CN110526505A - A kind of multiple metasynthesis of seawater utilizes method - Google Patents
A kind of multiple metasynthesis of seawater utilizes method Download PDFInfo
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- CN110526505A CN110526505A CN201910838111.2A CN201910838111A CN110526505A CN 110526505 A CN110526505 A CN 110526505A CN 201910838111 A CN201910838111 A CN 201910838111A CN 110526505 A CN110526505 A CN 110526505A
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- seawater
- water
- bromine
- algae
- salt
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- 239000013535 sea water Substances 0.000 title claims abstract description 102
- 238000000034 method Methods 0.000 title claims abstract description 53
- 241000894006 Bacteria Species 0.000 claims abstract description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 56
- 241000195493 Cryptophyta Species 0.000 claims abstract description 42
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims abstract description 32
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims abstract description 32
- 229910052794 bromium Inorganic materials 0.000 claims abstract description 32
- 150000003839 salts Chemical class 0.000 claims abstract description 30
- 241000238557 Decapoda Species 0.000 claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 claims abstract description 21
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000001301 oxygen Substances 0.000 claims abstract description 20
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 20
- 241000595940 Notostraca Species 0.000 claims abstract description 17
- 239000012267 brine Substances 0.000 claims abstract description 13
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims abstract description 13
- 238000009395 breeding Methods 0.000 claims abstract description 9
- 230000001488 breeding effect Effects 0.000 claims abstract description 9
- 238000000746 purification Methods 0.000 claims abstract description 8
- 238000012876 topography Methods 0.000 claims abstract description 4
- 230000008569 process Effects 0.000 claims description 15
- 230000009286 beneficial effect Effects 0.000 claims description 13
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims description 12
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims description 12
- 239000002253 acid Substances 0.000 claims description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 239000011521 glass Substances 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 8
- 238000007254 oxidation reaction Methods 0.000 claims description 8
- 239000011777 magnesium Substances 0.000 claims description 7
- 229910052749 magnesium Inorganic materials 0.000 claims description 7
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 6
- 229910002651 NO3 Inorganic materials 0.000 claims description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- 241000108664 Nitrobacteria Species 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 239000003337 fertilizer Substances 0.000 claims description 6
- 235000013305 food Nutrition 0.000 claims description 6
- 239000004310 lactic acid Substances 0.000 claims description 6
- 235000014655 lactic acid Nutrition 0.000 claims description 6
- 239000012452 mother liquor Substances 0.000 claims description 6
- 230000000243 photosynthetic effect Effects 0.000 claims description 6
- 244000063299 Bacillus subtilis Species 0.000 claims description 5
- 235000014469 Bacillus subtilis Nutrition 0.000 claims description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- 241000235342 Saccharomycetes Species 0.000 claims description 5
- 239000005864 Sulphur Substances 0.000 claims description 5
- 238000010521 absorption reaction Methods 0.000 claims description 5
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000000284 extract Substances 0.000 claims description 5
- BMYNFMYTOJXKLE-UHFFFAOYSA-N 3-azaniumyl-2-hydroxypropanoate Chemical compound NCC(O)C(O)=O BMYNFMYTOJXKLE-UHFFFAOYSA-N 0.000 claims description 4
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 4
- 230000015572 biosynthetic process Effects 0.000 claims description 4
- 239000011575 calcium Substances 0.000 claims description 4
- 229910052791 calcium Inorganic materials 0.000 claims description 4
- 238000001704 evaporation Methods 0.000 claims description 4
- 230000008020 evaporation Effects 0.000 claims description 4
- 239000007789 gas Substances 0.000 claims description 4
- 229910052736 halogen Inorganic materials 0.000 claims description 4
- 150000002367 halogens Chemical class 0.000 claims description 4
- 238000002156 mixing Methods 0.000 claims description 4
- 239000002689 soil Substances 0.000 claims description 4
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 claims description 3
- 240000007058 Halophila ovalis Species 0.000 claims description 3
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 claims description 3
- 238000013019 agitation Methods 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 210000003608 fece Anatomy 0.000 claims description 3
- 150000002926 oxygen Chemical class 0.000 claims description 3
- 230000001376 precipitating effect Effects 0.000 claims description 3
- 230000001954 sterilising effect Effects 0.000 claims description 3
