CN110250067A - Straw fish shelter and preparation method thereof - Google Patents

Straw fish shelter and preparation method thereof Download PDF

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Publication number
CN110250067A
CN110250067A CN201910644922.9A CN201910644922A CN110250067A CN 110250067 A CN110250067 A CN 110250067A CN 201910644922 A CN201910644922 A CN 201910644922A CN 110250067 A CN110250067 A CN 110250067A
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CN
China
Prior art keywords
straw
weight
parts
column
frame
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910644922.9A
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Chinese (zh)
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CN110250067B (en
Inventor
陈伟
潘志宏
徐亦冬
周娟兰
杨亚强
陆磊
马舒奇
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Ningbo Institute of Technology of ZJU
Marine Equipment and Technology Institute Jiangsu University of Science and Technology
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Ningbo Institute of Technology of ZJU
Marine Equipment and Technology Institute Jiangsu University of Science and Technology
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Application filed by Ningbo Institute of Technology of ZJU, Marine Equipment and Technology Institute Jiangsu University of Science and Technology filed Critical Ningbo Institute of Technology of ZJU
Priority to CN201910644922.9A priority Critical patent/CN110250067B/en
Publication of CN110250067A publication Critical patent/CN110250067A/en
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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01KANIMAL HUSBANDRY; AVICULTURE; APICULTURE; PISCICULTURE; FISHING; REARING OR BREEDING ANIMALS, NOT OTHERWISE PROVIDED FOR; NEW BREEDS OF ANIMALS
    • A01K61/00Culture of aquatic animals
    • A01K61/70Artificial fishing banks or reefs
    • A01K61/73Artificial fishing banks or reefs assembled of components
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/025Controlling the process
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/12Impregnating by coating the surface of the wood with an impregnating paste
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/16Inorganic impregnating agents
    • B27K3/20Compounds of alkali metals or ammonium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/34Organic impregnating agents
    • B27K3/36Aliphatic compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K9/00Chemical or physical treatment of reed, straw, or similar material
    • B27K9/007Straw
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00482Coating or impregnation materials
    • C04B2111/00508Cement paints
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00758Uses not provided for elsewhere in C04B2111/00 for agri-, sylvi- or piscicultural or cattle-breeding applications
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2201/00Mortars, concrete or artificial stone characterised by specific physical values
    • C04B2201/50Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/80Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in fisheries management
    • Y02A40/81Aquaculture, e.g. of fish

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Forests & Forestry (AREA)
  • Wood Science & Technology (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Engineering (AREA)
  • Environmental Sciences (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Animal Husbandry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Zoology (AREA)
  • Marine Sciences & Fisheries (AREA)
  • Artificial Fish Reefs (AREA)

Abstract

A kind of straw fish shelter and preparation method thereof, the fish shelter include frame and the straw that is set on frame, and frame includes the frame body of cuboid or square figure, and the crossbeam and column that frame body is mutually connected vertically by several are constituted;Straw rolling is in being provided with more bundle straw and be sequentially arranged along the length direction of column on column, in each column, and the equal one end of straw is tied on column more bundles, other end nature surrounding is scattered.Make full use of the nutritional ingredient of straw and the effective area of straw, after being scattered due to boling rice straw one end space diffusion, realize take up space it is big so that more seaweed, shellfish attachment, unit benefit are improved;This structure can also change the ocean current of ocean simultaneously, and the flow velocity of ocean is slack-off in the structure, to improve the time of contact with straw, light quality, structure are simple, be conducive to repair.

Description

Straw fish shelter and preparation method thereof
Technical field
The present invention relates to fish shelter technical fields, and in particular to a kind of straw fish shelter and preparation method thereof.
