CN110300757A - 用膦酸酯低聚物固化环氧树脂 - Google Patents

用膦酸酯低聚物固化环氧树脂 Download PDF

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Publication number
CN110300757A
CN110300757A CN201880007936.3A CN201880007936A CN110300757A CN 110300757 A CN110300757 A CN 110300757A CN 201880007936 A CN201880007936 A CN 201880007936A CN 110300757 A CN110300757 A CN 110300757A
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CN
China
Prior art keywords
oligomeric
phosphonate
composition
ester
phosphonate ester
Prior art date
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Pending
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CN201880007936.3A
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English (en)
Chinese (zh)
Inventor
J-P·伦斯
L·卡库姆巴
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FRX Polymers Inc
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FRX Polymers Inc
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Publication of CN110300757A publication Critical patent/CN110300757A/zh
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C08K5/5333—Esters of phosphonic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/14—Macromolecular materials
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0255—Phosphorus containing compounds
    • B01J31/0267—Phosphines or phosphonium compounds, i.e. phosphorus bonded to at least one carbon atom, including e.g. sp2-hybridised phosphorus compounds such as phosphabenzene, the other atoms bonded to phosphorus being either carbon or hydrogen
    • B01J31/0268—Phosphonium compounds, i.e. phosphine with an additional hydrogen or carbon atom bonded to phosphorous so as to result in a formal positive charge on phosphorous
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/06—Phosphorus compounds without P—C bonds
    • C07F9/08—Esters of oxyacids of phosphorus
    • C07F9/141—Esters of phosphorous acids
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/28—Phosphorus compounds with one or more P—C bonds
    • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
    • C07F9/40—Esters thereof
    • C07F9/4071—Esters thereof the ester moiety containing a substituent or a structure which is considered as characteristic
    • C07F9/4084—Esters with hydroxyaryl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007—Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4071—Curing agents not provided for by the groups C08G59/42 - C08G59/66 phosphorus containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/68—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used
    • C08G59/686—Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the catalysts used containing nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
    • C08G79/02—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing phosphorus
    • C08G79/04—Phosphorus linked to oxygen or to oxygen and carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0066—Flame-proofing or flame-retarding additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L85/00—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers
    • C08L85/02—Compositions of macromolecular compounds obtained by reactions forming a linkage in the main chain of the macromolecule containing atoms other than silicon, sulfur, nitrogen, oxygen and carbon; Compositions of derivatives of such polymers containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/18—Fireproof paints including high temperature resistant paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/06—Organic materials
    • C09K21/12—Organic materials containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
    • C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
    • C08K5/5333—Esters of phosphonic acids
    • C08K5/5357—Esters of phosphonic acids cyclic

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polymers With Sulfur, Phosphorus Or Metals In The Main Chain (AREA)
  • Fireproofing Substances (AREA)
  • Epoxy Resins (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201880007936.3A 2017-01-05 2018-01-05 用膦酸酯低聚物固化环氧树脂 Pending CN110300757A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201762442774P 2017-01-05 2017-01-05
US62/442,774 2017-01-05
PCT/US2018/012544 WO2018129288A1 (en) 2017-01-05 2018-01-05 Curing of epoxy resins with phosphonate oligomers

Publications (1)

Publication Number Publication Date
CN110300757A true CN110300757A (zh) 2019-10-01

Family

ID=62708882

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201880007936.3A Pending CN110300757A (zh) 2017-01-05 2018-01-05 用膦酸酯低聚物固化环氧树脂

Country Status (7)

Country Link
US (1) US10717931B2 (OSRAM)
EP (1) EP3565822A4 (OSRAM)
JP (1) JP2020504214A (OSRAM)
KR (1) KR102668113B1 (OSRAM)
CN (1) CN110300757A (OSRAM)
TW (1) TW201833194A (OSRAM)
WO (1) WO2018129288A1 (OSRAM)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113214454A (zh) * 2021-06-28 2021-08-06 西华大学 一种透明无卤阻燃环氧树脂、材料及其制备方法

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11286463B2 (en) 2012-03-08 2022-03-29 Advanced ReGen Medical Technologies, LLC Reprogramming of aged adult stem cells
RU2712107C1 (ru) * 2019-08-16 2020-01-24 Федеральное государственное бюджетное образовательное учреждение высшего образования "Волгоградский государственный технический университет" (ВолгГТУ) Применение олигоэфиракрилата ((((4-((1-(2-((бис((1-галоген-3-(метакрилоилокси)пропан-2-ил)окси)фосфин)окси)-3-галогенпропокси)-3-хлорпропан-2-ил)окси)-1-галогенбутан-2-ил)окси)фосфиндиил)бис(окси))бис(3-галогенпропан-2,1-диил)бис(2-метакрилата) в качестве мономера для получения термо- и теплостойких полимеров с пониженной горючестью
KR102596686B1 (ko) * 2020-06-30 2023-10-31 롯데케미칼 주식회사 폴리포스포네이트 수지 조성물 및 이로부터 제조된 성형품