- 238000004659 sterilization and disinfection Methods 0.000 claims description 3
- 229910052717 sulfur Inorganic materials 0.000 claims description 3
- 239000011593 sulfur Substances 0.000 claims description 3
- 235000002906 tartaric acid Nutrition 0.000 claims description 3
- 239000011975 tartaric acid Substances 0.000 claims description 3
- 238000009833 condensation Methods 0.000 claims description 2
- 230000005494 condensation Effects 0.000 claims description 2
- JGJLWPGRMCADHB-UHFFFAOYSA-N hypobromite Inorganic materials Br[O-] JGJLWPGRMCADHB-UHFFFAOYSA-N 0.000 claims description 2
- -1 hypochlorous acid Ammonia nitrogen Chemical compound 0.000 claims description 2
- 239000003595 mist Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 239000003895 organic fertilizer Substances 0.000 claims description 2
- 241000143060 Americamysis bahia Species 0.000 claims 1
- 244000046052 Phaseolus vulgaris Species 0.000 claims 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 8
- 238000000605 extraction Methods 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000001681 protective effect Effects 0.000 abstract description 3
- 230000003796 beauty Effects 0.000 abstract description 2
- 238000002425 crystallisation Methods 0.000 abstract description 2
- 230000008025 crystallization Effects 0.000 abstract description 2
- 230000004807 localization Effects 0.000 abstract description 2
- 241000927735 Penaeus Species 0.000 description 5
- 238000011161 development Methods 0.000 description 5
- 241000196324 Embryophyta Species 0.000 description 3
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 238000010612 desalination reaction Methods 0.000 description 3
- 238000006213 oxygenation reaction Methods 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 241000607479 Yersinia pestis Species 0.000 description 2
- 201000010099 disease Diseases 0.000 description 2
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000009313 farming Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 239000013505 freshwater Substances 0.000 description 2
- QWPPOHNGKGFGJK-UHFFFAOYSA-N hypochlorous acid Chemical compound ClO QWPPOHNGKGFGJK-UHFFFAOYSA-N 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 241000251468 Actinopterygii Species 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 208000018522 Gastrointestinal disease Diseases 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 238000012356 Product development Methods 0.000 description 1
- 241000589516 Pseudomonas Species 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 238000010923 batch production Methods 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 229910052729 chemical element Inorganic materials 0.000 description 1
- 230000001447 compensatory effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000004069 differentiation Effects 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000011010 flushing procedure Methods 0.000 description 1
- 239000004459 forage Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 230000036039 immunity Effects 0.000 description 1
- 239000008235 industrial water Substances 0.000 description 1
- 230000002262 irrigation Effects 0.000 description 1
- 238000003973 irrigation Methods 0.000 description 1
- 239000002101 nanobubble Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 230000000474 nursing effect Effects 0.000 description 1
- 235000016709 nutrition Nutrition 0.000 description 1
- 230000035764 nutrition Effects 0.000 description 1
- 230000001662 opsonic effect Effects 0.000 description 1
- 210000004681 ovum Anatomy 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 235000015277 pork Nutrition 0.000 description 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 239000006041 probiotic Substances 0.000 description 1
- 235000018291 probiotics Nutrition 0.000 description 1
- 102000004169 proteins and genes Human genes 0.000 description 1
- 108090000623 proteins and genes Proteins 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000013589 supplement Substances 0.000 description 1
- 230000009897 systematic effect Effects 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01G—HORTICULTURE; CULTIVATION OF VEGETABLES, FLOWERS, RICE, FRUIT, VINES, HOPS OR SEAWEED; FORESTRY; WATERING
- A01G33/00—Cultivation of seaweed or algae
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01K—ANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
- A01K61/00—Culture of aquatic animals
- A01K61/50—Culture of aquatic animals of shellfish
- A01K61/59—Culture of aquatic animals of shellfish of crustaceans, e.g. lobsters or shrimps
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B7/00—Halogens; Halogen acids
- C01B7/09—Bromine; Hydrogen bromide
- C01B7/096—Bromine
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01D—COMPOUNDS OF ALKALI METALS, i.e. LITHIUM, SODIUM, POTASSIUM, RUBIDIUM, CAESIUM, OR FRANCIUM
- C01D3/00—Halides of sodium, potassium or alkali metals in general
- C01D3/04—Chlorides
- C01D3/06—Preparation by working up brines; seawater or spent lyes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/08—Seawater, e.g. for desalination
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/32—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae
- C02F3/322—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae use of algae
