A kind of method for improving the fishing net dyeability of nylon 6
Technical field
The invention belongs to fishing net staining technique field, and in particular to a kind of method of the fishing net dyeability of raising nylon 6.
Background technology
Fishing net is the net of fishing, and modern fishing net mainly uses polyethylene, and the raw material such as nylon is processed, and has longer make
It is the more and more of fishing net application prepared by material with nylon 6 with cycle, and higher catching rate, according to the demand in market,
The fishing net of nylon 6 is needed to carry out different dyeing processing, its performance is improved, but the fishing net dyeing of existing nylon 6,
The dyeability of the fishing net of nylon 6 is general, during dyed on dye amount it is relatively low, dye levels are shallow.
The content of the invention
The purpose of the present invention is that there is provided a kind of method for improving the fishing net dyeability of nylon 6 the problem of being directed to existing.
The present invention is achieved by the following technical solutions:
It is a kind of improve the fishing net dyeability of nylon 6 method, to the master batch of nylon 6 carry out activation process after, then will be through overactivation at
The fishing net of nylon 6 is made in the master batch of nylon 6 after reason, and then the fishing net of nylon 6 being made is preheated, then to the nylon 6 after preheating
Fishing net carries out Low Temperature Plasma Treating, then using the immersion of grape pip extract solution, is then dried, you can carry out at dyeing
Reason.
Further, it is described to be specially to the master batch of nylon 6 progress activation process:The master batch of nylon 6 and deionized water are pressed 1:
12-15 mass ratios are uniformly mixed, and are then added the alum of the master batch quality 1.2% of nylon 6, are added in mixer
40min is stirred under 1200r/min rotating speeds, then the pH of suspension is adjusted to 8.8-9.2 using ammoniacal liquor, 90 DEG C are heated to, with
After 120r/min rotating speeds stirring 30min, using 350W ultrasonication 10-12min, then the master batch quality 0.08% of nylon 6 is added
Ammonium persulfate, after stirring, 15-18min is incubated at 72 DEG C, is then filtered, be dried at 60 DEG C to constant weight,
.
Further, the master batch of nylon 6 by after activation process is made the fishing net of nylon 6 and is specially:At activation
The master batch of nylon 6 melting extrusion, cooling preliminary draft, drafting forming, winding, line processed, knitmesh in an extruder after reason, is made nylon
6 fishing nets.
Further, the described pair of fishing net of nylon 6 being made is preheated, and is specially:The fishing net of nylon 6 is placed on air phase
To humidity in 70-75% environment, environment temperature is raised to 65-68 DEG C with 1 DEG C/min speed, 40min is incubated, you can.
Further, the fishing net of nylon 6 after described pair of preheating enters Low Temperature Plasma Treating:By the fishing net of nylon 6 using low
Isothermal plasma is handled, and processing gas is carbon dioxide, and operating pressure is 100Pa, and processing power is 180W, processing time
For 20-25s, you can.
Further, the grape pip extraction liquid and preparation method thereof is:Grape pip and camellia seed are pressed 10:1 mass ratio is mixed
It is combined together, smashs to pieces, then using 80% concentration of volume percent alcohol solvent, by solid-liquid ratio 1:20, flow back and carry at 60 DEG C
3h is taken, supernatant is centrifuged to obtain, then by rotary evaporation concentration, be then freeze-dried and solid extract is made, by solid extract
By 1:40 mass ratios are uniformly admixed together for 0.1% sodium hydroxide solution with mass fraction, produce.
Further, it is specially using the immersion of grape pip extract solution:The fishing net of nylon 6 is put into grape pip extract solution
Soak 2 hours, then take out at 40-50 DEG C, you can.
The present invention has advantages below compared with prior art:By the activation process to the master batch of nylon 6, it can significantly improve
The structural behaviour of the master batch of nylon 6 so that dyeability of the master batch of nylon 6 after the fishing net of nylon 6 is made obtains a certain degree of carry
Height, by being preheated to the fishing net of nylon 6, Low Temperature Plasma Treating, grape pip extract solution immersion treatment, can further change
The surface structure properties of the kind fishing net of nylon 6, improve the fishing net of nylon 6 to the upper dye amount of dyestuff, can by the synergy of three
So that the surface of nylon 6 produces microcosmic sliding and forms tired source, surface microscopic fatigue crack is produced, so as to improve nylon 6
Fishing net surface roughness, and the affinity on the fishing net surface of nylon 6 can be improved, dye molecule can be easier to enter wherein,
Mutually combined closely with the fishing net surface of nylon 6, can be easier to be diffused into the inside of the fishing net of nylon 6 by microfissure, and expand
Scattered is more uniform, and diffusion rate is fast, and dyefastness is good.
