CN105801972A - Algae-preventing anti-aging fishing net - Google Patents
Algae-preventing anti-aging fishing net Download PDFInfo
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- CN105801972A CN105801972A CN201610231018.1A CN201610231018A CN105801972A CN 105801972 A CN105801972 A CN 105801972A CN 201610231018 A CN201610231018 A CN 201610231018A CN 105801972 A CN105801972 A CN 105801972A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Health & Medical Sciences (AREA)
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- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
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Abstract
The invention discloses an algae-preventing anti-aging fishing net.The algae-preventing anti-aging fishing net is prepared from ethylene-propylene-diene monomer rubber, polybutylene terephthalate, polyethylene terephthalate, zinc oxide, polyethylene, polycarbonate, perlite, glass fiber, metamorphic rocks, a plasticizer and an additive.The algae-preventing anti-aging fishing net is simple in processing technology, the tensile strength of the fishing net material can be improved by 38.5% by the adoption of ethylene-propylene-diene monomer rubber pretreatment in coordination with other components in the fishing net, the compatibility of the ethylene-propylene-diene monomer rubber and other components can be improved, the comprehensive mechanical properties of the fishing net are improved, the anti-aging ability and algae attachment preventing performance of the manufactured fishing net can be greatly improved through the coordination between the additive and other components, the service life of the fishing net can be greatly prolonged, and the production cost is reduced.The toughness and algae-preventing and anti-aging properties of the fishing net can be improved through the mutual coordination of the perlite, the glass fiber, the surface modified nano zinc oxide and the metamorphic rocks.
Description
Technical field
The present invention relates to fishing gear field, particularly relate to a kind of anti-algae aging resistance fishing net.
Background technology
Fishing net is the net of fishing, and it is numb as raw material that men of old uses coarse cloth to add, makes fishnet by tying the method for volume.Although this fishing net is perishable, toughness is poor, but its fishing efficiency is greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.It is numb as raw material that men of old uses coarse cloth to add, by the method tying volume
Make fishnet.Although this fishing net is perishable, toughness is poor, but its fishing efficiency is greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.Modern fishing net mainly adopts polyethylene, the raw materials such as nylon are processed, there is longer life cycle, higher catching rate, but the mechanical property of polyethylene itself is general, hot strength is relatively low, creep resistance is bad, result in the intensity of tradition fishing net, anti-wear performance, toughness is unsuitable at the bottom of Complex Sea and wind and waves environment fishing operation, very easily aging, reduce the service life of fishing gear, not only waste resource, also directly affect catch, and but in existing fishing net, in using for a long time, the infection being easily subject in sea water algae, the fishing efficiency thus impact is known clearly, and fishnet is infected, reduce the service life of fishing net, add the cost of investment of fisherman.
Summary of the invention
It is an object of the invention to provide a kind of anti-algae aging resistance fishing net, be achieved through the following technical solutions:
A kind of anti-algae aging resistance fishing net, is made up of following component: ethylene propylene diene rubber 0.8, polybutylene terephthalate (PBT) 0.9, polyethylene terephthalate 0.8, zinc oxide 0.2, polyethylene 120, Merlon 0.7, perlite 0.1, glass fibre 0.1, metamorphic rock 0.1, plasticizer 1, auxiliary agent 0.1 by weight；Described auxiliary agent is the mixed extract of eragrostis cilianensisLink, Herba Digitariae, Herba Taraxaci, Semen Euphorbiae, needs 13 parts of eragrostis cilianensisLinks, 14 parts of Herba Digitariae, 10 parts of Herba Taraxacis, 12 parts of Semen Euphorbiaes by weight, and preparation method is: will pulverize after selected plant cleaning-drying；Then the plant after pulverizing is put in the solution that hydrochloric acid solution mixes with ethanol, mix homogeneously, the Chlorine in Solution hydrogen that described hydrochloric acid mixes with ethanol: water: the mass ratio of ethanol is 0.1:3.8:10；Said mixture is placed in ultrasonic extraction tank, adopts every 3 minutes of the ultrasound wave of 21.5kHZ, 26.5kHZ frequency to substitute circulation successively and carries out extracting operation to it, it is possible to improve extraction efficiency and extraction degree greatly, after 30 minutes extracting solution；Gained extracting solution is first adopted in ammonia and hydrochloric acid, then carry out recovered alcohol, remaining solution is carried out process of anhydrating, namely can be made into required auxiliary agent.
Further, described ethylene propylene diene rubber is through pretreatment: by weight is ethylene propylene diene rubber 1/26th calcium sulfate crystal whiskers mix at 198 DEG C with ethylene propylene diene rubber, after being incubated 15 minutes, carry out post vulcanization process.
