CN105778237A - Fishing net made of modified zeolite powder modified plastic - Google Patents
Fishing net made of modified zeolite powder modified plastic Download PDFInfo
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- CN105778237A CN105778237A CN201610287613.7A CN201610287613A CN105778237A CN 105778237 A CN105778237 A CN 105778237A CN 201610287613 A CN201610287613 A CN 201610287613A CN 105778237 A CN105778237 A CN 105778237A
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- fishing net
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a fishing net made of modified zeolite powder modified plastic. The fishing net is prepared from butyl stearate, polyvinylidene chloride, polyethylene, modified zeolite powder, low-vinyl polybutadiene rubber, polyvinylpyrrolidone, bamboo fibers, alumina powder, rosin and assistant modifier. The advantages of raw materials such as the polyvinylidene chloride, the polyethylene and the like are combined, the modified zeolite powder is utilized to perform modification treatment on the material, the alumina powder, the rosin, the assistant modifier and the like are used for assistant modification treatment of the material, the modified material has good processability, the made fishing net is high in strength, resistant to oxidation and high in strength of single thread knots of fishing net threads, particularly, high-low temperature resistance and ageing resistance are improved to a great extent, and when the fishing net is in use under the same circumstance of alternative high and low temperature, service life of the fishing net is 1.2 times longer than that of common fishing nets, and ageing resistance of the fishing net is 0.5 times stronger than that of the common fishing nets; normal service life of the made fishing net is prolonged by 21% as compared with that of the common fishing nets.
Description
Technical field
The present invention relates to fishing gear field, particularly relate to the fishing net that a kind of modified zeolite powder modified plastics is made.
Background technology
Fishing net is the net of fishing, and it is numb as raw material that men of old uses coarse cloth to add, makes fishnet by tying the method for volume.Although this fishing net is perishable, toughness is poor, but its fishing efficiency is greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.It is numb as raw material that men of old uses coarse cloth to add, by the method tying volume
Make fishnet.Although this fishing net is perishable, toughness is poor, but its fishing efficiency is greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.Modern fishing net mainly adopts polyethylene, the raw materials such as nylon are processed, there are longer life cycle and higher catching rate, but the mechanical property of polyethylene itself is general, hot strength is relatively low, creep resistance is bad, results in the tradition intensity of fishing net, anti-wear performance, toughness are unsuitable at the bottom of Complex Sea and wind and waves environment fishing operation, reduce the service life of fishing gear, not only waste resource, also directly affect catch.
Summary of the invention
It is an object of the invention to provide the fishing net that a kind of modified zeolite powder modified plastics is made, be achieved through the following technical solutions:
The fishing net that a kind of modified zeolite powder modified plastics is made, is made up of following component by weight: butyl stearate 1, Vingon 23, polyethylene 114, modified zeolite powder 0.4, Polybutadiene Rubber With Low Vinyl Structure Content 0.5, polyvinylpyrrolidone 0.2, bamboo fibre 0.3, alumina powder 0.1, Colophonium 2, auxiliary modifier 0.3;Described auxiliary modifier is made up of following component by weight: Folium Caryophylli oil 5, Pulvis Talci 1, glycol distearate 1, dicyclohexyl phthalate 3, sodium lauryl sulphate 2, Kojic Acid Dipalmitate 4, Hydroxypropyl acrylate 3;Preparation method is calcined 18 minutes at 300 DEG C by Pulvis Talci, adopt heating in water bath to 80 DEG C Folium Caryophylli oil, glycol distearate and dicyclohexyl phthalate, then the Pulvis Talci after calcining, sodium lauryl sulphate, Kojic Acid Dipalmitate, Hydroxypropyl acrylate are added, first stir 20 minutes with 450r/min speed, stir 15 minutes with 1000r/min speed again,;Auxiliary modifier can improve the comprehensive mechanical property of fishing net, promotes generation adhesion between each composition, improves the interfacial gluing of each one-tenth.
