CN110302114A

CN110302114A - A kind of shampoo and preparation method thereof containing tea-seed oil and tea seed extract

Info

Publication number: CN110302114A
Application number: CN201910728365.9A
Authority: CN
Inventors: 张绍良
Original assignee: HINGLONG HI-TECH Co Ltd
Current assignee: HINGLONG HI-TECH Co Ltd
Priority date: 2019-08-08
Filing date: 2019-08-08
Publication date: 2019-10-08

Abstract

The invention belongs to hair shampoo article technical fields, more particularly to a kind of shampoo and preparation method thereof containing tea-seed oil and tea seed extract, by weight, the shampoo includes at least following components: 0.5~1 part of conditioner for hair, 8~16 parts of skin conditioning agent, 8~20 parts of laurel based surfactants, 3~6 parts of nonionic surfactant, 5~10 parts of anionic surfactant, 2~7 parts of emulsifier, 0.3~0.5 part of antioxidant, 0.1~0.3 part of preservative, 0.2~0.7 part of chelating agent, 0.1~0.3 part of essence, 1~3 part of auxiliary agent, 45~55 parts of deionized water.Shampoo in the application can repair damaged hair, make the submissive more gloss, while anti-inflammatory anti-dandruff and itching-relieving of hair moisturizing with rapid osmotic into skin histology.

Description

A kind of shampoo and preparation method thereof containing tea-seed oil and tea seed extract

Technical field

The invention belongs to hair shampoo article technical fields, and in particular to a kind of shampoo containing tea-seed oil and tea seed extract and Preparation method.

Background technique

Shampoo is the hair being most widely used and scalp basic nursing cosmetic product, and being must not in people's daily life One of the daily necessity that can lack.Hair shampoo article numerous and complicated on the market at present, ingredient are rarer mostly based on chemical substance Natural component, although having stronger cleaning effect, long-time service can make the excessive degreasing of scalp, cause skin surface it is dry, Root of hair itch, inflammation keep hair quality impaired.

With the improvement of living standards, people increasingly pay attention to the application of green product, especially daily washing product.Cause This, research and develop it is a kind of containing green matter and meanwhile have preferably wash shield effect shampoo it is particularly significant.

Summary of the invention

In order to solve the above-mentioned technical problems, the present invention provides a kind of shampoo containing tea-seed oil and tea seed extract, is pressed Parts by weight meter includes at least following components: 0.5~1 part of conditioner for hair, 8~16 parts of skin conditioning agent, lauryl surface-active It is 8~20 parts of agent, 3~6 parts of nonionic surfactant, 5~10 parts of anionic surfactant, 2~7 parts of emulsifier, anti-oxidant 0.3~0.5 part of agent, 0.1~0.3 part of preservative, 0.2~0.7 part of chelating agent, 0.1~0.3 part of essence, 1~3 part of auxiliary agent, go from 45~55 parts of sub- water.

Further, the conditioner for hair in Polyquaternium-10, polyquaternium -43, polyquaternium -49 one Kind is a variety of.

Further, the skin conditioning agent is selected from one of plant extracts, vegetable fat, ethylhexyl palmitate Or it is a variety of.

Further, the plant extracts is selected from tea seed extract, grape seed extract, Folium clausenae lansii extract, wood One or more of rose of Sharon leaf extract.

Further, the vegetable fat is selected from one or more of tea-seed oil, grape seed oil, white pond flower seed oil.

Further, the laurel based surfactants are selected from laureth sodium sulfovinate, sodium lauroyl glutamate, the moon One or more of osmanthus acyl both sexes guanidine-acetic acid sodium, lauroyl dilactic acid sodium.

Further, the antioxidant is selected from pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate), two tertiary fourths One or more of base paracresol, dibutyl hydroxy toluene.

Further, the preservative is selected from methylchloroisothiazandnone, methylisothiazolinone, magnesium chloride, magnesium nitrate One or more of.

Further, the auxiliary agent is selected from one or more of citric acid, sodium chloride, double glycol stearates.

