CN105801980A - Fishing net prepared from ceramic powder-modified plastic - Google Patents
Fishing net prepared from ceramic powder-modified plastic Download PDFInfo
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- CN105801980A CN105801980A CN201610287598.6A CN201610287598A CN105801980A CN 105801980 A CN105801980 A CN 105801980A CN 201610287598 A CN201610287598 A CN 201610287598A CN 105801980 A CN105801980 A CN 105801980A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/20—Polyalkenes, polymers or copolymers of compounds with alkenyl groups bonded to aromatic groups
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Braiding, Manufacturing Of Bobbin-Net Or Lace, And Manufacturing Of Nets By Knotting (AREA)
Abstract
The invention discloses a fishing net prepared from ceramic powder-modified plastic. The fishing net is prepared from the following components: methyl laurate, a nylon 6 and polyvinylidene chloride mixture, polyethylene, ceramic powder, polyethylene terephthalate, medium vinyl polybutadiene rubber, polypropylene fiber, aluminum oxide powder, rosin and an assistant modifier. By combination of the advantages of the raw materials of the nylon and polyvinylidene chloride mixture, the polyethylene and the like, modified treatment is carried out by the ceramic powder as the material; auxiliary modified treatment is carried out on the raw materials by the raw materials of the aluminum oxide powder, the rosin, the assistant modifier and the like; the improved material has good mechanical property; the prepared fishing net has high strength, good tenacity and high impact resistance; the bending strength is greatly improved; especially, the tensile strength and the weather resistance are greatly improved; the service lifetime of the fishing net is 1.5 times that of an ordinary fishing net in the same complicated environment; and the tensile strength is 0.8 times that of the ordinary fishing net.
Description
Technical field
The present invention relates to fishing gear field, particularly relate to the fishing net that a kind of ceramics modified plastics is made.
Background technology
Fishing net is the net of fishing, and it is numb as raw material that men of old uses coarse cloth to add, makes fishnet by tying the method for volume.Although this fishing net is perishable, toughness is poor, but its fishing efficiency is greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.It is numb as raw material that men of old uses coarse cloth to add, by the method tying volume
Make fishnet.Although this fishing net is perishable, toughness is poor, but its fishing efficiency is greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.Modern fishing net mainly adopts polyethylene, the raw materials such as nylon are processed, there are longer life cycle and higher catching rate, but the mechanical property of polyethylene itself is general, hot strength is relatively low, creep resistance is bad, results in the tradition intensity of fishing net, anti-wear performance, toughness are unsuitable at the bottom of Complex Sea and wind and waves environment fishing operation, reduce the service life of fishing gear, not only waste resource, also directly affect catch.
Summary of the invention
It is an object of the invention to provide the fishing net that a kind of ceramics modified plastics is made, be achieved through the following technical solutions:
The fishing net that a kind of ceramics modified plastics is made, is made up of following component by weight: methyl laurate 0.7, nylon 6 and Vingon mixture 30, polyethylene 114, ceramics 0.4, polyethylene terephthalate 4, medium vinyl polybutadiene rubber 0.2, polypropylene fibre 0.3, alumina powder 0.1, Colophonium 2, auxiliary modifier 0.3；Described auxiliary modifier is made up of following component by weight: Folium Caryophylli oil 5, bentonite 1, triphenyl phosphite 1, diisononyl phthalate 3, sodium lauryl sulphate 2, Kojic Acid Dipalmitate 4, isopropyl methacrylate 3；Preparation method is calcined 18 minutes at 300 DEG C by bentonite, adopt heating in water bath to 80 DEG C Folium Caryophylli oil, triphenyl phosphite and diisononyl phthalate, then the bentonite after calcining, sodium lauryl sulphate, Kojic Acid Dipalmitate, isopropyl methacrylate are added, first stir 20 minutes with 450r/min speed, stir 15 minutes with 1000r/min speed again,；Auxiliary modifier can improve the comprehensive mechanical property of fishing net, promotes generation adhesion between each composition, improves the interfacial gluing of each one-tenth.
Further, the granularity of described ceramics is 5500-5800 order, in described ceramics, the content of half is through processing, second half is without process, it is: ceramics is carried out sonic oscillation and processes 15 minutes that then ceramics is put into mass concentration is, after soaking 3-4 hour in 6.35% cocamido propyl betaine solution, filter through processing the processing method of ceramics, washing surface, dry；Enabling to ceramic powder particles miniaturization, specific surface area increases, and improves the affinity on its surface and polyethylene, polrvinyl chloride and nylon 6.