Further, the granularity of described modified zeolite powder is 28-29nm, the preparation method of described modified zeolite powder is: zeolite powder carries out sonic oscillation and processes 15 minutes, then zeolite powder is put into mass concentration is after soaking 3-4 hour in 8.75% cocamido propyl betaine solution, filter, washing surface, dry;Enabling to zeolite powder Particle pollution, specific surface area increases, and improves the affinity on its surface and polyethylene, polrvinyl chloride.
Further, the granularity of described alumina powder is 5800-6000 order;Described talcous granularity is 5200-5400 order.
Further, described Colophonium is through pretreatment: after Colophonium adopting soaked in absolute ethyl alcohol 10 hours, filters, and adopts 35 DEG C of temperature to toast 1 minute.
Further, described bamboo fibre surface processes through inorganic agent, after bamboo fibre mixes 20 minutes with inorganic agent with inorganic agent at 55 DEG C, filters, washing, dries,;Described inorganic agent is made up of following component in percentage terms: 50% sodium laureth sulfate, 10% itaconic acid, 40% water;Add combine between treated bamboo fibre not only bamboo fibre and other composition tightr, and pliability and the tensile strength of fishing net can greatly be improved.
The preparation method of the fishing net that a kind of modified zeolite powder modified plastics is made, puts into mixing 40 minutes in the container of temperature 144-146 DEG C by weight by butyl stearate, Vingon, polyethylene, modified zeolite powder;When internal tank temperature is adjusted to 86-88 DEG C, be sequentially added into the Polybutadiene Rubber With Low Vinyl Structure Content of corresponding weight portion in container, polyvinylpyrrolidone, bamboo fibre, alumina powder are stirred, the speed of stirring is 700r/min, after stirring 10 minutes, the Colophonium and the auxiliary modifier that add corresponding weight portion again stir 20 minutes with 1200r/min speed, finally add extruder to and carry out pelletize, then injection machine injection moulding is used, then spray webbing machine spray webbing is used, finally weave, obtain made fishing net.
The invention has the beneficial effects as follows: present invention incorporates Vingon, the advantage of the raw materials such as polyethylene, utilize modified zeolite powder that material has been carried out modification, and with alumina powder, Colophonium, material has been carried out Aided Modification process by the raw materials such as auxiliary modifier, material after improvement has good processing characteristics and mechanical performance, the fishing net intensity made is high, good toughness, strong shock resistance, antioxidation, fishing lines single line knotting strength is high, tensile strength and bending strength are all improved largely, especially, high and low temperature resistance and ageing resistace obtain the raising of high degree, use longer than the service life of common fishing net 1.2 times under the environment that same high/low temperature is staggered, ageing resistace is stronger than common fishing net 0.5 times, the fishing net normal service life that the present invention makes improves 21% than common fishing net.
Detailed description of the invention
The fishing net that a kind of modified zeolite powder modified plastics is made, is made up of following component by weight: butyl stearate 1, Vingon 23, polyethylene 114, modified zeolite powder 0.4, Polybutadiene Rubber With Low Vinyl Structure Content 0.5, polyvinylpyrrolidone 0.2, bamboo fibre 0.3, alumina powder 0.1, Colophonium 2, auxiliary modifier 0.3;Described auxiliary modifier is made up of following component by weight: Folium Caryophylli oil 5, Pulvis Talci 1, glycol distearate 1, dicyclohexyl phthalate 3, sodium lauryl sulphate 2, Kojic Acid Dipalmitate 4, Hydroxypropyl acrylate 3;Preparation method is calcined 18 minutes at 300 DEG C by Pulvis Talci, adopt heating in water bath to 80 DEG C Folium Caryophylli oil, glycol distearate and dicyclohexyl phthalate, then the Pulvis Talci after calcining, sodium lauryl sulphate, Kojic Acid Dipalmitate, Hydroxypropyl acrylate are added, first stir 20 minutes with 450r/min speed, stir 15 minutes with 1000r/min speed again,.
Further, the granularity of described modified zeolite powder is 28-29nm, the preparation method of described modified zeolite powder is: zeolite powder carries out sonic oscillation and processes 15 minutes, then zeolite powder is put into mass concentration is after soaking 3-4 hour in 8.75% cocamido propyl betaine solution, filter, washing surface, dry;Enabling to zeolite powder Particle pollution, specific surface area increases, and improves the affinity on its surface and polyethylene, polrvinyl chloride.
