CN110520459B - 使用锌催化剂制备聚(呋喃二甲酸三亚甲酯)的方法 - Google Patents

使用锌催化剂制备聚(呋喃二甲酸三亚甲酯)的方法 Download PDF

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Publication number
CN110520459B
CN110520459B CN201880025372.6A CN201880025372A CN110520459B CN 110520459 B CN110520459 B CN 110520459B CN 201880025372 A CN201880025372 A CN 201880025372A CN 110520459 B CN110520459 B CN 110520459B
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poly
furandicarboxylate
polymer
zinc
trimethylene
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Chinese (zh)
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CN110520459A (zh
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H.B.森卡拉
R.H.博拉迪
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Ruixun Co ltd
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DuPont Industrial Biosciences USA LLC
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/18—Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181—Acids containing aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/826—Metals not provided for in groups C08G63/83 - C08G63/86
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78—Preparation processes
    • C08G63/82—Preparation processes characterised by the catalyst used
    • C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/88—Post-polymerisation treatment
    • C08G63/90—Purification; Drying
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/07—Aldehydes; Ketones
    • C08K5/08—Quinones

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201880025372.6A 2017-02-24 2018-02-23 使用锌催化剂制备聚(呋喃二甲酸三亚甲酯)的方法 Active CN110520459B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202310079467.9A CN116041675A (zh) 2017-02-24 2018-02-23 使用锌催化剂制备聚(呋喃二甲酸三亚甲酯)的方法

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762462948P 2017-02-24 2017-02-24
US62/462948 2017-02-24
PCT/US2018/019363 WO2018156859A1 (en) 2017-02-24 2018-02-23 Process for preparing poly(trimethylene furandicarboxylate) using zinc catalyst

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CN110520459B true CN110520459B (zh) 2022-12-02

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CN202310079467.9A Pending CN116041675A (zh) 2017-02-24 2018-02-23 使用锌催化剂制备聚(呋喃二甲酸三亚甲酯)的方法

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US (3) US20200017634A1 (enExample)
EP (2) EP3585827B1 (enExample)
JP (2) JP7204687B2 (enExample)
KR (2) KR20230067711A (enExample)
CN (2) CN110520459B (enExample)
AU (2) AU2018225205A1 (enExample)
CA (1) CA3054371A1 (enExample)
ES (1) ES2880324T3 (enExample)
MX (1) MX2019009974A (enExample)
WO (1) WO2018156859A1 (enExample)

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Publication number Priority date Publication date Assignee Title
CN111116880B (zh) * 2020-01-17 2021-11-30 沈阳化工大学 一种基于呋喃环的全生物基热塑性聚酯弹性体及其制备方法
CN117986551A (zh) * 2024-02-28 2024-05-07 华东理工大学 一种基于生物质基2,5-呋喃二甲酸的含支链的长碳链聚酯弹性体及其制备方法

Citations (5)

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CN1552754A (zh) * 2003-06-04 2004-12-08 中国石化集团天津石油化工公司 一种缩短聚酯生产中缩聚反应时间的方法
CN1961022A (zh) * 2004-05-05 2007-05-09 沙特基础工业公司 制备聚对苯二甲酸乙二醇酯共聚酯的方法，所获得的共聚酯及其用途和用于该方法的催化剂
CN101899145A (zh) * 2010-07-28 2010-12-01 江南大学 一种2,5-呋喃二甲酸基聚酯的制备方法
CN104334608A (zh) * 2012-06-05 2015-02-04 Sk化学株式会社 聚酯树脂及用于制备该聚酯树脂的方法
CN105849188A (zh) * 2013-12-20 2016-08-10 纳幕尔杜邦公司 聚(2，5-呋喃二甲酸1，3-丙二醇酯)(ptf)的成核结晶及其制品

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JP2000511211A (ja) * 1995-11-13 2000-08-29 イーストマン ケミカル カンパニー アンチモン化合物を触媒として使用して生成された熱安定性ポリエステル
US5608031A (en) * 1995-11-30 1997-03-04 Eastman Chemical Company Polyesters modified with 1,4-cyclohexaned imethanol having high clarity prepared utilizing an antimony containing catalyst/stabilizer system
JP4135581B2 (ja) * 2003-07-02 2008-08-20 三菱化学株式会社 有機系調色剤含有ポリエステルの製造方法
JP2008239771A (ja) * 2007-03-27 2008-10-09 Teijin Fibers Ltd ポリエチレンテレフタレートの連続式製造方法
JP5446121B2 (ja) * 2007-04-24 2014-03-19 三菱化学株式会社 フラン構造を含むポリエステル
WO2013062408A1 (en) * 2011-10-24 2013-05-02 Furanix Technologies B.V. A process for preparing a polymer product having a 2,5-furandicarboxylate moiety within the polymer backbone to be used in bottle, film or fibre applications
WO2013149157A1 (en) * 2012-03-30 2013-10-03 E. I. Du Pont De Nemours And Company Polyesters and fibers made therefrom
US10316140B2 (en) * 2014-03-21 2019-06-11 Furanix Technologies B.V. Polyesters comprising 2,5-furandicarboxylate and saturated diol units having a high glass transition temperature
CN106432701A (zh) * 2016-09-14 2017-02-22 中国科学院宁波材料技术与工程研究所 一种生物基不饱和聚酯及其制备方法和应用
EP3526272B1 (en) * 2016-10-14 2023-08-23 Covation Inc. Process for preparing poly(trimethylene furandicarboxylate)

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CN1552754A (zh) * 2003-06-04 2004-12-08 中国石化集团天津石油化工公司 一种缩短聚酯生产中缩聚反应时间的方法
CN1961022A (zh) * 2004-05-05 2007-05-09 沙特基础工业公司 制备聚对苯二甲酸乙二醇酯共聚酯的方法，所获得的共聚酯及其用途和用于该方法的催化剂
CN101899145A (zh) * 2010-07-28 2010-12-01 江南大学 一种2,5-呋喃二甲酸基聚酯的制备方法
CN104334608A (zh) * 2012-06-05 2015-02-04 Sk化学株式会社 聚酯树脂及用于制备该聚酯树脂的方法
CN105849188A (zh) * 2013-12-20 2016-08-10 纳幕尔杜邦公司 聚(2，5-呋喃二甲酸1，3-丙二醇酯)(ptf)的成核结晶及其制品

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Publication number Publication date
WO2018156859A1 (en) 2018-08-30
KR20190119112A (ko) 2019-10-21
US20210269589A1 (en) 2021-09-02
EP3878886A1 (en) 2021-09-15
EP3585827B1 (en) 2021-04-21
US20230257520A1 (en) 2023-08-17
JP2023036861A (ja) 2023-03-14
JP7204687B2 (ja) 2023-01-16
ES2880324T3 (es) 2021-11-24
BR112019017619A2 (pt) 2020-03-24
KR20230067711A (ko) 2023-05-16
AU2023274099A1 (en) 2023-12-14
AU2018225205A1 (en) 2019-09-05
JP2020508390A (ja) 2020-03-19
EP3585827A1 (en) 2020-01-01
US20200017634A1 (en) 2020-01-16
CN110520459A (zh) 2019-11-29
CA3054371A1 (en) 2018-08-30
CN116041675A (zh) 2023-05-02
MX2019009974A (es) 2020-01-27

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