CN105924719A - Fishing net prepared from nanometer tin antimony oxide modified plastic - Google Patents
Fishing net prepared from nanometer tin antimony oxide modified plastic Download PDFInfo
- Publication number
- CN105924719A CN105924719A CN201610287604.8A CN201610287604A CN105924719A CN 105924719 A CN105924719 A CN 105924719A CN 201610287604 A CN201610287604 A CN 201610287604A CN 105924719 A CN105924719 A CN 105924719A
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- fishing net
- tin oxide
- antimony tin
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- nano antimony
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/06—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyolefin as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/12—Applications used for fibers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a fishing net prepared from nanometer tin antimony oxide modified plastic. The fishing net is prepared from butyl acrylate, polybutylene terephthalate, polyethylene, nanometer tin antimony oxide, dilauryl thiodipropionate, epoxy resin, glass fiber, barium metaborate, peach gum and assistant modifier. The advantages of polybutylene terephthalate and polyethylene are combined, the material is modified by means of nanometer tin antimony oxide, assistant modification is conducted on the material through barium metaborate, peach gum and assistant modifier, and the improved material has high processibility and mechanical property; the prepared fishing net is high in strength, tenacity and impact resistance and resistant to thermal aging and low temperature, tensile strength and bending strength are improved greatly, and the service life of the prepared fishing net is longer than that of conventional fishing nets by 18%.
Description
Technical field
The present invention relates to fishing gear field, particularly relate to the fishing net that a kind of nano antimony tin oxide modified plastics is made.
Background technology
Fishing net is the net of fishing, and it is numb as raw material that men of old uses coarse cloth to add, the method rolled up by bundle makes fishnet.Although this fishing net is perishable, toughness is poor, but its fishing efficiency has been greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.Men of old uses coarse cloth to add, and fiber crops are as raw material, the method rolled up by bundle
Make fishnet.Although this fishing net is perishable, toughness is poor, but its fishing efficiency has been greatly improved.Along with the development of fishery, the object of fishing and hunting is more than fish, and the instrument fished for also grows with each passing hour.Modern fishing net mainly uses polyethylene, the raw materials such as nylon are processed, there are longer use cycle, and higher catching rate, but the mechanical property of polyethylene itself is general, hot strength is relatively low, creep resistance is bad, results in the tradition intensity of fishing net, anti-wear performance, toughness are unsuitable at the bottom of Complex Sea and wind and waves environment fishing operation, reduce the service life of fishing gear, not only waste resource, also directly affect catch.
Summary of the invention
It is an object of the invention to provide the fishing net that a kind of nano antimony tin oxide modified plastics is made, be achieved through the following technical solutions:
The fishing net that a kind of nano antimony tin oxide modified plastics is made, is made up of following component by weight: butyl acrylate 1, polybutylene terephthalate 30, polyethylene 110, nano antimony tin oxide 0.4, thio-2 acid double lauryl 0.5, epoxy resin 0.2, glass fibre 0.3, barium metaborate 0.1, Fructus Persicae fat 2, auxiliary modifier 0.3；Described auxiliary modifier is made up of following component by weight: clove-stems oil 5, precipitated calcium carbonate 1, Oleum Ricini 3, propylene glycol methyl ether acetate 3, benzyl acetate 2, Hexalin 4, glyceryl triacetate 3；Preparation method is to be calcined 18 minutes at 300 DEG C by precipitated calcium carbonate, use heating in water bath to 80 DEG C with propylene glycol methyl ether acetate clove-stems oil, Oleum Ricini, then the precipitated calcium carbonate after calcining, benzyl acetate, Hexalin, glyceryl triacetate are added, first stir 20 minutes with 450r/min speed, stir 15 minutes with 1000r/min speed again,；Auxiliary modifier can improve the comprehensive mechanical property of fishing net, promotes to produce between each composition adhesion, improves the interfacial gluing of each one-tenth.
Further, the granularity of described nano antimony tin oxide is 20-22nm.