The present invention also provides the preparation methods of above-mentioned shampoo, it is at least included the following steps:

(1) deionized water and conditioner for hair are added in main cooker, it is even equal that heating stirring disperses it, and laurel base table is added Face activating agent stirs to after being completely dissolved, sequentially adds nonionic surfactant, anionic surfactant, chelating agent, stir It mixes and is uniformly dissolved；

(2) antioxidant and emulsifier are mixed in advance, heating is completely dissolved antioxidant, and it is described that step (1) is added It is lasting to stir in main cooker；

(3) stop heating, carry out homogeneous after skin conditioning agent is added into step (1) described main cooker；Add after homogeneous Enter auxiliary agent, continues to stir；

(4) preservative, essence are added after cooling down, stirs evenly, through after the assay was approved, discharging filling.

The beneficial effects of the present invention are: provide a kind of shampoo containing tea-seed oil and tea seed extract, the shampoo In effective component can repair damaged hair with rapid osmotic into skin histology, make the submissive more gloss of hair moisturizing, simultaneously Anti-inflammatory anti-dandruff and itching-relieving.

Specific embodiment

In conjunction with preferred implementation method of the invention below detailed description and including embodiment can be further understood that this hair Bright content.Unless otherwise indicated, all technologies used herein and scientific term all have general with the application fields Logical technical staff's is generally understood identical meaning.If mentioned in the definition and the application of the concrete term disclosed in the prior art Any definition supplied is inconsistent, then term provided herein of being subject to defines.

It is used in the present context, unless being clearly dictated in context, otherwise without the spy of the single plural form of restriction Sign is also intended to the feature including plural form.It will also be appreciated that term as used herein " by ... preparation " it is synonymous with "comprising", " comprising ", " including ", " having ", "comprising" and/or " including " indicate stated group when used in this manual Object, step, method, product or device are closed, but does not preclude the presence or addition of one or more of the other composition, step, method, system Product or device.In addition, using " preferred ", " preferably ", " preferred " etc. to be when describing presently filed embodiment Refer to, can provide the embodiment of the present invention of certain beneficial effects in some cases.However, under identical circumstances or other feelings Under condition, other embodiments are also likely to be preferred.In addition to this, not dark to the statement of one or more preferred embodiments Show that other embodiments are unavailable, is also not intended to exclude other embodiments except the scope of the present invention.

In order to solve the above technical problems, the present invention provides a kind of shampoo containing tea-seed oil and Tea Saponin, by weight Meter, including at least following components: 0.5~1 part of conditioner for hair, 8~16 parts of skin conditioning agent, laurel based surfactants 8~ 20 parts, 3~6 parts of nonionic surfactant, 5~10 parts of anionic surfactant, 2~7 parts of emulsifier, antioxidant 0.3 ~0.5 part, 0.1~0.3 part of preservative, 0.2~0.7 part of chelating agent, 0.1~0.3 part of essence, 1~3 part of auxiliary agent, deionized water 45~55 parts.

Conditioner for hair

Conditioner for hair mainly includes grease type, change and class, plain ammonium salt class, protein-based and type siloxane etc., according to it Respective characteristic and effect can be used for different types of hair cosmetic.

In some preferred embodiments, the conditioner for hair is selected from Polyquaternium-10, polyquaternium -43, poly- season One or more of ammonium salt -49.

It is further preferred that the conditioner for hair is polyquaternium -49.

Still more preferably, the polyquaternium -49 in the embodiment of the present application, purchased from the development of Shanghai Ou Rong biotechnology The heart, the entitled RY SCB of the trade mark.

Skin conditioning agent

Skin conditioning agent, refer to it is readily permeable enter skin, the ingredient that can be repaired, be improved to skin, effect can be with Be whitening, it is crease-resistant, go red capillary, prevent allergy, improve skin resistance etc..

In some preferred embodiments, the skin conditioning agent is selected from plant extracts, vegetable fat, palmitinic acid second One or more of own ester of base.

It is further preferred that the plant extracts be selected from tea seed extract, grape seed extract, Folium clausenae lansii extract, One or more of rose of Sharon leaf extract.

It is further preferred that the vegetable fat is selected from one of tea-seed oil, grape seed oil, white pond flower seed oil or more Kind.

