CN105754189A - Anti-fouling antiaging fishing net - Google Patents
Anti-fouling antiaging fishing net Download PDFInfo
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- CN105754189A CN105754189A CN201610231021.3A CN201610231021A CN105754189A CN 105754189 A CN105754189 A CN 105754189A CN 201610231021 A CN201610231021 A CN 201610231021A CN 105754189 A CN105754189 A CN 105754189A
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- fishing net
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- antifouling
- aging resistance
- acrylic resin
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The invention discloses an anti-fouling antiaging fishing net, made from the following components: acrylic resin, polyethylene, ethylene-propylene-diene rubber, rosin, polyamide, high boiling solvent lignin epoxy resin, bamboo powder, nano bentonite, fiberglass, a plasticizer and an aid.The fishing net manufactured herein is simple to manufacture; by pretreating the acrylic resin in cooperation with the other components of the invention, tensile strength of fishing net material can be increased by 39.1%, comprehensive mechanical properties of the fishing net can be improved, and single-knot strength of the fishing net can be improved; through the cooperation of the aid with the other components, antiaging capacity of the fishing net can be improved greatly, compatibility of the components can be improved, the service life of the fishing net can be prolonged, and production cost is reduced; through the mutual cooperation of the bamboo powder, the mixed nano bentonite and rosin and the fiberglass, anti-fouling and antibacterial properties of the fishing net are improved, toughness of the fishing net can be increased by 42.6%, and antiaging property of the fishing net can be enhanced.
Description
Technical field
The present invention relates to fishing gear field, particularly relate to a kind of antifouling aging resistance fishing net.
Background technology
Fishing net is the net of fishing, and it is numb as raw material that men of old uses coarse cloth to add, makes fishnet by tying the method for volume.Although this fishing net is perishable, toughness is poor, but its fishing efficiency is greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.It is numb as raw material that men of old uses coarse cloth to add, by the method tying volume
Make fishnet.Although this fishing net is perishable, toughness is poor, but its fishing efficiency is greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.Modern fishing net mainly adopts polyethylene, the raw materials such as nylon are processed, and have longer life cycle and higher catching rate, but the mechanical property of polyethylene itself is general, hot strength is relatively low, and creep resistance is bad, results in the tradition intensity of fishing net, anti-wear performance, toughness are unsuitable at the bottom of Complex Sea and wind and waves environment fishing operation, very easily aging, reduce the service life of fishing gear, not only waste resource, also directly affect catch.
Summary of the invention
It is an object of the invention to provide a kind of antifouling aging resistance fishing net, be achieved through the following technical solutions:
A kind of antifouling aging resistance fishing net, is made up of following component: acrylic resin 1, polyethylene 130, ethylene propylene diene rubber 0.8, Colophonium 0.7, polyamide 0.9, high-boiling alcohol lignin epoxy resin 0.5, bamboo powder 0.1, nano-bentonite 0.1, glass fibre 0.3, plasticizer 1, auxiliary agent 0.1 by weight；Described auxiliary agent is the mixed extract of Herba Ranunculi Scelerati (Radix Anemones rupicolae), Herba Ranunculi Japonici, Herba Violae, Herba Pteridis Multifidae, needs 13 parts of Herba Ranunculi Scelerati (Radix Anemones rupicolae)s, 14 portions of Herba Ranunculi Japonicis, 14 portions of Herba Violaes, 16 portions of Herba Pteridis Multifidaes by weight, and preparation method is: will pulverize after selected plant cleaning-drying；Then the plant after pulverizing is put in the solution that hydrochloric acid solution mixes with ethanol, mix homogeneously, the Chlorine in Solution hydrogen that described hydrochloric acid mixes with ethanol: water: the mass ratio of ethanol is 0.1:2.2:10；Said mixture is placed in ultrasonic extraction tank, adopts every 3 minutes of the ultrasound wave of 20kHZ, 29.5kHZ frequency to substitute circulation successively and carries out extracting operation to it, it is possible to improve extraction efficiency and extraction degree greatly, after 30 minutes extracting solution；Gained extracting solution is first adopted in ammonia and hydrochloric acid, then carry out recovered alcohol, remaining solution is carried out process of anhydrating, namely can be made into required auxiliary agent.
