CN108049215A - A kind of fishing net colouring method - Google Patents
A kind of fishing net colouring method Download PDFInfo
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- CN108049215A CN108049215A CN201711294164.XA CN201711294164A CN108049215A CN 108049215 A CN108049215 A CN 108049215A CN 201711294164 A CN201711294164 A CN 201711294164A CN 108049215 A CN108049215 A CN 108049215A
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- fishing net
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/02—Material containing basic nitrogen
- D06P3/04—Material containing basic nitrogen containing amide groups
- D06P3/24—Polyamides; Polyurethanes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/62—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds with sulfate, sulfonate, sulfenic or sulfinic groups
- D06P1/621—Compounds without nitrogen
- D06P1/622—Sulfonic acids or their salts
- D06P1/623—Aliphatic, aralophatic or cycloaliphatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/642—Compounds containing nitrogen
- D06P1/647—Nitrogen-containing carboxylic acids or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65131—Compounds containing ether or acetal groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
- D06P1/67333—Salts or hydroxides
- D06P1/6735—Salts or hydroxides of alkaline or alkaline-earth metals with anions different from those provided for in D06P1/67341
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/22—Effecting variation of dye affinity on textile material by chemical means that react with the fibre
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of fishing net colouring method, including：（1）Activating solution processing；（2）Dyeing；（3）Drying；The present invention is by handling fishing net using the activating solution prepared, effectively the dye of positive ion can effectively be attracted during dyeing, and combine to form ionic bond, improve the combination power of dyestuff, it can be in the more carboxyls of fishing net Surface Creation and amino groups, so that treated fishing net and the hydroxyl on dye molecule, amino etc. is complexed, utilize this characteristic, during fishing net dyes, adsorptivity between dye molecule and fishing net significantly increases, dye-uptake and colour fixation are improved so as to reach, the present invention can solve fishing net dyeing and easily uneven dyeing occurs, dyeing flower, aberration, the problem of color defect, improve dye utilization rate and dyefastness, reduce dyeing process risk.
Description
Technical field
The invention belongs to fishing net staining technique fields, and in particular to a kind of fishing net colouring method.
Background technology
Fishing net is fishing net, and modern fishing net is mainly processed using the raw materials such as polyethylene, nylon, there is longer make
With cycle and higher catching rate, the fishing net using nylon or polyethylene as material preparation apply it is more and more, according to market
Demand, need to carry out different dyeing to fishing net and handle, improve its performance, but when existing fishing net dyes, to fishing
The dyeing rate of net is relatively low, and the entire dyeing course duration is long, and dyefastness is low, fugitive color, especially the building ring of fishing net
Border is not only that fresh water environment also has briny environment, and the working time is longer, and long period of soaking easily causes fishing in fresh water or seawater
Net is a large amount of to fade.
The content of the invention
The purpose of the present invention is being directed to the problem of existing, a kind of fishing net colouring method is provided.
The present invention is achieved by the following technical solutions：
A kind of fishing net colouring method dyes fishing net using the dye of positive ion, which comprises the following steps：
(1) activating solution is handled：Fishing net is put into activating solution and carries out initial immersion 30-40min, boiling is then heated to, keeps the temperature
15-20min, then 60 DEG C are adjusted the temperature to, it when heat preservation 2 is small, after ultrasonication 3-5min, is filtered, surface uses clear water
Washing, naturally dry；The activating solution is made by weight of following component：Sodium carbonate 3-5, furfural 2-4, potassium pyrophosphate 1-
3rd, dipotassium tetraborate 1.2-1.6, ammonium acid fluoride 1.3-1.5, neopelex 3-5, glycine 0.25-0.38, L- paddy ammonia
Sour 0.22-0.26, deionized water 100；
（2）Normal temperature state is by step（1）Treated, and fishing net is added in overflow dyeing machine, adds water, fully impregnates 25-30min, adds in
Citric acid solution adjusts pH to 4.5-5.0, stirs 30min, the dye of positive ion stirring 15min fully dissolved is added, with 2
DEG C/rate of 5s is warming up to 55 DEG C, keeps the temperature 30min, is then warming up to 78 DEG C at the same rate again, keep the temperature 45min, then with
The rate reduction temperature of 2 DEG C/5s keeps the temperature 30min, then takes out to 42 DEG C；
（3）In temperature to dry at 105 DEG C, cooled to room temperature to get.
