CN105885160A - Anti-ageing fishing net - Google Patents
Anti-ageing fishing net Download PDFInfo
- Publication number
- CN105885160A CN105885160A CN201610230998.3A CN201610230998A CN105885160A CN 105885160 A CN105885160 A CN 105885160A CN 201610230998 A CN201610230998 A CN 201610230998A CN 105885160 A CN105885160 A CN 105885160A
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- fishing net
- minutes
- improved
- metamorphic rock
- ethylene propylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
Abstract
The invention discloses an anti-ageing fishing net. The fishing net is prepared from components as follows: ethylene-propylene-diene monomers, polyethylene, acrylamide, zinc oxide, methyl methacrylate, polycarbonate, talc, metamorphic rock, a plasticizer and an aid. The processing technology of the produced fishing net is simple, ethylene-propylene-diene monomers are pretreated and cooperate with other components of the fishing net, the tensile strength of the fishing net material can be increased by 37.8%, the compatibility of the ethylene-propylene-diene monomers with other components is improved, the comprehensive mechanical property of the fishing net is improved, the single-knot strength of the fishing net can be improved, the anti-ageing capability of the produced fishing net can be greatly improved through cooperation of the aid with other components, the service life of the fishing net can be greatly prolonged, and the production cost is reduced; through cooperation of talc, surface-modified nano zinc oxide and metamorphic rock, the toughness of the fishing net can be improved by 43.5%, the anti-ageing performance of the fishing net can be improved, the mechanical property of the fishing net is improved, and the breaking strength of the fishing net can be improved.
Description
Technical field
The present invention relates to fishing gear field, particularly relate to a kind of anti-aging fishing net.
Background technology
Fishing net is the net of fishing, and it is numb as raw material that men of old uses coarse cloth to add, the method rolled up by bundle makes fishnet.Although this fishing net is perishable, toughness is poor, but its fishing efficiency has been greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.Men of old uses coarse cloth to add, and fiber crops are as raw material, the method rolled up by bundle
Make fishnet.Although this fishing net is perishable, toughness is poor, but its fishing efficiency has been greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.Modern fishing net mainly uses polyethylene, the raw materials such as nylon are processed, and have longer use cycle, and higher catching rate, but the mechanical property of polyethylene itself is general, hot strength is relatively low, and creep resistance is bad, results in the tradition intensity of fishing net, anti-wear performance, toughness are unsuitable at the bottom of Complex Sea and wind and waves environment fishing operation, the most aging, reduce the service life of fishing gear, not only waste resource, also directly affect catch.
Summary of the invention
It is an object of the invention to provide a kind of anti-aging fishing net, be achieved through the following technical solutions:
A kind of anti-aging fishing net, is made up of following component: ethylene propylene diene rubber 0.8, polyethylene 127, acrylamide 0.8, zinc oxide 0.2, methyl methacrylate 0.7, Merlon 0.8, talcum 0.1, metamorphic rock 0.1, plasticizer 2, auxiliary agent 0.1 by weight；Described auxiliary agent is the mixed extract of Bermuda grass, wild oat, hispid arthraxon, moleplant seed, needs 13 parts of Bermuda grass, 14 parts of wild oats, 10 parts of hispid arthraxons, 12 parts of moleplant seeds by weight, and preparation method is: will pulverize after selected plant cleaning-drying；Then the plant after pulverizing is put in the solution that hydrochloric acid solution mixes with alcohol, mixes, the Chlorine in Solution hydrogen that described hydrochloric acid mixes with alcohol: water: the mass ratio of ethanol is 0.1:2.8:10；Said mixture is placed in ultrasonic extraction tank, uses every 3 minutes of the ultrasonic wave of 20.5kHZ, 25.5kHZ frequency to substitute circulation successively and carries out extracting operation to it, it is possible to improve extraction efficiency and extraction degree greatly, after 30 minutes extract；Gained extract is first used in ammoniacal liquor and hydrochloric acid, then carry out recovered alcohol, remaining solution is carried out process of anhydrating, i.e. can be made into required auxiliary agent.