Further, described acrylic resin is through pretreatment: by weight is acrylic resin 3 percent polysiloxane mix with acrylic resin after under 2.5MPa pressure, heating, to 162 DEG C, is incubated 30 minutes.
Further, described plasticizer is di-n-octyl sebacate and epoxyoleic acid butyl ester composite elasticizer, wherein di-n-octyl sebacate is 1:2 with the composite quality ratio of epoxyoleic acid butyl ester, combined temp is between 70-73 DEG C, the plasticizer that thus compound goes out, plasticization effect is more preferably notable, and can also improve the single line knot brute force of fishing lines.
Further, the granularity of described nano-bentonite is 25-28nm, nano-bentonite and Colophonium are through mixing pretreatment: by nano-bentonite and Colophonium Homogeneous phase mixing to together with, mixture is added in the maleic acid solution that mass fraction is 7.5%, hermetic container heats to 76-79 DEG C, and stir with 750r/min speed, after 40 minutes, remove maleic acid, and be dried.
Further, described glass fibre is short glass fiber, and glass fibre is through pretreatment: adopt the methacryloxypropyl silane of glass fibre a thirtieth weight, at 125 DEG C, glass fibre is carried out surface treatment 30 minutes.
Further, the granularity of described bamboo powder is 300-350 order, bamboo powder is through pretreatment: after the fumaric acid that bamboo powder adopts mass concentration be 5.5% soaks 30 minutes at 5-8 DEG C, filter, dry, the bamboo powder after fumaric acid processes, the compatibility between bamboo powder surface and other composition of the present invention can be improved, and antifouling property and the anti-microbial property of fishing net can also be improved, strengthen weatherability.
Further, described ethylene propylene diene rubber is through pretreatment: by weight is ethylene propylene diene rubber 1/23rd calcium sulfate crystal whiskers mix at 195 DEG C with ethylene propylene diene rubber, after being incubated 15 minutes, carry out post vulcanization process.
The preparation method of a kind of antifouling aging resistance fishing net: by weight by acrylic resin, polyethylene, ethylene propylene diene rubber, polyamide, high-boiling alcohol lignin epoxy resin glue is put in the container that temperature is 100-108 DEG C and is mixed 40 minutes, when internal tank temperature is adjusted to 70-72 DEG C, the Colophonium of corresponding weight portion it is sequentially added in container, nano-bentonite, bamboo powder and glass fibre are stirred, the speed of stirring is 680r/min, after stirring 10 minutes, add plasticizer and the auxiliary agent of corresponding weight portion again, stir 15 minutes with 1000r/min speed, finally add extruder to and carry out pelletize, then injection machine injection moulding is used, then spray webbing machine spray webbing is used, finally weave, obtain described antifouling aging resistance fishing net.
The invention has the beneficial effects as follows: the fishing net processing technique that the present invention makes is simple, by adopting, acrylic resin is carried out other composition in the pretreatment cooperation present invention, fishing net tensile strength of material can improve 39.1%, and improve the comprehensive mechanical property of fishing net, fishing net single line knot brute force can be improved, the ageing resistance coordinating the fishing net that can greatly improve making by auxiliary agent with other composition, improve the compatibility between each composition, can greatly improve bactericidal properties and the antifouling capacity of fishing net, and can greatly improve the service life of fishing net, reduce production cost；By bamboo powder, cooperate through nano-bentonite and Colophonium, the glass fibre of mixed processing, the high and low temperature resistance of fishing net can be improved, improve antifouling property and the anti-microbial property of fishing net, strengthen weatherability, fishing net toughness can improve 42.6%, fishing net fishing output is many, and can strengthen the ageing resistace of fishing net, improves its mechanical property；Fishing net of the present invention, it is possible in using for a long time, be avoided that and be subject to seawater pollution possess extremely strong ageing resistace, from without therefore have impact on fishing efficiency, it is ensured that in the service life of fishing net, reduce the cost of investment of fisherman.