Further, the step（1）Middle ultrasonic power is 850W, frequency 45kHz.
Further, the step（1）The middle initial soaking temperature of activating solution is 40 DEG C.
Further, the step（2）Middle citric acid solution mass fraction is 15%.
Further, the step（2）The middle dye of positive ion is conjugated cation dyestuff.
Further, the step（3）In in temperature to dry at 105 DEG C, drying time 30min.
The present invention has the following advantages compared with prior art：The present invention is by using at the activating solution prepared fishing net
Reason, effectively can effectively attract the dye of positive ion during dyeing, and combine to form ionic bond, improve
The combination power of dyestuff, can be in the more carboxyls of fishing net Surface Creation and amino groups so that treated fishing net can be with
Hydroxyl, amino on dye molecule etc. are complexed, and utilize this characteristic, during fishing net dyes, dye molecule and fishing
Adsorptivity between net significantly increases, and improves dye-uptake and colour fixation so as to reach, the present invention can solve fishing net dye
Easily there is the problem of uneven dyeing, dyeing flower, aberration, color defect in color, improves dye utilization rate and dyefastness, reduces dyeing process wind
Danger.
Specific embodiment
Embodiment 1
A kind of fishing net colouring method dyes fishing net using the dye of positive ion, which comprises the following steps：
(1) activating solution is handled：Fishing net is put into activating solution and carries out initial immersion 30min, boiling is then heated to, keeps the temperature
15min, then 60 DEG C are adjusted the temperature to, when heat preservation 2 is small, after ultrasonication 3min, it is filtered, surface is washed using clear water,
Naturally dry；The activating solution is made by weight of following component：Sodium carbonate 3, furfural 2, potassium pyrophosphate 1, dipotassium tetraborate
1.2nd, ammonium acid fluoride 1.3, neopelex 3, glycine 0.25, Pidolidone 0.22, deionized water 100；
（2）Normal temperature state is by step（1）Treated, and fishing net is added in overflow dyeing machine, adds water, fully impregnates 25min, adds in lemon
Lemon acid solution adjusts pH to 4.5, stirs 30min, the dye of positive ion stirring 15min fully dissolved is added, with 2 DEG C/5s's
Rate is warming up to 55 DEG C, keeps the temperature 30min, is then warming up to 78 DEG C at the same rate again, keeps the temperature 45min, then with 2 DEG C/5s
Rate reduction temperature to 42 DEG C, keep the temperature 30min, then take out；
（3）In temperature to dry at 105 DEG C, cooled to room temperature to get.
Further, the step（1）Middle ultrasonic power is 850W, frequency 45kHz.
Further, the step（1）The middle initial soaking temperature of activating solution is 40 DEG C.
Further, the step（2）Middle citric acid solution mass fraction is 15%.
Further, the step（2）The middle dye of positive ion is conjugated cation dyestuff.
Further, the step（3）In in temperature to dry at 105 DEG C, drying time 30min.