Further, the granularity of described barium metaborate is 5800-6000 mesh；The granularity of described precipitated calcium carbonate is 5200-5400 mesh.
Further, described Fructus Persicae fat is through pretreatment: after Fructus Persicae fat is used soaked in absolute ethyl alcohol 10 hours, filters, and uses 35 DEG C of temperature to toast 1 minute.
Further, described fiberglass surfacing processes through inorganic agent, after glass fibre mixes 20 minutes with inorganic agent with inorganic agent at 55 DEG C, filters, washing, dries,；Described inorganic agent is made up of following component in percentage terms: 72% Methyol resorcinol, 28% itaconic acid；Add combine between treated glass fibre not only glass fibre and other composition tightr, and toughness and the tensile strength of fishing net can greatly be improved.
The preparation method of the fishing net that a kind of nano antimony tin oxide modified plastics is made, puts into butyl acrylate, polybutylene terephthalate, polyethylene, nano antimony tin oxide by weight in the container of temperature 144-146 DEG C and mixes 40 minutes；When container internal temperature is adjusted to 86-88 DEG C, be sequentially added into the double lauryl of thio-2 acid of corresponding weight portion in container, epoxy resin, glass fibre, barium metaborate are stirred, the speed of stirring is 700r/min, after stirring 10 minutes, then add the Fructus Persicae fat of corresponding weight portion and auxiliary modifier and stir 20 minutes with 1200r/min speed, finally add extruder to and carry out pelletize, then injection machine injection is used, then use spray webbing machine spray webbing, finally weave, obtain made fishing net.
The invention has the beneficial effects as follows: present invention incorporates polybutylene terephthalate, the advantage of the raw materials such as polyethylene, utilize nano antimony tin oxide that material has been carried out modification, and with barium metaborate, Fructus Persicae fat, the raw materials such as auxiliary modifier have carried out Aided Modification process to material, material after improvement has good processing characteristics and mechanical performance, the fishing net intensity made is high, good toughness, heat-proof aging, low temperature resistant, tensile strength and bending strength are all improved largely, especially shock resistance has raising greatly, stronger than the erosion-resisting characteristics of common fishing net 0.5 times, the fishing net life-span made improves 18% than common fishing net.
Detailed description of the invention
The fishing net that a kind of nano antimony tin oxide modified plastics is made, is made up of following component by weight: butyl acrylate 1, polybutylene terephthalate 30, polyethylene 110, nano antimony tin oxide 0.4, thio-2 acid double lauryl 0.5, epoxy resin 0.2, glass fibre 0.3, barium metaborate 0.1, Fructus Persicae fat 2, auxiliary modifier 0.3；Described auxiliary modifier is made up of following component by weight: clove-stems oil 5, precipitated calcium carbonate 1, Oleum Ricini 3, propylene glycol methyl ether acetate 3, benzyl acetate 2, Hexalin 4, glyceryl triacetate 3；Preparation method is to be calcined 18 minutes at 300 DEG C by precipitated calcium carbonate, use heating in water bath to 80 DEG C with propylene glycol methyl ether acetate clove-stems oil, Oleum Ricini, then the precipitated calcium carbonate after calcining, benzyl acetate, Hexalin, glyceryl triacetate are added, first stir 20 minutes with 450r/min speed, stir 15 minutes with 1000r/min speed again,.
Further, the granularity of described nano antimony tin oxide is 20-22nm.
Further, the granularity of described barium metaborate is 5800-6000 mesh；The granularity of described precipitated calcium carbonate is 5200-5400 mesh.
Further, described Fructus Persicae fat is through pretreatment: after Fructus Persicae fat is used soaked in absolute ethyl alcohol 10 hours, filters, and uses 35 DEG C of temperature to toast 1 minute.
Further, described fiberglass surfacing processes through inorganic agent, after glass fibre mixes 20 minutes with inorganic agent with inorganic agent at 55 DEG C, filters, washing, dries,；Described inorganic agent is made up of following component in percentage terms: 72% Methyol resorcinol, 28% itaconic acid.
