CN105754307A - Anticorrosion antibacterial fishing net - Google Patents
Anticorrosion antibacterial fishing net Download PDFInfo
- Publication number
- CN105754307A CN105754307A CN201610231024.7A CN201610231024A CN105754307A CN 105754307 A CN105754307 A CN 105754307A CN 201610231024 A CN201610231024 A CN 201610231024A CN 105754307 A CN105754307 A CN 105754307A
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- fishing net
- antibacterial
- minutes
- diene rubber
- metamorphic rock
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses an anticorrosion antibacterial fishing net, made from the following components: ethylene-propylene-diene rubber, polyethylene terephthalate, polyethylene, zinc oxide, polystyrene, epoxy resin, basalt fiber, metamorphic rock, a plasticizer and an antibacterial agent.The fishing net made herein is simple to manufacture, by pretreating the ethylene-propylene-diene rubber, it is possible to increase tensile strength of fishing net material by 35.8% and improve the mutual compatibility of the fishing net material with other components, and comprehensive mechanical properties of the fishing net is improved; by the cooperation of the antibacterial agent with the other components, antiaging and anticorrosion capacities of the manufactured fishing net can be improved greatly, the service life of the fishing net is greatly prolonged, and production cost is reduced; through the mutual cooperation of the basalt fiber, the surface-modified nano zinc oxide and the metamorphic rock, toughness of the fishing net can be improved, mechanical properties of the fishing net are improved, tension degree of the fishing net can be increased, and the quality of the fishing net is improved greatly.
Description
Technical field
The present invention relates to fishing gear field, particularly relate to a kind of anti-corrosive antibacterial fishing net.
Background technology
Fishing net is the net of fishing, and it is numb as raw material that men of old uses coarse cloth to add, makes fishnet by tying the method for volume.Although this fishing net is perishable, toughness is poor, but its fishing efficiency is greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.It is numb as raw material that men of old uses coarse cloth to add, by the method tying volume
Make fishnet.Although this fishing net is perishable, toughness is poor, but its fishing efficiency is greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.Modern fishing net mainly adopts polyethylene, the raw materials such as nylon are processed, and have longer life cycle and higher catching rate, but the mechanical property of polyethylene itself is general, hot strength is relatively low, and creep resistance is bad, results in the tradition intensity of fishing net, anti-wear performance, toughness are unsuitable at the bottom of Complex Sea and wind and waves environment fishing operation, reduce the service life of fishing gear, not only waste resource, also directly affect catch, and the anti-corruption antibacterial effect of fishing net is poor.
Summary of the invention
It is an object of the invention to provide a kind of anti-corrosive antibacterial fishing net, be achieved through the following technical solutions:
A kind of anti-corrosive antibacterial fishing net, is made up of following component: ethylene propylene diene rubber 1, polyethylene terephthalate 100, polyethylene 80, zinc oxide 0.2, polystyrene 0.5, epoxy resin 0.2, basalt fibre 0.3, metamorphic rock 0.1, plasticizer 2, antibacterial 0.4 by weight.
Further, described ethylene propylene diene rubber is through pretreatment: by weight is ethylene propylene diene rubber 1/22nd calcium sulfate crystal whiskers mix at 210 DEG C with ethylene propylene diene rubber, after being incubated 15 minutes, carry out post vulcanization process.
Further, described plasticizer is adipate ester and tributyl citrate composite elasticizer, wherein adipate ester is 5:1 with the composite quality ratio of tributyl citrate, combined temp is between 65-75 DEG C, the plasticizer that thus compound goes out, plasticization effect is more preferably notable, and can also improve the tensile property of fishing net material.
Further, described zinc oxide is that to adopt zinc sulphate heptahydrate and sodium bicarbonate be the nano zine oxide that raw material is prepared, granularity is 22-25nm, and nano zine oxide is through surface modification treatment: mix airtight at 65-70 DEG C to nano zine oxide and liquid treating agent, and stir with 1000r/min speed, after 50 minutes, filter, dry；Described liquid treating agent is made up of 1.5% palmitic acid, 10% stearic acid and 88.5% water by mass percentage.
Further, described metamorphic rock is that quartzy sandstone is formed through regional metamorphism, and deterroration is 500-650 DEG C, pressure 4-6 × 10^8Pa, and it is 5500-5600 order that metamorphic rock grinds to form granularity, and metamorphic rock surface processes through Silane coupling reagent KH-570.