- C02F3/325—Biological treatment of water, waste water, or sewage characterised by the animals or plants used, e.g. algae use of algae as symbiotic combination of algae and bacteria
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
- C02F3/342—Biological treatment of water, waste water, or sewage characterised by the microorganisms used characterised by the enzymes used
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F7/00—Aeration of stretches of water
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/80—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/80—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
- Y02A40/81—Aquaculture, e.g. of fish
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Environmental Sciences (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Marine Sciences & Fisheries (AREA)
- Biodiversity & Conservation Biology (AREA)
- Animal Husbandry (AREA)
- Zoology (AREA)
- Materials Engineering (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Micro-Organisms Or Cultivation Processes Thereof (AREA)
Abstract
The invention discloses a kind of multiple metasynthesis of seawater to utilize method, it receives and takes seawater, according to topography and each cultivation, the drop situation in brewed brine pond formulates the route of leaking water of seawater, it is controlled in each different link with gate, accomplish that a step one card allows seawater to improve salinity step by step, using seawater salinity as boundary, point gradient comprehensively utilizes seawater, it successively includes the following links: receiving and take seawater, remaining water reconfigures allotment after taking bacterium algae and biological control method → ecosystem to support shrimp → bromine extraction → nano oxygen enriching → fairy shrimp cultivation → high-quality shrimp culture → salt algae cultivation → salt manufacturing → purification.The present invention is to adapt to the crystallization of localization original ecological breeding, fully demonstrate nature and the beauty using the natural law, realize the reasonable utilization of resource, this collection fishing, salt, that bromine is produced in integrated novel production model is not only safe and efficient, and ecological, environmental protective, not only " multi-purpose water ", but also " moving in circles " have achieved the purpose that society, ecology, economic benefit win-win.
Description
Technical field
The present invention relates to seawater utilization fields more particularly to a kind of multiple metasynthesis of seawater to utilize method.
Background technique
With the development of society, the resource of land is increasingly depleted, resource abundant has attracted the sight of people in ocean.
Multipurpose use of sea water is mainly to be produced on land using seawater resources, solve new industry based on the growth requirement of land,
It is also the industry for having significant role to " blue area " economic society sustainable development.Some developed countries especially Japan, the U.S. are at this
Aspect is constantly in leading position.They have accumulated direct seawater utilization, sea water desalination and sewater chemistry after over half a century
Many experiences of comprehensive utilization of resources etc., multipurpose use of sea water have evolved into larger industry.
The Bohai Sea is faced in Dongying City east, and coastline 412.67 kilometers of overall length, accounts for about North gets the river mouth Shun Jianggou, south to the exit or entrance of a clitch Zi Mai
The 1/9 of Shandong Province coastline." 0 " rice is to 10.19 ten thousand hectares of water front beach area.Shallow sea area 4800 within minus 10 meters of isobaths
Square kilometre.Littoral sea bottom is relatively flat, and shallow sea substrate shale flour sand accounts for 77.8%, and sandy flour sand accounts for 22.2%.Seawater transparency
It is 32~55 centimetres.Ocean temperature, salinity are affected by continental climate and the Yellow River runoff.Winter bank has 2 months ice ages,
Seawater floating ice range is 0~5 nautical mile, and salinity is 35 ‰ or so；Spring ocean temperature is 12 DEG C~20 DEG C, salinity is mostly 22 ‰~
31‰；Summer ocean temperature is 24 DEG C~28 DEG C, and salinity is 21 ‰~30 ‰；
Multipurpose use of sea water mainly includes that sea water desalination, direct seawater utilization and sewater chemistry element utilize three aspects at present.
Sea water desalination is that the process of fresh water is obtained from seawater, is generally divided into thermal method (way of distillation) and embrane method two major classes.Seawater is directly sharp
With referring to using seawater as raw water, directly instead of fresh water, for living and producing.It is industrially cooled down with seawater, also can be used as
Printing and dyeing, pharmacy, alkaline, marine products processing industrial water.It can also be used for seawater resources, shoaly land and salt-tolerant plant
For the special agricultural irrigation of object, certain seawater is also a good selection for flushing the toilet.Sewater chemistry element extraction refers to
Chemical elements and the molten processing technologies such as sodium, bromine, magnesium are extracted from seawater.