Detailed description of the invention
A kind of antifouling aging resistance fishing net, is made up of following component: acrylic resin 1, polyethylene 130, ethylene propylene diene rubber 0.8, Colophonium 0.7, polyamide 0.9, high-boiling alcohol lignin epoxy resin 0.5, bamboo powder 0.1, nano-bentonite 0.1, glass fibre 0.3, plasticizer 1, auxiliary agent 0.1 by weight；Described auxiliary agent is the mixed extract of Herba Ranunculi Scelerati (Radix Anemones rupicolae), Herba Ranunculi Japonici, Herba Violae, Herba Pteridis Multifidae, needs 13 parts of Herba Ranunculi Scelerati (Radix Anemones rupicolae)s, 14 portions of Herba Ranunculi Japonicis, 14 portions of Herba Violaes, 16 portions of Herba Pteridis Multifidaes by weight, and preparation method is: will pulverize after selected plant cleaning-drying；Then the plant after pulverizing is put in the solution that hydrochloric acid solution mixes with ethanol, mix homogeneously, the Chlorine in Solution hydrogen that described hydrochloric acid mixes with ethanol: water: the mass ratio of ethanol is 0.1:2.2:10；Said mixture is placed in ultrasonic extraction tank, adopts every 3 minutes of the ultrasound wave of 20kHZ, 29.5kHZ frequency to substitute circulation successively and carries out extracting operation to it, it is possible to improve extraction efficiency and extraction degree greatly, after 30 minutes extracting solution；Gained extracting solution is first adopted in ammonia and hydrochloric acid, then carry out recovered alcohol, remaining solution is carried out process of anhydrating, namely can be made into required auxiliary agent.
Further, described acrylic resin is through pretreatment: by weight is acrylic resin 3 percent polysiloxane mix with acrylic resin after under 2.5MPa pressure, heating, to 162 DEG C, is incubated 30 minutes.
Further, described plasticizer is di-n-octyl sebacate and epoxyoleic acid butyl ester composite elasticizer, wherein di-n-octyl sebacate is 1:2 with the composite quality ratio of epoxyoleic acid butyl ester, combined temp is between 70-73 DEG C, the plasticizer that thus compound goes out, plasticization effect is more preferably notable, and can also improve the single line knot brute force of fishing lines.
Further, the granularity of described nano-bentonite is 25-28nm, nano-bentonite and Colophonium are through mixing pretreatment: by nano-bentonite and Colophonium Homogeneous phase mixing to together with, mixture is added in the maleic acid solution that mass fraction is 7.5%, hermetic container heats to 76-79 DEG C, and stir with 750r/min speed, after 40 minutes, remove maleic acid, and be dried.
Further, described glass fibre is short glass fiber, and glass fibre is through pretreatment: adopt the methacryloxypropyl silane of glass fibre a thirtieth weight, at 125 DEG C, glass fibre is carried out surface treatment 30 minutes.
Further, the granularity of described bamboo powder is 300-350 order, bamboo powder is through pretreatment: after the fumaric acid that bamboo powder adopts mass concentration be 5.5% soaks 30 minutes at 5-8 DEG C, filter, dry, the bamboo powder after fumaric acid processes, the compatibility between bamboo powder surface and other composition of the present invention can be improved, and antifouling property and the anti-microbial property of fishing net can also be improved, strengthen weatherability.
Further, described ethylene propylene diene rubber is through pretreatment: by weight is ethylene propylene diene rubber 1/23rd calcium sulfate crystal whiskers mix at 195 DEG C with ethylene propylene diene rubber, after being incubated 15 minutes, carry out post vulcanization process.
