CN110512440A - 一种羊毛西服面料的染色阻燃整理方法 - Google Patents

一种羊毛西服面料的染色阻燃整理方法 Download PDF

Info

Publication number
CN110512440A
CN110512440A CN201910869340.0A CN201910869340A CN110512440A CN 110512440 A CN110512440 A CN 110512440A CN 201910869340 A CN201910869340 A CN 201910869340A CN 110512440 A CN110512440 A CN 110512440A
Authority
CN
China
Prior art keywords
wool
suiting
dyeing
dye liquor
sorting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910869340.0A
Other languages
English (en)
Inventor
刘丽艳
陆晓明
周建玉
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Sunshine Co Ltd
Original Assignee
Jiangsu Sunshine Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Sunshine Co Ltd filed Critical Jiangsu Sunshine Co Ltd
Priority to CN201910869340.0A priority Critical patent/CN110512440A/zh
Publication of CN110512440A publication Critical patent/CN110512440A/zh
Pending legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/44—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen containing nitrogen and phosphorus
    • D06M13/447—Phosphonates or phosphinates containing nitrogen atoms
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/60—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing polyethers
    • D06P1/613—Polyethers without nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/673—Inorganic compounds
    • D06P1/67333—Salts or hydroxides
    • D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
    • D06P3/02—Material containing basic nitrogen
    • D06P3/04—Material containing basic nitrogen containing amide groups
    • D06P3/14—Wool
    • D06P3/148—Wool using reactive dyes
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02—Natural fibres, other than mineral fibres
    • D06M2101/10—Animal fibres
    • D06M2101/12—Keratin fibres or silk
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/30—Flame or heat resistance, fire retardancy properties

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Coloring (AREA)

Abstract

本发明公开了一种羊毛西服面料的染色阻燃整理方法，包括染色和阻燃整理两步骤，染色采用活性染料，阻燃整理的活性成分为β‑(N‑苯基酰胺)乙基甲基次膦酸。该羊毛西服面料的染色阻燃整理方法采用活性染料染色，并且采用含氮磷的具有反应活性的β‑(N‑苯基酰胺)乙基甲基次膦酸作为阻燃整理剂的活性成分，阻燃活性成分与羊毛分子链发生交联，所得羊毛西服面料具有类似半永久的阻燃效果，染色色深K/S值下降不超过15%。

