CN103865292B - A kind of ecological dyeing liked plum natural dyestuff, preparation method and be applied to thiozell - Google Patents
A kind of ecological dyeing liked plum natural dyestuff, preparation method and be applied to thiozell Download PDFInfo
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- CN103865292B CN103865292B CN201410122603.9A CN201410122603A CN103865292B CN 103865292 B CN103865292 B CN 103865292B CN 201410122603 A CN201410122603 A CN 201410122603A CN 103865292 B CN103865292 B CN 103865292B
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- dyeing
- thiozell
- plum
- natural dyestuff
- ecological
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- 238000004043 dyeing Methods 0.000 title claims abstract description 41
- 239000000975 dye Substances 0.000 title claims abstract description 31
- 238000002360 preparation method Methods 0.000 title abstract description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 18
- 238000000034 method Methods 0.000 claims abstract description 13
- 239000012192 staining solution Substances 0.000 claims abstract description 12
- 239000004744 fabric Substances 0.000 claims abstract description 8
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000010790 dilution Methods 0.000 claims abstract description 6
- 239000012895 dilution Substances 0.000 claims abstract description 6
- 238000005406 washing Methods 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 3
- 239000000835 fiber Substances 0.000 claims description 7
- 210000000085 cashmere Anatomy 0.000 claims description 4
- 239000007921 spray Substances 0.000 claims description 4
- 210000002268 wool Anatomy 0.000 claims description 4
- 238000005516 engineering process Methods 0.000 claims description 3
- 238000009434 installation Methods 0.000 claims description 2
- 238000002156 mixing Methods 0.000 claims description 2
- 102000004169 proteins and genes Human genes 0.000 claims description 2
- 108090000623 proteins and genes Proteins 0.000 claims description 2
- -1 yarn Substances 0.000 claims description 2
- 239000000049 pigment Substances 0.000 abstract description 3
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 2
- 239000002351 wastewater Substances 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 229960000583 acetic acid Drugs 0.000 description 3
- 239000007864 aqueous solution Substances 0.000 description 3
- 239000003085 diluting agent Substances 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 235000013399 edible fruits Nutrition 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 241000196324 Embryophyta Species 0.000 description 1
- 241000305492 Gastrodia Species 0.000 description 1
- 229930182559 Natural dye Natural products 0.000 description 1
- 235000011158 Prunus mume Nutrition 0.000 description 1
- 244000018795 Prunus mume Species 0.000 description 1
- 241000220317 Rosa Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 235000011389 fruit/vegetable juice Nutrition 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000000978 natural dye Substances 0.000 description 1
- 230000007170 pathology Effects 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
- 235000019633 pungent taste Nutrition 0.000 description 1
- 230000028327 secretion Effects 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
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Abstract
The invention discloses a kind of ecological dyeing liked plum natural dyestuff, preparation method and be applied to thiozell.Happiness plum is cleaned, dries, mechanical disintegration, be soaked in the water of 10 ~ 50 times, add 5 ~ 10g/L sodium hydroxide, 5 ~ 10g/L sodium-chlor, at 30 ~ 100 DEG C after dip treating, cross and filter residue, obtain liking the rainy season right stock staining solution; After liking the rainy season right stock staining solution dilution, for dyeing to thiozell, dyeing condition will be: bath raio 1: 10 ~ 50, pH5 ~ 7, dyeing temperature 80 ~ 100 DEG C, dyeing time 45 ~ 90min; Again through washing, dry and obtain dyeing product.Dyeing process of the present invention carries out fixation without the need to heavy metal, and fabric color after dyeing is even, and fastness is up to 3 ~ 4, and dyeing is simple, pigment is stablized, and dye uptake is high, substantially without color in waste water, biodegradable, be a kind of pure ecological dyeing method, market outlook are very wide.
Description
Technical field
The present invention relates to and a kind ofly like the ecological dyeing method of plum natural dyestuff to thiozell, belong to fabrics printing and dyeing technical field.
Background technology
Textiles, after the dyeing of chemosynthesis, can cause pungency to skin, easily causes human body skin pathology.And the dyestuff of chemosynthesis can affect to environment in production and use procedure, does not meet the requirement of science Sustainable development.Along with going deep into of environmental protection idea, natural dyestuff is more and more subject to the favor of people.Natural dyestuff refers to and to extract from the root of plant, leaf, bark, trunk, shell, flower or animal secretions, mineral substance, preparation process can not cause environmental pollution, dyeing after textiles wear safety, and natural dyestuff and ecotope consistency good, biodegradable.But natural dye dying colour fastness is low, and usually need heavy metal fixation, therefore, find the focus that high color fastness natural dyestuff becomes investigator.