But there are serious waste of resources for the above method, cause subsequent environments pollution, do not combine closely local practical, skill
The problems such as art is normative poor.
Summary of the invention
In view of the deficiencies of the prior art, the present invention provides a kind of multiple metasynthesis of seawater to utilize method, and this method is based oneself upon
Practical, working specification is to realize that the multiple metasynthesis of seawater utilizes, the powerful technique of zero-emission supports, and technical solution is:
A kind of multiple metasynthesis of seawater utilizes method, receives take seawater first, is fallen according to topography and each cultivation, brewed brine pond
Poor situation formulates the route of leaking water of seawater, is controlled in each different link with gate, accomplish a step one card allow seawater by
Grade improves salinity, and using seawater salinity as boundary, a point gradient comprehensively utilizes seawater, successively includes the following links:
(1) it receives and takes seawater, take bacterium algae and biological control method
It receives and takes seawater to pond, the initial salinity of seawater is 26 ‰ -30 ‰, takes bacterium algae and biological control method, utilizes a variety of bacterium
Calcium and magnesium fertilizer in algae and brine carries out reasonably combined in due course dispensing, and stablizing improves water quality, goes the harmful bacteria in water removal, purification
The excreta and bait in pond remain, while being capable of quick microelement-supplementing；
(2) ecosystem supports shrimp
Korneforos is moved into after precipitating carries out the feeding shrimp of ecosystem；
(3) bromine extracts
Out after shrimp, seawater salinity reaches 30 ‰ -50 ‰, carries out chlorine sterilization into bromine factory, then balances PH using food-grade acid
To between 4.0-4.3, bromine is slightly then mentioned using the progress of sulphur rich water, after extract seawater 55% ~ 65%, forms slight hypochlorous acid
Ammonia nitrogen and nitrate reaction in mother liquor, with salt-soda soil generate organic fertilizer, generate a variety of ecological baits needed for cultivating；
(4) nano oxygen enriching
Make water quality fast lifting saturated oxygen water through the oxidation of closed glass pipeline sidespin, carries out nanometer increasing to settling zone oxidation pond
Oxygen simultaneously injects beneficial bacterium algae raising pH value, and pH value adjustment to 7.8-8.8 carries out sea grass purification and beneficial bacterium algae propagation, then adds
Seawater or rainwater, make full use of the natural resources；
(5) fairy shrimp cultivates
PH value is controlled in 7.8-8.8, is repeatedly recycled, ammonia nitrogen is adjusted and nitrate dissolved oxygen, seawater salinity reaches 60 ‰ -120 ‰
When, cultivate the high-quality open-mouthed bait based on fairy shrimp；
(6) high-quality shrimp culture
After adjusting purifies water, carries out high-quality shrimps and put seedling cultivation；
(7) salt algae cultivates
Circulation is repeatedly adjusted, when seawater salinity reaches 120 ‰ -230 ‰, carries out the cultivation of salt algae；
(8) salt manufacturing
Breeding process forms the higher seawater of salinity, when seawater salinity reaches 240 ‰ -280 ‰, successively orderly enters salt manufacturing area
Evaporation tank, brewed brine pond, crystallizing pond carry out Salt production；Rainwater is covered in the old brine formed in salt-making process, the modeling with self-assembling formation with mat
And after sea water mixing, the beneficial bacterium algae and fairy shrimp cultivation of next round are participated in, purifies water quality further；
(9) remaining water reconfigures allotment after purifying
Purified remaining water, the salinity for above-mentioned production link are adjusted, and are recycled to form repeatedly first closed type, finally
Realize the zero-emission of seawater utilization process.
Further, the link (1) take the bacterium algae in bacterium algae and biological control method include EM bacterium, photosynthetic bacteria,
One of lactic acid bacteria, spore bacteria, nitrobacteria, saccharomycete, Bacillus natto, Facultative Halophiles are a variety of.
Further, food-grade acid is in food-grade sulfuric acid, food grade hydrochloric acid or tartaric acid in link (3) the bromine extraction
One kind.
Further, sulfur burning generates sulfur dioxide in link (3) the bromine extraction, and sulfur dioxide is absorbing tower top
It is sucked under portion's moment negative pressure state, bromine mixed gas is absorbed in the air duct at top of absorption tower by sulfur dioxide gas fair current, is formed
Hydrobromic acid droplet steam fog, is enriched with through absorption tower mist eliminator, congeals into hydrobromic acid mother liquor, distills into next link, bromine after condensation
It is separated with bromine water mixture, and forms bromine.