The preparation method of the fishing net that a kind of nano antimony tin oxide modified plastics is made, puts into butyl acrylate, polybutylene terephthalate, polyethylene, nano antimony tin oxide by weight in the container of temperature 144-146 DEG C and mixes 40 minutes；When container internal temperature is adjusted to 86-88 DEG C, be sequentially added into the double lauryl of thio-2 acid of corresponding weight portion in container, epoxy resin, glass fibre, barium metaborate are stirred, the speed of stirring is 700r/min, after stirring 10 minutes, then add the Fructus Persicae fat of corresponding weight portion and auxiliary modifier and stir 20 minutes with 1200r/min speed, finally add extruder to and carry out pelletize, then injection machine injection is used, then use spray webbing machine spray webbing, finally weave, obtain made fishing net.
Claims (6)
1. the fishing net that a nano antimony tin oxide modified plastics is made, it is characterized in that, be made up of following component by weight: butyl acrylate 1, polybutylene terephthalate 30, polyethylene 110, nano antimony tin oxide 0.4, thio-2 acid double lauryl 0.5, epoxy resin 0.2, glass fibre 0.3, barium metaborate 0.1, Fructus Persicae fat 2, auxiliary modifier 0.3；Described auxiliary modifier is made up of following component by weight: clove-stems oil 5, precipitated calcium carbonate 1, Oleum Ricini 3, propylene glycol methyl ether acetate 3, benzyl acetate 2, Hexalin 4, glyceryl triacetate 3；Preparation method is to be calcined 18 minutes at 300 DEG C by precipitated calcium carbonate, use heating in water bath to 80 DEG C with propylene glycol methyl ether acetate clove-stems oil, Oleum Ricini, then the precipitated calcium carbonate after calcining, benzyl acetate, Hexalin, glyceryl triacetate are added, first stir 20 minutes with 450r/min speed, stir 15 minutes with 1000r/min speed again,.
The fishing net that a kind of nano antimony tin oxide modified plastics the most according to claim 1 is made, it is characterised in that the granularity of described nano antimony tin oxide is 20-22nm.
The fishing net that a kind of nano antimony tin oxide modified plastics the most according to claim 1 is made, it is characterised in that the granularity of described barium metaborate is 5800-6000 mesh；The granularity of described precipitated calcium carbonate is 5200-5400 mesh.
The fishing net that a kind of nano antimony tin oxide modified plastics the most according to claim 1 is made, it is characterised in that described Fructus Persicae fat is through pretreatment: after Fructus Persicae fat is used soaked in absolute ethyl alcohol 10 hours, filters, and uses 35 DEG C of temperature to toast 1 minute.
The fishing net that a kind of nano antimony tin oxide modified plastics the most according to claim 1 is made, it is characterised in that described fiberglass surfacing processes through inorganic agent, after glass fibre mixes 20 minutes with inorganic agent with inorganic agent at 55 DEG C, filter, washing, dry,；Described inorganic agent is made up of following component in percentage terms: 72% Methyol resorcinol, 28% itaconic acid.