Embodiment 2
A kind of fishing net colouring method dyes fishing net using the dye of positive ion, which comprises the following steps：
(1) activating solution is handled：Fishing net is put into activating solution and carries out initial immersion 40min, boiling is then heated to, keeps the temperature
20min, then 60 DEG C are adjusted the temperature to, when heat preservation 2 is small, after ultrasonication 5min, it is filtered, surface is washed using clear water,
Naturally dry；The activating solution is made by weight of following component：Sodium carbonate 5, furfural 4, potassium pyrophosphate 3, dipotassium tetraborate
1.6th, ammonium acid fluoride 1.5, neopelex 5, glycine 0.38, Pidolidone 0.26, deionized water 100；
（2）Normal temperature state is by step（1）Treated, and fishing net is added in overflow dyeing machine, adds water, fully impregnates 30min, adds in lemon
Lemon acid solution adjusts pH to 5.0, stirs 30min, the dye of positive ion stirring 15min fully dissolved is added, with 2 DEG C/5s's
Rate is warming up to 55 DEG C, keeps the temperature 30min, is then warming up to 78 DEG C at the same rate again, keeps the temperature 45min, then with 2 DEG C/5s
Rate reduction temperature to 42 DEG C, keep the temperature 30min, then take out；
（3）In temperature to dry at 105 DEG C, cooled to room temperature to get.
Further, the step（1）Middle ultrasonic power is 850W, frequency 45kHz.
Further, the step（1）The middle initial soaking temperature of activating solution is 40 DEG C.
Further, the step（2）Middle citric acid solution mass fraction is 15%.
Further, the step（2）The middle dye of positive ion is conjugated cation dyestuff.
Further, the step（3）In in temperature to dry at 105 DEG C, drying time 30min.
Embodiment 3
A kind of fishing net colouring method dyes fishing net using the dye of positive ion, which comprises the following steps：
(1) activating solution is handled：Fishing net is put into activating solution and carries out initial immersion 35min, boiling is then heated to, keeps the temperature
18min, then 60 DEG C are adjusted the temperature to, when heat preservation 2 is small, after ultrasonication 3-5min, it is filtered, surface is washed using clear water
It washs, naturally dry；The activating solution is made by weight of following component：Sodium carbonate 4, furfural 3, potassium pyrophosphate 2, tetraboric acid
Potassium 1.5, ammonium acid fluoride 1.4, neopelex 4, glycine 0.26, Pidolidone 0.24, deionized water 100；
（2）Normal temperature state is by step（1）Treated, and fishing net is added in overflow dyeing machine, adds water, fully impregnates 28min, adds in lemon
Lemon acid solution adjusts pH to 4.6, stirs 30min, the dye of positive ion stirring 15min fully dissolved is added, with 2 DEG C/5s's
Rate is warming up to 55 DEG C, keeps the temperature 30min, is then warming up to 78 DEG C at the same rate again, keeps the temperature 45min, then with 2 DEG C/5s
Rate reduction temperature to 42 DEG C, keep the temperature 30min, then take out；
（3）In temperature to dry at 105 DEG C, cooled to room temperature to get.
Further, the step（1）Middle ultrasonic power is 850W, frequency 45kHz.
Further, the step（1）The middle initial soaking temperature of activating solution is 40 DEG C.
Further, the step（2）Middle citric acid solution mass fraction is 15%.
Further, the step（2）The middle dye of positive ion is conjugated cation dyestuff.
Further, the step（3）In in temperature to dry at 105 DEG C, drying time 30min.
Comparative example 1：It is differed only in embodiment 1 without step（1）Processing.
Comparative example 2：Step is differed only in embodiment 1（1）Dipotassium tetraborate and ammonium acid fluoride are not added in middle activating solution.
Experiment：Embodiment is respectively adopted to dye the nylon fishing net that same quality of lot is 500g with comparative example method, adopts
Dyeing stoste optical density is tested with ultraviolet specrophotometer, dye liquor raffinate absorbance is recorded, records each time of half dyeing：
Time of half dyeing：Time of half dyeing is to reach the equilibrium adsorption capacity half required time to dyestuff on fishing net, and time of half dyeing is
A very important performance indicator of fishing net is contaminated on dyestuff, time of half dyeing is shorter, and dyestuff dyeing rate is faster；
Table 1
| Time of half dyeing | |
| Embodiment 1 | 9min20s |
| Embodiment 2 | 9min22s |
| Embodiment 3 | 9min25s |
| Comparative example 1 | 12min38s |
| Comparative example 2 | 10min45s |
As can be seen from Table 1, the fishing net time of half dyeing dyed by the method for the present invention greatly reduces；
Fishing net after being dyed to above-mentioned experiment carries out washing fastness test, is graded using standard grey scale, as a result such as table
2：
Table 2
| Colour fading fastness/grade | Staining fastness/grade | |
| Embodiment 1 | 5 | 4 |
| Embodiment 2 | 5 | 4 |
| Embodiment 3 | 5 | 4 |
| Comparative example 1 | 3 | 2 |
| Comparative example 2 | 4 | 3 |
As can be seen from Table 2, by the pretreated fishing net dyefastness higher of the present invention.