Still more preferably, the tea seed extract, tea-seed oil, ethylhexyl palmitate weight ratio be (1~3): (4~6): 1.

Still more preferably, the tea seed extract, tea-seed oil, ethylhexyl palmitate weight ratio be 2:5:1.

In some preferred embodiments, the tea-seed oil the preparation method comprises the following steps:

Except the tea seed kernel of shell drying must squeeze crude oil after squeezer is fuel-displaced, freezing degreasing obtains institute after filtering removal impurity State tea-seed oil.

It is further preferred that the tea-seed oil the preparation method comprises the following steps:

It will be sent into twin-screw oil mill except the tea seed kernel of shell drying at 20~30 DEG C, controls oil extruder bore temperature 50 It is squeezed under conditions of~60 DEG C fuel-displaced；After gained squeezing crude oil is removed by filtration part filter residue, under 9~10 DEG C of low temperature successively Multi-filtering is carried out by filter paper；Filtered oil pump is entered into maturator, is cooled to 0~2 DEG C, keeps standing 12~16h progress Crystallization, growing the grain, a small amount of glyceride of precipitation is finally filtered under 9~10 DEG C of low temperature, obtains the tea-seed oil.

Most preferably, the tea seed extract in the embodiment of the present application is our company oneself production, the entitled Tea Saponin of the trade mark；This Apply the tea-seed oil in embodiment for our company oneself production, the entitled tea oil of the trade mark；Palm acid ethyl in the embodiment of the present application Own ester is purchased from upper marine Dehua work Co., Ltd, the entitled 2EHP of the trade mark.

Tea-seed oil in the embodiment of the present application containing organic acid, vitamin A. D. E abundant and squalene, flavones etc. effectively Ingredient can be absorbed by hair and skin, and nutrition needed for supply is metabolized promotes cell repair, prevented the withered fracture of hair, made it It is more glossy, submissive, and have the effects that permanent moisturizing.However most of effective component is to the infiltration inside skin in tea-seed oil Thoroughly and absorbed speed is slower, and due to part of effective component, its activity is very strong, may be also not by human skin cell It absorbs just by external environmental disruption structure, loses effect, cause effect that there is biggish difference, effect is unstable.

Tea seed extract in the embodiment of the present application contains the effective ingredients such as tocopherol, squalene, sterol, helps to inhibit The expression of inflammatory factor in skin histology improves the symptom of pruitus, raw bits,；But effective component is multiple in tea seed extract It is miscellaneous, and its activity needs being excited slowly, and short time inner skin state does not have apparent change；Especially to some oil Property skin be easy to cause pore to be blocked by grease since secretion of the sebaceous glands to grease is very fast, influences effective component in skin The infiltration in portion, or even under the action of between all kinds of lubricant components, the effective component in tea seed extract can may be blocked also Pore causes hair follicle inflammation instead.

Ethylhexyl palmitate property in the embodiment of the present application is stablized, not oxidizable or generation peculiar smell, and molecular weight is small, Easily penetrate into and clean grease in pore, cleaning effect is good, but simultaneously because ethylhexyl palmitate easy permeability, may lead Keratoderma disease is caused, dry scalp is made to generate the scales of skin that peel off.

The applicant has been surprisingly found that is added a certain amount of tea-seed oil, tea seed extract and palm acid ethyl in shampoo Own ester can largely improve damaged hair, make the submissive more gloss of hair moisturizing, moreover it is possible to anti-inflammatory anti-dandruff and itching-relieving；And And when the weight ratio of tea seed extract, tea-seed oil, ethylhexyl palmitate be 2:5:1 when, reach wash shield effect it is optimal.It may The reason of be: under the synergistic effect of aforementioned proportion component, ethylhexyl palmitate Peppermint Extract removes the grease of clogging of pores Equal ingredients, improve the infiltration of tea-seed oil and tea seed extract isoreactivity ingredient.And due to the synergistic effect between each component Under, the dispersibility and spreadability of shampoo significantly improve, and each active constituent preferably parent can invest hair and scalp group in system It knits, it is easier to be absorbed.