Background technique
Fishery resources are important one of the protein sources of the mankind, but due to the toxic action of marine pollution, marine organisms It is destroyed, climate warming, Ocean acidification, sea fishery the fishing increase of pressure, the diffusion of ocean pathogenic microorganisms etc. Reason, global marine fishery resources are significantly failing.At the same time, fishery resources structure is also significantly changed, by High trophic levels fingerling is converted to low value and low nutrition level fingerling, is embodied in fished species and is constantly substituted, in catches Juvenile fish ratio constantly increases, and demersal fishes proportion is constantly reduced, in, epipelagic fish and shrimp, crab and jellyfish class ratio year by year Increase.How fishery resources are conserved, maintain its existing level, in addition improve fishery resources level become one it is global The problem of.Aquafarm is settling mode one of of the mankind to this problem, and aquafarm can be understood as a kind of novel fishing Industry aquaculture system, the corresponding mode of different waters is different, the main placement for passing through subbottom structure object (referring mainly to artificial marine habitat), Change the abiotic environments such as shadow effect, flow field effect, the sound effect in local sea area, is built for part marine organisms good Habitat is inhabited, the place multiplied and lived is provided, is finally reached the purpose of the living marine resources such as protection, proliferation fish.It presses The type of purpose classification, artificial marine habitat can be divided into: trap fish shelter, proliferation fish shelter, oviposition reef, sparing of undersized fish reef and algal reef etc.. It, need to be according to the spy of different waters since there are difference for the marine environment such as the ocean current of different waters, substrate and aquafarm target Point and target need to be arranged the artificial marine habitat of different configuration type.
Currently, have been reported that about artificial marine habitat also more, a kind of canvas substrate artificial marine habitat and its system applied such as applicant Preparation Method is a kind of a kind of fish shelter that coating package outer layer slurry preparation is carried out using canvas tent as matrix, this fish shelter weight Properly, it salvages, repair and be easy, and can also effectively improve seaweed takes root the whole not easy to crack, toughness of stability and fish shelter Strong advantage;But this fish shelter cost is high, is unfavorable for the control of cost;In addition, applicant also provided a kind of utilization The method of house frame manufacture artificial marine habitat to be torn open, this reinforced concrete frame using house frame to be torn open constitute base Body, although there is certain technical effect, overall weight weight is not easy to salvage and repair;In addition, also provided it is a kind of it is durable and The artificial marine habitat of proliferation mainly is used to enhance the switching performance and firmness of fish shelter using bamboo cane, but bamboo cane surface is excessively It is smooth, it is unfavorable for the secure bond of cladding material.
Straw is a kind of common agricultural crop straw, and yield is very big, it is general gather in after paddy just straw filled or For feed or manufacture paper etc.;Straw nutrition rich in fact, and it is very easy to degradation, if by itself and Artificial Fish Reef combines, and for manufacturing aquafarm, has boundless prospect.
Summary of the invention
The present invention is directed to the above-mentioned deficiency of the prior art, and provide a kind of nutritional ingredient for making full use of straw and straw has Imitate area, after being scattered due to boling rice straw one end space diffusion, realize take up space it is big so that more seaweed, shellfish Attachment, unit benefit improve;This structure can also change the ocean current of ocean simultaneously, and the flow velocity of ocean is slack-off in the structure, from And the time of contact with straw is improved, in addition, nutriment can be obtained more by complicated channel, increase flow route Nutrition, the minute protrusions that not will cause environmental pollution and its surface spikes shape conducive to degradation are more conducive to cohering for covering material And hanging, and it is capable of providing that light quality, structure are simple, conducive to the straw fish shelter and preparation method thereof of reparation.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention are as follows: a kind of straw fish shelter, the fish shelter include frame Frame and the straw being set on frame, the frame include the frame body of cuboid or square figure, frame body by Several crossbeams being mutually connected vertically and column are constituted;The straw is rolled on column, is provided in each column More bundle straw are simultaneously sequentially arranged along the length direction of column, and more bundle equal one end of straw are tied on column, the other end is natural Surrounding is scattered.
The present invention uses straw as the main material of fish shelter for the first time, straw due to rich in nutrition content, be conducive to degradation not It will cause environmental pollution, more natural, nutritious growing environment, the more conducively life of marine organisms can be provided for marine organisms Long and attachment, and this is simple and light, facilitates the picking and reparation of shellfish seaweed etc.;In addition, above structure of the present invention can To make full use of the effective area of straw, due to straw be it is bundled rolling and one end scatter after space realize diffusion, realize The big technical effect that takes up space can thus make the attachment of more seaweed shellfishes, unit benefit improve;While this Kind structure can also change the ocean current of ocean, and the flow velocity of ocean is slack-off in the structure, to improve the time of contact with straw, more Conducive to the attachment of seaweed shellfish;In addition, nutriment can by complicated channel, increase flow route, obtain more nutrition, The minute protrusions that not will cause environmental pollution and the surface spikes shape of its straw conducive to degradation are more conducive to cohering for covering material And hanging, and it is capable of providing that light quality, structure are simple, conducive to the straw fish shelter and preparation method thereof of reparation.