Further, described ethylene propylene diene rubber is through pretreatment: by weight is ethylene propylene diene rubber 1/21st calcium sulfate crystal whiskers mix at 195 DEG C with ethylene propylene diene rubber, after being incubated 15 minutes, carry out post vulcanization process.
Further, described plasticizer is phosphate ester fatty alcohol and triacetin composite elasticizer, wherein phosphate ester fatty alcohol is 1:6 with the composite quality ratio of triacetin, combined temp is between 60-69 DEG C, the plasticizer being thus combined out, plasticization effect is more preferably notable, and can also improve the single line knot strength of fishing lines.
Further, described zinc oxide is that to use white vitriol and sodium acid carbonate be the nano zine oxide that raw material is prepared, granularity is 28-32nm, and nano zine oxide is through surface modification treatment: mix airtight at 62-67 DEG C to nano zine oxide and liquid treating agent, and stir with 1050r/min speed, after 50 minutes, filter, be dried；Described liquid treating agent is made up of 5% stearic acid, 5% titanate esters and 90% water by mass percentage.
Further, described metamorphic rock is that quartzy sandstone is formed through contact metasomatism metamorphism, and deterroration is 350-380 DEG C, pressure 0.5-1 × 10^8Pa, and in metamorphic rock, the content of silica is 65-68%, and metamorphic rock surface processes through Silane coupling reagent KH-570.
The preparation method of a kind of anti-aging fishing net: by weight ethylene propylene diene rubber, polyethylene, acrylamide, methyl methacrylate, Merlon glue being put in the container that temperature is 105-110 DEG C and mixed 40 minutes, talcum and metamorphic rock being mixed and carrying out being ground to granularity is 5000-5200 mesh；When container internal temperature is adjusted to 70-72 DEG C, in container, it is sequentially added into the zinc oxide of corresponding weight portion, talcum and metamorphic rock be stirred, the speed of stirring is 680r/min, after stirring 10 minutes, then adds plasticizer and the auxiliary agent of corresponding weight portion, stir 15 minutes with 1050r/min speed, finally add extruder to and carry out granulation, then use injection machine injection, then use spinneret machine spinneret, finally weave, obtain described anti-aging fishing net.
The invention has the beneficial effects as follows: the fishing net processing technology that the present invention makes is simple, by using, ethylene propylene diene rubber is carried out other composition in the pretreatment cooperation present invention, fishing net tensile strength of material can improve 37.8%, and improve the compatibility of itself and other composition, improve the comprehensive mechanical property of fishing net, fishing net single line knot strength can be improved, the ageing resistance coordinating the fishing net that can greatly improve making by auxiliary agent with other composition, and the service life of fishing net can be greatly improved, reduce production cost；By talcum, cooperating through nano zine oxide and the metamorphic rock of surface modification, fishing net toughness can improve 43.5%, it is possible to strengthens the ageing resistace of fishing net, improves its mechanical property, improves the ultimate strength of fishing net.
Detailed description of the invention
A kind of anti-aging fishing net, is made up of following component: ethylene propylene diene rubber 0.8, polyethylene 127, acrylamide 0.8, zinc oxide 0.2, methyl methacrylate 0.7, Merlon 0.8, talcum 0.1, metamorphic rock 0.1, plasticizer 2, auxiliary agent 0.1 by weight；Described auxiliary agent is the mixed extract of Bermuda grass, wild oat, hispid arthraxon, moleplant seed, needs 13 parts of Bermuda grass, 14 parts of wild oats, 10 parts of hispid arthraxons, 12 parts of moleplant seeds by weight, and preparation method is: will pulverize after selected plant cleaning-drying；Then the plant after pulverizing is put in the solution that hydrochloric acid solution mixes with alcohol, mixes, the Chlorine in Solution hydrogen that described hydrochloric acid mixes with alcohol: water: the mass ratio of ethanol is 0.1:2.8:10；Said mixture is placed in ultrasonic extraction tank, uses every 3 minutes of the ultrasonic wave of 20.5kHZ, 25.5kHZ frequency to substitute circulation successively and carries out extracting operation to it, it is possible to improve extraction efficiency and extraction degree greatly, after 30 minutes extract；Gained extract is first used in ammoniacal liquor and hydrochloric acid, then carry out recovered alcohol, remaining solution is carried out process of anhydrating, i.e. can be made into required auxiliary agent.