Further, described antibacterial is the mixed extract of Amaranthus retroflexus, wrinkle fruit Herba Amaranthi tricoloris, Radix Scutellariae, carpet weed, needs 10 parts of Amaranthus retroflexus, 14 parts of wrinkles fruit Herba Amaranthi tricoloris, 10 parts of Radix Scutellariae, 11 parts of carpet weeds by weight, and preparation method is: will pulverize after selected plant cleaning-drying；Then the plant after pulverizing is put in the solution that hydrochloric acid solution mixes with ethanol, mix homogeneously, the Chlorine in Solution hydrogen that described hydrochloric acid mixes with ethanol: water: the mass ratio of ethanol is 0.1:2.5:10；Said mixture is placed in ultrasonic extraction tank, adopts every 3 minutes of the ultrasound wave of 21kHZ, 24kHZ frequency to substitute circulation successively and carries out extracting operation to it, it is possible to improve extraction efficiency and extraction degree greatly, after 30 minutes extracting solution；Gained extracting solution is first adopted in ammonia and hydrochloric acid, then carry out recovered alcohol, remaining solution is carried out process of anhydrating, namely can be made into required antibacterial.
The preparation method of a kind of anti-corrosive antibacterial fishing net: by weight ethylene propylene diene rubber, polyethylene terephthalate, polyethylene, polystyrene, epoxide-resin glue are put in the container that temperature is 115-120 DEG C and mixed 40 minutes；When internal tank temperature is adjusted to 75-85 DEG C, in container, it is sequentially added into the zinc oxide of corresponding weight portion, basalt fibre and metamorphic rock be stirred, the speed of stirring is 600r/min, after stirring 10 minutes, then adds plasticizer and the antibacterial of corresponding weight portion, stir 15 minutes with 1000r/min speed, finally add extruder to and carry out pelletize, then use injection machine injection moulding, then use spray webbing machine spray webbing, finally weave, obtain described anti-corrosive antibacterial fishing net.
The invention has the beneficial effects as follows: the fishing net processing technique that the present invention makes is simple, by adopting, ethylene propylene diene rubber is carried out pretreatment, fishing net tensile strength of material can improve 35.8%, and improve the mutual degrees of fusion of itself and other composition, improve the comprehensive mechanical property of fishing net, coordinating the cooperation of other composition can greatly improve the aging resistance of fishing net and the anti-corrosive antibacterial ability of making by antibacterial, thus greatly improving the service life of fishing net, reducing production cost；By basalt fibre, cooperate through nano zine oxide and the metamorphic rock of surface modification, it is possible to increase fishing net toughness, improve its mechanical property, it is possible to increase the rate of tension of fishing net, greatly improve the quality of fishing net.
Detailed description of the invention
A kind of anti-corrosive antibacterial fishing net, is made up of following component: ethylene propylene diene rubber 1, polyethylene terephthalate 100, polyethylene 80, zinc oxide 0.2, polystyrene 0.5, epoxy resin 0.2, basalt fibre 0.3, metamorphic rock 0.1, plasticizer 2, antibacterial 0.4 by weight.
Further, described ethylene propylene diene rubber is through pretreatment: by weight is ethylene propylene diene rubber 1/22nd calcium sulfate crystal whiskers mix at 210 DEG C with ethylene propylene diene rubber, after being incubated 15 minutes, carry out post vulcanization process.
Further, described plasticizer is adipate ester and tributyl citrate composite elasticizer, wherein adipate ester is 5:1 with the composite quality ratio of tributyl citrate, combined temp is between 65-75 DEG C, the plasticizer that thus compound goes out, plasticization effect is more preferably notable, and can also improve the tensile property of fishing net material.
Further, described zinc oxide is that to adopt zinc sulphate heptahydrate and sodium bicarbonate be the nano zine oxide that raw material is prepared, granularity is 22-25nm, and nano zine oxide is through surface modification treatment: mix airtight at 65-70 DEG C to nano zine oxide and liquid treating agent, and stir with 1000r/min speed, after 50 minutes, filter, dry；Described liquid treating agent is made up of 1.5% palmitic acid, 10% stearic acid and 88.5% water by mass percentage.
Further, described metamorphic rock is that quartzy sandstone is formed through regional metamorphism, and deterroration is 500-650 DEG C, pressure 4-6 × 10^8Pa, and it is 5500-5600 order that metamorphic rock grinds to form granularity, and metamorphic rock surface processes through Silane coupling reagent KH-570.