Further, the granularity of described alumina powder is 5800-6000 order；Described bentonitic granularity is 5200-5400 order.
Further, described Colophonium is through pretreatment: after Colophonium adopting soaked in absolute ethyl alcohol 10 hours, filters, and adopts 35 DEG C of temperature to toast 1 minute.
Further, described polypropylene fibre surface processes through inorganic agent, after polypropylene fibre mixes 20 minutes with inorganic agent with inorganic agent at 68 DEG C, filters, washing, dries,；Described inorganic agent is made up of following component in percentage terms: 50% sodium laureth sulfate, 10% silane resin acceptor kh-550,40% water；Add combine between treated polypropylene fibre not only polypropylene fibre and other composition tightr, and pliability and the tensile strength of fishing net can greatly be improved.
Further, described nylon 6 and nylon in Vingon mixture 6 are be uniformly mixed at 224 DEG C by 5:2 mass ratio with Vingon.
The preparation method of the fishing net that a kind of ceramics modified plastics is made, puts into methyl laurate, nylon 6 with Vingon mixture, polyethylene, ceramics by weight in the container of temperature 144-146 DEG C and mixes 40 minutes；When internal tank temperature is adjusted to 86-88 DEG C, be sequentially added into the polyethylene terephthalate of corresponding weight portion in container, medium vinyl polybutadiene rubber, polypropylene fibre, alumina powder are stirred, the speed of stirring is 700r/min, after stirring 10 minutes, the Colophonium and the auxiliary modifier that add corresponding weight portion again stir 20 minutes with 1200r/min speed, finally add extruder to and carry out pelletize, then injection machine injection moulding is used, then spray webbing machine spray webbing is used, finally weave, obtain made fishing net.
The invention has the beneficial effects as follows: present invention incorporates nylon 6 and Vingon mixture, the advantage of the raw materials such as polyethylene, utilize ceramics that material has been carried out modification, and with alumina powder, Colophonium, material has been carried out Aided Modification process by the raw materials such as auxiliary modifier, material after improvement has good processing characteristics and mechanical performance, the fishing net intensity made is high, good toughness, strong shock resistance, antioxidation, aging resistance, fishing lines single line knotting strength is high, bending strength is improved largely, especially, tensile strength and weather resistance obtain the raising of high degree, use longer than the service life of common fishing net 1.5 times under same complicated border, tensile strength is stronger than common fishing net 0.8 times, the fishing net normal service life that the present invention makes improves 22% than common fishing net.
Detailed description of the invention
The fishing net that a kind of ceramics modified plastics is made, is made up of following component by weight: methyl laurate 0.7, nylon 6 and Vingon mixture 30, polyethylene 114, ceramics 0.4, polyethylene terephthalate 4, medium vinyl polybutadiene rubber 0.2, polypropylene fibre 0.3, alumina powder 0.1, Colophonium 2, auxiliary modifier 0.3；Described auxiliary modifier is made up of following component by weight: Folium Caryophylli oil 5, bentonite 1, triphenyl phosphite 1, diisononyl phthalate 3, sodium lauryl sulphate 2, Kojic Acid Dipalmitate 4, isopropyl methacrylate 3；Preparation method is calcined 18 minutes at 300 DEG C by bentonite, adopt heating in water bath to 80 DEG C Folium Caryophylli oil, triphenyl phosphite and diisononyl phthalate, then the bentonite after calcining, sodium lauryl sulphate, Kojic Acid Dipalmitate, isopropyl methacrylate are added, first stir 20 minutes with 450r/min speed, stir 15 minutes with 1000r/min speed again,；Auxiliary modifier can improve the comprehensive mechanical property of fishing net, promotes generation adhesion between each composition, improves the interfacial gluing of each one-tenth.
Further, the granularity of described ceramics is 5500-5800 order, in described ceramics, the content of half is through processing, second half is without process, it is: ceramics is carried out sonic oscillation and processes 15 minutes that then ceramics is put into mass concentration is, after soaking 3-4 hour in 6.35% cocamido propyl betaine solution, filter through processing the processing method of ceramics, washing surface, dry；Enabling to ceramic powder particles miniaturization, specific surface area increases, and improves the affinity on its surface and polyethylene, polrvinyl chloride and nylon 6.