Fruit plum is in existing more than the 3000 year history of China, aboundresources, there are 205 kinds altogether, wherein Japanese apricot class 13, green plum class 95, red plum class 83, Introduced from Japan kind 14, happiness plum belongs to the one of fruit plum, is mainly distributed in Guangdong, Taiwan, Guangxi, torrid areas, Fujian, be distributed as master with wild species, be generally used for squeezing juice.Publication number is that the Chinese invention patent of CN102746972A discloses a kind of happiness plum gastrodia liquor and preparation method thereof, has nourishing function.But the investigation and application at present for pigment contained in happiness plum has no report.
Summary of the invention
The present invention utilizes in happiness plum and contains abundant pigment, provides a kind of happiness plum natural dyestuff and preparation method thereof, and the happiness plum natural dyestuff obtained is used for the ecological dyeing method to thiozell.Technical scheme provided by the invention has environmental and ecological, that dyeing product uniform color, fastness are good feature.
What realize the object of the invention is that technical scheme is to provide a kind of preparation method liking plum natural dyestuff, comprise step as follows: happiness plum is cleaned, dried, mechanical disintegration, by weight, be soaked in the water of 10 ~ 50 times, add sodium hydroxide 5 ~ 10g/L, sodium-chlor 5 ~ 10g/L, under the temperature condition of 30 ~ 100 DEG C after dip treating, cross and filter residue, obtain liking the rainy season right stock staining solution.
The dip treating time of the present invention is 30 ~ 100min.
Technical solution of the present invention also comprises the happiness plum natural dyestuff stoste obtained by above-mentioned preparation method.
Happiness plum natural dyestuff of the present invention is applied to the ecological dyeing method to thiozell, step is as follows: will like the rainy season right stock staining solution dilution, in dyeing installation, carry out Colour Difference to thiozell; bath raio is 1:10 ~ 50, the pH of dye liquor is 5 ~ 7, and dyeing temperature is 80 ~ 100 DEG C; dyeing time is 45 ~ 90min; again through washing, dries, obtains a kind of red protein fiber.
Colour Difference of the present invention comprise adopt flood, pad, spray, spray technology.Described thiozell comprises the one in silk, wool, cashmere, or their blending product; The state of thiozell comprises bulk fibre, yarn, fabric or finished product dress ornament.
Beneficial effect of the present invention is: preparation method has that technique is simple, environmental protection and energy saving, dyeing behavior excellence feature; Dyeing product have take safety, added value is high, to skin without advantages such as supersensitivity; To contaminate fiber color bright-coloured, environmental protection, is particularly suitable for production that is next to the skin and children's fabric.The happiness plum that the present invention adopts is a kind of rose natural dyestuff of excellent property, and market outlook are very wide.
Accompanying drawing explanation
Fig. 1 is the photo in kind of embodiment of the present invention happiness used plum;
Fig. 2 is the upper dye trend map of the happiness plum natural dyestuff dyeing silk that the embodiment of the present invention 1 provides.
Embodiment
Below in conjunction with embodiment and accompanying drawing, technical scheme of the present invention is further elaborated.
Embodiment 1:
See accompanying drawing 1, it is the photo in kind of the present embodiment happiness used plum.100g is liked plum to clean, dry rear mechanical disintegration, join in the aqueous solution of 50 times and soak, add 5g/L sodium hydroxide and 5g/L sodium-chlor, at 60 DEG C of temperature dipping 60min, cross after filtering residue, obtain liking the rainy season right stock staining solution.Right for happiness rainy season stock staining solution is diluted 20 multiples, take out 100mL and like the rainy season right dye-dilution liquid, 10g real silk fabric is put into diluent dye, be 6 with vinegar acid for adjusting pH, dyeing temperature 100 DEG C, dyeing time 75min, the real silk fabric after dyeing carries out washing dries, obtain bright-coloured red real silk, colour fastness after tested result see table 1.
See accompanying drawing 2, it is the upper dye trend map of the real silk fabric obtained by the present embodiment working method.In figure, curve B is before dye, and curve C is for contaminating rear 10 minutes 60 DEG C, and curve D is for contaminating rear 20 minutes 80 DEG C, curve E is for contaminating rear 30 minutes 100 DEG C, and curve F is for contaminating latter 40 minutes, and curve G is 50 minutes, curve H is for contaminating latter 60 minutes, and curve I is for contaminating latter 70 minutes, and curve J is latter 75 minutes of dye.