Embodiment
Embodiment 1
It is a kind of improve the fishing net dyeability of nylon 6 method, to the master batch of nylon 6 carry out activation process after, then will be through overactivation at
The fishing net of nylon 6 is made in the master batch of nylon 6 after reason, and then the fishing net of nylon 6 being made is preheated, then to the nylon 6 after preheating
Fishing net carries out Low Temperature Plasma Treating, then using the immersion of grape pip extract solution, is then dried, you can carry out at dyeing
Reason.
It is described to be specially to the master batch of nylon 6 progress activation process:The master batch of nylon 6 and deionized water are pressed 1:12 mass ratios
Uniform mixing, then adds the alum of the master batch quality 1.2% of nylon 6, is added in mixer under 1200r/min rotating speeds
40min is stirred, then the pH of suspension is adjusted to 8.8 using ammoniacal liquor, 90 DEG C are heated to, is stirred with 120r/min rotating speeds
After 30min, using 350W ultrasonication 10min, then the ammonium persulfate of the master batch quality 0.08% of nylon 6 is added, stirred
Afterwards, 15min is incubated at 72 DEG C, is then filtered, is dried at 60 DEG C to constant weight, you can.
The fishing net of nylon 6 is made in the master batch of nylon 6 by after activation process:By the nylon after activation process
Melting extrusion, cooling preliminary draft, drafting forming, winding, line processed, the knitmesh in an extruder of 6 master batches, is made the fishing net of nylon 6.
The described pair of fishing net of nylon 6 being made is preheated, and is specially:The fishing net of nylon 6 is placed on into relative air humidity is
In 70% environment, environment temperature is raised to 65 DEG C with 1 DEG C/min speed, 40min is incubated, you can.
The fishing net of nylon 6 after described pair of preheating enters Low Temperature Plasma Treating:The fishing net of nylon 6 is used into low temperature plasma
Handled, processing gas is carbon dioxide, operating pressure is 100Pa, and processing power is 180W, and processing time is 20s, i.e.,
Can.
The grape pip extracts liquid and preparation method thereof:Grape pip and camellia seed are pressed 10:1 mass ratio is admixed together,
Smash to pieces, then using 80% concentration of volume percent alcohol solvent, by solid-liquid ratio 1:20, the refluxing extraction 3h at 60 DEG C, centrifugation
Supernatant is obtained, then by rotary evaporation concentration, is then freeze-dried and solid extract is made, by solid extract by 1:40 mass
Ratio is uniformly admixed together for 0.1% sodium hydroxide solution with mass fraction, produces.
It is specially using the immersion of grape pip extract solution:The fishing net of nylon 6 is put into grape pip extract solution and soaks 2 at 40 DEG C
Hour, then take out, you can.
Embodiment 2
It is a kind of improve the fishing net dyeability of nylon 6 method, to the master batch of nylon 6 carry out activation process after, then will be through overactivation at
The fishing net of nylon 6 is made in the master batch of nylon 6 after reason, and then the fishing net of nylon 6 being made is preheated, then to the nylon 6 after preheating
Fishing net carries out Low Temperature Plasma Treating, then using the immersion of grape pip extract solution, is then dried, you can carry out at dyeing
Reason.
It is described to be specially to the master batch of nylon 6 progress activation process:The master batch of nylon 6 and deionized water are pressed 1:15 mass ratios
Uniform mixing, then adds the alum of the master batch quality 1.2% of nylon 6, is added in mixer under 1200r/min rotating speeds
40min is stirred, then the pH of suspension is adjusted to 9.2 using ammoniacal liquor, 90 DEG C are heated to, is stirred with 120r/min rotating speeds
After 30min, using 350W ultrasonication 12min, then the ammonium persulfate of the master batch quality 0.08% of nylon 6 is added, stirred
Afterwards, 18min is incubated at 72 DEG C, is then filtered, is dried at 60 DEG C to constant weight, you can.
The fishing net of nylon 6 is made in the master batch of nylon 6 by after activation process:By the nylon after activation process
Melting extrusion, cooling preliminary draft, drafting forming, winding, line processed, the knitmesh in an extruder of 6 master batches, is made the fishing net of nylon 6.
The described pair of fishing net of nylon 6 being made is preheated, and is specially:The fishing net of nylon 6 is placed on into relative air humidity is
In 75% environment, environment temperature is raised to 68 DEG C with 1 DEG C/min speed, 40min is incubated, you can.
The fishing net of nylon 6 after described pair of preheating enters Low Temperature Plasma Treating:The fishing net of nylon 6 is used into low temperature plasma
Handled, processing gas is carbon dioxide, operating pressure is 100Pa, and processing power is 180W, and processing time is 25s, i.e.,
Can.
The grape pip extracts liquid and preparation method thereof:Grape pip and camellia seed are pressed 10:1 mass ratio is admixed together,
Smash to pieces, then using 80% concentration of volume percent alcohol solvent, by solid-liquid ratio 1:20, the refluxing extraction 3h at 60 DEG C, centrifugation
Supernatant is obtained, then by rotary evaporation concentration, is then freeze-dried and solid extract is made, by solid extract by 1:40 mass
Ratio is uniformly admixed together for 0.1% sodium hydroxide solution with mass fraction, produces.