Preferably, being provided with lantern ring in each column, the lantern ring is axially sleeved on column, lantern ring Internal diameter is greater than the outer diameter of column, and hole of the straw between lantern ring and column is pierced by;It is located at lantern ring on the column Lower section has been arranged radially at least one stop bar, for lantern ring axial limiting;Straw can be bundled in using the structure vertical On column, while the setting of lantern ring can be very good to limit straw and fixed.
Preferably, the straw is additionally provided with stirrup after passing through lantern ring, straw to be fixed on column.Stirrup can Using elastic material or the material that can be tensioned.
Further, buoy is provided with above the frame, the buoy passes through extra large hawser or hose and frame Frame is connected, the delivery depth for controlling straw fish shelter, while can also play that recycling is convenient, regularly replaces the work of straw With.
Preferably, the column and crossbeam are hollow setting, and are provided with aperture on column and crossbeam;Using the structure Nutrient solution or oxygen etc. can be introduced into fish shelter by column and crossbeam, provide nutrition for sea area.The sea cable Binding has sealing pipe to be connected to column and crossbeam on rope, for conveying oxygen or nutrient solution to fish shelter.
Preferably, the crossbeam and column of the frame are hollow plastic tube or hollow antirust steel pipe (antirust, price Cheaply) or hollow aluminium alloy pipe, the hose is also hollow setting, and the hose of the hollow setting and the crossbeam of frame or Column connection;Weight can be mitigated as frame using hollow above-mentioned various pipelines, while preventing corrosion contamination water body;This Outside, nutriment can also be facilitated to be passed through by the hollow setting of hose and crossbeam, column, provides nutrient for seaweed, shellfish.
Preferably, the lower end of the frame is provided with anchor structure by drawstring;Rice can be guaranteed using the structure The dispensing depth of grass carp reef.
Preferably, the lower end of the column is provided with extended segment, and extended segment can be with bottom silt grafting;The knot The stability of straw fish shelter placement position, the more conducively attachment and growth of seaweed and shellfish can be improved in structure.
Preferably, it is additionally provided with flow detector and temperature monitor on the frame, the setting of the structure can be examined The detection flow velocity of ocean current is surveyed, nutrition residence time and fish-gathering effect are understood;Temperature can be convenient judgement and launch different fish, shellfish The type of the nutriment of class and investment etc. is combined with facilitating with specific fish shelter environment, preferably improves making for fish shelter Use effect.
The present invention also provides the preparation method of above-mentioned straw fish shelter, preparation step includes:
(1) the fresh straw for removing paddy is taken first, is soaked in rice straw in sodium hydrate aqueous solution and is put into 10-15h is impregnated in the NaOH solution that mass fraction is 3-5%;
(2) straw is taken out after the completion of impregnating, the sodium hydroxide (acquisition is shower water) on surface is removed in leaching, is then set It impregnates progress surface in alkyl-glucoside solution to be modified, the mass percent concentration of alkyl-glucoside solution is 8-12% It impregnates 3-6 minutes, takes out;
(3) the modified straw in step (2) surface is subjected to hanging, in two times hanging, the raw material components of first time slurry Are as follows: cement 100-150 parts by weight, miberal powder 70-120 parts by weight, flyash 40-60 parts by weight, steel-making slag powder 20-30 parts by weight subtract Aqua 1-2 parts by weight, low viscosity polyvinyl alcohol 2-5 parts by weight (binder improves the adhesive force of slurry and straw), step (2) The resulting leacheate 400-500 parts by weight of the sodium hydroxide on surface are gone in leaching;
The raw material components of second of slurry are as follows: cement 100-150 parts by weight, miberal powder 70-120 parts by weight, flyash 40-60 Parts by weight, sand 450-550 parts by weight, steel-making slag powder 20-30 parts by weight, water-reducing agent 1-2 parts by weight, low viscosity polyvinyl alcohol 2-5 The resulting leacheate 400-500 parts by weight of the sodium hydroxide on surface, the modification of cement weight 3-5% are gone in parts by weight, step (2) leaching Vinal;After the completion of hanging, straw is dried;
(4) fish shelter frame is prepared, frame includes the frame body of cuboid or square figure, and frame body is by several The crossbeam and column being mutually connected vertically are constituted;By the straw rolling obtained after step (3) processing on column, in each column It is provided with more bundle straw and is sequentially arranged along the length direction of column, and more bundle equal one end of straw are tied on column, are another One end nature surrounding is scattered.