Further, the granularity of described alumina powder is 5800-6000 order；Described bentonitic granularity is 5200-5400 order.
Further, described Colophonium is through pretreatment: after Colophonium adopting soaked in absolute ethyl alcohol 10 hours, filters, and adopts 35 DEG C of temperature to toast 1 minute.
Further, described polypropylene fibre surface processes through inorganic agent, after polypropylene fibre mixes 20 minutes with inorganic agent with inorganic agent at 68 DEG C, filters, washing, dries,；Described inorganic agent is made up of following component in percentage terms: 50% sodium laureth sulfate, 10% silane resin acceptor kh-550,40% water；Add combine between treated polypropylene fibre not only polypropylene fibre and other composition tightr, and pliability and the tensile strength of fishing net can greatly be improved.
Further, described nylon 6 and nylon in Vingon mixture 6 are be uniformly mixed at 224 DEG C by 5:2 mass ratio with Vingon.
The preparation method of the fishing net that a kind of ceramics modified plastics is made, puts into methyl laurate, nylon 6 with Vingon mixture, polyethylene, ceramics by weight in the container of temperature 144-146 DEG C and mixes 40 minutes；When internal tank temperature is adjusted to 86-88 DEG C, be sequentially added into the polyethylene terephthalate of corresponding weight portion in container, medium vinyl polybutadiene rubber, polypropylene fibre, alumina powder are stirred, the speed of stirring is 700r/min, after stirring 10 minutes, the Colophonium and the auxiliary modifier that add corresponding weight portion again stir 20 minutes with 1200r/min speed, finally add extruder to and carry out pelletize, then injection machine injection moulding is used, then spray webbing machine spray webbing is used, finally weave, obtain made fishing net.
Claims (7)
1. the fishing net that a ceramics modified plastics is made, it is characterized in that, be made up of following component by weight: methyl laurate 0.7, nylon 6 and Vingon mixture 30, polyethylene 114, ceramics 0.4, polyethylene terephthalate 4, medium vinyl polybutadiene rubber 0.2, polypropylene fibre 0.3, alumina powder 0.1, Colophonium 2, auxiliary modifier 0.3；Described auxiliary modifier is made up of following component by weight: Folium Caryophylli oil 5, bentonite 1, triphenyl phosphite 1, diisononyl phthalate 3, sodium lauryl sulphate 2, Kojic Acid Dipalmitate 4, isopropyl methacrylate 3；Preparation method is calcined 18 minutes at 300 DEG C by bentonite, adopt heating in water bath to 80 DEG C Folium Caryophylli oil, triphenyl phosphite and diisononyl phthalate, then the bentonite after calcining, sodium lauryl sulphate, Kojic Acid Dipalmitate, isopropyl methacrylate are added, first stir 20 minutes with 450r/min speed, stir 15 minutes with 1000r/min speed again,.
2. the fishing net that a kind of ceramics modified plastics according to claim 1 is made, it is characterized in that, the granularity of described ceramics is 5500-5800 order, in described ceramics, the content of half is through processing, and second half is without process, and the processing method through process ceramics is: ceramics carries out sonic oscillation and processes 15 minutes, then ceramics is put into mass concentration is after soaking 3-4 hour in 6.35% cocamido propyl betaine solution, filter, washing surface, dry.
3. the fishing net that a kind of ceramics modified plastics according to claim 1 is made, it is characterised in that the granularity of described alumina powder is 5800-6000 order；Described bentonitic granularity is 5200-5400 order.
4. the fishing net that a kind of ceramics modified plastics according to claim 1 is made, it is characterised in that described Colophonium is through pretreatment: after Colophonium adopting soaked in absolute ethyl alcohol 10 hours, filters, and adopts 35 DEG C of temperature to toast 1 minute.
5. the fishing net that a kind of ceramics modified plastics according to claim 1 is made, it is characterised in that described polypropylene fibre surface processes through inorganic agent, after polypropylene fibre mixes 20 minutes with inorganic agent with inorganic agent at 68 DEG C, filter, washing, dry,；Described inorganic agent is made up of following component in percentage terms: 50% sodium laureth sulfate, 10% silane resin acceptor kh-550,40% water.