6. the preparation method of the fishing net made according to a kind of nano antimony tin oxide modified plastics described in any one of claim 1-5, it is characterized in that, by weight butyl acrylate, polybutylene terephthalate, polyethylene, nano antimony tin oxide are put in the container of temperature 144-146 DEG C and mix 40 minutes；When container internal temperature is adjusted to 86-88 DEG C, be sequentially added into the double lauryl of thio-2 acid of corresponding weight portion in container, epoxy resin, glass fibre, barium metaborate are stirred, the speed of stirring is 700r/min, after stirring 10 minutes, then add the Fructus Persicae fat of corresponding weight portion and auxiliary modifier and stir 20 minutes with 1200r/min speed, finally add extruder to and carry out pelletize, then injection machine injection is used, then use spray webbing machine spray webbing, finally weave, obtain made fishing net.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610287604.8A CN105924719A (en) | 2016-05-04 | 2016-05-04 | Fishing net prepared from nanometer tin antimony oxide modified plastic |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610287604.8A CN105924719A (en) | 2016-05-04 | 2016-05-04 | Fishing net prepared from nanometer tin antimony oxide modified plastic |
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| Publication Number | Publication Date |
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| CN105924719A true CN105924719A (en) | 2016-09-07 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610287604.8A Pending CN105924719A (en) | 2016-05-04 | 2016-05-04 | Fishing net prepared from nanometer tin antimony oxide modified plastic |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234364A (en) * | 2020-03-27 | 2020-06-05 | 山东天海新材料工程有限公司 | High-toughness tensile-resistant geomembrane and preparation method thereof |
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|---|---|---|---|---|
| CN102251303A (en) * | 2011-05-03 | 2011-11-23 | 鑫海绳网制造有限公司 | Method for preparing trimeric high-strength and high-toughness energy-saving fishing net |
| CN102924804A (en) * | 2012-11-23 | 2013-02-13 | 重庆澳彩科鼎塑染色母有限责任公司 | Antibacterial anti-alga color master batch dedicated to fishing net and preparation method thereof |
| CN103724769A (en) * | 2013-12-11 | 2014-04-16 | 巢湖亚塑网具制造有限公司 | Nylon-reinforced fishing net |
| CN103724766A (en) * | 2013-12-11 | 2014-04-16 | 巢湖亚塑网具制造有限公司 | Fishing net for reducing marine biological pollution |
| CN103726121A (en) * | 2013-12-11 | 2014-04-16 | 巢湖市翔宇渔具有限公司 | High-strength stretch-proof fishing net |
| CN104559163A (en) * | 2014-09-13 | 2015-04-29 | 巢湖市瑞强渔具有限责任公司 | Corrosion resistant fishing line |
| CN105386156A (en) * | 2015-11-13 | 2016-03-09 | 巢湖市强力渔业有限责任公司 | High-quality fishing net |
| CN105463622A (en) * | 2015-12-24 | 2016-04-06 | 巢湖市瑞强渔具有限责任公司 | Anticorrosion antiageing fishing net |
| CN105504438A (en) * | 2015-12-24 | 2016-04-20 | 巢湖市瑞强渔具有限责任公司 | Anticorrosive and antibacterial fishing net |
-
2016
- 2016-05-04 CN CN201610287604.8A patent/CN105924719A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102251303A (en) * | 2011-05-03 | 2011-11-23 | 鑫海绳网制造有限公司 | Method for preparing trimeric high-strength and high-toughness energy-saving fishing net |
| CN102924804A (en) * | 2012-11-23 | 2013-02-13 | 重庆澳彩科鼎塑染色母有限责任公司 | Antibacterial anti-alga color master batch dedicated to fishing net and preparation method thereof |
| CN103724769A (en) * | 2013-12-11 | 2014-04-16 | 巢湖亚塑网具制造有限公司 | Nylon-reinforced fishing net |
| CN103724766A (en) * | 2013-12-11 | 2014-04-16 | 巢湖亚塑网具制造有限公司 | Fishing net for reducing marine biological pollution |
| CN103726121A (en) * | 2013-12-11 | 2014-04-16 | 巢湖市翔宇渔具有限公司 | High-strength stretch-proof fishing net |
| CN104559163A (en) * | 2014-09-13 | 2015-04-29 | 巢湖市瑞强渔具有限责任公司 | Corrosion resistant fishing line |
| CN105386156A (en) * | 2015-11-13 | 2016-03-09 | 巢湖市强力渔业有限责任公司 | High-quality fishing net |
| CN105463622A (en) * | 2015-12-24 | 2016-04-06 | 巢湖市瑞强渔具有限责任公司 | Anticorrosion antiageing fishing net |
| CN105504438A (en) * | 2015-12-24 | 2016-04-20 | 巢湖市瑞强渔具有限责任公司 | Anticorrosive and antibacterial fishing net |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111234364A (en) * | 2020-03-27 | 2020-06-05 | 山东天海新材料工程有限公司 | High-toughness tensile-resistant geomembrane and preparation method thereof |
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Application publication date: 20160907 |
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