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US3671469A (en) * 1969-10-20 1972-06-20 Dow Chemical Co Method of preparing halogen-containing polymers
US4033927A (en) * 1971-11-01 1977-07-05 General Electric Company Flame retardant polyester resin compositions
WO2008073872A1 (en) * 2006-12-11 2008-06-19 Albemarle Corporation Organophosphonate oligomers, mixtures thereof, and processes for producing organophosphonate oligomers and mixtures thereof
CN102775442A (zh) * 2012-07-11 2012-11-14 合肥安聚达新材料科技有限公司 低聚物型膦酸酯及其制备方法和用途
CN103619959A (zh) * 2011-04-14 2014-03-05 Frx聚合物股份有限公司 聚膦酸酯和共聚膦酸酯添加剂混合物
EP2816048A1 (en) * 2010-12-22 2014-12-24 Frx Polymers, Inc. Oligomeric Phosphonates And Compositions Including The Same

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US4035442A (en) * 1976-05-20 1977-07-12 E. I. Du Pont De Nemours And Company Polyester filaments flame retarded with end-capped poly(m-phenylene cyclohexylphosphonate)
US4481350A (en) * 1982-03-22 1984-11-06 Bayer Aktiengesellschaft Process for the preparation of thermoplastic aromatic polyphosphonates containing small proportions of carbonate structures and product thereof
CN100546992C (zh) * 2001-10-04 2009-10-07 旭瑞达有限公司 羟基封端的低聚膦酸酯
US6861499B2 (en) 2003-02-24 2005-03-01 Triton Systems, Inc. Branched polyphosphonates that exhibit an advantageous combination of properties, and methods related thereto
US7645850B2 (en) 2005-08-11 2010-01-12 Frx Polymers, Inc. Poly(block-phosphonato-ester) and poly(block-phosphonato-carbonate) and methods of making same
US7838604B2 (en) 2005-12-01 2010-11-23 Frx Polymers, Inc. Method for the production of block copolycarbonate/phosphonates and compositions therefrom
ES2549732T3 (es) 2007-07-30 2015-11-02 Frx Polymers, Inc. Polifosfonatos insolubles y ramificados y métodos relacionados con los mismos
TW201022335A (en) * 2008-10-21 2010-06-16 Albemarle Corp Mixed glycol polyphosphonate compounds
EP2616496A4 (en) 2010-09-16 2016-05-18 Frx Polymers Inc ACCORDING BISPHENOL COPOLY (PHOSPHONATE CARBONATE) OF HIGH MOLECULAR WEIGHT
KR101913669B1 (ko) * 2010-11-17 2018-11-01 에프알엑스 폴리머스, 인코포레이티드 폴리에스테르 섬유를 위한 난연제로서의 포스포네이트 중합체, 공중합체, 및 이들의 각각의 올리고머
KR101362871B1 (ko) * 2010-12-29 2014-02-14 제일모직주식회사 가교형 폴리포스포네이트, 그의 제조 방법 및 이를 포함하는 난연성 열가소성 수지 조성물
TWI460212B (zh) 2011-12-22 2014-11-11 Frx Polymers Inc 高度分枝寡聚膦酸酯及包含該高度分枝寡聚膦酸酯之組成物
JP6600440B2 (ja) * 2012-06-29 2019-10-30 エフアールエックス ポリマーズ、インク． ポリエステルコ−ホスホネート
JP6056103B2 (ja) * 2012-08-22 2017-01-11 株式会社クラレ ポリエステル繊維
WO2016090083A1 (en) * 2014-12-03 2016-06-09 Frx Polymers, Inc. Flame retardant thermoplastic and thermoset compositions

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3671469A (en) * 1969-10-20 1972-06-20 Dow Chemical Co Method of preparing halogen-containing polymers
US4033927A (en) * 1971-11-01 1977-07-05 General Electric Company Flame retardant polyester resin compositions
WO2008073872A1 (en) * 2006-12-11 2008-06-19 Albemarle Corporation Organophosphonate oligomers, mixtures thereof, and processes for producing organophosphonate oligomers and mixtures thereof
EP2816048A1 (en) * 2010-12-22 2014-12-24 Frx Polymers, Inc. Oligomeric Phosphonates And Compositions Including The Same
CN103619959A (zh) * 2011-04-14 2014-03-05 Frx聚合物股份有限公司 聚膦酸酯和共聚膦酸酯添加剂混合物
CN102775442A (zh) * 2012-07-11 2012-11-14 合肥安聚达新材料科技有限公司 低聚物型膦酸酯及其制备方法和用途

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113214454A (zh) * 2021-06-28 2021-08-06 西华大学 一种透明无卤阻燃环氧树脂、材料及其制备方法
CN113214454B (zh) * 2021-06-28 2022-06-07 西华大学 一种透明无卤阻燃环氧树脂、材料及其制备方法

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Publication number Publication date
EP3565822A4 (en) 2020-08-05
TW201833194A (zh) 2018-09-16
WO2018129288A1 (en) 2018-07-12
JP2020504214A (ja) 2020-02-06
US10717931B2 (en) 2020-07-21
US20180187084A1 (en) 2018-07-05
EP3565822A1 (en) 2019-11-13
KR20190105036A (ko) 2019-09-11
KR102668113B1 (ko) 2024-05-23

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