The preparation method of a kind of antifouling aging resistance fishing net: by weight by acrylic resin, polyethylene, ethylene propylene diene rubber, polyamide, high-boiling alcohol lignin epoxy resin glue is put in the container that temperature is 100-108 DEG C and is mixed 40 minutes, when internal tank temperature is adjusted to 70-72 DEG C, the Colophonium of corresponding weight portion it is sequentially added in container, nano-bentonite, bamboo powder and glass fibre are stirred, the speed of stirring is 680r/min, after stirring 10 minutes, add plasticizer and the auxiliary agent of corresponding weight portion again, stir 15 minutes with 1000r/min speed, finally add extruder to and carry out pelletize, then injection machine injection moulding is used, then spray webbing machine spray webbing is used, finally weave, obtain described antifouling aging resistance fishing net.
Claims (8)
1. an antifouling aging resistance fishing net, it is characterized in that, be made up of following component by weight: acrylic resin 1, polyethylene 130, ethylene propylene diene rubber 0.8, Colophonium 0.7, polyamide 0.9, high-boiling alcohol lignin epoxy resin 0.5, bamboo powder 0.1, nano-bentonite 0.1, glass fibre 0.3, plasticizer 1, auxiliary agent 0.1；Described auxiliary agent is the mixed extract of Herba Ranunculi Scelerati (Radix Anemones rupicolae), Herba Ranunculi Japonici, Herba Violae, Herba Pteridis Multifidae, needs 13 parts of Herba Ranunculi Scelerati (Radix Anemones rupicolae)s, 14 portions of Herba Ranunculi Japonicis, 14 portions of Herba Violaes, 16 portions of Herba Pteridis Multifidaes by weight, and preparation method is: will pulverize after selected plant cleaning-drying；Then the plant after pulverizing is put in the solution that hydrochloric acid solution mixes with ethanol, mix homogeneously, the Chlorine in Solution hydrogen that described hydrochloric acid mixes with ethanol: water: the mass ratio of ethanol is 0.1:2.2:10；Being placed in ultrasonic extraction tank by said mixture, the ultrasound wave of employing 20kHZ, 29.5kHZ frequency substitutes circulation for every 3 minutes successively to carry out extracting operation to it, obtains extracting solution after 30 minutes；Gained extracting solution is first adopted in ammonia and hydrochloric acid, then carry out recovered alcohol, remaining solution is carried out process of anhydrating, namely can be made into required auxiliary agent.
2. the antifouling aging resistance fishing net of one according to claim 1, it is characterized in that, described acrylic resin is through pretreatment: by weight is acrylic resin 3 percent polysiloxane mix with acrylic resin after under 2.5MPa pressure, heating, to 162 DEG C, is incubated 30 minutes.
3. the antifouling aging resistance fishing net of one according to claim 1, it is characterized in that, described plasticizer is di-n-octyl sebacate and epoxyoleic acid butyl ester composite elasticizer, and wherein di-n-octyl sebacate is 1:2 with the composite quality ratio of epoxyoleic acid butyl ester, and combined temp is between 70-73 DEG C.
4. the antifouling aging resistance fishing net of one according to claim 1, it is characterized in that, the granularity of described nano-bentonite is 25-28nm, nano-bentonite and Colophonium are through mixing pretreatment: by nano-bentonite and Colophonium Homogeneous phase mixing to together with, mixture is added in the maleic acid solution that mass fraction is 7.5%, heats in hermetic container to 76-79 DEG C, and stir with 750r/min speed, after 40 minutes, remove maleic acid, and be dried.
5. the antifouling aging resistance fishing net of one according to claim 1, it is characterized in that, described glass fibre is short glass fiber, and glass fibre is through pretreatment: adopt the methacryloxypropyl silane of glass fibre a thirtieth weight, at 125 DEG C, glass fibre is carried out surface treatment 30 minutes.
