CN107524003A - A kind of method for strengthening fishing net weatherability - Google Patents
A kind of method for strengthening fishing net weatherability Download PDFInfo
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- CN107524003A CN107524003A CN201710709924.2A CN201710709924A CN107524003A CN 107524003 A CN107524003 A CN 107524003A CN 201710709924 A CN201710709924 A CN 201710709924A CN 107524003 A CN107524003 A CN 107524003A
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- fishing net
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- weatherability
- soak
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- 238000000034 method Methods 0.000 title claims abstract description 28
- 238000005728 strengthening Methods 0.000 title claims abstract description 10
- 239000011248 coating agent Substances 0.000 claims abstract description 40
- 238000000576 coating method Methods 0.000 claims abstract description 40
- 238000007654 immersion Methods 0.000 claims abstract description 13
- 238000011017 operating method Methods 0.000 claims abstract description 8
- 238000001035 drying Methods 0.000 claims abstract description 6
- 230000002708 enhancing effect Effects 0.000 claims abstract description 6
- 239000002270 dispersing agent Substances 0.000 claims description 21
- 239000013530 defoamer Substances 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 15
- -1 oxypropylene glycerin Chemical class 0.000 claims description 12
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 11
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 10
- LRRJQNMXIDXNIM-UHFFFAOYSA-M benzyl(trimethyl)azanium;iodide Chemical compound [I-].C[N+](C)(C)CC1=CC=CC=C1 LRRJQNMXIDXNIM-UHFFFAOYSA-M 0.000 claims description 10
- 239000000839 emulsion Substances 0.000 claims description 10
- CMZUMMUJMWNLFH-UHFFFAOYSA-N sodium metavanadate Chemical compound [Na+].[O-][V](=O)=O CMZUMMUJMWNLFH-UHFFFAOYSA-N 0.000 claims description 10
- UYCAUPASBSROMS-AWQJXPNKSA-M sodium;2,2,2-trifluoroacetate Chemical compound [Na+].[O-][13C](=O)[13C](F)(F)F UYCAUPASBSROMS-AWQJXPNKSA-M 0.000 claims description 10
- 229910000166 zirconium phosphate Inorganic materials 0.000 claims description 10
- HXITXNWTGFUOAU-UHFFFAOYSA-N phenylboronic acid Chemical compound OB(O)C1=CC=CC=C1 HXITXNWTGFUOAU-UHFFFAOYSA-N 0.000 claims description 9
- 238000003756 stirring Methods 0.000 claims description 9
- 239000001177 diphosphate Substances 0.000 claims description 8
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 claims description 8
- 150000003585 thioureas Chemical class 0.000 claims description 8
- 238000009736 wetting Methods 0.000 claims description 6
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 4
- MDFFNEOEWAXZRQ-UHFFFAOYSA-N aminyl Chemical compound [NH2] MDFFNEOEWAXZRQ-UHFFFAOYSA-N 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 230000000996 additive effect Effects 0.000 claims description 3
- OVRQXQSDQWOJIL-UHFFFAOYSA-N 1,1-dibutylthiourea Chemical compound CCCCN(C(N)=S)CCCC OVRQXQSDQWOJIL-UHFFFAOYSA-N 0.000 claims description 2
- OSCBARYHPZZEIS-UHFFFAOYSA-N phenoxyboronic acid Chemical class OB(O)OC1=CC=CC=C1 OSCBARYHPZZEIS-UHFFFAOYSA-N 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 238000005336 cracking Methods 0.000 description 10
- 230000000052 comparative effect Effects 0.000 description 5
- 125000004494 ethyl ester group Chemical group 0.000 description 4
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 4
- 235000012239 silicon dioxide Nutrition 0.000 description 4
- XQRLCLUYWUNEEH-UHFFFAOYSA-N diphosphonic acid Chemical compound OP(=O)OP(O)=O XQRLCLUYWUNEEH-UHFFFAOYSA-N 0.000 description 3
- 239000004677 Nylon Substances 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/47—Oxides or hydroxides of elements of Groups 5 or 15 of the Periodic Table; Vanadates; Niobates; Tantalates; Arsenates; Antimonates; Bismuthates
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/207—Substituted carboxylic acids, e.g. by hydroxy or keto groups; Anhydrides, halides or salts thereof
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- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/282—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
- D06M13/292—Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
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- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
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- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
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Abstract
The present invention discloses a kind of method for strengthening fishing net weatherability, including following operating procedure:(1)After fishing net is put into soak into immersion treatment 23 hours, taking-up is dried up with air-heater;(2)Fishing net is put into coating after the 30min of immersion treatment 20, after taking out air-heater drying, finished product.The method of enhancing fishing net weatherability provided by the invention, simple to operate, cost is cheap, safety and environmental protection, obtained fishing net, every excellent in mechanical performance, good weatherability.