Preferably, the mass percent concentration range of the sodium hydrate aqueous solution is 4%, soaking time 12h.
Preferably, the mass percent concentration of the alkyl-glucoside solution is 9-11%, and soaking time 4-5 divides Clock.
Preferably, the raw material components of the first time slurry are as follows: cement 120-140 parts by weight, miberal powder 80-110 weight Measure part, flyash 45-55 parts by weight, steel-making slag powder 22-38 parts by weight, water-reducing agent 1-2 parts by weight, low viscosity polyvinyl alcohol 3-4 weight Part is measured, step (1) impregnates the remaining sodium hydrate aqueous solution 420-460 parts by weight after straw;The original of second of slurry Expect component are as follows: cement 120-140 parts by weight, miberal powder 80-110 parts by weight, flyash 45-55 parts by weight, sand 450-550 weight Part, steel-making slag powder 22-38 parts by weight, water-reducing agent 1-2 parts by weight, low viscosity polyvinyl alcohol 3-4 parts by weight, step (1) immersion straw Remaining sodium hydrate aqueous solution 420-460 parts by weight afterwards, the modified polyvinyl alcohol fabric of cement weight 3-5%.
Low viscosity polyvinyl alcohol of the invention or referred to as low-viscosity polyvinyl alcohol, specific range of viscosities are 4.0- 7.0。
Preferably, the sand be fineness less than 2.2 fineness modulus fine sand (can use sea sand, sea sand it is thin Degree meets above-mentioned requirements, and sea sand is cheap, because not being metalwork in the straw handled in the straw fish shelter of the application, because This is using sea sand without worrying corrosion of steel caused by wherein there are problems that of Cl ion).
The above-mentioned preparation step of the present invention, thickness the internal layer 2-3mm, outer layer 2-3mm, overall thickness 4-5mm of hanging.
Modified polyvinyl alcohol fabric of the invention can be sold using commercially available Anhui Wanwei New High-tech Materials Co., Ltd The modified polyvinyl alcohol fabric sold.
The advantages of the present invention:
1. preparation method of the invention, the creative matrix using straw as fish shelter during the preparation process;The tool of straw Body processing method first carries out dipping by lye, this is because the main component in rice straw is lignin and hemicellulose and fiber Element, there are also a small amount of pectin and fructose.Organic matter when pectin present in it and fructose will affect the aquation of cement and be easy corruption It is rotten.NaOH solution removes organic matter, to improve the rotproofness of straw;In addition, by after dipping by lye can by straw into Row hardens and opens the aperture of straw, then carries out surface with alkyl-glucoside again and is modified, and alkyl-glucoside is a kind of Starch isolation object, no any pollution, pure natural material;And alkyl-glucoside is modified straw and obtains straw hole Diameter is opened more thorough, conducive to the entrance and adherency of subsequent hanging;Then hanging processing is carried out, in order to prevent the receipts of cement slurry Modified polyvinyl alcohol fabric is added in contracting, improves the cracking resistance and tensile resistance of straw;And the use of the invention is twice Hanging mode, without using sand and modified polyvinyl alcohol fabric in first time hanging material, be in order to allow slurries adequately into Enter in the aperture of straw, prevents sand and modified low viscosity vinal from existing and aperture is caused to block, fill aperture It is not thorough, causes the intensity, toughness of straw and corrosion resistance undesirable in this way, and by the way of hanging twice, for the first time It is sufficient filling with aperture, second makes that straw is not easy to crack, tensile strength is high by sand and modified polyvinyl alcohol fabric, anti-corruption Corrosion can be more stable.
2. preparation method of the present invention passes through soaking with sodium hydroxide first, then alkyl-glucoside surface is modified, so Carry out hanging again afterwards, the toughness that fiber raising straw is added in hanging material prevents from cracking;Specific processing step this simultaneously Suddenly the pore plugging of straw is prevented, so that on the surface of the more thorough hole for invading straw of slurry and straw, adherency It is stronger, processing effectively is modified to straw, the corrosion for improving the fastness of straw, preventing seawater to straw.
3. preparation method of the present invention, wherein the sand added is fine sand, this sand can guarantee hanging thickness not Can be too thick, and hanging is more uniform, comprehensive cladding, also more conducively slurry enters in the hole of straw;It effectively prevent straw to hang Starch blocked up phenomena such as causing fracture.