Further, the control of bromine amount is proposed the 60% of seawater in link (3) the bromine extraction.
Further, glass pipe inner wall is screw thread columnar structure in link (4) nano oxygen enriching, and water flows in pipeline
It just will form screw type rotary agitation, the oxygenation of water promoted to aoxidize.
Further, glass pipe length is 2 kilometers in link (4) nano oxygen enriching.
It further, is photosynthetic bacteria, spore bacteria, nitrobacteria, ferment beneficial to bacterium algae in link (4) nano oxygen enriching
One or more of female bacterium, EM bacterium, lactic acid bacteria, Bacillus natto, Facultative Halophiles.
Compared with prior art, the invention has the following advantages that the present invention is to adapt to the crystallization of localization original ecological breeding,
Also in person's character, food fully demonstrates nature and the beauty using the natural law, realizes the conjunction of resource object in good source, healthy one family
Reason utilizes, and it is not only safe and efficient that this collection fishing of the present invention, salt, bromine are produced in integrated novel production model, but also ecological, environmental protective,
Not only " multi-purpose water ", but also " moving in circles " have achieved the purpose that society, ecology, economic benefit win-win.
Detailed description of the invention
Fig. 1 is that the multiple metasynthesis of seawater of the present invention utilizes new ant algorithms schematic diagram.
Specific embodiment
In order to make the objectives, technical solutions, and advantages of the present invention clearer, below in conjunction with embodiment, to this hair
It is bright to be further elaborated.It should be appreciated that described herein, the specific embodiments are only for explaining the present invention, is not used to
Limit the present invention.
The description for being such as related to " first ", " second " in the present invention is used for description purposes only, and should not be understood as indicating
Or it implies its relative importance or implicitly indicates the quantity of indicated technical characteristic." first ", " second " are defined as a result,
Feature can explicitly or implicitly include at least one of the features.In the description of the present invention, the meaning of " plurality " is extremely
It is two few, such as two, three etc., unless otherwise specifically defined.
It is to be appreciated that experimental method is conventional method unless otherwise specified, and material is without special theory in the embodiment of the present invention
It is bright commercially available.
A kind of multiple metasynthesis of seawater utilizes method, receives take seawater first, according to topography and each cultivation, brewed brine pond
Drop situation formulate the route of leaking water of seawater, controlled in each different link with gate, accomplish that a step one card allows sea
Water improves salinity step by step, and using seawater salinity as boundary, a point gradient comprehensively utilizes seawater, successively includes following ring referring to Fig.1
Section:
(1) it receives and takes seawater, take bacterium algae and biological control method
It receives and takes seawater to pond, the initial salinity of seawater is 26 ‰ -30 ‰, takes bacterium algae and biological control method, utilizes a variety of bacterium
Calcium and magnesium fertilizer in algae and brine carries out reasonably combined in due course dispensing, and stablizing improves water quality, goes the harmful bacteria in water removal, purification
The excreta and bait in pond remain, while can quickly supplement the microelements such as calcium and magnesium nitre, enhance the immunity of shrimp, reach with
Algae controls worm, fungus treatment, is cured the disease with bacterium.The great advantage of biological control is free from environmental pollution, is the abiotic controls such as pesticide
Pest and disease damage method cannot ratio.It is free from environmental pollution using biological pest control, do not influence human health；
Bacterium algae has EM bacterium, photosynthetic bacteria, lactic acid bacteria, spore bacteria, nitrobacteria, saccharomycete, Bacillus natto, Facultative Halophiles etc..These
Pseudomonas all can be used in biological feed, sunny day rainy day, oxygenation deodorization, the steady water of water transfer, the penetrating degree of opsonic water, while also belong to height
Active bacterial strain promotes the food calling of shrimp, increases the food ration of shrimp, accelerates gastrointestinal disturbances and absorbs.
(2) ecosystem supports shrimp
Korneforos is moved into after precipitating carries out the feeding shrimp of ecosystem.