Description

一种羊毛西服面料的染色阻燃整理方法
技术领域
本发明涉及面料制造技术领域，具体涉及一种羊毛西服面料的染色阻燃整理方法。
背景技术
羊毛的阻燃整理按照阻燃功效持续时间分为非永久性、半永久性和永久性三种。非永久性阻燃整理不耐水洗、如羊毛经正磷酸等无机酸或者氨基磺酸等有机酸溶液浸渍烘干后能暂时阻燃，水洗后失效；半永久性阻燃整理可耐五次左右洗涤，或在特定条件下耐多次洗涤，永久阻燃整理耐洗涤次数更多，现有技术中的半永久性和永久性阻燃整理例如氨基磺酸和尿素轧烘焙、四羟基甲基氯化磷与尿素或者三聚氰胺混合轧烘焙。改进的羊毛西服面料的阻燃整理剂中，多采用氧化物溶胶如氧化锌、氧化锡、硅溶胶等，或者采用传统的含卤阻燃剂，羊毛西服面料的纤维中鳞片呈龟裂状，溶胶整理得到的面料耐洗性较差，而含卤阻燃剂整理的面料安全性不足，对于永久半永久整理剂在纤维表面的附着力差。另外，阻燃整理还会明显降低染色的深度，影响布面强力。
发明内容
本发明的目的在于克服现有技术中存在的缺陷，提供一种羊毛西服面料的染色阻燃整理方法，经上述染色和阻燃整理的面料色深下降幅度较小，具有良好的阻燃性能。
为实现上述目的，本发明的技术方案为：一种羊毛西服面料的染色阻燃整理方法，其特征在于，包括以下步骤：
S1：将羊毛西服面料置于由活性染料、元明粉、非离子表面活性剂和聚氧乙烯醚硫酸铵、酸性pH值调节剂和水组成的染液中，所述染液的pH值为4.5～5.5，所述染液的入染温度为45～50℃，染液升温至90℃并保温70～90min，取出羊毛西服面料，清洗烘干；
S2：将β-(N-苯基酰胺)乙基甲基次膦酸、润湿剂和水混合制成阻燃浸轧液，将S1所得羊毛西服面料置于所述阻燃浸轧液中至少两次浸轧处理，经预烘、焙烘，水洗晾干，得到具有阻燃功能的染色羊毛西服面料。
优选的技术方案为，所述羊毛西服面料在染液中的升温速率为1～1.5℃/min，所述羊毛西服面料与所述染液的浴比为1：（40～50）。
优选的技术方案为，所述活性染料为LANASOL系列活性染料，所述染液中活性染料的含量为1.5～3%（o.w.f.），所述非离子表面活性剂的含量为0.5～2%（o.w.f.），聚氧乙烯醚硫酸铵的含量为5～8%（o.w.f.）。
优选的技术方案为，阻燃浸轧液的pH值为5.5～6.2，所述阻燃浸轧液中β-(N-苯基酰胺)乙基甲基次膦酸的含量为5～11g/L。
本发明的优点和有益效果在于：
该羊毛西服面料的染色阻燃整理方法采用活性染料染色，并且采用含氮磷的具有反应活性的β-(N-苯基酰胺)乙基甲基次膦酸作为阻燃整理剂的活性成分，阻燃活性成分与羊毛分子链发生交联，所得羊毛西服面料具有类似半永久的阻燃效果，染色色深K/S值下降不超过15%。
具体实施方式
下面结合实施例，对本发明的具体实施方式作进一步描述。以下实施例仅用于更加清楚地说明本发明的技术方案，而不能以此来限制本发明的保护范围。
实施例1
实施例1 羊毛西服面料的染色阻燃整理方法包括以下步骤：
S1：将羊毛西服面料置于由活性染料、元明粉、非离子表面活性剂和聚氧乙烯醚硫酸铵、酸性pH值调节剂和水组成的染液中，染液的pH值为4.5，染液的入染温度为50℃，染液升温至90℃并保温7min，取出羊毛西服面料，清洗烘干；
S2：将β-(N-苯基酰胺)乙基甲基次膦酸、润湿剂和水混合制成阻燃浸轧液，将S1所得羊毛西服面料置于阻燃浸轧液中至少两次浸轧处理，经预烘、焙烘，水洗晾干，得到具有阻燃功能的染色羊毛西服面料。
羊毛西服面料在染液中的升温速率为1.5℃/min，羊毛西服面料与染液的浴比为1：40。
活性染料为LANASOL蓝，染液中活性染料的含量为3%（o.w.f.），非离子表面活性剂的含量为0.5%（o.w.f.），聚氧乙烯醚硫酸铵的含量为8%（o.w.f.）。
阻燃浸轧液的pH值为5.5，阻燃浸轧液中β-(N-苯基酰胺)乙基甲基次膦酸的含量为11g/L。
实施例2
实施例2基于实施例1，区别在于：染液的pH值为5.5，染液的入染温度为45℃，染液升温至90℃并保温90min，取出羊毛西服面料，清洗烘干；
羊毛西服面料在染液中的升温速率为1℃/min，羊毛西服面料与染液的浴比为1：50。
染液中活性染料的含量为1.5%（o.w.f.），非离子表面活性剂的含量为2%（o.w.f.），聚氧乙烯醚硫酸铵的含量为5%（o.w.f.）。
阻燃浸轧液的pH值为6.2，阻燃浸轧液中β-(N-苯基酰胺)乙基甲基次膦酸的含量为5g/L。
实施例3
实施例3基于实施例1，区别在于，羊毛西服面料在染液中的升温速率为1.25℃/min，羊毛西服面料与染液的浴比为1：45。
染液中活性染料的含量为2%（o.w.f.），非离子表面活性剂的含量为1.2%（o.w.f.），聚氧乙烯醚硫酸铵的含量为6%（o.w.f.）。
阻燃浸轧液的pH值为5.8，阻燃浸轧液中β-(N-苯基酰胺)乙基甲基次膦酸的含量为8g/L。
对比例
对比例1为经实施例1染色步骤得到的羊毛西服面料；
对比例2为经实施例2染色步骤得到的羊毛西服面料；
对比例3为经实施例3染色步骤得到的羊毛西服面料；
与相应的对比例相比，经垂直燃烧试验验证，实施例所得羊毛西服面料的阻燃级别LOI分别为21.8%、24.2%、26.1%。
采用D65光源和10°视角，测定织物的色度参数L*、a、b和C*，与相应的对比例相比，羊毛西服面料的表观染色深度下降幅度分别为5.87%、8.35%、12.69%。
以上所述仅是本发明的优选实施方式，应当指出，对于本技术领域的普通技术人员来说，在不脱离本发明技术原理的前提下，还可以做出若干改进和润饰，这些改进和润饰也应视为本发明的保护范围。

Claims (4)