4. in preparation method of the invention, using steel-making slag powder, this powder has the effect of microdilatancy, because containing in slurry A large amount of moisture makes the hanging on straw be easy cracking fastly if not adding steel-making slag powder and will lead to washiness evaporation;And steel The effect of ground-slag microdilatancy effectively overcomes drawbacks described above, has the function of limitation cracking, fills up microcrack.Preparation of the invention In method, the dosage of water can also be effectively reduced using water-reducing agent, to reduce hanging cracking risk.
5. water of the invention efficiently uses raw material using the shower water of remaining sodium hydroxide on the removal straw of step (2); This water lotion of addition can adequately impregnate straw simultaneously, realize more thorough slurry attachment;And using alkalinity Water lotion can also realize that admixture (flyash, slag, steel-making slag powder) is excited as the solvent of slurry, and it is strong to improve slurry hardening Degree;It is added to the polyvinyl alcohol of low viscosity in slurry of the present invention, effectively improves adhesion property.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of straw artificial marine habitat prepared by the present invention.
Fig. 2 is the pillar construction schematic diagram in straw artificial marine habitat prepared by the present invention (straw is visible).
Fig. 3 is the pillar construction schematic diagram in straw artificial marine habitat prepared by the present invention (straw is not shown).
Fig. 4 is of the invention provided with column or crossbeam.
Specific embodiment
Method of the present invention is described further below with reference to some specific embodiments.Specific embodiment be into The present invention will be described in detail for one step, non-limiting protection scope of the present invention, unless stated otherwise, method used in the embodiment of the present invention It is this field conventional selection with raw material.
As shown in Fig. 1: a kind of straw fish shelter of the invention, the fish shelter include frame 1 and the straw that is set on frame 2, the frame includes the frame body of cuboid or square figure, the cross that frame body is mutually connected vertically by several Beam 1.1 and vertical 1.2 columns are constituted;The described straw rolling is in being provided with more bundle straw and along vertical on column, in each column The length direction of column is sequentially arranged, and the equal one end of straw is tied on column more bundles, other end nature surrounding is scattered.
The present invention uses straw as the main material of fish shelter for the first time, and straw will not be made due to nutritional ingredient, conducive to degradation At environmental pollution, more natural, nutritious growing environment can be provided for marine organisms, more conducively the growth of marine organisms and Attachment, and this is simple and light, facilitates picking and reparation.
Shown in attached drawing 2-3: being provided with lantern ring 3 in each column 1.2, the lantern ring is axially sleeved on column On, the internal diameter of lantern ring is greater than the outer diameter of column, and hole of the straw between lantern ring and column is pierced by;On the column At least one stop bar 4 is arranged radially below lantern ring, for lantern ring axial limiting;It can be by straw using the structure It is bundled on column, while the setting of lantern ring can be very good to limit straw and fixed.
Shown in attached drawing 2: the straw is additionally provided with stirrup 5 after passing through lantern ring, straw to be fixed on column.Hoop Muscle can be using elastic material or the material that can be tensioned.The either above or below of lantern ring can be located at, or up and down simultaneously It is provided with stirrup, guarantees that the connection between straw and column is closer.
Shown in attached drawing 1: the top of the frame 1 is provided with buoy 6, the buoy by sea with hawser 6.1 (or Hose) it is connected with frame 1, the delivery depth for controlling straw fish shelter.
Shown in attached drawing 2: the crossbeam and column of the frame are hollow plastic tube or hollow stainless steel tube or hollow Aluminium-alloy pipe etc.;Weight can be mitigated as frame using above-mentioned tubing, while preventing corrosion contamination water body.
Shown in attached drawing 1: the lower end of the frame is provided with anchor structure 7 with hawser by sea;Use the structure can be with Guarantee the dispensing depth of straw fish shelter.Such as stone, ceramic block can haul fish shelter will not float to water surface material it is equal It can be with.
As shown in Fig. 4, column and crossbeam of the present invention are hollow setting, and are provided with aperture on column and crossbeam 8;Nutrient solution or oxygen etc. can be introduced into fish shelter using the structure by column and crossbeam, provide nutrition for sea area. Binding has sealing pipe or directlys adopt hollow hose on the extra large hawser, for conveying oxygen or nutrition to fish shelter Liquid.
As shown in Fig. 1, the lower end of the column 1.2 is provided with extended segment 1.3, and extended segment energy and bottom silt Grafting;The stability of straw fish shelter placement position, the more conducively attachment and growth of seaweed and shellfish can be improved in the structure.