Further, the granularity of described alumina powder is 5800-6000 order;Described talcous granularity is 5200-5400 order.
Further, described Colophonium is through pretreatment: after Colophonium adopting soaked in absolute ethyl alcohol 10 hours, filters, and adopts 35 DEG C of temperature to toast 1 minute.
Further, described bamboo fibre surface processes through inorganic agent, after bamboo fibre mixes 20 minutes with inorganic agent with inorganic agent at 55 DEG C, filters, washing, dries,;Described inorganic agent is made up of following component in percentage terms: 50% sodium laureth sulfate, 10% itaconic acid, 40% water.
The preparation method of the fishing net that a kind of modified zeolite powder modified plastics is made, puts into mixing 40 minutes in the container of temperature 144-146 DEG C by weight by butyl stearate, Vingon, polyethylene, modified zeolite powder;When internal tank temperature is adjusted to 86-88 DEG C, be sequentially added into the Polybutadiene Rubber With Low Vinyl Structure Content of corresponding weight portion in container, polyvinylpyrrolidone, bamboo fibre, alumina powder are stirred, the speed of stirring is 700r/min, after stirring 10 minutes, the Colophonium and the auxiliary modifier that add corresponding weight portion again stir 20 minutes with 1200r/min speed, finally add extruder to and carry out pelletize, then injection machine injection moulding is used, then spray webbing machine spray webbing is used, finally weave, obtain made fishing net.
Claims (6)
1. the fishing net that a modified zeolite powder modified plastics is made, it is characterized in that, be made up of following component by weight: butyl stearate 1, Vingon 23, polyethylene 114, modified zeolite powder 0.4, Polybutadiene Rubber With Low Vinyl Structure Content 0.5, polyvinylpyrrolidone 0.2, bamboo fibre 0.3, alumina powder 0.1, Colophonium 2, auxiliary modifier 0.3;Described auxiliary modifier is made up of following component by weight: Folium Caryophylli oil 5, Pulvis Talci 1, glycol distearate 1, dicyclohexyl phthalate 3, sodium lauryl sulphate 2, Kojic Acid Dipalmitate 4, Hydroxypropyl acrylate 3;Preparation method is calcined 18 minutes at 300 DEG C by Pulvis Talci, adopt heating in water bath to 80 DEG C Folium Caryophylli oil, glycol distearate and dicyclohexyl phthalate, then the Pulvis Talci after calcining, sodium lauryl sulphate, Kojic Acid Dipalmitate, Hydroxypropyl acrylate are added, first stir 20 minutes with 450r/min speed, stir 15 minutes with 1000r/min speed again,.
2. the fishing net that a kind of modified zeolite powder modified plastics according to claim 1 is made, it is characterized in that, the granularity of described modified zeolite powder is 28-29nm, the preparation method of described modified zeolite powder is: zeolite powder carries out sonic oscillation and processes 15 minutes, then zeolite powder is put into mass concentration is after soaking 3-4 hour in 8.75% cocamido propyl betaine solution, filter, washing surface, dry.
3. the fishing net that a kind of modified zeolite powder modified plastics according to claim 1 is made, it is characterised in that the granularity of described alumina powder is 5800-6000 order;Described talcous granularity is 5200-5400 order.
4. the fishing net that a kind of modified zeolite powder modified plastics according to claim 1 is made, it is characterised in that described Colophonium is through pretreatment: after Colophonium adopting soaked in absolute ethyl alcohol 10 hours, filters, and adopts 35 DEG C of temperature to toast 1 minute.
5. the fishing net that a kind of modified zeolite powder modified plastics according to claim 1 is made, it is characterised in that described bamboo fibre surface processes through inorganic agent, after bamboo fibre mixes 20 minutes with inorganic agent with inorganic agent at 55 DEG C, filters, washing, dries,;Described inorganic agent is made up of following component in percentage terms: 50% sodium laureth sulfate, 10% itaconic acid, 40% water.
