CN108797123A - A kind of polythene fishing net wear-resistant antibacterial coating - Google Patents
A kind of polythene fishing net wear-resistant antibacterial coating Download PDFInfo
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- CN108797123A CN108797123A CN201810706247.3A CN201810706247A CN108797123A CN 108797123 A CN108797123 A CN 108797123A CN 201810706247 A CN201810706247 A CN 201810706247A CN 108797123 A CN108797123 A CN 108797123A
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- kaolin
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic System; Zincates; Cadmates
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/77—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
- D06M11/79—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
Abstract
The invention discloses a kind of polythene fishing net wear-resistant antibacterial coating, by adding kaolin-ZnOw-nano silver wear-resistant antibacterial agent into coating, improve wear-resisting, anti-aging, antistatic, antibacterial the performance of coating, applied to polythene fishing net, it not only can preferably be adsorbed on fishing net, but also enhance the wear-resistant antibacterial of fishing net, effectively prevent the biodeterioration problem of fishing net, extend the service life of fishing net simultaneously, it is cost-effective.
Description
Technical field
The invention belongs to technical field of coatings, and in particular to a kind of polythene fishing net wear-resistant antibacterial coating.
Background technology
Recently as the rapid growth of world population, culture fishery also rapidly develops.However aquaculture also faces
Serious biodeterioration problem.Some organic matters and macromolecular adhere to absorption on netting cage first, form initial item
Part film, some subsequent bacteriums, fungi and algae are adhered to, and then some large-scale sea-plants and marine animal etc. carry out attached
It, grow and breeds, ultimately form complicated marine fouling organism group, this will certainly reduce dictyosome product, reduce the penetrating of net
Property, increase the weight of net, cause flow switching congestion, oxygen supply insufficient, seriously affect the quality of aquaculture organism, in some instances it may even be possible to
The death for leading to institute's aquaculture organism causes huge economic loss.Therefore, square biological attachment first has to be held back from source
System, i.e., will improve the anti-microbial property of fishing net, also, netting cage is due to often carrying out use of exposing to the weather, wear-resisting property
It is faced with test.
Invention content
In view of the above-mentioned problems, the present invention is intended to provide a kind of for polythene fishing net, there is good wearability and anti-
The fishing-net composition of bacterium property.
The invention is realized by the following technical scheme：
A kind of polythene fishing net wear-resistant antibacterial coating, by acrylic resin, high chlorinated polyethylene resin, chlorosulfonated polyethylene tree
One or more in fat is base-material, adds dispersant, pigment, antifoaming agent, anti-settling agent and is obtained by dispersion, abrasive material, further includes
Mass fraction is kaolin-ZnOw-nano silver wear-resistant antibacterial agent of 10-20%, and the preparation method of the antiseptic is：
（1）5-10 parts of ZnOws are dispersed in the acetone of 10-30 times of its volume, 50-60 DEG C of temperature is kept, and are utilized super
Sonication 20-40min, then takes out, and after distilled water flushing, is added in modification liquid, is aided with ultraviolet light, in 30-50
DEG C, confined reaction 3-5h under 600-1200rpm rotating speeds, after filter, and dry, obtain in 70-90 DEG C of vacuum drying chamber
Modified zinc oxide whisker, wherein modification liquid are：50-60 parts of polyvinyl resin lotions, 2-3 parts of silane coupling agents, 1-2 parts of dodecanes
Base benzene sulfonic acid sodium salt, 10-20 part silver ammino solution；
（2）10-20 parts of kaolin are put into freeze drying box, after -20~-30 DEG C of low temperature drying 2-4h, put into calcining
In stove, 30-50min first is calcined at 350-400 DEG C, then heats to 500-550 DEG C, continued to calcine 40-60min, then drop
Temperature takes out natural cooling, and carry out ball milling to 300-350 DEG C, isothermal holding 30-40min, until granularity is 100-1000 μm；
（3）By step（2）Gained kaolin and step（1）Gained modified zinc oxide whisker is dispersed in the two of 10-20 times of its volume
In methyl sulfoxide solution, it is passed through nitrogen protection, is warming up to 60-80 DEG C, reaction 5- is mixed with the rotating speed of 500-800rpm
Then 10h is filtered, rinsed 3-5 times repeatedly with distilled water, ethyl alcohol, and in 50-70 DEG C of drying in oven, is ground to 200-
500 mesh sieve to get kaolin-ZnOw-nano silver wear-resistant antibacterial agent.