Surfactant

Surfactant, which refers to, is added the substance that significant change occurs for the interface state that can make its solution system on a small quantity.Have Fixed hydrophilic lipophilic group can align on the surface of solution；Surfactant range is very extensive, mentions for concrete application For multiple functions, including foaming effect, surface is modified, cleaning, lotion etc..

Surfactant in the application is divided into laurel based surfactants, nonionic surfactant, anionic surface Activating agent.

In some preferred embodiments, the laurel based surfactants are selected from laureth sodium sulfovinate, the moon One or more of osmanthus acyl sodium glutamate, Sodium Lauroamphoacetate, lauroyl dilactic acid sodium.

It is further preferred that the laurel based surfactants by laureth sodium sulfovinate, sodium lauroyl glutamate, Sodium Lauroamphoacetate, lauroyl dilactic acid sodium composition.

In some preferred embodiments, the nonionic surfactant is selected from coconut oleoyl amine methyl MEA, polyglycereol One or more of caprylate, coconut acid diethanolamide.

It is further preferred that the nonionic surfactant is coconut oleoyl amine methyl MEA.

In some preferred embodiments, the anionic surfactant is selected from sodium lauroyl sarcosine, dodecane One or more of three ethyl alcohol of base sulfuric acid, cocoyl sarcosine.

It is further preferred that the anionic surfactant is sodium lauroyl sarcosine.

Most preferably, by laureth sodium sulfovinate, sodium lauroyl glutamate, lauroyl both sexes in the embodiment of the present application The laurel based surfactants that guanidine-acetic acid sodium, lauroyl dilactic acid sodium form are purchased from Shanghai Ou Rong biotechnology centre of development, The entitled HM 60 of the trade mark；Coconut oleoyl amine methyl MEA in the embodiment of the present application is purchased from the prosperous Industrial Co., Ltd. of Shanghai Rui, trade mark name For CMMEA；Sodium lauroyl sarcosine in the embodiment of the present application is purchased from Shanghai Bo Shuo cause Co., Ltd, the entitled LS-30 of the trade mark.

Emulsifier

Emulsifier contains two kinds of groups of hydrophilic group and lipophilic group in molecule simultaneously, can be in regulation system between each phase Surface tension, allows that multiphase is evenly dispersed and character is stablized.

In some preferred embodiments, the emulsifier is selected from cetostearyl alcohol, glyceryl oleate, -3 rouge of polyglycereol One of fat acid esters is several.

It is further preferred that the emulsifier is cetostearyl alcohol.

Most preferably, the cetostearyl alcohol in the embodiment of the present application is purchased from Shanghai Yi Chuan chemistry Science and Technology Ltd., the trade mark For 16/18ol.

Antioxidant

Antioxidants Antioxidants are to prevent the dysgenic substance of oxygen.It is that one kind can help to capture and neutralize freedom Base, to dispel the substance that free radical damages human body.

In some preferred embodiments, the antioxidant is selected from the (double-tert-butyl hydroxy hydrogenation meat of pentaerythrite four Cinnamic acid) ester, di-tert-butyl p-cresol, one or more of dibutyl hydroxy toluene.

It is further preferred that the antioxidant is pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate).

Most preferably, the pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate) in the embodiment of the present application is purchased from upper Auspicious industry development Co., Ltd, Taiwan Strait Exchange Association, the entitled TT of the trade mark.

Preservative

In order to guarantee that shampoo undergoes no deterioration in validity period, preservative is wherein essential ingredient.

In some preferred embodiments, the preservative be selected from methylchloroisothiazandnone, methylisothiazolinone, One or more of magnesium chloride, magnesium nitrate.

It is further preferred that the preservative is by methylchloroisothiazandnone, methylisothiazolinone, magnesium chloride, nitric acid Magnesium composition.

Still more preferably, in the embodiment of the present application by methylchloroisothiazandnone, methylisothiazolinone, chlorination The preservative that magnesium, magnesium nitrate form does a Chemical Company, the entitled CM of the trade mark purchased from Shanghai.