It is specially using the immersion of grape pip extract solution:The fishing net of nylon 6 is put into grape pip extract solution and soaks 2 at 50 DEG C
Hour, then take out, you can.
Embodiment 3
It is a kind of improve the fishing net dyeability of nylon 6 method, to the master batch of nylon 6 carry out activation process after, then will be through overactivation at
The fishing net of nylon 6 is made in the master batch of nylon 6 after reason, and then the fishing net of nylon 6 being made is preheated, then to the nylon 6 after preheating
Fishing net carries out Low Temperature Plasma Treating, then using the immersion of grape pip extract solution, is then dried, you can carry out at dyeing
Reason.
It is described to be specially to the master batch of nylon 6 progress activation process:The master batch of nylon 6 and deionized water are pressed 1:14 mass ratios
Uniform mixing, then adds the alum of the master batch quality 1.2% of nylon 6, is added in mixer under 1200r/min rotating speeds
40min is stirred, then the pH of suspension is adjusted to 9.0 using ammoniacal liquor, 90 DEG C are heated to, is stirred with 120r/min rotating speeds
After 30min, using 350W ultrasonication 11min, then the ammonium persulfate of the master batch quality 0.08% of nylon 6 is added, stirred
Afterwards, 16min is incubated at 72 DEG C, is then filtered, is dried at 60 DEG C to constant weight, you can.
The fishing net of nylon 6 is made in the master batch of nylon 6 by after activation process:By the nylon after activation process
Melting extrusion, cooling preliminary draft, drafting forming, winding, line processed, the knitmesh in an extruder of 6 master batches, is made the fishing net of nylon 6.
The described pair of fishing net of nylon 6 being made is preheated, and is specially:The fishing net of nylon 6 is placed on into relative air humidity is
In 72% environment, environment temperature is raised to 66 DEG C with 1 DEG C/min speed, 40min is incubated, you can.
The fishing net of nylon 6 after described pair of preheating enters Low Temperature Plasma Treating:The fishing net of nylon 6 is used into low temperature plasma
Handled, processing gas is carbon dioxide, operating pressure is 100Pa, and processing power is 180W, and processing time is 22s, i.e.,
Can.
The grape pip extracts liquid and preparation method thereof:Grape pip and camellia seed are pressed 10:1 mass ratio is admixed together,
Smash to pieces, then using 80% concentration of volume percent alcohol solvent, by solid-liquid ratio 1:20, the refluxing extraction 3h at 60 DEG C, centrifugation
Supernatant is obtained, then by rotary evaporation concentration, is then freeze-dried and solid extract is made, by solid extract by 1:40 mass
Ratio is uniformly admixed together for 0.1% sodium hydroxide solution with mass fraction, produces.
It is specially using the immersion of grape pip extract solution:The fishing net of nylon 6 is put into grape pip extract solution and soaks 2 at 45 DEG C
Hour, then take out, you can.
Comparative example 1:Differed only in embodiment 1 and activation process is not carried out to the master batch of nylon 6.
Comparative example 2:Differed only in embodiment 1 and the pre-heat treatment is not carried out to the fishing net of nylon 6.
Comparative example 3:Differed only in embodiment 1 and Low Temperature Plasma Treating is not carried out to the fishing net of nylon 6.
Comparative example 4:Differed only in embodiment 1 and grape pip extract solution immersion treatment is not used to the fishing net of nylon 6.
Experiment:Using infrared high-temperature overflow dyeing machine, dyestuff is cationic red 5BL, respectively to embodiment and comparative example method
The fishing net of nylon 6 of processing is dyed, and bath raio is 1:40, dyeing condition is:55 DEG C enter dye, 2 DEG C of heating per minute, to 93
DEG C stop, being cooled to 60 DEG C of cleaning fishing net surface loose colour 10min, dried at 60 DEG C to constant weight, using ultraviolet specrophotometer
Test dyeing stoste optical density, records dye liquor raffinate absorbance, calculates and is contaminated on dyeing time 2min, 5min and 10min nylon 6
Amount of dye:
Table 1
Control group is:The fishing net of nylon 6 is made using the common untreated master batch of nylon 6, it is laggard by Low Temperature Plasma Treating
Row dyeing, Low Temperature Plasma Treating method is with colouring method with this experiment;
Can be so that the upper dye amount of dye of the fishing net of nylon 6 can be improved to the activation process of the master batch of nylon 6 in the application, to fishing by table 1
Net carries out the pre-heat treatment, grape pip extract solution immersion treatment is carried out after Low Temperature Plasma Treating, can cooperating with low-temperature etc. from
The effect of daughter processing improves the upper dye amount of dye of the fishing net of nylon 6, improves the dyeability of the fishing net of nylon 6.