Further, step（1）The supersound process condition is 60-80Hz, 800-1500W.
Further, step（1）The a length of 315-400nm of ultraviolet light wave.
Further, step（1）The polyvinyl resin emulsion solid content is 30-40%.
Beneficial effects of the present invention：The present invention is wear-resisting anti-by adding kaolin-ZnOw-nano silver into coating
Microbial inoculum improves wear-resisting, anti-aging, antistatic, antibacterial the performance of coating, is applied to polythene fishing net, not only can be preferable
Be adsorbed on fishing net, and enhance the wear-resistant antibacterial of fishing net, effectively prevent the biodeterioration problem of fishing net, same to time delay
The service life of long fishing net, it is cost-effective；By ZnOw by the modification of modification liquid, zinc oxide crystalline substance is not only increased
It must improve the adhesive force of coating and polythene fishing net in the dispersibility and compatibility in paint-based bottom, enhance the wearability of coating
Can, meanwhile, the silver ammino solution in modification liquid generates uniform fine and closely woven nano-silver ionic, is attached to oxygen under the irradiation of ultraviolet light
Change zinc whisker surface, there is significant anti-microbial property, while also providing attachment point, further enhance ZnOw and base
The binding force at bottom；By kaolin by a series of processing after, it is more loose between layers, it is soft, be conducive to zinc oxide crystalline substance
The compound insertion of palpus-nano-ag composite, meanwhile, improve adhesive force of the coating on fishing net；By ZnOw-nano silver
Compound is inserted into kaolinic interlayer structure, not only makes each component fusion even closer, provides wearability, be uniformly dispersed simultaneously,
Avoid the generation of sedimentation phenomenon.
Specific implementation mode
Illustrate the present invention with specific embodiment below, but is not limitation of the present invention.
Embodiment 1
A kind of polythene fishing net wear-resistant antibacterial coating, by acrylic resin, high chlorinated polyethylene resin, chlorosulfonated polyethylene tree
One or more in fat is base-material, adds dispersant, pigment, antifoaming agent, anti-settling agent and is obtained by dispersion, abrasive material, further includes
Kaolin-ZnOw-nano silver wear-resistant antibacterial agent that mass fraction is 10%, the preparation method of the antiseptic are：
（1）5 parts of ZnOws are dispersed in the acetone of 10 times of its volume, keep temperature 50 C, and utilize supersound process
20min then takes out, and after distilled water flushing, is added in modification liquid, is aided with ultraviolet light, in 30 DEG C, 600rpm rotating speeds
Lower confined reaction 3h, after filter, and dried in 70 DEG C of vacuum drying chamber, obtain modified zinc oxide whisker, wherein modified
Liquid is：50 parts of polyvinyl resin lotions, 2 parts of silane coupling agents, 1 part of neopelex, 10 parts of silver ammino solutions；
（2）10 parts of kaolin are put into freeze drying box, after -20 DEG C of low temperature drying 2h, are put into calcining furnace, are first existed
30min is calcined at 350 DEG C, then heats to 500 DEG C, continues to calcine 40min, is then cooled to 300 DEG C, isothermal holding 30min,
Natural cooling is taken out, and carries out ball milling, until granularity is 100 μm；
（3）By step（2）Gained kaolin and step（1）Gained modified zinc oxide whisker is dispersed in the dimethyl of 10 times of its volume
In sulfoxide solution, it is passed through nitrogen protection, is warming up to 60 DEG C, reaction 5h is mixed with the rotating speed of 500rpm, is then filtered, with steaming
Distilled water, ethyl alcohol rinse 3 times repeatedly, and in 50 DEG C of drying in oven, it is brilliant to get kaolin-zinc oxide to be ground to 200 mesh sieve
The wear-resistant antibacterial agent of palpus-nano silver.