As shown in Fig. 1, flow detector 9 (such as commercially available doppler velocimeter) and temperature are additionally provided on the frame Detector 10 is spent (if " microcomputer information " the 35th phase in 2010 report is " based on the ocean temperature detector of 51 single-chip microcontrollers Develop " or commercially available other suitable ocean temperature detections instrument, can be with), the setting of the structure can detecte ocean current Flow velocity is detected, nutrition residence time and fish-gathering effect are understood;The monitoring of temperature can be convenient judgement and launch different fish, shellfish It with the type of the nutriment of investment etc., is combined with facilitating with specific fish shelter environment, preferably improves the use of fish shelter Effect.Above-mentioned flow rate detection instrument and temperature detection instrument can be self-powered or electrical connection etc. mode.
Straw artificial marine habitat of the present invention specifically prepares embodiment:
Embodiment 1
(1) the fresh straw for removing paddy is taken first, is soaked in rice straw in sodium hydrate aqueous solution and is put into 12h is impregnated in the NaOH solution that mass fraction is 4%;
(2) straw is taken out after the completion of impregnating, the sodium hydroxide on surface is removed in leaching, and it is molten then to place it in alkyl-glucoside It impregnates progress surface in liquid to be modified, the mass percent concentration of alkyl-glucoside solution is 10% immersion 5 minutes, is taken out;
(3) the modified straw in step (2) surface is subjected to hanging, in two times hanging, the raw material components of first time slurry Are as follows: 120 parts by weight of cement, 90 parts by weight of miberal powder, 50 parts by weight of flyash, 25 parts by weight of steel-making slag powder, 1.5 parts by weight of water-reducing agent, Resulting 450 parts by weight of leacheate of the sodium hydroxide on surface are gone in 3 parts by weight of low viscosity polyvinyl alcohol, step (2) leaching;Second of slurry The raw material components of material are as follows: 120 parts by weight of cement, 90 parts by weight of miberal powder, 50 parts by weight of flyash, 500 parts by weight of sand, steel-making slag powder 25 parts by weight, 1.5 parts by weight of water-reducing agent, 3 parts by weight of low viscosity polyvinyl alcohol, step (2) leaching are gone obtained by the sodium hydroxide on surface 450 parts by weight of leacheate, the modified polyvinyl alcohol fabric of cement weight 3%;After the completion of hanging, straw is dried;
(4) fish shelter frame is prepared, frame includes the frame body of cuboid or square figure, and frame body is by several The crossbeam and column being mutually connected vertically are constituted;By the straw rolling obtained after step (3) processing on column, in each column It is provided with more bundles and is sequentially arranged along the length direction of column, and more bundle equal one end of straw are tied on column, the other end Natural surrounding is scattered.
The cement slurry of above-mentioned two layers simple of hanging, is made into solid test block, compression strength 65MPa, the anti-folding of cement slurry Intensity 11MPa, tensile strength 6MPa;Tensile strength 4.5MPa of the straw after hanging is dried twice.
Three months be placed between the Zhoushan sea area 3-5 month, biological attachment amount 140-150g/m2
Embodiment 2
(1) the fresh straw for removing paddy is taken first, is soaked in rice straw in sodium hydrate aqueous solution and is put into 11h is impregnated in the NaOH solution that mass fraction is 3%;
(2) straw is taken out after the completion of impregnating, the sodium hydroxide on surface is removed in leaching, and it is molten then to place it in alkyl-glucoside It impregnates progress surface in liquid to be modified, the mass percent concentration of alkyl-glucoside solution is 10% immersion 4 minutes, is taken out;
(3) the modified straw in step (2) surface is subjected to hanging, in two times hanging, the raw material components of first time slurry Are as follows: 110 parts by weight of cement, 80 parts by weight of miberal powder, 42 parts by weight of flyash, 23 parts by weight of steel-making slag powder, 1 parts by weight of water-reducing agent are low Resulting 420 parts by weight of leacheate of the sodium hydroxide on surface are gone in 3 parts by weight of viscosity polyvinyl alcohol, step (2) leaching;
The raw material components of second of slurry are as follows: 110 parts by weight of cement, 80 parts by weight of miberal powder, 42 parts by weight of flyash, sand Surface is gone in 450 parts by weight, 23 parts by weight of steel-making slag powder, 1 parts by weight of water-reducing agent, 3 parts by weight of low viscosity polyvinyl alcohol, step (2) leaching Resulting 420 parts by weight of leacheate of sodium hydroxide, the modified polyvinyl alcohol fabric of cement weight 3%;After the completion of hanging, by rice Grass dries;
(4) fish shelter frame is prepared, frame includes the frame body of cuboid or square figure, and frame body is by several The crossbeam and column being mutually connected vertically are constituted;By the straw rolling obtained after step (3) processing on column, in each column It is provided with more bundles and is sequentially arranged along the length direction of column, and more bundle equal one end of straw are tied on column, the other end Natural surrounding is scattered.