Further, described ethylene propylene diene rubber is through pretreatment: by weight is ethylene propylene diene rubber 1/21st calcium sulfate crystal whiskers mix at 195 DEG C with ethylene propylene diene rubber, after being incubated 15 minutes, carry out post vulcanization process.
Further, described plasticizer is phosphate ester fatty alcohol and triacetin composite elasticizer, wherein phosphate ester fatty alcohol is 1:6 with the composite quality ratio of triacetin, combined temp is between 60-69 DEG C, the plasticizer being thus combined out, plasticization effect is more preferably notable, and can also improve the single line knot strength of fishing lines.
Further, described zinc oxide is that to use white vitriol and sodium acid carbonate be the nano zine oxide that raw material is prepared, granularity is 28-32nm, and nano zine oxide is through surface modification treatment: mix airtight at 62-67 DEG C to nano zine oxide and liquid treating agent, and stir with 1050r/min speed, after 50 minutes, filter, be dried；Described liquid treating agent is made up of 5% stearic acid, 5% titanate esters and 90% water by mass percentage.
Further, described metamorphic rock is that quartzy sandstone is formed through contact metasomatism metamorphism, and deterroration is 350-380 DEG C, pressure 0.5-1 × 10^8Pa, and in metamorphic rock, the content of silica is 65-68%, and metamorphic rock surface processes through Silane coupling reagent KH-570.
The preparation method of a kind of anti-aging fishing net: by weight ethylene propylene diene rubber, polyethylene, acrylamide, methyl methacrylate, Merlon glue being put in the container that temperature is 105-110 DEG C and mixed 40 minutes, talcum and metamorphic rock being mixed and carrying out being ground to granularity is 5000-5200 mesh；When container internal temperature is adjusted to 70-72 DEG C, in container, it is sequentially added into the zinc oxide of corresponding weight portion, talcum and metamorphic rock be stirred, the speed of stirring is 680r/min, after stirring 10 minutes, then adds plasticizer and the auxiliary agent of corresponding weight portion, stir 15 minutes with 1050r/min speed, finally add extruder to and carry out granulation, then use injection machine injection, then use spinneret machine spinneret, finally weave, obtain described anti-aging fishing net.
Claims (6)
1. an anti-aging fishing net, it is characterized in that, be made up of following component by weight: ethylene propylene diene rubber 0.8, polyethylene 127, acrylamide 0.8, zinc oxide 0.2, methyl methacrylate 0.7, Merlon 0.8, talcum 0.1, metamorphic rock 0.1, plasticizer 2, auxiliary agent 0.1；Described auxiliary agent is the mixed extract of Bermuda grass, wild oat, hispid arthraxon, moleplant seed, needs 13 parts of Bermuda grass, 14 parts of wild oats, 10 parts of hispid arthraxons, 12 parts of moleplant seeds by weight, and preparation method is: will pulverize after selected plant cleaning-drying；Then the plant after pulverizing is put in the solution that hydrochloric acid solution mixes with alcohol, mixes, the Chlorine in Solution hydrogen that described hydrochloric acid mixes with alcohol: water: the mass ratio of ethanol is 0.1:2.8:10；Being placed in ultrasonic extraction tank by said mixture, the ultrasonic wave of employing 20.5kHZ, 25.5kHZ frequency substitutes circulation for every 3 minutes successively to carry out extracting operation to it, obtains extract after 30 minutes；Gained extract is first used in ammoniacal liquor and hydrochloric acid, then carry out recovered alcohol, remaining solution is carried out process of anhydrating, i.e. can be made into required auxiliary agent.