Further, step（1）The supersound process condition is 60Hz, 800W.
Further, step（1）The a length of 315nm of ultraviolet light wave.
Further, step（1）The polyvinyl resin emulsion solid content is 30%.
Embodiment 2
A kind of polythene fishing net wear-resistant antibacterial coating, by acrylic resin, high chlorinated polyethylene resin, chlorosulfonated polyethylene tree
One or more in fat is base-material, adds dispersant, pigment, antifoaming agent, anti-settling agent and is obtained by dispersion, abrasive material, further includes
Kaolin-ZnOw-nano silver wear-resistant antibacterial agent that mass fraction is 15%, the preparation method of the antiseptic are：
（1）7 parts of ZnOws are dispersed in the acetone of 20 times of its volume, keep 55 DEG C of temperature, and utilize supersound process
30min then takes out, and after distilled water flushing, is added in modification liquid, is aided with ultraviolet light, in 40 DEG C, 800rpm rotating speeds
Lower confined reaction 4h, after filter, and dried in 80 DEG C of vacuum drying chamber, obtain modified zinc oxide whisker, wherein modified
Liquid is：55 parts of polyvinyl resin lotions, 3 parts of silane coupling agents, 2 parts of neopelexes, 15 parts of silver ammino solutions；
（2）15 parts of kaolin are put into freeze drying box, after -25 DEG C of low temperature drying 3h, are put into calcining furnace, are first existed
40min is calcined at 380 DEG C, then heats to 530 DEG C, continues to calcine 50min, is then cooled to 320 DEG C, isothermal holding 35min,
Natural cooling is taken out, and carries out ball milling, until granularity is 500 μm；
（3）By step（2）Gained kaolin and step（1）Gained modified zinc oxide whisker is dispersed in the dimethyl of 15 times of its volume
In sulfoxide solution, it is passed through nitrogen protection, is warming up to 70 DEG C, reaction 8h is mixed with the rotating speed of 700rpm, is then filtered, with steaming
Distilled water, ethyl alcohol rinse 4 times repeatedly, and in 60 DEG C of drying in oven, it is brilliant to get kaolin-zinc oxide to be ground to 300 mesh sieve
The wear-resistant antibacterial agent of palpus-nano silver.
Further, step（1）The supersound process condition is 70Hz, 1000W.
Further, step（1）The a length of 350nm of ultraviolet light wave.
Further, step（1）The polyvinyl resin emulsion solid content is 35%.