Further, described antibacterial is the mixed extract of Amaranthus retroflexus, wrinkle fruit Herba Amaranthi tricoloris, Radix Scutellariae, carpet weed, needs 10 parts of Amaranthus retroflexus, 14 parts of wrinkles fruit Herba Amaranthi tricoloris, 10 parts of Radix Scutellariae, 11 parts of carpet weeds by weight, and preparation method is: will pulverize after selected plant cleaning-drying；Then the plant after pulverizing is put in the solution that hydrochloric acid solution mixes with ethanol, mix homogeneously, the Chlorine in Solution hydrogen that described hydrochloric acid mixes with ethanol: water: the mass ratio of ethanol is 0.1:2.5:10；Said mixture is placed in ultrasonic extraction tank, adopts every 3 minutes of the ultrasound wave of 21kHZ, 24kHZ frequency to substitute circulation successively and carries out extracting operation to it, it is possible to improve extraction efficiency and extraction degree greatly, after 30 minutes extracting solution；Gained extracting solution is first adopted in ammonia and hydrochloric acid, then carry out recovered alcohol, remaining solution is carried out process of anhydrating, namely can be made into required antibacterial.
The preparation method of a kind of anti-corrosive antibacterial fishing net: by weight ethylene propylene diene rubber, polyethylene terephthalate, polyethylene, polystyrene, epoxide-resin glue are put in the container that temperature is 115-120 DEG C and mixed 40 minutes；When internal tank temperature is adjusted to 75-85 DEG C, in container, it is sequentially added into the zinc oxide of corresponding weight portion, basalt fibre and metamorphic rock be stirred, the speed of stirring is 600r/min, after stirring 10 minutes, then adds plasticizer and the antibacterial of corresponding weight portion, stir 15 minutes with 1000r/min speed, finally add extruder to and carry out pelletize, then use injection machine injection moulding, then use spray webbing machine spray webbing, finally weave, obtain described anti-corrosive antibacterial fishing net.
Claims (7)
1. an anti-corrosive antibacterial fishing net, it is characterized in that, be made up of following component by weight: ethylene propylene diene rubber 1, polyethylene terephthalate 100, polyethylene 80, zinc oxide 0.2, polystyrene 0.5, epoxy resin 0.2, basalt fibre 0.3, metamorphic rock 0.1, plasticizer 2, antibacterial 0.4.
2. a kind of anti-corrosive antibacterial fishing net according to claim 1, it is characterized in that, described ethylene propylene diene rubber is through pretreatment: by weight is ethylene propylene diene rubber 1/22nd calcium sulfate crystal whiskers mix at 210 DEG C with ethylene propylene diene rubber, after being incubated 15 minutes, carry out post vulcanization process.
3. a kind of anti-corrosive antibacterial fishing net according to claim 1, it is characterized in that, described plasticizer is adipate ester and tributyl citrate composite elasticizer, and wherein adipate ester is 5:1 with the composite quality ratio of tributyl citrate, and combined temp is between 65-75 DEG C.
4. a kind of anti-corrosive antibacterial fishing net according to claim 1, it is characterized in that, described zinc oxide is that to adopt zinc sulphate heptahydrate and sodium bicarbonate be the nano zine oxide that raw material is prepared, granularity is 22-25nm, and nano zine oxide is through surface modification treatment: mix airtight at 65-70 DEG C to nano zine oxide and liquid treating agent, and stir with 1000r/min speed, after 50 minutes, filter, dry；Described liquid treating agent is made up of 1.5% palmitic acid, 10% stearic acid and 88.5% water by mass percentage.
5. a kind of anti-corrosive antibacterial fishing net according to claim 1, it is characterized in that, described metamorphic rock is that quartzy sandstone is formed through regional metamorphism, deterroration is 500-650 DEG C, pressure 4-6 × 10^8Pa, it is 5500-5600 order that metamorphic rock grinds to form granularity, and metamorphic rock surface processes through Silane coupling reagent KH-570.