The cement slurry of above-mentioned two layers simple of hanging, is made into solid test block, compression strength 60MPa, the anti-folding of cement slurry Intensity 10MPa, tensile strength 5MPa;Tensile strength 4.5MPa of the straw after hanging is dried twice.
Three months be placed between the Zhoushan sea area 3-5 month, biological attachment amount 120-130g/m2
Embodiment 3
(1) the fresh straw for removing paddy is taken first, is soaked in rice straw in sodium hydrate aqueous solution and is put into 10h is impregnated in the NaOH solution that mass fraction is 5%;
(2) straw is taken out after the completion of impregnating, the sodium hydroxide on surface is removed in leaching, and it is molten then to place it in alkyl-glucoside It impregnates progress surface in liquid to be modified, the mass percent concentration of alkyl-glucoside solution is 12% immersion 3 minutes, is taken out;
(3) the modified straw in step (2) surface is subjected to hanging, in two times hanging, the raw material components of first time slurry Are as follows: 150 parts by weight of cement, 120 parts by weight of miberal powder, 60 parts by weight of flyash, 30 parts by weight of steel-making slag powder, 2 parts by weight of water-reducing agent are low Resulting 480 parts by weight of leacheate of the sodium hydroxide on surface are gone in 4 parts by weight of viscosity polyvinyl alcohol, step (2) leaching;
The raw material components of second of slurry are as follows: 150 parts by weight of cement, 120 parts by weight of miberal powder, 60 parts by weight of flyash, sand Table is removed in sub 540 parts by weight, 30 parts by weight of steel-making slag powder, 2 parts by weight of water-reducing agent, 4 parts by weight of low viscosity polyvinyl alcohol, step (2) leaching Resulting 480 parts by weight of leacheate of the sodium hydroxide in face, the modified polyvinyl alcohol fabric of cement weight 4%;It, will after the completion of hanging Straw dries;
(4) fish shelter frame is prepared, frame includes the frame body of cuboid or square figure, and frame body is by several The crossbeam and column being mutually connected vertically are constituted;By the straw rolling obtained after step (3) processing on column, in each column It is provided with more bundles and is sequentially arranged along the length direction of column, and more bundle equal one end of straw are tied on column, the other end Natural surrounding is scattered.
The cement slurry of above-mentioned two layers simple of hanging, is made into solid test block, compression strength 55MPa, the anti-folding of cement slurry Intensity 8MPa, tensile strength 4.5MPa;Tensile strength 4MPa of the straw after hanging is dried twice.
Three months be placed between the Zhoushan sea area 3-5 month, biological attachment amount 135-140g/m2
A kind of seawater quality of trimestral water quality and China between the Zhoushan sea area 3-5 month that placed straw fish shelter of the present invention Standard (GB 3097) is compared, and is specifically shown in shown in the following table 1:
1 heavy metal ion leaching concentration testing result of table
Illustrate that straw fish shelter of the invention can effectively reduce the pollution to seawater, while people can also be played well The effect of work fish shelter.

Claims (10)

1. a kind of straw fish shelter, it is characterised in that: the fish shelter includes frame and the straw that is set on frame, the frame packet The frame body of cuboid or square figure is included, the crossbeam and column that frame body is mutually connected vertically by several are constituted; The described straw rolling is in being provided with more bundle straw and sequentially arrange along the length direction of column on column, in each column Column, and the equal one end of straw is tied on column more bundles, other end nature surrounding is scattered.
2. straw fish shelter according to claim 1, it is characterised in that: be provided with lantern ring, institute in each column The lantern ring stated axially is sleeved on column, and the internal diameter of lantern ring is greater than the outer diameter of column, and the straw is between lantern ring and column Hole be pierced by;It is located at below lantern ring on the column and has been arranged radially at least one stop bar, for axially limiting lantern ring Position.
3. straw fish shelter according to claim 2, it is characterised in that: the straw is additionally provided with hoop after passing through lantern ring Muscle, straw to be fixed on column.