Chelating agent

Metallic atom or ion are acted on the ligand containing two or more coordination atoms, and generating has cyclic annular knot The complex compound of structure, the complex compound are called chelate；This ligand substance of chelate can be generated chelating agent, be also referred to as complexed Agent；Most of chelating agent is organic ligand.

In some preferred embodiments, the chelating agent is selected from EDETATE SODIUM, disodium ethylene diamine tetraacetate, glucoheptose One or more of sour sodium.

It is further preferred that the chelating agent is EDETATE SODIUM.

Most preferably, the EDETATE SODIUM in the embodiment of the present application (CAS 139-33-3), it is limited purchased from the rich bright industry in Shanghai Company.

Essence

Though essence dosage in washing product is few, but indispensable important source material.Fragrance and essence are washing shield use Main function is to generate pleasant smell in product, covers the smell of product matrix.

In some preferred embodiments, the essence is selected from one of flavoring rose essence, tree peony essence, pear flower essence Or it is a variety of.

It is further preferred that the essence is selected from tree peony essence.

Most preferably, the tree peony essence in the embodiment of the present application is purchased from Shanghai Bo Shuo Industrial Co., Ltd., and the trade mark is entitled RH028371。

Auxiliary agent

Auxiliary agent in the application is mainly used to the pH value and viscosity of regulation system.

In some preferred embodiments, the auxiliary agent is in citric acid, sodium chloride, double glycol stearates It is one or more kinds of.

It is further preferred that the auxiliary agent is citric acid and sodium chloride.

Still more preferably, the citric acid, sodium chloride weight ratio be 1:(5~8).

Most preferably, the citric acid in the embodiment of the present application (CAS 77-92-9), sodium chloride (CAS 7647-14-5) It is purchased from Shanghai Yi Chuan chemistry Science and Technology Ltd..

The preparation method of the shampoo containing tea-seed oil and tea seed extract, comprising the following steps:

(1) deionized water and polyquaternium -49 are added in main cooker, being heated to 60~80 DEG C of stirrings makes it be uniformly dispersed, Laureth sodium sulfovinate, sodium lauroyl glutamate, Sodium Lauroamphoacetate, lauroyl dilactic acid sodium is added, stirs It mixes to after being completely dissolved, sequentially adds coconut oleoyl amine methyl MEA, sodium lauroyl sarcosine, EDETATE SODIUM, stirring and dissolving is uniform；

(2) pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate) and cetostearyl alcohol are mixed in advance, is heated to After 85~95 DEG C are completely dissolved pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate), step (1) described main cooker is added In, it is lasting to stir；

(3) stop heating, after tea seed extract, tea-seed oil, ethylhexyl palmitate is added into step (1) described main cooker Carry out 3~7min of homogeneous；Citric acid, sodium chloride are added after homogeneous, continues to stir；

(4) preservative, essence are added after being cooled to 30~50 DEG C, stirs evenly, through after the assay was approved, discharging filling.

Embodiment

Technical solution of the present invention is described in detail by the following examples, but protection scope of the present invention is not limited to In the embodiment.Raw material use herein is unless otherwise specified commercially available.

Embodiment 1

Embodiment 1 provides a kind of shampoo containing tea-seed oil and tea seed extract, by weight, including with the following group Point: 0.8 part of conditioner for hair, 12 parts of skin conditioning agent, 14 parts of laurel based surfactants, 5 parts of nonionic surfactant, yin 8 parts of ionic surface active agent, 5 parts of emulsifier, 0.4 part of antioxidant, 0.2 part of preservative, 0.4 part of chelating agent, 0.2 part of essence, 2 parts of auxiliary agent, 50 parts of deionized water.

The conditioner for hair is polyquaternium -49, is purchased from Shanghai Ou Rong biotechnology centre of development, the entitled RY of the trade mark SCB。

The skin conditioning agent is made of tea seed extract, tea-seed oil, ethylhexyl palmitate.

The tea seed extract, tea-seed oil, ethylhexyl palmitate weight ratio be 2:5:1.