Description
Technical field
The invention belongs to fishing net preparing technical field, and in particular to a kind of method for strengthening fishing net weatherability.
Background technology
Fishing net, the net of fishing, specific purpose tool is fished, more than 99% is process with synthetic fibers.Mainly have nylon 6 or
Monofilament, multifilament or the multiple monofilament of modification of nylon, the fibers such as polyethylene, polyester, Vingon can also be used.Presently commercially available is general
The weatherability of logical fishing net is poor, and in being exposed to the sun with after immersion for a long time for the sun, the phenomenon being cracked easily occurs in its surface, and easily
Discoloration, intensity step-down, the service life of fishing net is shorter, and then adds culture fishery and the cost of fishery.
The content of the invention
In order to solve the above-mentioned technical problem, the present invention provides a kind of method for strengthening fishing net weatherability.
The present invention is achieved by the following technical solutions.
A kind of method for strengthening fishing net weatherability, including following operating procedure:
(1)Fishing net is put into soak after immersion treatment 2-3 hours, taking-up is dried up with air-heater, and wherein soak is by following
The component of parts by weight is made:Benzyltrimethylammonium iodide 9-12 parts, sodium vanadate 5-8 parts, sodium trifluoroacetate 6-10 parts, water 150-
180 parts;
(2)Fishing net is put into coating after immersion treatment 20-30min, after taking out air-heater drying, finished product, wherein coating
It is made up of the component of following parts by weight:Acrylic emulsion 38-46 parts, N, N- dibutyl thiourea 6-10 parts, 4- amyl group phenyl boric acids 7-
9 parts, hydroxy ethylidene-diphosphate 1-2 parts, silester 3-6 parts, hmds 5-10 parts, dispersant 2-5 parts, defoamer
3-6 parts.
Specifically, above-mentioned soak is made of following methods:Sodium vanadate is added into water, after being completely dissolved, after
It is continuous to add benzyltrimethylammonium iodide, sodium trifluoroacetate thereto, after persistently stirring 10min using 300r/min rotating speed, system
Obtain soak.
Specifically, above-mentioned dispersant is the high wetting dispersing agent of coating additive 760W, OMG 0755 of enlightening, wetting dispersing agent
Any one in DH-CF10.
Specifically, above-mentioned defoamer is polypropylene glycerol aether, one kind of polyoxyethylene polyoxy propyl alcohol amidogen ether.
Specifically, above-mentioned coating is made of following methods:Dispersant, defoamer are added into acrylic emulsion, mixed
After conjunction stirs, N, N- dibutyl thioureas, 4- amyl groups phenyl boric acid, hydroxy ethylidene-diphosphate, silicic acid are added thereto successively
Ethyl ester, hmds, after being mixed evenly, coating is made.
Technical scheme more than, the beneficial effects of the invention are as follows:
The method of enhancing fishing net weatherability provided by the invention, simple to operate, cost is cheap, safety and environmental protection, obtained fishing net, respectively
Item excellent in mechanical performance, good weatherability.Wherein, soak provided by the invention, the intermolecular effect of fishing net can effectively be strengthened
Power, prevent that chain rupture and the phenomenon decomposed occurs to fishing net in its internal molecular structure after heated and long-time is soaked;The present invention carries
The coating of confession, there is extremely excellent high temperature resistant and water soak resistance energy, be less prone to the phenomenon of cracking, effectively extend fishing net
Service life, and 4- amyl groups phenyl boric acid in coating, hydroxy ethylidene-diphosphate synergy can effectively lift coating
Antifouling property, prevent microorganisms in water fishing net surface multiply reproduction.
Embodiment
In order to make the purpose , technical scheme and advantage of the present invention be clearer, following examples are carried out to the present invention
It is further described.It should be appreciated that specific embodiment party example described herein is not used to limit only to explain the present invention
The fixed present invention.
