CN110181910A - 一种磁性阻燃环保型tpo合成革与制备 - Google Patents
一种磁性阻燃环保型tpo合成革与制备 Download PDFInfo
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Abstract
本发明公开了一种磁性阻燃环保型TPO合成革与制备，所述TPO合成革包括：TPO基材、位于所述TPO基材上表面的耐刮涂层、位于所述TPO基材下表面的具有磁性吸附的磁性层，所述TPO基材包括：改性TPO膜、和与所述改性TPO膜热压合在一起的聚苯乙烯泡沫，所述改性TPO膜包括如下重量份的成分：嵌段共聚聚丙烯40‑60份，聚烯烃弹性体10‑20份，Fe2O3粉末10‑30份，金属的粉末氧化物0.5‑5份，光稳定剂0.1‑0.5，耐磨剂5‑20份，颜料5‑10份。所述制备方法包括：(1)改性TPO膜制备；(2)TPO基材制备；(3)表面处理；通过上述方式，本发明无需添加任何胶黏剂，通过添加磁性材料或者可磁化材料，在同时制得的合成革时又使其具有装饰简便的优异性能。
Description
技术领域
本发明涉及合成革制造技术领域，特别是设计一种磁性阻燃环保TPO合成革及其制备方法。
背景技术
随着社会的发展和人们生活的提高，室内环境受到了越来越多的重视，目前用于室内隔墙、顶墙的外层装修大多为涂料、油漆等，其中含有大量的甲醛和其它致癌物质，对居民身体健康造成重大危害。TPO材料作为一种绿色、经济、环保的材料，具有保温、隔热等特点，在建筑装修领域获得了广泛的应用，尤其是在室内隔墙、顶墙的表层装修领域，而磁性TPO薄膜材料由于其本身具有磁性，只需要墙体具有磁性即可将磁性TPO薄膜固定，可随意更换、施工工期短获到了广泛的关注。
发明内容
本发明主要解决的技术问题是：针对现有技术的不足，提供一种磁性阻燃环保型TPO合成革及其制备方法，无需任何胶黏剂就可以进行装修覆盖，且无需添加任何阻燃剂就可以达到阻燃要求，同时制造成本低。
为解决上述技术问题，本发明采用的一个技术方案是：提供一种磁性阻燃环保型TPO合成革，包括：TPO基材、位于所述TPO基材上表面的耐刮涂层。所述TPO基材包括：改性TPO膜、和与所述改性TPO膜热压合在一起的聚丙烯泡沫，所述改性TPO膜包括如下重量份的成分：嵌段共聚聚丙烯40-60份，聚烯烃弹性体5-50份，Fe2O3磁性粉末20-50份，金属的粉末氧化物5-15份，光稳定剂0.5-1，耐磨剂1-5份，颜料1-15份。
在本发明一个较佳实施例中，所述改性TPO膜包括如下重量份的成分：嵌段共聚聚丙烯40-60份，聚烯烃弹性体5-50份，Fe2O3磁性粉末20-50份，金属的粉末氧化物5-15份，光稳定剂0.5-1，耐磨剂1-5份，颜料1-15份。在本发明一个较佳实施例中，所述光稳定剂为水杨酸脂类和二苯甲酮类光稳定剂。
在本发明一个较佳实施例中，所述聚丙烯泡沫的厚度为：1.0mm、1.5mm、2.0mm、2.5mm或3.0mm，宽度为1000-5000mm，发泡率为15、20、25或30倍。在本发明一个较佳实施例中，所述耐刮涂层包括依次附着在所述TPO基材上表面的底面处理剂层。
本发明还提供一种磁性阻燃环保型TPO合成革的制备方法，包括如下步骤：
(1)Fe2O3粉末、金属的粉末氧化物的聚合改性：采用原为聚合的方法制备外聚丙烯-金属粉末的改性物。
(2)改性TPO膜制备：嵌段共聚聚丙烯40-60份，聚烯烃弹性体5-50份，Fe2O3磁性粉末20-50份，金属的粉末氧化物5-15份，光稳定剂0.5-1，耐磨剂1-5份，颜料1-15份，加入挤出机，经挤出机混合、熔融挤出、压光、冷却、卷曲制成改性TPO膜片材；
(3)TPO基材制备：将改性TPO膜片材背面通过辊筒加热到110～180℃，将聚苯乙烯泡沫的表面通过辊筒或红外线加热到80～100℃，在压力为2～6MPa下将所述改性TPO膜片材与聚苯乙烯泡沫熔接复合在一起，得到TPO基材；
(4)表面处理：对上述制得的TPO基材的上表面进行电晕处理，在其表面涂覆底面处理剂，烘干后再涂覆表面处理剂，再次烘干，然后冷却；
本发明的有益效果是：通过优化TPO膜的原料及其配比，采用硫化TPO，其在吸附时不变形，花纹稳定性好，并且阻燃性好、耐热、耐候性好；同时加入嵌段共聚聚丙烯，起到花纹保持不变的作用，尺寸稳定性好；添加Fe2O3以及金属氧化物粉末，能够停止对胶黏剂的使用，利用金属氧化物及其粉末的可磁化性进行装修；并加入光稳定剂，能够防止阳光照射产生的光老化；上述原料通过挤出成型方式获得改性TPO膜片材，并与聚苯乙烯泡沫热复合获得的TPO基材，同时对TPO基材进行表面处理，使获得的TPO革具有磁性、阻燃性好、耐高低温、低气味、耐候性、环保可回收、加工性好、耐刮擦性、合格率高、成本低且与骨架粘结性好的优点。