(3) bromine extracts
Out after shrimp, seawater salinity reaches 30 ‰ -50 ‰, carries out chlorine sterilization into bromine factory, then balances PH using food-grade acid,
Into water ph value in the discharge water ph value after 8.7 or so, balance between 4.0-4.3, then carried out using sulphur rich water slight
Bromine is mentioned, after extracting 60% of seawater or so, forms slight hypochlorous acid mother liquor, with the ammonia nitrogen and nitrate reaction in salt-soda soil, is generated
The fertilizer such as organic sodium and organic-magnesium generate a variety of ecological baits needed for cultivating；
Food-grade acid is other than it can use food-grade sulfuric acid, moreover it is possible to use food grade hydrochloric acid or tartaric acid.There is no particular/special requirement in terms of concentration,
Usage amount, such as 98 degree of bright sulfur acid need to be only adjusted according to specific concentration；
60% or so of seawater is extracted, can float 5% up and down, is i.e. between 55%-65%, in conjunction with itself process characteristic, further according to seawater
Halogen degree, temperature, the indexs such as brominated amount, utilize DCS automatic control system to adjust the flow of the raw and auxiliary materials such as chlorine, acid and sulphur
And usage amount controls 60% this index parameter.Tracking chemical examination is carried out to discharge water and determines that remaining brominated amount is mentioned with this to detect
Bromine amount.
(4) nano oxygen enriching
Make water quality fast lifting saturated oxygen water by the oxidation of nearly 2 kilometers of closed glass pipeline sidespin, arrives settling zone oxidation pond
Carry out nano oxygen enriching and inject beneficial bacterium algae to improve pH value, pH value adjustment to 7.8-8.8, carries out sea grass purification and beneficial bacterium algae is numerous
It grows, then adds seawater or rainwater, make full use of the natural resources to reach the higher water standard of cultivation demand；
Glass pipe inner wall is screw thread columnar structure, and water flows just in pipeline will form screw type rotary agitation, promotes the increasing of water
Oxygen oxidation；Nano oxygen enriching carries out oxygenation using the Japanese micro-nano bubble generator of advanced technology super oxygen.
It is photosynthetic bacteria, spore bacteria, nitrobacteria, saccharomycete, EM bacterium, lactic acid bacteria, Bacillus natto, Facultative Halophiles beneficial to bacterium algae
Equal probiotics.
(5) fairy shrimp cultivates
PH value is controlled in 7.8-8.8, is repeatedly recycled, ammonia nitrogen is adjusted and nitrate dissolved oxygen, seawater salinity reaches 60 ‰ -120 ‰
When, cultivate the high-quality open-mouthed bait based on fairy shrimp；
After the processing of link (4), seawater is further purified and is cultivated a variety of Homonemeae plants, utilizes bacterium algae
Class plant cultivation fairy shrimp.Fairy shrimp young protein rich in, fat and a variety of unsaturated fatty acids and active material.
Nutrition contained by its adult is also very high, therefore fairy shrimp is the fabulous bait of the young such as fish, shrimp and crab and adult.Use fairy shrimp
The shrimp of nursing not only a pork fertilizer, delicious flavour, and because without forage feed so still green non-pollution product, protects
Ecosystem.
(6) high-quality shrimp culture
After adjusting purifies water, carries out high-quality shrimps and put seedling cultivation, high-quality shrimps are Penaeus Vannmei seedling.(Chinese patent
104206319 A of CN discloses a kind of cultural method of Penaeus Vannmei, describes the cultural method of Penaeus Vannmei in detail,
The inventive point of the cultural method non-present invention of Penaeus Vannmei, details are not described herein again)
(7) salt algae cultivates
Circulation is repeatedly adjusted, when seawater salinity reaches 120 ‰ -230 ‰, carries out the cultivation of salt algae.(Chinese document " salt algae batch production
Cultural technique and product development " describe salt algae cultural method in detail, the inventive point of specific salt algae cultural method non-present invention,
Details are not described herein again)
(8) salt manufacturing
Breeding process forms the higher seawater of salinity, when seawater salinity reaches 240 ‰ -280 ‰, successively orderly enters salt manufacturing area
Evaporation tank, brewed brine pond, crystallizing pond carry out Salt production；Rainwater is covered in the old brine formed in salt-making process, the modeling with self-assembling formation with mat
And after sea water mixing, the beneficial bacterium algae and fairy shrimp cultivation of next link are participated in, purifies water quality further.
(9) remaining water reconfigures allotment after purifying
Purified remaining water, the salinity for above-mentioned production link are adjusted, and are recycled to form repeatedly first closed type, finally
Realize the zero-emission of seawater utilization process.