The tea-seed oil the preparation method comprises the following steps:

It will be sent into twin-screw oil mill except the tea seed kernel of shell drying at 25 DEG C, controls oil extruder bore temperature at 55 DEG C Under the conditions of squeeze it is fuel-displaced；After gained squeezing crude oil is removed by filtration part filter residue, filter paper progress is passed sequentially through under 9 DEG C of low temperature Multi-filtering；Filtered oil pump is entered into maturator, is cooled to 1 DEG C, keeps standing 14h to be crystallized, growing the grain, finally at 9 DEG C A small amount of glyceride that precipitation is filtered under low temperature, obtains the tea-seed oil.

The tea seed extract, tea-seed oil are our company oneself production, and trade mark name is respectively Tea Saponin, tea oil；It is described Ethylhexyl palmitate is purchased from upper marine Dehua work Co., Ltd, the entitled 2EHP of the trade mark.

The laurel based surfactants are by laureth sodium sulfovinate, sodium lauroyl glutamate, lauroyl both sexes base Sodium acetate, lauroyl dilactic acid sodium composition.

The laurel based surfactants are purchased from Shanghai Ou Rong biotechnology centre of development, the entitled HM 60 of the trade mark.

The nonionic surfactant is coconut oleoyl amine methyl MEA, is purchased from the prosperous Industrial Co., Ltd. of Shanghai Rui, trade mark name For CMMEA.

The anionic surfactant is sodium lauroyl sarcosine, is purchased from Shanghai Bo Shuo cause Co., Ltd, trade mark name For LS-30.

The emulsifier is cetostearyl alcohol, is purchased from Shanghai Yi Chuan chemistry Science and Technology Ltd., trade mark 16/18ol.

The antioxidant is pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate), is purchased from the auspicious industry of upper Taiwan Strait Exchange Association Development Co., Ltd, the entitled TT of the trade mark.

The preservative is made of methylchloroisothiazandnone, methylisothiazolinone, magnesium chloride, magnesium nitrate, purchased from upper Hai Ganyi Chemical Company, the entitled CM of the trade mark.

The chelating agent is EDETATE SODIUM (CAS 139-33-3), is purchased from Shanghai Bo Shuo Industrial Co., Ltd..

The essence is tree peony essence, is purchased from Shanghai Bo Shuo Industrial Co., Ltd., the entitled RH028371 of the trade mark.

The auxiliary agent is citric acid and sodium chloride.

The citric acid, sodium chloride mass ratio be 1:6.

The citric acid (CAS 77-92-9), sodium chloride (CAS 7647-14-5) are purchased from Shanghai Yi Chuan chemistry science and technology Co., Ltd.

(1) deionized water and polyquaternium -49 are added in main cooker, being heated to 75 DEG C of stirrings makes it be uniformly dispersed, and is added Laureth sodium sulfovinate, sodium lauroyl glutamate, Sodium Lauroamphoacetate, lauroyl dilactic acid sodium, stirring is extremely After being completely dissolved, coconut oleoyl amine methyl MEA, sodium lauroyl sarcosine, EDETATE SODIUM are sequentially added, stirring and dissolving is uniform；

(2) pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate) and cetostearyl alcohol are mixed in advance, is heated to After 90 DEG C are completely dissolved pentaerythritol tetra (di-tert-butyl hydroxy hydrocinnamate), it is added in step (1) described main cooker, Lasting stirring；

(3) stop heating, after tea seed extract, tea-seed oil, ethylhexyl palmitate is added into step (1) described main cooker Carry out homogeneous 5min；Citric acid, sodium chloride are added after homogeneous, continues to stir；

(4) preservative, essence are added after being cooled to 40 DEG C, stirs evenly, through after the assay was approved, discharging filling.

Embodiment 2

Embodiment 2 provides a kind of shampoo containing tea-seed oil and tea seed extract, and difference from Example 1 is, 0.5 part of conditioner for hair, 8 parts of skin conditioning agent, 8 parts of laurel based surfactants, nonionic surfactant 3 in the component Part, 5 parts of anionic surfactant, 2 parts of emulsifier, 0.3 part of antioxidant, 0.1 part of preservative, 0.2 part of chelating agent, essence 0.1 part, 1 part of auxiliary agent, 45 parts of deionized water.

This example additionally provides a kind of preparation method of shampoo containing tea-seed oil and tea seed extract, step and embodiment 1 is identical.