The anti-aging fishing net of one the most according to claim 1, it is characterized in that, described ethylene propylene diene rubber is through pretreatment: by weight is ethylene propylene diene rubber 1/21st calcium sulfate crystal whiskers mix at 195 DEG C with ethylene propylene diene rubber, after being incubated 15 minutes, carry out post vulcanization process.
The anti-aging fishing net of one the most according to claim 1, it is characterized in that, described plasticizer is phosphate ester fatty alcohol and triacetin composite elasticizer, and wherein phosphate ester fatty alcohol is 1:6 with the composite quality ratio of triacetin, and combined temp is between 60-69 DEG C.
The anti-aging fishing net of one the most according to claim 1, it is characterized in that, described zinc oxide is that to use white vitriol and sodium acid carbonate be the nano zine oxide that raw material is prepared, granularity is 28-32nm, and nano zine oxide is through surface modification treatment: mix airtight at 62-67 DEG C to nano zine oxide and liquid treating agent, and stir with 1050r/min speed, after 50 minutes, filter, be dried；Described liquid treating agent is made up of 5% stearic acid, 5% titanate esters and 90% water by mass percentage.
The anti-aging fishing net of one the most according to claim 1, it is characterized in that, described metamorphic rock is that quartzy sandstone is formed through contact metasomatism metamorphism, deterroration is 350-380 DEG C, pressure 0.5-1 × 10^8Pa, in metamorphic rock, the content of silica is 65-68%, and metamorphic rock surface processes through Silane coupling reagent KH-570.
6. according to the preparation method of a kind of anti-aging fishing net described in any one of claim 1-5, it is characterized in that, by weight ethylene propylene diene rubber, polyethylene, acrylamide, methyl methacrylate, Merlon glue being put in the container that temperature is 105-110 DEG C and mixed 40 minutes, talcum and metamorphic rock being mixed and carrying out being ground to granularity is 5000-5200 mesh；When container internal temperature is adjusted to 70-72 DEG C, in container, it is sequentially added into the zinc oxide of corresponding weight portion, talcum and metamorphic rock be stirred, the speed of stirring is 680r/min, after stirring 10 minutes, then adds plasticizer and the auxiliary agent of corresponding weight portion, stir 15 minutes with 1050r/min speed, finally add extruder to and carry out granulation, then use injection machine injection, then use spinneret machine spinneret, finally weave, obtain described anti-aging fishing net.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610230998.3A CN105885160A (en) | 2016-04-14 | 2016-04-14 | Anti-ageing fishing net |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610230998.3A CN105885160A (en) | 2016-04-14 | 2016-04-14 | Anti-ageing fishing net |
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| Publication Number | Publication Date |
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| CN105885160A true CN105885160A (en) | 2016-08-24 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610230998.3A Pending CN105885160A (en) | 2016-04-14 | 2016-04-14 | Anti-ageing fishing net |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103739907A (en) * | 2013-11-25 | 2014-04-23 | 吴江市董鑫塑料包装厂 | LDPE fishing net filament |
| CN105367866A (en) * | 2015-10-29 | 2016-03-02 | 六安市沪渔网具有限公司 | Anti-aging fishing net |
| CN105385074A (en) * | 2015-10-23 | 2016-03-09 | 巢湖市荷花渔网有限公司 | Fishing net with bactericidal and heat-resistant properties |
| CN105386156A (en) * | 2015-11-13 | 2016-03-09 | 巢湖市强力渔业有限责任公司 | High-quality fishing net |
-
2016
- 2016-04-14 CN CN201610230998.3A patent/CN105885160A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103739907A (en) * | 2013-11-25 | 2014-04-23 | 吴江市董鑫塑料包装厂 | LDPE fishing net filament |
| CN105385074A (en) * | 2015-10-23 | 2016-03-09 | 巢湖市荷花渔网有限公司 | Fishing net with bactericidal and heat-resistant properties |
| CN105367866A (en) * | 2015-10-29 | 2016-03-02 | 六安市沪渔网具有限公司 | Anti-aging fishing net |
| CN105386156A (en) * | 2015-11-13 | 2016-03-09 | 巢湖市强力渔业有限责任公司 | High-quality fishing net |
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Application publication date: 20160824 |