Further, described plasticizer is phosphate ester fatty alcohol and epoxy tetrahydro-2-ethylhexyl phthalate composite elasticizer, wherein phosphate ester fatty alcohol is 2:5 with the composite quality ratio of epoxy tetrahydro-2-ethylhexyl phthalate, combined temp is between 58-63 DEG C, the plasticizer that thus compound goes out, plasticization effect is more preferably notable, and can also improve the high and low temperature resistance of fishing lines.
Further, described zinc oxide is that to adopt zinc sulphate heptahydrate and sodium bicarbonate be the nano zine oxide that raw material is prepared, granularity is 18.5-20nm, and nano zine oxide is through surface modification treatment: mix airtight at 61-63 DEG C to nano zine oxide and liquid treating agent, and stir with 1100r/min speed, after 50 minutes, filter, dry；Described liquid treating agent is made up of 0.5% oleic acid, 11% titanate esters and 88.5% water by mass percentage.
Further, described metamorphic rock is that quartzy sandstone is formed through regional metamorphism, and deterroration is 580-640 DEG C, pressure 3-5 × 10^8Pa, and in metamorphic rock, the content of silicon dioxide is 60-65.5%.
The preparation method of a kind of anti-algae aging resistance fishing net: by weight ethylene propylene diene rubber, polybutylene terephthalate (PBT), polyethylene terephthalate, polyethylene, Merlon glue are put in the container that temperature is 105-110 DEG C and mixed 40 minutes, perlite and metamorphic rock being mixed and carrying out being ground to granularity is 6000 orders, and metamorphic rock surface processes through Silane coupling reagent KH-570；When internal tank temperature is adjusted to 70-72 DEG C, in container, it is sequentially added into the zinc oxide of corresponding weight portion, glass fibre, perlite and metamorphic rock be stirred, the speed of stirring is 620r/min, after stirring 10 minutes, then adds plasticizer and the auxiliary agent of corresponding weight portion, stir 15 minutes with 1100r/min speed, finally add extruder to and carry out pelletize, then use injection machine injection moulding, then use spray webbing machine spray webbing, finally weave, obtain described anti-algae aging resistance fishing net.
The invention has the beneficial effects as follows: the fishing net processing technique that the present invention makes is simple, by adopting, ethylene propylene diene rubber is carried out other composition in the pretreatment cooperation present invention, fishing net tensile strength of material can improve 38.5%, and improve the compatibility of itself and other composition, improve the comprehensive mechanical property of fishing net, by the auxiliary agent ageing resistance coordinating the fishing net that can greatly improve making with other composition with prevent the performance that Sargassum adheres to, and can greatly improve the service life of fishing net, reduce production cost；By perlite, glass fibre, cooperating through nano zine oxide and the metamorphic rock of surface modification, fishing net toughness can improve 42%, it is possible to strengthens anti-algae performance and the ageing resistace of fishing net, improves its mechanical property, improves the ultimate strength of fishing net.
Detailed description of the invention
A kind of anti-algae aging resistance fishing net, is made up of following component: ethylene propylene diene rubber 0.8, polybutylene terephthalate (PBT) 0.9, polyethylene terephthalate 0.8, zinc oxide 0.2, polyethylene 120, Merlon 0.7, perlite 0.1, glass fibre 0.1, metamorphic rock 0.1, plasticizer 1, auxiliary agent 0.1 by weight；Described auxiliary agent is the mixed extract of eragrostis cilianensisLink, Herba Digitariae, Herba Taraxaci, Semen Euphorbiae, needs 13 parts of eragrostis cilianensisLinks, 14 parts of Herba Digitariae, 10 parts of Herba Taraxacis, 12 parts of Semen Euphorbiaes by weight, and preparation method is: will pulverize after selected plant cleaning-drying；Then the plant after pulverizing is put in the solution that hydrochloric acid solution mixes with ethanol, mix homogeneously, the Chlorine in Solution hydrogen that described hydrochloric acid mixes with ethanol: water: the mass ratio of ethanol is 0.1:3.8:10；Said mixture is placed in ultrasonic extraction tank, adopts every 3 minutes of the ultrasound wave of 21.5kHZ, 26.5kHZ frequency to substitute circulation successively and carries out extracting operation to it, it is possible to improve extraction efficiency and extraction degree greatly, after 30 minutes extracting solution；Gained extracting solution is first adopted in ammonia and hydrochloric acid, then carry out recovered alcohol, remaining solution is carried out process of anhydrating, namely can be made into required auxiliary agent.