附图说明
图1为一种磁性阻燃环保型TPO合成革的侧面图
图中：1-耐刮涂层；2-改性TPO膜；3-聚苯乙烯泡沫；4-磁性吸附层
具体实施方式
实例一：
(1)Fe2O3粉末、金属的粉末氧化物的聚合改性：采用原为聚合的方法制备外聚丙烯-金属粉末的改性物。
(2)改性TPO膜制备：嵌段共聚聚丙烯40份，聚烯烃弹性体15份，Fe2O3磁性粉末20份，金属的粉末氧化物5份，光稳定剂0.5份，耐磨剂1.5份，颜料2份，加入挤出机，经挤出机混合、熔融挤出、压光、冷却、卷曲制成改性TPO膜片材；
(3)TPO基材制备：将改性TPO膜片材背面通过辊筒加热到120℃，将聚苯乙烯泡沫的表面通过辊筒或红外线加热到80℃，在压力为3MPa下将所述改性TPO膜片材与聚苯乙烯泡沫熔接复合在一起，得到TPO基材；
(4)表面处理：对上述制得的TPO基材的上表面进行电晕处理，在其表面涂覆底面处理剂，烘干后再涂覆表面处理剂，再次烘干，然后冷却；
实例二：
(1)Fe2O3粉末、金属的粉末氧化物的聚合改性：采用原为聚合的方法制备外聚丙烯-金属粉末的改性物。
(2)改性TPO膜制备：嵌段共聚聚丙烯50份，聚烯烃弹性体10份，Fe2O3磁性粉末20份，金属的粉末氧化物10份，光稳定剂1，耐磨剂1.5份，颜料3份，加入挤出机，经挤出机混合、熔融挤出、压光、冷却、卷曲制成改性TPO膜片材；
(3)TPO基材制备：将改性TPO膜片材背面通过辊筒加热到130℃，将聚苯乙烯泡沫的表面通过辊筒或红外线加热到90℃，在压力为4MPa下将所述改性TPO膜片材与聚苯乙烯泡沫熔接复合在一起，得到TPO基材；
(4)表面处理：对上述制得的TPO基材的上表面进行电晕处理，在其表面涂覆底面处理剂，烘干后再涂覆表面处理剂，再次烘干，然后冷却；
实例三：
(1)Fe2O3粉末、金属的粉末氧化物的聚合改性：采用原为聚合的方法制备外聚丙烯-金属粉末的改性物。
(2)改性TPO膜制备：嵌段共聚聚丙烯60份，聚烯烃弹性体5份，Fe2O3磁性粉末25份，金属的粉末氧化物5份，光稳定剂1.5，耐磨剂1.5份，颜料1.5份，加入挤出机，经挤出机混合、熔融挤出、压光、冷却、卷曲制成改性TPO膜片材；
(3)TPO基材制备：将改性TPO膜片材背面通过辊筒加热到160℃，将聚苯乙烯泡沫的表面通过辊筒或红外线加热到100℃，在压力为6MPa下将所述改性TPO膜片材与聚苯乙烯泡沫熔接复合在一起，得到TPO基材；
(4)表面处理：对上述制得的TPO基材的上表面进行电晕处理，在其表面涂覆底面处理剂，烘干后再涂覆表面处理剂，再次烘干，然后冷却；
本发明揭示了一种磁性阻燃环保型TPO合成革及其制备方法，采用合理配比的原料成分、并通过挤出成型方式获得改性TPO膜片材，无需添加任何加工助剂，加工性能好、成本低；同时对TPO基材进行表面处理，使获得的TPO革具有可磁化性、阻燃性好、低雾性、低气味、环保可回收、加工性好、耐刮擦性、耐高低温、耐候性、合格率高、成本低且与骨架粘结性好的优点。以上所述仅为本发明的实施例，并非因此限制本发明的专利范围，凡是利用本发明说明书及附图内容所作的等效结构或等效流程变换，或直接或间接运用在其他相关的技术领域，均同理包括在本发明的专利保护范围内。
Claims (8)
1.一种磁性阻燃环保型TPO合成革与制备，其特征在于，包括TPO基材、位于所述TPO基材上表面的耐刮涂层、位于所述TPO基材下表面的具有磁性吸附的磁性层，所述TPO基材包括：改性TPO膜、和与所述改性TPO膜热压合在一起的聚苯乙烯泡沫，所述改性TPO膜包括如下重量份的成分：嵌段共聚聚丙烯40-60份，聚烯烃弹性体10-20份，Fe2O3粉末10-30份，金属的粉末氧化物0.5-5份，光稳定剂0.1-0.5，耐磨剂5-20份，颜料5-10份。
2.根据权利要求1所述的磁性阻燃环保型TPO合成革，其特征在于，所述改性TPO膜包括如下重量份的成分嵌段共聚聚丙烯40-60份，聚烯烃弹性体5-50份，Fe2O3磁性粉末20-50份，金属的粉末氧化物5-15份，光稳定剂0.5-1，耐磨剂1-5份，颜料1-15份。
3.根据权利要求1或2所述的磁性阻燃环保型TPO合成革，其特征在于，所述金属的粉末氧化物为锌、镁、钡、锶、铅金属的粉末氧化物。
4.根据权利要求1或2所述的磁性阻燃环保型TPO合成革，其特征在于，所述光稳定剂可以为水杨酸脂类、二苯甲酮类、苯并三唑类、三嗪类、取代丙烯晴类、草酰胺类、有机镍化合物类、受阻胺类。
5.根据权利要求1所述的磁性阻燃环保型TPO合成革，其特征在于，所述聚丙烯泡沫的厚度为：1.0mm、1.5mm、2.0mm、2.5mm或3.0mm，宽度为1000-5000mm，发泡率为15、20、25或30倍。