Embodiment 1
A kind of method for strengthening fishing net weatherability, including following operating procedure:
(1)After fishing net is put into soak into immersion treatment 2 hours, taking-up is dried up with air-heater, and wherein soak is by following heavy
The component of amount part is made:9 parts of benzyltrimethylammonium iodide, 5 parts of sodium vanadate, 6 parts of sodium trifluoroacetate, 150 parts of water;
(2)Fishing net is put into coating after immersion treatment 20min, take out air-heater drying after, finished product, wherein coating by with
The component of lower parts by weight is made:38 parts of acrylic emulsion, N, 6 parts of N- dibutyl thioureas, 7 parts of 4- amyl groups phenyl boric acid, hydroxyl Asia second
1 part of base diphosphonic acid, 3 parts of silester, 5 parts of hmds, 2 parts of dispersant, 3 parts of defoamer.
Specifically, above-mentioned soak is made of following methods:Sodium vanadate is added into water, after being completely dissolved, after
It is continuous to add benzyltrimethylammonium iodide, sodium trifluoroacetate thereto, after persistently stirring 10min using 300r/min rotating speed, system
Obtain soak.
Specifically, above-mentioned dispersant is the high coating additive 760W of enlightening.
Specifically, above-mentioned defoamer is polypropylene glycerol aether.
Specifically, above-mentioned coating is made of following methods:Dispersant, defoamer are added into acrylic emulsion, mixed
After conjunction stirs, N, N- dibutyl thioureas, 4- amyl groups phenyl boric acid, hydroxy ethylidene-diphosphate, silicic acid are added thereto successively
Ethyl ester, hmds, after being mixed evenly, coating is made.
Embodiment 2
A kind of method for strengthening fishing net weatherability, including following operating procedure:
(1)After fishing net is put into soak into immersion treatment 2.5 hours, taking-up is dried up with air-heater, and wherein soak is by following
The component of parts by weight is made:11 parts of benzyltrimethylammonium iodide, 7 parts of sodium vanadate, 8 parts of sodium trifluoroacetate, 170 parts of water;
(2)Fishing net is put into coating after immersion treatment 25min, take out air-heater drying after, finished product, wherein coating by with
The component of lower parts by weight is made:42 parts of acrylic emulsion, N, 8 parts of N- dibutyl thioureas, 8 parts of 4- amyl groups phenyl boric acid, hydroxyl Asia second
1 part of base diphosphonic acid, 5 parts of silester, 8 parts of hmds, 3 parts of dispersant, 5 parts of defoamer.
Specifically, above-mentioned soak is made of following methods:Sodium vanadate is added into water, after being completely dissolved, after
It is continuous to add benzyltrimethylammonium iodide, sodium trifluoroacetate thereto, after persistently stirring 10min using 300r/min rotating speed, system
Obtain soak.
Specifically, above-mentioned dispersant is the wetting dispersing agents of OMG 0755.
Specifically, above-mentioned defoamer is polyoxyethylene polyoxy propyl alcohol amidogen ether.
Specifically, above-mentioned coating is made of following methods:Dispersant, defoamer are added into acrylic emulsion, mixed
After conjunction stirs, N, N- dibutyl thioureas, 4- amyl groups phenyl boric acid, hydroxy ethylidene-diphosphate, silicic acid are added thereto successively
Ethyl ester, hmds, after being mixed evenly, coating is made.
Embodiment 3
A kind of method for strengthening fishing net weatherability, including following operating procedure:
(1)After fishing net is put into soak into immersion treatment 3 hours, taking-up is dried up with air-heater, and wherein soak is by following heavy
The component of amount part is made:12 parts of benzyltrimethylammonium iodide, 8 parts of sodium vanadate, 10 parts of sodium trifluoroacetate, 180 parts of water;
(2)Fishing net is put into coating after immersion treatment 30min, take out air-heater drying after, finished product, wherein coating by with
The component of lower parts by weight is made:46 parts of acrylic emulsion, N, 10 parts of N- dibutyl thioureas, 9 parts of 4- amyl groups phenyl boric acid, hydroxyl Asia second
2 parts of base diphosphonic acid, 6 parts of silester, 10 parts of hmds, 5 parts of dispersant, 6 parts of defoamer.
Specifically, above-mentioned soak is made of following methods:Sodium vanadate is added into water, after being completely dissolved, after
It is continuous to add benzyltrimethylammonium iodide, sodium trifluoroacetate thereto, after persistently stirring 10min using 300r/min rotating speed, system
Obtain soak.
Specifically, above-mentioned dispersant is wetting dispersing agent DH-CF10.