Embodiment 2:
100g is liked plum and clean rear mechanical disintegration, then join in 50 times of aqueous solution and soak, add 3g/L sodium hydroxide, add 10g/L sodium-chlor, at 80 DEG C of temperature dipping 80min, cross after filtering residue, obtain liking the rainy season right stock staining solution, right for happiness rainy season stock staining solution is diluted 20 times, take out 100mL and like the rainy season right dye-dilution liquid, 10g cashmere fiber is put into diluent dye, be 5 with vinegar acid for adjusting pH, dyeing temperature 90 DEG C, dyeing time 80min, cashmere fiber after dyeing carry out washing dry, colour fastness after tested result see table 1.
Embodiment 3:
100g is liked plum and clean rear mechanical disintegration, then join in 50 times of aqueous solution and soak, add 5g/L sodium hydroxide, add 10g/L sodium-chlor, at 60 DEG C of temperature dipping 60min, cross after filtering residue, obtain liking the rainy season right stock staining solution, right for happiness rainy season stock staining solution is diluted 20 times, take out 100mL and like the rainy season right dye-dilution liquid, 10g wool yarn is put into diluent dye, be 5 with vinegar acid for adjusting pH, dyeing temperature 90 DEG C, dyeing time 80min, wool yarn after dyeing carry out washing dry, colour fastness after tested result see table 1.
The colour fastness test result of each embodiment product of table 1
Claims (4)
1. like plum natural dyestuff and be applied to ecological dyeing method to thiozell for one kind, described happiness plum natural dyestuff is adopted and is prepared with the following method, happiness plum is cleaned, dry, mechanical disintegration, by weight, be soaked in the water of 10 ~ 50 times, add sodium hydroxide 5 ~ 10g/L, sodium-chlor 5 ~ 10g/L, under the temperature condition of 30 ~ 100 DEG C after dip treating, cross and filter residue, obtain liking the rainy season right stock staining solution, it is characterized in that step is as follows: the rainy season right stock staining solution dilution will be liked, in dyeing installation, Colour Difference is carried out to thiozell, bath raio is 1:10 ~ 50, the pH of dye liquor is 5 ~ 7, dyeing temperature is 80 ~ 100 DEG C, dyeing time is 45 ~ 90min, again through washing, dry, obtain a kind of red protein fiber.
2. according to claim 1ly a kind ofly like the ecological dyeing method of plum natural dyestuff to thiozell, it is characterized in that: described Colour Difference comprise adopt flood, pad, spray, spray technology.
3. according to claim 1ly a kind ofly like the ecological dyeing method of plum natural dyestuff to thiozell, it is characterized in that: described thiozell comprises the one in silk, wool, cashmere, or their blending product.
4. according to claim 1ly a kind ofly like the ecological dyeing method of plum natural dyestuff to thiozell, it is characterized in that: the state of thiozell comprises bulk fibre, yarn, fabric or finished product dress ornament.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410122603.9A CN103865292B (en) | 2014-03-28 | 2014-03-28 | A kind of ecological dyeing liked plum natural dyestuff, preparation method and be applied to thiozell |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410122603.9A CN103865292B (en) | 2014-03-28 | 2014-03-28 | A kind of ecological dyeing liked plum natural dyestuff, preparation method and be applied to thiozell |
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| Publication Number | Publication Date |
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| CN103865292A CN103865292A (en) | 2014-06-18 |
| CN103865292B true CN103865292B (en) | 2015-10-28 |
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| CN201410122603.9A Expired - Fee Related CN103865292B (en) | 2014-03-28 | 2014-03-28 | A kind of ecological dyeing liked plum natural dyestuff, preparation method and be applied to thiozell |
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Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105421111B (en) * | 2015-12-22 | 2017-11-14 | 广州番禺职业技术学院 | A kind of technique for Animal Skin of being printed and dyed using Dragonfruit Juice |
| CN106046846B (en) * | 2016-05-26 | 2017-08-25 | 惠州同富康生物科技有限公司 | The extracting method of green plum pericarp pigment |