Embodiment 3
A kind of polythene fishing net wear-resistant antibacterial coating, by acrylic resin, high chlorinated polyethylene resin, chlorosulfonated polyethylene tree
One or more in fat is base-material, adds dispersant, pigment, antifoaming agent, anti-settling agent and is obtained by dispersion, abrasive material, further includes
Kaolin-ZnOw-nano silver wear-resistant antibacterial agent that mass fraction is 20%, the preparation method of the antiseptic are：
（1）10 parts of ZnOws are dispersed in the acetone of 30 times of its volume, keep temperature 60 C, and utilize supersound process
40min then takes out, and after distilled water flushing, is added in modification liquid, is aided with ultraviolet light, turns in 50 DEG C, 1200rpm
The lower confined reaction 5h of speed, after filter, and dried in 90 DEG C of vacuum drying chamber, modified zinc oxide whisker obtained, wherein changing
Property liquid is：60 parts of polyvinyl resin lotions, 3 parts of silane coupling agents, 2 parts of neopelexes, 20 parts of silver ammino solutions；
（2）20 parts of kaolin are put into freeze drying box, after -30 DEG C of low temperature drying 4h, are put into calcining furnace, are first existed
50min is calcined at 400 DEG C, then heats to 550 DEG C, continues to calcine 60min, is then cooled to 350 DEG C, isothermal holding 40min,
Natural cooling is taken out, and carries out ball milling, until granularity is 100 μm；
（3）By step（2）Gained kaolin and step（1）Gained modified zinc oxide whisker is dispersed in the dimethyl of 20 times of its volume
In sulfoxide solution, it is passed through nitrogen protection, is warming up to 80 DEG C, reaction 10h is mixed with the rotating speed of 800rpm, then filters, uses
Distilled water, ethyl alcohol rinse 5 times repeatedly, and in 70 DEG C of drying in oven, are ground to 500 mesh sieve to get kaolin-zinc oxide
Whisker-nano silver wear-resistant antibacterial agent.
Further, step（1）The supersound process condition is 80Hz, 1500W.
Further, step（1）The a length of 400nm of ultraviolet light wave.
Further, step（1）The polyvinyl resin emulsion solid content is 40%.
Comparative example 1
The addition of kaolin-ZnOw-nano silver wear-resistant antibacterial agent is omitted compared to embodiment 1 in this comparative example.
Comparative example 2
The modification of ZnOw is omitted compared to embodiment 1 in this comparative example, and method and step in addition to this is equal
It is identical.
Comparative example 3
Step is omitted compared to embodiment 1 in this comparative example（3）Operation processing step, method and step in addition to this
All same.
Experiment：
Adhesive force is tested：Polythene fishing net doubling 20 times back and forth that each group coating will be coated with and be completely dried, visually observe fishing net:
Coating is without falling off on cable, flawless, then it is assumed that adhesive force is 1 grade, the slight crackle of film, without falling off, then it is assumed that adhesive force 2
Grade, coating fall off on a small quantity, then it is assumed that adhesive force is 3 grades, and coating crack falls off obviously, then it is assumed that adhesive force is 4 grades.
Anti-halobios adhersion is tested：The polythene fishing net for being coated with each group coating and being completely dried is subjected to real extra large linked network or reality
After the net cage application of border, anti-halobios adhersion performance test is examined, sea organism attachment area is less than 10%, it is believed that antifouling paint is effective,
Anti-halobios adhersion performance is indicated with effect of antifouling phase.
Flexibility：Film flexibility is tested using GB/T 1731-93 film flexibility measuring methods.
Hardness：It is tested by pencil hardness GB/T6379-1996.
Its test result is as shown in table 1：
Table 1
| Antifouling phase effect（Month） | Flexibility/mm | Hardness（H） | Adhesive force（Grade） | |
| Embodiment 1 | 15 | 2 | 4 | 1 |
| Embodiment 2 | 15 | 2 | 4 | 1 |
| Embodiment 3 | 15 | 2 | 4 | 1 |
| Comparative example 1 | 4 | 0.5 | 1 | 4 |
| Comparative example 2 | 6 | 1 | 2 | 3 |
| Comparative example 3 | 8 | 1 | 2 | 3 |
As can be seen from Table 1, the present invention is by the way that kaolin-ZnOw of preparation-nano silver wear-resistant antibacterial agent to be added to
In coating, after carrying out application to polythene fishing net, the anti-halobios adhersion of fishing net is significantly improved, while coating and fishing net is attached
Put forth effort well, flexibility, hardness are improved, and service life extends.