Embodiment 3

Embodiment 3 provides a kind of shampoo containing tea-seed oil and tea seed extract, and difference from Example 1 is, 1 part of conditioner for hair, 16 parts of skin conditioning agent, 20 parts of laurel based surfactants, nonionic surfactant 6 in the component Part, 10 parts of anionic surfactant, 7 parts of emulsifier, 0.5 part of antioxidant, 0.3 part of preservative, 0.7 part of chelating agent, essence 0.3 part, 3 parts of auxiliary agent, 55 parts of deionized water.

Embodiment 4

Embodiment 4 provides a kind of shampoo containing tea-seed oil and tea seed extract, and difference from Example 1 is, Tea-seed oil is free of in the skin conditioning agent.

Embodiment 5

Embodiment 5 provides a kind of shampoo containing tea-seed oil and tea seed extract, and difference from Example 1 is, Tea seed extract is free of in the skin conditioning agent.

Embodiment 6

Embodiment 6 provides a kind of shampoo containing tea-seed oil and tea seed extract, and difference from Example 1 is, Ethylhexyl palmitate is free of in the skin conditioning agent.

Embodiment 7

Embodiment 7 provides a kind of shampoo containing tea-seed oil and tea seed extract, and difference from Example 1 is, Tea-seed oil, tea seed extract are free of in the skin conditioning agent.

Embodiment 8

Embodiment 8 provides a kind of shampoo containing tea-seed oil and tea seed extract, and difference from Example 1 is, The tea seed extract, tea-seed oil, ethylhexyl palmitate weight ratio be 10:5:1.

Embodiment 9

Embodiment 9 provides a kind of shampoo containing tea-seed oil and tea seed extract, and difference from Example 1 is, The tea seed extract, tea-seed oil, ethylhexyl palmitate weight ratio be 2:10:1.

Embodiment 10

Embodiment 10 provides a kind of shampoo containing tea-seed oil and tea seed extract, and difference from Example 1 is, The tea seed extract, tea-seed oil, ethylhexyl palmitate weight ratio be 2:5:10.

Embodiment 11

Embodiment 11 provides a kind of shampoo containing tea-seed oil and tea seed extract, and difference from Example 1 is, The tea-seed oil is purchased from the permanent really natural perfume material oil Co., Ltd in Jiangxi, the entitled HCXL4006 of the trade mark.

Embodiment 12

Embodiment 12 provides a kind of shampoo containing tea-seed oil and tea seed extract, and difference from Example 1 is, The tea seed extract is purchased from Yang Lingci edge Bioisystech Co., Ltd, the entitled Tea Saponin of the trade mark.

Performance evaluation

It is resulting to embodiment 1~12 to carry out physicochemical property, using effect containing the shampoo of tea-seed oil and tea seed extract Evaluation.

1. physicochemical property is evaluated

Sample is respectively put into -18 DEG C of electro-heating standing-temperature cultivator it is each for 24 hours, observe sample, no phase point after restoring room temperature It is qualification from phenomenon, it is unqualified for having phenomenon of phase separation.Test result is shown in Table 1.

2. using effect is evaluated

The method for using investigation on probation: each sample number of users each has dandruff, itching of the scalp, hair for 20 people per capita The impaired problem of matter using primary, uses 10 times altogether for every 2 days, to anti-dandruff and itching-relieving and washes the flexibility after hair and comments It is fixed.

Anti-dandruff and itching-relieving effect be divided into significant effective, effectively, it is invalid.

Significant effective: dandruff, itching of the scalp phenomenon completely disappear；

Effective: dandruff is reduced, scalp has slight itch；

Invalid: dandruff is slightly reduced or unchanged, itching of the scalp phenomenon slightly mitigates or the same.

Submissive effect be divided into significant effective, effectively, it is invalid.

Significant effective: hair quality is submissive, easily combs；

It is effective: without obvious tangling phenomenon, easily to comb；

It is invalid: to have stronger tangling phenomenon when combing and relatively comb resistance by force.Test result is shown in Table 2.