Further, described ethylene propylene diene rubber is through pretreatment: by weight is ethylene propylene diene rubber 1/26th calcium sulfate crystal whiskers mix at 198 DEG C with ethylene propylene diene rubber, after being incubated 15 minutes, carry out post vulcanization process.
Further, described plasticizer is phosphate ester fatty alcohol and epoxy tetrahydro-2-ethylhexyl phthalate composite elasticizer, wherein phosphate ester fatty alcohol is 2:5 with the composite quality ratio of epoxy tetrahydro-2-ethylhexyl phthalate, combined temp is between 58-63 DEG C, the plasticizer that thus compound goes out, plasticization effect is more preferably notable, and can also improve the high and low temperature resistance of fishing lines.
Further, described zinc oxide is that to adopt zinc sulphate heptahydrate and sodium bicarbonate be the nano zine oxide that raw material is prepared, granularity is 18.5-20nm, and nano zine oxide is through surface modification treatment: mix airtight at 61-63 DEG C to nano zine oxide and liquid treating agent, and stir with 1100r/min speed, after 50 minutes, filter, dry；Described liquid treating agent is made up of 0.5% oleic acid, 11% titanate esters and 88.5% water by mass percentage.
Further, described metamorphic rock is that quartzy sandstone is formed through regional metamorphism, and deterroration is 580-640 DEG C, pressure 3-5 × 10^8Pa, and in metamorphic rock, the content of silicon dioxide is 60-65.5%.
The preparation method of a kind of anti-algae aging resistance fishing net: by weight ethylene propylene diene rubber, polybutylene terephthalate (PBT), polyethylene terephthalate, polyethylene, Merlon glue are put in the container that temperature is 105-110 DEG C and mixed 40 minutes, perlite and metamorphic rock being mixed and carrying out being ground to granularity is 6000 orders, and metamorphic rock surface processes through Silane coupling reagent KH-570；When internal tank temperature is adjusted to 70-72 DEG C, in container, it is sequentially added into the zinc oxide of corresponding weight portion, glass fibre, perlite and metamorphic rock be stirred, the speed of stirring is 620r/min, after stirring 10 minutes, then adds plasticizer and the auxiliary agent of corresponding weight portion, stir 15 minutes with 1100r/min speed, finally add extruder to and carry out pelletize, then use injection machine injection moulding, then use spray webbing machine spray webbing, finally weave, obtain described anti-algae aging resistance fishing net.
Claims (6)
1. an anti-algae aging resistance fishing net, it is characterized in that, be made up of following component by weight: ethylene propylene diene rubber 0.8, polybutylene terephthalate (PBT) 0.9, polyethylene terephthalate 0.8, zinc oxide 0.2, polyethylene 120, Merlon 0.7, perlite 0.1, glass fibre 0.1, metamorphic rock 0.1, plasticizer 1, auxiliary agent 0.1；Described auxiliary agent is the mixed extract of eragrostis cilianensisLink, Herba Digitariae, Herba Taraxaci, Semen Euphorbiae, needs 13 parts of eragrostis cilianensisLinks, 14 parts of Herba Digitariae, 10 parts of Herba Taraxacis, 12 parts of Semen Euphorbiaes by weight, and preparation method is: will pulverize after selected plant cleaning-drying；Then the plant after pulverizing is put in the solution that hydrochloric acid solution mixes with ethanol, mix homogeneously, the Chlorine in Solution hydrogen that described hydrochloric acid mixes with ethanol: water: the mass ratio of ethanol is 0.1:3.8:10；Being placed in ultrasonic extraction tank by said mixture, the ultrasound wave of employing 21.5kHZ, 26.5kHZ frequency substitutes circulation for every 3 minutes successively to carry out extracting operation to it, obtains extracting solution after 30 minutes；Gained extracting solution is first adopted in ammonia and hydrochloric acid, then carry out recovered alcohol, remaining solution is carried out process of anhydrating, namely can be made into required auxiliary agent.
2. the anti-algae aging resistance fishing net of one according to claim 1, it is characterized in that, described ethylene propylene diene rubber is through pretreatment: by weight is ethylene propylene diene rubber 1/26th calcium sulfate crystal whiskers mix at 198 DEG C with ethylene propylene diene rubber, after being incubated 15 minutes, carry out post vulcanization process.
3. the anti-algae aging resistance fishing net of one according to claim 1, it is characterized in that, described plasticizer is phosphate ester fatty alcohol and epoxy tetrahydro-2-ethylhexyl phthalate composite elasticizer, wherein phosphate ester fatty alcohol is 2:5 with the composite quality ratio of epoxy tetrahydro-2-ethylhexyl phthalate, and combined temp is between 58-63 DEG C.