60,000 mu of project occupied area of the present invention or so at present, integrate sea-farming, crude salt, bromine production and sales.Its
In, 370158 acres of salt pan occupied area, 85913 acres of effective area is (wherein: 61118 acres of disengagement area, crystallizing pool area
21615 acres).300,000 tons of crude salt designed productive capacity, to cultivate the bromine designed productive capacity that demand is main adequate and systematic service
2000 tons/year, produce 5000000 jin of high-quality Penaeus Vannmei per year, 1,000,000 jin of fairy shrimp, fairy shrimp goes out 20,000 jin of ovum.Around " a water
The thinking of multi-purpose, clear production, cycle development ", Green industrial chain.According to " reasonable development, protecting ecology, sustainable development
The principle of exhibition " is planned that change resources advantage is economic advantages.
By the continuous upgrading of many years, the industries compensatory each other of each industry intermodule is done step-by-step and has recycled.
Sea-farming is transformed into full ecologic breeding from tradition cultivation: receiving and seawater process is taken to take bacterium algae and biological control method, precipitate
Korneforos is moved into afterwards and carries out the feeding shrimp of ecosystem, is sterilized by chlorine, breeding environment is optimized in early period, while 98 degree of scientific utilization pure
Acid balance pH value slightly mentions bromine using the progress of sulphur rich water, slight hypochlorous acid mother liquor is formed, with the ammonia nitrogen and nitric acid in salt-soda soil
Reactant salt, generates the fertilizer such as organic sodium and organic-magnesium, generates a variety of ecological baits needed for cultivating, in large area ecologic breeding area,
High-quality shrimp, worm, the classification cultivation of salt algae differentiation are carried out according to seawater salinity difference.Breeding process forms the higher sea of halogen degree
Water successively orderly enters salt manufacturing area evaporation tank, brewed brine pond, crystallizing pond progress Salt production.The old halogen that will be formed in salt-making process
Water after rainwater and sea water mixing are covered in the modeling with self-assembling formation with mat, participates in the beneficial bacterium algae and fairy shrimp cultivation of next round, obtains water quality
To further purification.Purified remaining water, the salinity for above-mentioned production link are adjusted, to form repeatedly first closed type circulation
It utilizes, the final zero-emission for realizing seawater utilization process.
It is not only safe and efficient that this collection fishing, salt, bromine are produced in integrated novel production model, but also ecological, environmental protective, and both " one
Water is multi-purpose ", it " moves in circles " again, has achieved the purpose that society, ecology, economic benefit win-win.
The present invention is not limited to above-mentioned embodiments, within the knowledge of those skilled in the art, may be used also
To make a variety of changes without departing from the purpose of the present invention, the content after variation still falls within protection scope of the present invention.
Claims (8)
1. a kind of multiple metasynthesis of seawater utilizes method, which is characterized in that receive and take seawater, according to topography and each cultivation, system
The drop situation in halogen pond formulates the route of leaking water of seawater, is controlled in each different link with gate, accomplishes a step one
Card allows seawater to improve salinity step by step, and using seawater salinity as boundary, a point gradient comprehensively utilizes seawater, successively includes following ring
Section:
(1) it receives and takes seawater, take bacterium algae and biological control method
It receives and takes seawater to pond, the initial salinity of seawater is 26 ‰ -30 ‰, takes bacterium algae and biological control method, utilizes a variety of bacterium
Calcium and magnesium fertilizer in algae and brine carries out reasonably combined in due course dispensing, and stablizing improves water quality, goes the harmful bacteria in water removal, purification
The excreta and bait in pond remain, while being capable of quick microelement-supplementing；
(2) ecosystem supports shrimp
Korneforos is moved into after precipitating carries out the feeding shrimp of ecosystem；
(3) bromine extracts
Out after shrimp, seawater salinity reaches 30 ‰ -50 ‰, carries out chlorine sterilization into bromine factory, then balances PH using food-grade acid
To between 4.0-4.3, bromine is slightly then mentioned using the progress of sulphur rich water, after extract seawater 55% ~ 65%, forms slight hypochlorous acid