6. the preparation method of the fishing net that a kind of modified zeolite powder modified plastics according to any one of claim 1-5 is made, it is characterized in that, by weight butyl stearate, Vingon, polyethylene, modified zeolite powder are put into mixing 40 minutes in the container of temperature 144-146 DEG C;When internal tank temperature is adjusted to 86-88 DEG C, be sequentially added into the Polybutadiene Rubber With Low Vinyl Structure Content of corresponding weight portion in container, polyvinylpyrrolidone, bamboo fibre, alumina powder are stirred, the speed of stirring is 700r/min, after stirring 10 minutes, the Colophonium and the auxiliary modifier that add corresponding weight portion again stir 20 minutes with 1200r/min speed, finally add extruder to and carry out pelletize, then injection machine injection moulding is used, then spray webbing machine spray webbing is used, finally weave, obtain made fishing net.
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CN201610287613.7A CN105778237A (en) | 2016-05-04 | 2016-05-04 | Fishing net made of modified zeolite powder modified plastic |
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CN201610287613.7A CN105778237A (en) | 2016-05-04 | 2016-05-04 | Fishing net made of modified zeolite powder modified plastic |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107974149A (en) * | 2017-12-23 | 2018-05-01 | 安徽国电能源设备工程有限公司 | A kind of preparation method of hot water storage tank high-temperature resistant coating |
CN108823668A (en) * | 2018-04-11 | 2018-11-16 | 安徽省义顺渔网渔具有限公司 | A kind of method of netting twine reactive extrursion |
CN109177255A (en) * | 2018-08-21 | 2019-01-11 | 巢湖市大江渔具有限公司 | A kind of processing method of nonwoven fishing net |
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CN102251303A (en) * | 2011-05-03 | 2011-11-23 | 鑫海绳网制造有限公司 | Method for preparing trimeric high-strength and high-toughness energy-saving fishing net |
CN102924804A (en) * | 2012-11-23 | 2013-02-13 | 重庆澳彩科鼎塑染色母有限责任公司 | Antibacterial anti-alga color master batch dedicated to fishing net and preparation method thereof |
CN103724769A (en) * | 2013-12-11 | 2014-04-16 | 巢湖亚塑网具制造有限公司 | Nylon-reinforced fishing net |
CN104559163A (en) * | 2014-09-13 | 2015-04-29 | 巢湖市瑞强渔具有限责任公司 | Corrosion resistant fishing line |
CN105386156A (en) * | 2015-11-13 | 2016-03-09 | 巢湖市强力渔业有限责任公司 | High-quality fishing net |
-
2016
- 2016-05-04 CN CN201610287613.7A patent/CN105778237A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102251303A (en) * | 2011-05-03 | 2011-11-23 | 鑫海绳网制造有限公司 | Method for preparing trimeric high-strength and high-toughness energy-saving fishing net |
CN102924804A (en) * | 2012-11-23 | 2013-02-13 | 重庆澳彩科鼎塑染色母有限责任公司 | Antibacterial anti-alga color master batch dedicated to fishing net and preparation method thereof |
CN103724769A (en) * | 2013-12-11 | 2014-04-16 | 巢湖亚塑网具制造有限公司 | Nylon-reinforced fishing net |
CN104559163A (en) * | 2014-09-13 | 2015-04-29 | 巢湖市瑞强渔具有限责任公司 | Corrosion resistant fishing line |
CN105386156A (en) * | 2015-11-13 | 2016-03-09 | 巢湖市强力渔业有限责任公司 | High-quality fishing net |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN107974149A (en) * | 2017-12-23 | 2018-05-01 | 安徽国电能源设备工程有限公司 | A kind of preparation method of hot water storage tank high-temperature resistant coating |
CN108823668A (en) * | 2018-04-11 | 2018-11-16 | 安徽省义顺渔网渔具有限公司 | A kind of method of netting twine reactive extrursion |
CN109177255A (en) * | 2018-08-21 | 2019-01-11 | 巢湖市大江渔具有限公司 | A kind of processing method of nonwoven fishing net |
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