备方法以及包括该阴极的锂电池
US6174621B1 (en) Electroactive high storage capacity polyacetylene-co-polysulfur materials and electrolytic cells containing same
US11424441B2 (en) Electrode and lithium secondary battery comprising same
CN110582873A (zh) 作为电池活性材料的硫族物聚合物-碳复合物
CN117766729A (zh) 用于锂二次电池的阴极活性材料层和制造方法
JPH11514128A (ja) 電気活性な高蓄容量ポリカーボン−スルフィド物質およびそれを含む電解セル
CN109256554B (zh) 一种硫化聚合物复合材料及其制备方法和应用
Manoj et al. Sulfur-polyaniline coated mesoporous carbon composite in combination with carbon nanotubes interlayer as a superior cathode assembly for high capacity lithium-sulfur cells
CN1214074C (zh) 电化学电源正极用单质硫/导电聚合物复合材料及方法
CN103904329B (zh) 锂离子电池
KR102835605B1 (ko) 고성능 황 양극재, 이의 제조방법 및 이를 포함하는 리튬-황 전지
CN110857333A (zh) 一类锂硫电池正极用乙烯基单体-硫共聚物及制备方法
CN108565465A (zh) 一种氰酸酯改性pvdf粘结剂、应用该粘结剂的正极极片及锂硫电池
JP2000311684A (ja) リチウム二次電池およびその正極の製造方法
KR102315537B1 (ko) 다공성 고분자 박막-황 나노입자-그래핀 복합체, 이의 제조 방법 및 이를 포함하는 리튬-황 전지
US6309778B1 (en) Electroactive high storage capacity polyacetylene-co-polysulfur materials and electrolytic cells containing same
CN116376279B (zh) 一种硫-苯二胺聚合物复合材料及其制备方法与应用
KR102959964B1 (ko) 전도성 첨가제 및 이를 포함하는 전지
WO2025000557A1 (zh) 一种电池和电子设备
CN120380604A (zh) 用于锂离子电池单元的阳极材料

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20191217

WD01 Invention patent application deemed withdrawn after publication