6. a kind of anti-corrosive antibacterial fishing net according to claim 1, it is characterized in that, described antibacterial is the mixed extract of Amaranthus retroflexus, wrinkle fruit Herba Amaranthi tricoloris, Radix Scutellariae, carpet weed, needing 10 parts of Amaranthus retroflexus, 14 parts of wrinkles fruit Herba Amaranthi tricoloris, 10 parts of Radix Scutellariae, 11 parts of carpet weeds by weight, preparation method is: will pulverize after selected plant cleaning-drying；Then the plant after pulverizing is put in the solution that hydrochloric acid solution mixes with ethanol, mix homogeneously, the Chlorine in Solution hydrogen that described hydrochloric acid mixes with ethanol: water: the mass ratio of ethanol is 0.1:2.5:10；Being placed in ultrasonic extraction tank by said mixture, the ultrasound wave of employing 21kHZ, 24kHZ frequency substitutes circulation for every 3 minutes successively to carry out extracting operation to it, obtains extracting solution after 30 minutes；Gained extracting solution is first adopted in ammonia and hydrochloric acid, then carry out recovered alcohol, remaining solution is carried out process of anhydrating, namely can be made into required antibacterial.
7. the preparation method of a kind of anti-corrosive antibacterial fishing net according to any one of claim 1-6, it is characterized in that, by weight ethylene propylene diene rubber, polyethylene terephthalate, polyethylene, polystyrene, epoxide-resin glue are put in the container that temperature is 115-120 DEG C and mixed 40 minutes；When internal tank temperature is adjusted to 75-85 DEG C, in container, it is sequentially added into the zinc oxide of corresponding weight portion, basalt fibre and metamorphic rock be stirred, the speed of stirring is 600r/min, after stirring 10 minutes, then add the plasticizer of corresponding weight portion and antibacterial and stir 15 minutes with 1000r/min speed, finally add extruder to and carry out pelletize, then injection machine injection moulding is used, then use spray webbing machine spray webbing, finally weave, obtain described anti-corrosive antibacterial fishing net.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610231024.7A CN105754307A (en) | 2016-04-14 | 2016-04-14 | Anticorrosion antibacterial fishing net |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610231024.7A CN105754307A (en) | 2016-04-14 | 2016-04-14 | Anticorrosion antibacterial fishing net |
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| Publication Number | Publication Date |
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| CN105754307A true CN105754307A (en) | 2016-07-13 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610231024.7A Pending CN105754307A (en) | 2016-04-14 | 2016-04-14 | Anticorrosion antibacterial fishing net |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110685032A (en) * | 2019-08-19 | 2020-01-14 | 浙江海洋大学 | Preparation method of polyethylene mesh wire monofilament with marine fouling prevention characteristic |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044861A (en) * | 2011-10-14 | 2013-04-17 | 合肥杰事杰新材料股份有限公司 | Antibacterial polybutylene terephthalate composition and preparation method thereof |
| CN103726122A (en) * | 2013-12-11 | 2014-04-16 | 巢湖市瑞强渔具有限责任公司 | Antiseptic and bactericidal fishing net |
| CN103724766A (en) * | 2013-12-11 | 2014-04-16 | 巢湖亚塑网具制造有限公司 | Fishing net for reducing marine biological pollution |
| CN104562282A (en) * | 2014-06-25 | 2015-04-29 | 巢湖市荷花渔网有限公司 | Fishing net thread suitable for being used in seawater |
-
2016
- 2016-04-14 CN CN201610231024.7A patent/CN105754307A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103044861A (en) * | 2011-10-14 | 2013-04-17 | 合肥杰事杰新材料股份有限公司 | Antibacterial polybutylene terephthalate composition and preparation method thereof |
| CN103726122A (en) * | 2013-12-11 | 2014-04-16 | 巢湖市瑞强渔具有限责任公司 | Antiseptic and bactericidal fishing net |
| CN103724766A (en) * | 2013-12-11 | 2014-04-16 | 巢湖亚塑网具制造有限公司 | Fishing net for reducing marine biological pollution |
| CN104562282A (en) * | 2014-06-25 | 2015-04-29 | 巢湖市荷花渔网有限公司 | Fishing net thread suitable for being used in seawater |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110685032A (en) * | 2019-08-19 | 2020-01-14 | 浙江海洋大学 | Preparation method of polyethylene mesh wire monofilament with marine fouling prevention characteristic |
| CN110685032B (en) * | 2019-08-19 | 2022-04-19 | 浙江海洋大学 | Preparation method of polyethylene mesh wire monofilament with marine fouling prevention characteristic |
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Application publication date: 20160713 |
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