6. the antifouling aging resistance fishing net of one according to claim 1, it is characterized in that, the granularity of described bamboo powder is 300-350 order, and bamboo powder is through pretreatment: after the fumaric acid that bamboo powder adopts mass concentration be 5.5% soaks 30 minutes at 5-8 DEG C, filter, dry.
7. the antifouling aging resistance fishing net of one according to claim 1, it is characterized in that, described ethylene propylene diene rubber is through pretreatment: by weight is ethylene propylene diene rubber 1/23rd calcium sulfate crystal whiskers mix at 195 DEG C with ethylene propylene diene rubber, after being incubated 15 minutes, carry out post vulcanization process.
null8. the preparation method of a kind of antifouling aging resistance fishing net according to any one of claim 1-7，It is characterized in that，By weight by acrylic resin、Polyethylene、Ethylene propylene diene rubber、Polyamide、High-boiling alcohol lignin epoxy resin glue is put in the container that temperature is 100-108 DEG C and is mixed 40 minutes，When internal tank temperature is adjusted to 70-72 DEG C，The Colophonium of corresponding weight portion it is sequentially added in container、Nano-bentonite、Bamboo powder and glass fibre are stirred，The speed of stirring is 680r/min，After stirring 10 minutes，Add plasticizer and the auxiliary agent of corresponding weight portion again，Stir 15 minutes with 1000r/min speed，Finally add extruder to and carry out pelletize，Then injection machine injection moulding is used，Then spray webbing machine spray webbing is used，Finally weave，Obtain described antifouling aging resistance fishing net.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610231021.3A CN105754189A (en) | 2016-04-14 | 2016-04-14 | Anti-fouling antiaging fishing net |
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| CN201610231021.3A CN105754189A (en) | 2016-04-14 | 2016-04-14 | Anti-fouling antiaging fishing net |
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| CN201610231021.3A Pending CN105754189A (en) | 2016-04-14 | 2016-04-14 | Anti-fouling antiaging fishing net |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107099871A (en) * | 2017-05-09 | 2017-08-29 | 巢湖市翔宇渔具有限公司 | A kind of nylon 6 fishing net of high dyeing rate |
| CN107190345A (en) * | 2017-05-09 | 2017-09-22 | 巢湖市翔宇渔具有限公司 | A kind of preparation technology of long-life fishing lines monofilament |
| CN107524003A (en) * | 2017-08-18 | 2017-12-29 | 巢湖市俊业渔具有限公司 | A kind of method for strengthening fishing net weatherability |
| CN107556587A (en) * | 2017-10-19 | 2018-01-09 | 宋军华 | A kind of high-performance fishing net and preparation method thereof |
| CN110685046A (en) * | 2019-08-19 | 2020-01-14 | 浙江海洋大学 | Anti-fouling and anti-fatigue multi-strand monofilament mixed-twisted net wire and preparation method thereof |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107099871A (en) * | 2017-05-09 | 2017-08-29 | 巢湖市翔宇渔具有限公司 | A kind of nylon 6 fishing net of high dyeing rate |
| CN107190345A (en) * | 2017-05-09 | 2017-09-22 | 巢湖市翔宇渔具有限公司 | A kind of preparation technology of long-life fishing lines monofilament |
| CN107524003A (en) * | 2017-08-18 | 2017-12-29 | 巢湖市俊业渔具有限公司 | A kind of method for strengthening fishing net weatherability |
| CN107556587A (en) * | 2017-10-19 | 2018-01-09 | 宋军华 | A kind of high-performance fishing net and preparation method thereof |
| CN110685046A (en) * | 2019-08-19 | 2020-01-14 | 浙江海洋大学 | Anti-fouling and anti-fatigue multi-strand monofilament mixed-twisted net wire and preparation method thereof |
| CN110685046B (en) * | 2019-08-19 | 2022-04-22 | 浙江海洋大学 | Anti-fouling and anti-fatigue multi-strand monofilament mixed-twisted net wire and preparation method thereof |
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Application publication date: 20160713 |