1.一种羊毛西服面料的染色阻燃整理方法，其特征在于，包括以下步骤：
S1：将羊毛西服面料置于由活性染料、元明粉、非离子表面活性剂和聚氧乙烯醚硫酸铵、酸性pH值调节剂和水组成的染液中，所述染液的pH值为4.5～5.5，所述染液的入染温度为45～50℃，染液升温至90℃并保温70～90min，取出羊毛西服面料，清洗烘干；
S2：将β-(N-苯基酰胺)乙基甲基次膦酸、润湿剂和水混合制成阻燃浸轧液，将S1所得羊毛西服面料置于所述阻燃浸轧液中至少两次浸轧处理，经预烘、焙烘，水洗晾干，得到具有阻燃功能的染色羊毛西服面料。
2.根据权利要求1所述的羊毛西服面料的染色阻燃整理方法，其特征在于，所述羊毛西服面料在染液中的升温速率为1～1.5℃/min，所述羊毛西服面料与所述染液的浴比为1：（40～50）。
3.根据权利要求2所述的羊毛西服面料的染色阻燃整理方法，其特征在于，所述活性染料为LANASOL系列活性染料，所述染液中活性染料的含量为1.5～3%（o.w.f.），所述非离子表面活性剂的含量为0.5～2%（o.w.f.），聚氧乙烯醚硫酸铵的含量为5～8%（o.w.f.）。
4.根据权利要求1所述的羊毛西服面料的染色阻燃整理方法，其特征在于，阻燃浸轧液的pH值为5.5～6.2，所述阻燃浸轧液中β-(N-苯基酰胺)乙基甲基次膦酸的含量为5～11g/L。
CN201910869340.0A 2019-09-16 2019-09-16 一种羊毛西服面料的染色阻燃整理方法 Pending CN110512440A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910869340.0A CN110512440A (zh) 2019-09-16 2019-09-16 一种羊毛西服面料的染色阻燃整理方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910869340.0A CN110512440A (zh) 2019-09-16 2019-09-16 一种羊毛西服面料的染色阻燃整理方法

Publications (1)

Publication Number Publication Date
CN110512440A true CN110512440A (zh) 2019-11-29

Family

ID=68632322

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910869340.0A Pending CN110512440A (zh) 2019-09-16 2019-09-16 一种羊毛西服面料的染色阻燃整理方法

Country Status (1)

Country Link
CN (1) CN110512440A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112921676A (zh) * 2021-01-29 2021-06-08 太仓市尤赫普染整有限公司 一种阻燃线的染色工艺流程

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105544243A (zh) * 2015-12-30 2016-05-04 江阴市长泾花园毛纺织有限公司 一种羊毛面料的活性染料低温染色方法
CN106283657A (zh) * 2016-08-19 2017-01-04 常熟市大正纺织制版有限公司 羊毛针织面料的后整理工艺

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105544243A (zh) * 2015-12-30 2016-05-04 江阴市长泾花园毛纺织有限公司 一种羊毛面料的活性染料低温染色方法
CN106283657A (zh) * 2016-08-19 2017-01-04 常熟市大正纺织制版有限公司 羊毛针织面料的后整理工艺

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
孙山等: ""新型反应型磷-氮阻燃剂的合成与应用"", 《中国塑料》 *
睢成琳等: ""DDPSi-FR阻燃整理对羊毛织物染色性能的影响"", 《现代纺织技术》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112921676A (zh) * 2021-01-29 2021-06-08 太仓市尤赫普染整有限公司 一种阻燃线的染色工艺流程
CN112921676B (zh) * 2021-01-29 2023-05-26 太仓市尤赫普染整有限公司 一种阻燃线的染色工艺流程

Similar Documents

Publication Publication Date Title
US20060030228A1 (en) High-visibility, flame resistant fabrics and methods for making same
CN101855318B (zh) 方法和组合物
LT3627B (en) Method for processing which giv the fire endurance for ground
CN104975497A (zh) 一种阻燃剂及其制备方法与应用
CN102465452A (zh) 纤维素织物的阻燃整理方法及得到的织物
CN106192423A (zh) 一种阻燃拒油水抗静电织物的制备方法及静电织物
CN102851953A (zh) 一种纤维织物阻燃剂
CN110512440A (zh) 一种羊毛西服面料的染色阻燃整理方法
CN101381958A (zh) 一种阻燃整理材料及用这种材料整理织物的方法
CN107435199A (zh) 一种轻丝光染色工艺
CN105862389A (zh) 一种阻燃腈纶的制备方法
JP5975521B2 (ja) 酸性染料組成物及びそれを用いる染色法
CN109056320A (zh) 一种基于棉织物的阻燃疏水整理方法
CN104995246A (zh) 无甲醛阻燃组合物及其用于制造耐洗的无甲醛阻燃纤维素材料的用途
US10662580B1 (en) Method for dyeing modacrylic/cellulosic blend fabrics
CN109680483A (zh) 一种耐洗、抗菌、阻燃面料的制备工艺
CN104264461A (zh) 一种阻燃感光变色蚕丝织物的制备方法
CN101845745A (zh) 高吸湿和阻燃多重功能改性腈纶的制造方法
CN101845749B (zh) 阻燃改性腈纶的制造方法
CN107780202A (zh) 一种迷彩面料的印染工艺
RU2212481C1 (ru) Состав для огнезащитной отделки целлюлозосодержащих текстильных материалов
CN101851857B (zh) 腈纶纱线、腈纶绒线或腈纶毛线阻燃改性的制造方法
CN109267349A (zh) 一种顺毛呢大衣面料的阻燃处理工艺
CN108914562A (zh) 一种阻燃锦纶面料的制备方法
CN108951095A (zh) 一种阻燃型功能面料的染色工艺

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20191129