6. the fishing net that a kind of ceramics modified plastics according to claim 1 is made, it is characterised in that described nylon 6 and nylon in Vingon mixture 6 are be uniformly mixed at 224 DEG C by 5:2 mass ratio with Vingon.
7. the preparation method of the fishing net that a kind of ceramics modified plastics according to any one of claim 1-6 is made, it is characterized in that, by weight methyl laurate, nylon 6 are put into Vingon mixture, polyethylene, ceramics in the container of temperature 144-146 DEG C and mix 40 minutes；When internal tank temperature is adjusted to 86-88 DEG C, be sequentially added into the polyethylene terephthalate of corresponding weight portion in container, medium vinyl polybutadiene rubber, polypropylene fibre, alumina powder are stirred, the speed of stirring is 700r/min, after stirring 10 minutes, the Colophonium and the auxiliary modifier that add corresponding weight portion again stir 20 minutes with 1200r/min speed, finally add extruder to and carry out pelletize, then injection machine injection moulding is used, then spray webbing machine spray webbing is used, finally weave, obtain made fishing net.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610287598.6A CN105801980A (en) | 2016-05-04 | 2016-05-04 | Fishing net prepared from ceramic powder-modified plastic |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610287598.6A CN105801980A (en) | 2016-05-04 | 2016-05-04 | Fishing net prepared from ceramic powder-modified plastic |
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| Publication Number | Publication Date |
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| CN105801980A true CN105801980A (en) | 2016-07-27 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610287598.6A Pending CN105801980A (en) | 2016-05-04 | 2016-05-04 | Fishing net prepared from ceramic powder-modified plastic |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108691025A (en) * | 2018-04-11 | 2018-10-23 | 巢湖市瀚海渔具有限公司 | A kind of fishing net of the ester modified far-infrared ceramic powder filled nylon of sulfonic acid |
| CN108823668A (en) * | 2018-04-11 | 2018-11-16 | 安徽省义顺渔网渔具有限公司 | A kind of method of netting twine reactive extrursion |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102251303A (en) * | 2011-05-03 | 2011-11-23 | 鑫海绳网制造有限公司 | Method for preparing trimeric high-strength and high-toughness energy-saving fishing net |
| CN102924804A (en) * | 2012-11-23 | 2013-02-13 | 重庆澳彩科鼎塑染色母有限责任公司 | Antibacterial anti-alga color master batch dedicated to fishing net and preparation method thereof |
| CN103724769A (en) * | 2013-12-11 | 2014-04-16 | 巢湖亚塑网具制造有限公司 | Nylon-reinforced fishing net |
| CN104559163A (en) * | 2014-09-13 | 2015-04-29 | 巢湖市瑞强渔具有限责任公司 | Corrosion resistant fishing line |
| CN105386156A (en) * | 2015-11-13 | 2016-03-09 | 巢湖市强力渔业有限责任公司 | High-quality fishing net |
-
2016
- 2016-05-04 CN CN201610287598.6A patent/CN105801980A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102251303A (en) * | 2011-05-03 | 2011-11-23 | 鑫海绳网制造有限公司 | Method for preparing trimeric high-strength and high-toughness energy-saving fishing net |
| CN102924804A (en) * | 2012-11-23 | 2013-02-13 | 重庆澳彩科鼎塑染色母有限责任公司 | Antibacterial anti-alga color master batch dedicated to fishing net and preparation method thereof |
| CN103724769A (en) * | 2013-12-11 | 2014-04-16 | 巢湖亚塑网具制造有限公司 | Nylon-reinforced fishing net |
| CN104559163A (en) * | 2014-09-13 | 2015-04-29 | 巢湖市瑞强渔具有限责任公司 | Corrosion resistant fishing line |
| CN105386156A (en) * | 2015-11-13 | 2016-03-09 | 巢湖市强力渔业有限责任公司 | High-quality fishing net |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108691025A (en) * | 2018-04-11 | 2018-10-23 | 巢湖市瀚海渔具有限公司 | A kind of fishing net of the ester modified far-infrared ceramic powder filled nylon of sulfonic acid |
| CN108823668A (en) * | 2018-04-11 | 2018-11-16 | 安徽省义顺渔网渔具有限公司 | A kind of method of netting twine reactive extrursion |
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Application publication date: 20160727 |