Table 1

Embodiment	Physicochemical property
		Embodiment 1	It is qualified
Embodiment 2	It is qualified
		Embodiment 3	It is qualified
Embodiment 4	It is qualified
		Embodiment 5	It is qualified
Embodiment 6	It is qualified
		Embodiment 7	It is qualified
Embodiment 8	It is unqualified
		Embodiment 9	It is unqualified
Embodiment 10	It is unqualified
		Embodiment 11	It is qualified
Embodiment 12	It is qualified

Table 2

By embodiment 1~12 it can be appreciated that tea-seed oil, tea seed extract and each active group of ethylhexyl palmitate The synergistic effect divided, can largely improve damaged hair, make the submissive more gloss of hair moisturizing, moreover it is possible to which anti-inflammatory is anti-dandruff It is antipruritic.And since under the synergistic effect between system each component, the dispersibility and spreadability of shampoo are significantly improved, system Middle active constituent can preferably parent invest on hair and scalp tissue, it is easier to be absorbed, reach and preferably wash shield effect.

At last it is pointed out that the foregoing is merely illustrative of the preferred embodiments of the present invention, it is not intended to limit the invention, it is all at this Made any modifications, equivalent replacements, and improvements etc., should be included in protection model of the invention within the spirit and principle of invention Within enclosing.

Claims

1. a kind of shampoo containing tea-seed oil and tea seed extract, which is characterized in that by weight, include at least with the following group Point: 0.5~1 part of conditioner for hair, 8~16 parts of skin conditioning agent, 8~20 parts of laurel based surfactants, non-ionic surface are living Property 3~6 parts of agent, 5~10 parts of anionic surfactant, 2~7 parts of emulsifier, 0.3~0.5 part of antioxidant, preservative 0.1 ~0.3 part, 0.2~0.7 part of chelating agent, 0.1~0.3 part of essence, 1~3 part of auxiliary agent, 45~55 parts of deionized water.

2. shampoo as described in claim 1, which is characterized in that the conditioner for hair is selected from Polyquaternium-10, polyquaternary amine One or more of salt -43, polyquaternium -49.

3. shampoo as described in claim 1, which is characterized in that the skin conditioning agent is selected from plant extracts, vegetable oil One or more of rouge, ethylhexyl palmitate.

4. shampoo as claimed in claim 3, which is characterized in that the plant extracts is selected from tea seed extract, grape pip One or more of extract, Folium clausenae lansii extract, rose of Sharon leaf extract.

5. shampoo as described in claim 3 or 4, which is characterized in that the vegetable fat be selected from tea-seed oil, grape seed oil, One or more of white pond flower seed oil.

6. shampoo as described in claim 1, which is characterized in that the laurel based surfactants are selected from laureth sulphur One or more of acid esters sodium, sodium lauroyl glutamate, Sodium Lauroamphoacetate, lauroyl dilactic acid sodium.

7. shampoo as described in claim 1, which is characterized in that the antioxidant is selected from the (double-tert-butyl of pentaerythrite four Hydroxyhydrocinnamic acid) ester, di-tert-butyl p-cresol, one or more of dibutyl hydroxy toluene.

8. shampoo as described in claim 1, which is characterized in that the preservative is selected from methylchloroisothiazandnone, methyl One or more of isothiazolinone, magnesium chloride, magnesium nitrate.

9. shampoo as described in claim 1, which is characterized in that the auxiliary agent is selected from citric acid, sodium chloride, double stearic acid second One or more of diol ester.

10. a kind of preparation method such as shampoo according to any one of claims 1 to 9, which is characterized in that include at least with Lower step:

(1) deionized water and conditioner for hair are added in main cooker, it is even equal that heating stirring disperses it, and it is living that laurel primary surface is added Property agent, stir to after being completely dissolved, sequentially add nonionic surfactant, anionic surfactant, chelating agent, stir molten Solution is uniform；

(2) antioxidant and emulsifier are mixed in advance, heating is completely dissolved antioxidant, and step (1) described main cooker is added In, it is lasting to stir；

(3) stop heating, carry out homogeneous after skin conditioning agent is added into step (1) described main cooker；It is added and helps after homogeneous Agent continues to stir；