6.根据权利要求1所述的磁性阻燃环保型TPO合成革，其特征在于，磁性粉末为Fe2O3粉末。
7.改性TPO膜制备：其特征在于，包括如下步骤：
(1)Fe2O3粉末、金属的粉末氧化物的聚合改性：采用原为聚合的方法制备外聚丙烯-金属粉末的改性物。
(2)改性TPO膜制备：嵌段共聚聚丙烯40-60份，聚烯烃弹性体5-50 份，Fe2O3磁性粉末20-50份，金属的粉末氧化物5-15份，光稳定剂0.5-1，耐磨剂1-5份，颜料1-15份，加入挤出机，经挤出机混合、熔融挤出、压光、冷却、卷曲制成改性TPO膜片材；
(3)TPO基材制备：将改性TPO膜片材背面通过辊筒加热到110～180℃，将聚苯乙烯泡沫的表面通过辊筒或红外线加热到80～100℃，在压力为2～6MPa下将所述改性TPO膜片材与聚苯乙烯泡沫熔接复合在一起，得到TPO基材；
(4)表面处理：对上述制得的TPO基材的上表面进行电晕处理，在其表面涂覆底面处理剂，烘干后再涂覆表面处理剂，再次烘干，然后冷却。
8.根据权利要求6所述的磁性阻燃环保型TPO合成革的制备方法，其特征在于，所述步骤(2)中，嵌段共聚聚丙烯40-60份，聚烯烃弹性体5-50份，Fe2O3磁性粉末20-50份，金属的粉末氧化物5-15份，光稳定剂0.5-1，耐磨剂1-5份，颜料1-15份。
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Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005290707A (ja) * | 2004-03-31 | 2005-10-20 | Nichirei Magnet Kk | 防火磁性壁面材及びそれを用いた防火磁性壁 |
| KR20080031792A (ko) * | 2006-10-05 | 2008-04-11 | 제이에스알 가부시끼가이샤 | 적층체 |
| US20150147553A1 (en) * | 2013-11-27 | 2015-05-28 | Ultraflex Systems, Inc. | Printable Magnetic Receptive Composite Sheet and Method of Making |
| CN105907323A (zh) * | 2016-05-30 | 2016-08-31 | 苏州瑞高新材料有限公司 | 一种阻燃环保型tpo合成革及其制备方法 |
| CN106221155A (zh) * | 2016-08-04 | 2016-12-14 | 苏州锐特捷化工制品有限公司 | 一种磁性塑型石墨烯的功能外墙板材料及其制备方法 |
| CN109057235A (zh) * | 2018-08-28 | 2018-12-21 | 江苏肯帝亚木业有限公司 | 一种磁性自吸地板及其安装方法 |
-
2019
- 2019-06-13 CN CN201910512799.5A patent/CN110181910A/zh active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2005290707A (ja) * | 2004-03-31 | 2005-10-20 | Nichirei Magnet Kk | 防火磁性壁面材及びそれを用いた防火磁性壁 |
| KR20080031792A (ko) * | 2006-10-05 | 2008-04-11 | 제이에스알 가부시끼가이샤 | 적층체 |
| US20150147553A1 (en) * | 2013-11-27 | 2015-05-28 | Ultraflex Systems, Inc. | Printable Magnetic Receptive Composite Sheet and Method of Making |
| CN105907323A (zh) * | 2016-05-30 | 2016-08-31 | 苏州瑞高新材料有限公司 | 一种阻燃环保型tpo合成革及其制备方法 |
| CN106221155A (zh) * | 2016-08-04 | 2016-12-14 | 苏州锐特捷化工制品有限公司 | 一种磁性塑型石墨烯的功能外墙板材料及其制备方法 |
| CN109057235A (zh) * | 2018-08-28 | 2018-12-21 | 江苏肯帝亚木业有限公司 | 一种磁性自吸地板及其安装方法 |
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