4. straw fish shelter according to claim 1, it is characterised in that: it is provided with buoy above the frame, it is described Buoy is connected by extra large hawser or hose with frame, the delivery depth for controlling straw fish shelter;The column and Crossbeam is hollow setting, and is provided with aperture on column and crossbeam.
5. straw fish shelter according to claim 4, it is characterised in that: the crossbeam and column of the frame are hollow plastics Pipe or hollow antirust steel pipe or hollow aluminium alloy pipe, the hose are also hollow setting, and the hose of the hollow setting with The crossbeam or column of frame are connected to.
6. straw fish shelter according to claim 1, it is characterised in that: the lower end of the frame is provided with anchor by drawstring Fixing structure;The lower end of the column is provided with extended segment, and extended segment can be with bottom silt grafting;On the frame also It is provided with flow detector and temperature monitor.
7. a kind of preparation method of straw fish shelter, it is characterised in that: preparation step includes:
(1) the fresh straw for removing paddy is taken first, is soaked in sodium hydrate aqueous solution, rice straw is put into quality 10-15h is impregnated in the NaOH solution that score is 3-5%;
(2) straw is taken out after the completion of impregnating, the sodium hydroxide on surface is removed in leaching, then places it in alkyl-glucoside solution It impregnates progress surface to be modified, the mass percent concentration of alkyl-glucoside solution is that 8-12% impregnates 3-6 minutes, is taken out;
(3) the modified straw in step (2) surface is subjected to hanging, in two times hanging, the raw material components of first time slurry are as follows: water Mud 100-150 parts by weight, miberal powder 70-120 parts by weight, flyash 40-60 parts by weight, steel-making slag powder 20-30 parts by weight, water-reducing agent 1- The resulting leacheate 400-500 of the sodium hydroxide on surface is removed in 2 parts by weight, low viscosity polyvinyl alcohol 2-5 parts by weight, step (2) leaching Parts by weight;
The raw material components of second of slurry are as follows: cement 100-150 parts by weight, miberal powder 70-120 parts by weight, flyash 40-60 weight Part, sand 450-550 parts by weight, steel-making slag powder 20-30 parts by weight, water-reducing agent 1-2 parts by weight, low viscosity polyvinyl alcohol 2-5 weight Part, the resulting leacheate 400-500 parts by weight of the sodium hydroxide on surface, the poly- second of the modification of cement weight 3-5% are gone in step (2) leaching Enol fiber;After the completion of hanging, straw is dried;
(4) fish shelter frame is prepared, frame includes the frame body of cuboid or square figure, and frame body is mutual by several Crossbeam and column connected vertically are constituted;The straw obtained after step (3) processing is rolled on column, is all provided in each column It is equipped with more bundle straw and is sequentially arranged along the length direction of column, and more bundle equal one end of straw are tied on column, the other end Natural surrounding is scattered.
8. the preparation method of straw fish shelter according to claim 7, it is characterised in that: the sodium hydrate aqueous solution Concentration range is 4%, soaking time 12h;The mass percent concentration of the alkyl-glucoside solution is 9-11%, leaching Bubble time 4-5 minutes.
9. the preparation method of straw fish shelter according to claim 7, it is characterised in that: the raw material of the first time slurry Component are as follows: cement 120-140 parts by weight, miberal powder 80-110 parts by weight, flyash 45-55 parts by weight, steel-making slag powder 22-38 weight Part, water-reducing agent 1-2 parts by weight, low viscosity polyvinyl alcohol 3-4 parts by weight, step (1) impregnate the remaining sodium hydroxide water after straw Solution 420-460 parts by weight;
The raw material components of second of slurry are as follows: cement 120-140 parts by weight, miberal powder 80-110 parts by weight, flyash 45- 55 parts by weight, sand 450-550 parts by weight, steel-making slag powder 22-38 parts by weight, water-reducing agent 1-2 parts by weight, low viscosity polyvinyl alcohol 3- 4 parts by weight, step (1) impregnate the remaining sodium hydrate aqueous solution 420-460 parts by weight after straw, and cement weight 3-5%'s changes Property vinal.
10. the preparation method of straw fish shelter according to claim 7, it is characterised in that: the sand is less than for fineness The fine sand of 2.2 fineness modulus;Thickness the internal layer 2-3mm, outer layer 2-3mm, overall thickness 4-5mm of the hanging, its hanging.
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