Claims (4)
1. a kind of polythene fishing net wear-resistant antibacterial coating, by acrylic resin, high chlorinated polyethylene resin, chlorosulfonated polyethylene
One or more in resin is base-material, adds dispersant, pigment, antifoaming agent, anti-settling agent and is obtained by dispersion, abrasive material, special
Sign is, further includes kaolin-ZnOw-nano silver wear-resistant antibacterial agent that mass fraction is 10-20%, the antiseptic
Preparation method be：
（1）5-10 parts of ZnOws are dispersed in the acetone of 10-30 times of its volume, 50-60 DEG C of temperature is kept, and are utilized super
Sonication 20-40min, then takes out, and after distilled water flushing, is added in modification liquid, is aided with ultraviolet light, in 30-50
DEG C, confined reaction 3-5h under 600-1200rpm rotating speeds, after filter, and dry, obtain in 70-90 DEG C of vacuum drying chamber
Modified zinc oxide whisker, wherein modification liquid are：50-60 parts of polyvinyl resin lotions, 2-3 parts of silane coupling agents, 1-2 parts of dodecanes
Base benzene sulfonic acid sodium salt, 10-20 part silver ammino solution；
（2）10-20 parts of kaolin are put into freeze drying box, after -20~-30 DEG C of low temperature drying 2-4h, put into calcining
In stove, 30-50min first is calcined at 350-400 DEG C, then heats to 500-550 DEG C, continued to calcine 40-60min, then drop
Temperature takes out natural cooling, and carry out ball milling to 300-350 DEG C, isothermal holding 30-40min, until granularity is 100-1000 μm；
（3）By step（2）Gained kaolin and step（1）Gained modified zinc oxide whisker is dispersed in the two of 10-20 times of its volume
In methyl sulfoxide solution, it is passed through nitrogen protection, is warming up to 60-80 DEG C, reaction 5- is mixed with the rotating speed of 500-800rpm
Then 10h is filtered, rinsed 3-5 times repeatedly with distilled water, ethyl alcohol, and in 50-70 DEG C of drying in oven, is ground to 200-
500 mesh sieve to get kaolin-ZnOw-nano silver wear-resistant antibacterial agent.
2. kaolin-ZnOw according to claim 1-nano silver wear-resistant antibacterial agent preparation method, feature exist
In step（1）The supersound process condition is 60-80Hz, 800-1500W.
3. kaolin-ZnOw according to claim 1-nano silver wear-resistant antibacterial agent preparation method, feature exist
In step（1）The a length of 315-400nm of ultraviolet light wave.
4. kaolin-ZnOw according to claim 1-nano silver wear-resistant antibacterial agent preparation method, feature exist
In step（1）The polyvinyl resin emulsion solid content is 30-40%.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810706247.3A CN108797123A (en) | 2018-07-02 | 2018-07-02 | A kind of polythene fishing net wear-resistant antibacterial coating |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810706247.3A CN108797123A (en) | 2018-07-02 | 2018-07-02 | A kind of polythene fishing net wear-resistant antibacterial coating |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112779791A (en) * | 2020-12-29 | 2021-05-11 | 南京博普思睿医疗科技有限公司 | Environment-friendly biomass bacteriostatic wear-resisting agent and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533074A (en) * | 2010-12-20 | 2012-07-04 | 海洋化工研究院 | Aqueous fishing net antifouling paint and preparation method thereof |
| CN104017409A (en) * | 2014-06-18 | 2014-09-03 | 杜一挺 | Antibacterial coating and preparation method thereof |
-
2018
- 2018-07-02 CN CN201810706247.3A patent/CN108797123A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102533074A (en) * | 2010-12-20 | 2012-07-04 | 海洋化工研究院 | Aqueous fishing net antifouling paint and preparation method thereof |
| CN104017409A (en) * | 2014-06-18 | 2014-09-03 | 杜一挺 | Antibacterial coating and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112779791A (en) * | 2020-12-29 | 2021-05-11 | 南京博普思睿医疗科技有限公司 | Environment-friendly biomass bacteriostatic wear-resisting agent and preparation method thereof |
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Application publication date: 20181113 |