4. the anti-algae aging resistance fishing net of one according to claim 1, it is characterized in that, described zinc oxide is that to adopt zinc sulphate heptahydrate and sodium bicarbonate be the nano zine oxide that raw material is prepared, granularity is 18.5-20nm, and nano zine oxide is through surface modification treatment: mix airtight at 61-63 DEG C to nano zine oxide and liquid treating agent, and stir with 1100r/min speed, after 50 minutes, filter, dry；Described liquid treating agent is made up of 0.5% oleic acid, 11% titanate esters and 88.5% water by mass percentage.
5. the anti-algae aging resistance fishing net of one according to claim 1, it is characterized in that, described metamorphic rock is that quartzy sandstone is formed through regional metamorphism, and deterroration is 580-640 DEG C, pressure 3-5 × 10^8Pa, in metamorphic rock, the content of silicon dioxide is 60-65.5%.
6. the preparation method of a kind of anti-algae aging resistance fishing net according to any one of claim 1-5, it is characterized in that, by weight ethylene propylene diene rubber, polybutylene terephthalate (PBT), polyethylene terephthalate, polyethylene, Merlon glue are put in the container that temperature is 105-110 DEG C and mixed 40 minutes, perlite and metamorphic rock being mixed and carrying out being ground to granularity is 6000 orders, and metamorphic rock surface processes through Silane coupling reagent KH-570；When internal tank temperature is adjusted to 70-72 DEG C, in container, it is sequentially added into the zinc oxide of corresponding weight portion, glass fibre, perlite and metamorphic rock be stirred, the speed of stirring is 620r/min, after stirring 10 minutes, then adds plasticizer and the auxiliary agent of corresponding weight portion, stir 15 minutes with 1100r/min speed, finally add extruder to and carry out pelletize, then use injection machine injection moulding, then use spray webbing machine spray webbing, finally weave, obtain described anti-algae aging resistance fishing net.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610231018.1A CN105801972A (en) | 2016-04-14 | 2016-04-14 | Algae-preventing anti-aging fishing net |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610231018.1A CN105801972A (en) | 2016-04-14 | 2016-04-14 | Algae-preventing anti-aging fishing net |
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| CN105801972A true CN105801972A (en) | 2016-07-27 |
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| CN201610231018.1A Pending CN105801972A (en) | 2016-04-14 | 2016-04-14 | Algae-preventing anti-aging fishing net |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112553736A (en) * | 2020-11-11 | 2021-03-26 | 山东金冠网具有限公司 | Production method of reticular breathable hole yarn |
| CN114457450A (en) * | 2022-02-17 | 2022-05-10 | 山东惠民展鹏网业有限公司 | High-strength antifouling salvage net and preparation method thereof |
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| CN103739907A (en) * | 2013-11-25 | 2014-04-23 | 吴江市董鑫塑料包装厂 | LDPE fishing net filament |
| CN105367866A (en) * | 2015-10-29 | 2016-03-02 | 六安市沪渔网具有限公司 | Anti-aging fishing net |
| CN105386156A (en) * | 2015-11-13 | 2016-03-09 | 巢湖市强力渔业有限责任公司 | High-quality fishing net |
| CN105385074A (en) * | 2015-10-23 | 2016-03-09 | 巢湖市荷花渔网有限公司 | Fishing net with bactericidal and heat-resistant properties |
| CN105442086A (en) * | 2015-12-18 | 2016-03-30 | 巢湖市天宇渔具有限公司 | Anti-algae anti-aging fishing net |
-
2016
- 2016-04-14 CN CN201610231018.1A patent/CN105801972A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103739907A (en) * | 2013-11-25 | 2014-04-23 | 吴江市董鑫塑料包装厂 | LDPE fishing net filament |
| CN105385074A (en) * | 2015-10-23 | 2016-03-09 | 巢湖市荷花渔网有限公司 | Fishing net with bactericidal and heat-resistant properties |
| CN105367866A (en) * | 2015-10-29 | 2016-03-02 | 六安市沪渔网具有限公司 | Anti-aging fishing net |
| CN105386156A (en) * | 2015-11-13 | 2016-03-09 | 巢湖市强力渔业有限责任公司 | High-quality fishing net |
| CN105442086A (en) * | 2015-12-18 | 2016-03-30 | 巢湖市天宇渔具有限公司 | Anti-algae anti-aging fishing net |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112553736A (en) * | 2020-11-11 | 2021-03-26 | 山东金冠网具有限公司 | Production method of reticular breathable hole yarn |
| CN114457450A (en) * | 2022-02-17 | 2022-05-10 | 山东惠民展鹏网业有限公司 | High-strength antifouling salvage net and preparation method thereof |
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Application publication date: 20160727 |