Ammonia nitrogen and nitrate reaction in mother liquor, with salt-soda soil generate organic fertilizer, generate a variety of ecological baits needed for cultivating；
(4) nano oxygen enriching
Make water quality fast lifting saturated oxygen water through the oxidation of closed glass pipeline sidespin, carries out nanometer increasing to settling zone oxidation pond
Oxygen simultaneously injects beneficial bacterium algae raising pH value, and pH value adjustment to 7.8-8.8 carries out sea grass purification and beneficial bacterium algae propagation, then adds
Seawater or rainwater, make full use of the natural resources；
(5) fairy shrimp cultivates
PH value is controlled in 7.8-8.8, is repeatedly recycled, ammonia nitrogen is adjusted and nitrate dissolved oxygen, seawater salinity reaches 60 ‰ -120 ‰
When, cultivate the high-quality open-mouthed bait based on fairy shrimp；
(6) high-quality shrimp culture
After adjusting purifies water, carries out high-quality shrimps and put seedling cultivation；
(7) salt algae cultivates
Circulation is repeatedly adjusted, when seawater salinity reaches 120 ‰ -230 ‰, carries out the cultivation of salt algae；
(8) salt manufacturing
Breeding process forms the higher seawater of salinity, when seawater salinity reaches 240 ‰ -280 ‰, successively orderly enters salt manufacturing area
Evaporation tank, brewed brine pond, crystallizing pond carry out Salt production；Rainwater is covered in the old brine formed in salt-making process, the modeling with self-assembling formation with mat
And after sea water mixing, the beneficial bacterium algae and fairy shrimp cultivation of next round are participated in, purifies water quality further；
(9) remaining water reconfigures allotment after purifying
Purified remaining water, the salinity for above-mentioned production link are adjusted, and are recycled to form repeatedly first closed type, finally
Realize the zero-emission of seawater utilization process.
2. the multiple metasynthesis of seawater according to claim 1 utilizes method, which is characterized in that the link (1) takes bacterium
Bacterium algae in algae and biological control method includes EM bacterium, photosynthetic bacteria, lactic acid bacteria, spore bacteria, nitrobacteria, saccharomycete, receives
One of beans bacterium, Facultative Halophiles are a variety of.
3. the multiple metasynthesis of seawater according to claim 1 utilizes method, which is characterized in that link (3) bromine mentions
Taking middle food-grade acid is one of food-grade sulfuric acid, food grade hydrochloric acid or tartaric acid.
4. the multiple metasynthesis of seawater according to claim 3 utilizes method, which is characterized in that link (3) bromine mentions
Middle sulfur burning is taken to generate sulfur dioxide, sulfur dioxide sucks under moment negative pressure state at the top of absorption tower, and bromine mixed gas exists
It is absorbed in the air duct at top of absorption tower by sulfur dioxide gas fair current, forms hydrobromic acid droplet steam fog, through absorption tower mist eliminator richness
Collection, congeals into hydrobromic acid mother liquor, distills into next link, bromine is separated with bromine water mixture after condensation, and forms bromine.
5. the multiple metasynthesis of seawater according to claim 4 utilizes method, which is characterized in that link (3) bromine mentions
The control of bromine amount is proposed in taking the 60% of seawater.
6. the multiple metasynthesis of seawater according to claim 1 utilizes method, which is characterized in that link (4) nanometer increases
Glass pipe inner wall is screw thread columnar structure in oxygen, and water flows just in pipeline will form screw type rotary agitation, promotes the increasing of water
Oxygen oxidation.
7. the multiple metasynthesis of seawater according to claim 6 utilizes method, which is characterized in that link (4) nanometer increases
Glass pipe length is 2 kilometers in oxygen.
8. the multiple metasynthesis of seawater according to claim 7 utilizes method, which is characterized in that link (4) nanometer increases
In oxygen beneficial to bacterium algae be photosynthetic bacteria, spore bacteria, nitrobacteria, saccharomycete, EM bacterium, lactic acid bacteria, Bacillus natto, in Facultative Halophiles
It is one or more of.
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| CN111514862A (en) * | 2020-05-19 | 2020-08-11 | 唐山市银海食盐有限公司 | Heavy metal adsorbing brine alga, application and preparation method thereof, and application of brine alga in sea salt preparation |
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| CN113003586A (en) * | 2021-03-02 | 2021-06-22 | 湛江市农海科技有限公司 | Industrial method for comprehensive utilization of coastal mudflat, seawater, wind energy and solar energy |
| CN113562941A (en) * | 2021-09-24 | 2021-10-29 | 渤海水产科技(滨州)有限公司 | Treatment method and application of prawn culture tail water |
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