Claims (6)
1. a kind of fishing net colouring method, which is characterized in that dyed using the dye of positive ion to fishing net, which includes
Following steps：
(1) activating solution is handled：Fishing net is put into activating solution and carries out initial immersion 30-40min, boiling is then heated to, keeps the temperature
15-20min, then 60 DEG C are adjusted the temperature to, it when heat preservation 2 is small, after ultrasonication 3-5min, is filtered, surface uses clear water
Washing, naturally dry；The activating solution is made by weight of following component：Sodium carbonate 3-5, furfural 2-4, potassium pyrophosphate 1-
3rd, dipotassium tetraborate 1.2-1.6, ammonium acid fluoride 1.3-1.5, neopelex 3-5, glycine 0.25-0.38, L- paddy ammonia
Sour 0.22-0.26, deionized water 100；
（2）Normal temperature state is by step（1）Treated, and fishing net is added in overflow dyeing machine, adds water, fully impregnates 25-30min, adds in
Citric acid solution adjusts pH to 4.5-5.0, stirs 30min, the dye of positive ion stirring 15min fully dissolved is added, with 2
DEG C/rate of 5s is warming up to 55 DEG C, keeps the temperature 30min, is then warming up to 78 DEG C at the same rate again, keep the temperature 45min, then with
The rate reduction temperature of 2 DEG C/5s keeps the temperature 30min, then takes out to 42 DEG C；
（3）In temperature to dry at 105 DEG C, cooled to room temperature to get.
A kind of 2. fishing net colouring method as described in claim 1, which is characterized in that the step（1）Middle ultrasonic power is
850W, frequency 45kHz.
A kind of 3. fishing net colouring method as described in claim 1, which is characterized in that the step（1）Middle activating solution initially soaks
It is 40 DEG C to steep temperature.
A kind of 4. fishing net colouring method as described in claim 1, which is characterized in that the step（2）Middle citric acid solution matter
It is 15% to measure fraction.
A kind of 5. fishing net colouring method as described in claim 1, which is characterized in that the step（2）The middle dye of positive ion is
Conjugated cation dyestuff.
A kind of 6. fishing net colouring method as described in claim 1, which is characterized in that the step（3）In temperature be 105 DEG C
Lower drying, drying time 30min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711294164.XA CN108049215A (en) | 2017-12-08 | 2017-12-08 | A kind of fishing net colouring method |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711294164.XA CN108049215A (en) | 2017-12-08 | 2017-12-08 | A kind of fishing net colouring method |
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| Publication Number | Publication Date |
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| CN108049215A true CN108049215A (en) | 2018-05-18 |
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ID=62122608
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| CN201711294164.XA Pending CN108049215A (en) | 2017-12-08 | 2017-12-08 | A kind of fishing net colouring method |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109024001A (en) * | 2018-08-03 | 2018-12-18 | 巢湖市渔郎渔具有限公司 | A method of improving fishing net dyeing efficiency |
| CN109098021A (en) * | 2018-06-28 | 2018-12-28 | 巢湖市荷花渔网有限公司 | A kind of efficient dyeing of fishing net |
| CN110093790A (en) * | 2019-04-30 | 2019-08-06 | 巢湖市翔宇渔具有限公司 | A kind of method of fishing net natural pigment dyeing |
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| CN109098021A (en) * | 2018-06-28 | 2018-12-28 | 巢湖市荷花渔网有限公司 | A kind of efficient dyeing of fishing net |
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