| CN107354739B (en) * | 2017-07-05 | 2020-03-10 | 苏州大学 | Modified silk fabric and preparation method thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1030924A (en) * | 1988-08-06 | 1989-02-08 | 陕西省微生物研究所 | The extracting method of fructus pyracanthae red pigment |
| JPH0959884A (en) * | 1995-08-14 | 1997-03-04 | Goshiyogawarashi | Dyeing with red apple tree |
| CN101177542A (en) * | 2007-11-16 | 2008-05-14 | 浙江理工大学 | Method for preparing aspidium rhizoma natural dye and product thereof |
| CN101182391A (en) * | 2007-11-29 | 2008-05-21 | 浙江理工大学 | Method for preparing water chestnut hull natural dye and uses thereof |
| CN101798468A (en) * | 2010-01-29 | 2010-08-11 | 王振宇 | Preparation method of hazelnut shell brown pigment |
| CN102010615A (en) * | 2010-11-29 | 2011-04-13 | 南通大学 | Bamboo leaf dye and extraction method and application thereof |
| CN102051063A (en) * | 2010-11-29 | 2011-05-11 | 南通职业大学 | Camphor tree dye, extracting method thereof and use thereof |
| CN102304296A (en) * | 2011-06-23 | 2012-01-04 | 张家港市鸿钻贸易有限公司 | Method for preparing dye by plum peel and application thereof |
| CN102504575A (en) * | 2011-11-04 | 2012-06-20 | 南通大学 | Rhododendron pulchrum leaf dye, and extraction method and application thereof |
| CN102746972A (en) * | 2011-04-19 | 2012-10-24 | 朱大信 | Xi mei tall gastrodia rhizome wine |
-
2014
- 2014-03-28 CN CN201410122603.9A patent/CN103865292B/en not_active Expired - Fee Related
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1030924A (en) * | 1988-08-06 | 1989-02-08 | 陕西省微生物研究所 | The extracting method of fructus pyracanthae red pigment |
| JPH0959884A (en) * | 1995-08-14 | 1997-03-04 | Goshiyogawarashi | Dyeing with red apple tree |
| CN101177542A (en) * | 2007-11-16 | 2008-05-14 | 浙江理工大学 | Method for preparing aspidium rhizoma natural dye and product thereof |
| CN101182391A (en) * | 2007-11-29 | 2008-05-21 | 浙江理工大学 | Method for preparing water chestnut hull natural dye and uses thereof |
| CN101798468A (en) * | 2010-01-29 | 2010-08-11 | 王振宇 | Preparation method of hazelnut shell brown pigment |
| CN102010615A (en) * | 2010-11-29 | 2011-04-13 | 南通大学 | Bamboo leaf dye and extraction method and application thereof |
| CN102051063A (en) * | 2010-11-29 | 2011-05-11 | 南通职业大学 | Camphor tree dye, extracting method thereof and use thereof |
| CN102746972A (en) * | 2011-04-19 | 2012-10-24 | 朱大信 | Xi mei tall gastrodia rhizome wine |
| CN102304296A (en) * | 2011-06-23 | 2012-01-04 | 张家港市鸿钻贸易有限公司 | Method for preparing dye by plum peel and application thereof |
| CN102504575A (en) * | 2011-11-04 | 2012-06-20 | 南通大学 | Rhododendron pulchrum leaf dye, and extraction method and application thereof |
Non-Patent Citations (4)
| Title |
|---|
| 天然色素的提取方法和应用;黄俊娴等;《广东化工》;20060625;第33卷(第06期);63-66 * |
| 西梅果皮色素提取及其稳定性研究;闫宁环等;《西北农林科技大学学报(自然科学版)》;20070225;第35卷(第02期);160-166 * |
| 西梅果皮色素的提取工艺及其稳定性研究;杨永利等;《食品科学》;20081015;第29卷(第10期);303-309 * |
| 青梅果皮色素的提取工艺;李阿娜等;《经济林研究》;20100630;第28卷(第2期);29-36 * |
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Effective date of registration: 20160601 Address after: 200135 room D02, building, No. 2000, Pudong Avenue, Pudong New Area Free Trade Zone, Shanghai Patentee after: ABESS NANOTECHNOLOGY (SHANGHAI) Co.,Ltd. Address before: 215123 Suzhou City, Suzhou Province Industrial Park, No. love road, No. 199 Patentee before: Soochow University |
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Address after: 200135 room D02, building, No. 2000, Pudong Avenue, Pudong New Area Free Trade Zone, Shanghai Patentee after: ABS INTERNATIONAL Inc. Address before: 200135 room D02, building, No. 2000, Pudong Avenue, Pudong New Area Free Trade Zone, Shanghai Patentee before: ABESS NANOTECHNOLOGY (SHANGHAI) Co.,Ltd. |
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Effective date of registration: 20170308 Address after: 215138 Suzhou, Xiangcheng District Yangcheng Lake Town, Lake Road, painter, No. 13, No. Patentee after: SUZHOU HEXIANG TEXTILE CO.,LTD. Address before: 200135 room D02, building, No. 2000, Pudong Avenue, Pudong New Area Free Trade Zone, Shanghai Patentee before: ABS INTERNATIONAL Inc. |
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Address after: 215138 Suzhou, Xiangcheng District Yangcheng Lake Town, Lake Road, painter, No. 13, No. Patentee after: SUZHOU HEXIANG TEXTILE TECHNOLOGY CO.,LTD. Address before: 215138 Suzhou, Xiangcheng District Yangcheng Lake Town, Lake Road, painter, No. 13, No. Patentee before: SUZHOU HEXIANG TEXTILE CO.,LTD. |
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