Specifically, above-mentioned defoamer is polyoxyethylene polyoxy propyl alcohol amidogen ether.
Specifically, above-mentioned coating is made of following methods:Dispersant, defoamer are added into acrylic emulsion, mixed
After conjunction stirs, N, N- dibutyl thioureas, 4- amyl groups phenyl boric acid, hydroxy ethylidene-diphosphate, silicic acid are added thereto successively
Ethyl ester, hmds, after being mixed evenly, coating is made.
Comparative example 1
Step(1)In soak be clear water, remaining operating procedure is identical with embodiment 1.
Comparative example 2
Step(2)In coating be commercially available common coating, remaining operating procedure is identical with embodiment 2.
Fishing net is made with the method for each embodiment and comparative example respectively, obtained fishing net is placed under the sun be exposed to the sun respectively
Soaked 30 days in 60 days and water, check whether fishing net face coat occurs crack performance, result of the test is as shown in table 1:
The weatherability of the fishing net of table 1
Project | It is exposed to the sun under the sun 60 days | Soaked 30 days in water |
Embodiment 1 | Coating no cracking | Coating no cracking |
Comparative example 1 | Coating is slightly cracked | Coating cracking is serious |
Embodiment 2 | Coating no cracking | Coating no cracking |
Comparative example 2 | Coating cracking is serious | Coating cracking is serious |
Embodiment 3 | Coating no cracking | Coating no cracking |
Coating produced by the present invention, there is excellent resistance to bubble and resistance to performance of being exposed to the sun, service life length, quality better.
Certainly, it is limitation of the present invention that described above, which is not, and the present invention is also not limited to the example above, the art
Those of ordinary skill, the present invention essential scope in, change, change, addition or the replacement made, should all belong to the present invention
Protection domain.
Claims (5)
- A kind of 1. method for strengthening fishing net weatherability, it is characterised in that including following operating procedure:(1)Fishing net is put into soak after immersion treatment 2-3 hours, taking-up is dried up with air-heater, and wherein soak is by following The component of parts by weight is made:Benzyltrimethylammonium iodide 9-12 parts, sodium vanadate 5-8 parts, sodium trifluoroacetate 6-10 parts, water 150- 180 parts;(2)Fishing net is put into coating after immersion treatment 20-30min, after taking out air-heater drying, finished product, wherein coating It is made up of the component of following parts by weight:Acrylic emulsion 38-46 parts, N, N- dibutyl thiourea 6-10 parts, 4- amyl group phenyl boric acids 7- 9 parts, hydroxy ethylidene-diphosphate 1-2 parts, silester 3-6 parts, hmds 5-10 parts, dispersant 2-5 parts, defoamer 3-6 parts.
- 2. according to a kind of method of enhancing fishing net weatherability described in claim 1, it is characterised in that above-mentioned soak uses Following methods are made:Sodium vanadate is added into water, after being completely dissolved, continue thereto add benzyltrimethylammonium iodide, Sodium trifluoroacetate, after persistently stirring 10min using 300r/min rotating speed, soak is made.
- 3. according to a kind of method of enhancing fishing net weatherability described in claim 1, it is characterised in that above-mentioned dispersant is Any one in the high wetting dispersing agent of coating additive 760W, OMG 0755 of enlightening, wetting dispersing agent DH-CF10.
- 4. according to a kind of method of enhancing fishing net weatherability described in claim 1, it is characterised in that above-mentioned defoamer is poly- One kind of oxypropylene glycerin ether, polyoxyethylene polyoxy propyl alcohol amidogen ether.
- 5. according to a kind of method of enhancing fishing net weatherability described in claim 1, it is characterised in that above-mentioned coating use with Lower section method is made:Dispersant, defoamer are added into acrylic emulsion, after being mixed evenly, add N thereto successively, N- dibutyl thioureas, 4- amyl groups phenyl boric acid, hydroxy ethylidene-diphosphate, silester, hmds, mix equal After even, coating is made.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710709924.2A CN107524003A (en) | 2017-08-18 | 2017-08-18 | A kind of method for strengthening fishing net weatherability |
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CN109137501A (en) * | 2018-08-03 | 2019-01-04 | 巢湖市渔郎渔具有限公司 | A kind of method that plasma promotes fishing net wettability |
CN109162085A (en) * | 2018-08-03 | 2019-01-08 | 巢湖市渔郎渔具有限公司 | The preparation method of wear-resisting trawlnet is used in a kind of seawater |
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