CN110139917A - 一种汽油的处理方法 - Google Patents
一种汽油的处理方法 Download PDFInfo
- Publication number
- CN110139917A CN110139917A CN201780064852.9A CN201780064852A CN110139917A CN 110139917 A CN110139917 A CN 110139917A CN 201780064852 A CN201780064852 A CN 201780064852A CN 110139917 A CN110139917 A CN 110139917A
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- CN
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- Prior art keywords
- gasoline
- catalyst
- desulfurization
- weight
- aromatization
- Prior art date
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- 238000000034 method Methods 0.000 title claims abstract description 88
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- 239000003054 catalyst Substances 0.000 claims abstract description 254
- 238000006477 desulfuration reaction Methods 0.000 claims abstract description 110
- 230000023556 desulfurization Effects 0.000 claims abstract description 102
- 238000005899 aromatization reaction Methods 0.000 claims abstract description 97
- 238000006266 etherification reaction Methods 0.000 claims abstract description 64
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- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 37
- 239000001257 hydrogen Substances 0.000 claims abstract description 37
- 238000012545 processing Methods 0.000 claims abstract description 35
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 26
- 239000005864 Sulphur Substances 0.000 claims abstract description 9
- 238000003672 processing method Methods 0.000 claims abstract description 9
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- 239000002253 acid Substances 0.000 claims description 67
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- 230000032683 aging Effects 0.000 claims description 41
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- 239000002184 metal Substances 0.000 claims description 39
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- 239000010937 tungsten Substances 0.000 claims description 2
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- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims 1
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract description 32
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 abstract description 16
- 125000004435 hydrogen atom Chemical class [H]* 0.000 abstract 1
- 239000000047 product Substances 0.000 description 84
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
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- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 6
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- 229910052700 potassium Inorganic materials 0.000 description 1
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- 238000012797 qualification Methods 0.000 description 1
- 150000003248 quinolines Chemical class 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
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- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
- C10G69/14—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process plural parallel stages only
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- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
- C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
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- B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
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- B01J35/61—Surface area
- B01J35/615—100-500 m2/g
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- C10G29/22—Organic compounds not containing metal atoms containing oxygen as the only hetero atom
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- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
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- C10G45/68—Aromatisation of hydrocarbon oil fractions
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- C10G69/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one other conversion process
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Abstract
一种汽油的处理方法及处理系统,该处理方法包括:使汽油原料与混合催化剂接触并在氢气存在下进行脱硫和芳构化反应,得到脱硫‑芳构化产物;任选地将所得脱硫‑芳构化产物进行分割,得到轻汽油馏分和重汽油馏分;以及任选地将所得轻汽油馏分进行醚化处理,得到醚化油;其中,所述混合催化剂包括吸附脱硫催化剂和芳构化催化剂。该方法能降低汽油中的硫和烯烃含量,并能够同时提高汽油的辛烷值和保持高汽油收率。
Description
PCT国内申请,说明书已公开。
Claims (18)
- PCT国内申请,权利要求书已公开。
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CN201610921806.3A CN107974293B (zh) | 2016-10-21 | 2016-10-21 | 一种汽油的处理方法和系统 |
CN2016109220063 | 2016-10-21 | ||
CN201610921175.5A CN107974297B (zh) | 2016-10-21 | 2016-10-21 | 一种汽油的处理方法 |
CN2016109218063 | 2016-10-21 | ||
CN201610921955.XA CN107974290B (zh) | 2016-10-21 | 2016-10-21 | 一种汽油的处理方法 |
CN2016109219992 | 2016-10-21 | ||
CN201610921999.2A CN107974296B (zh) | 2016-10-21 | 2016-10-21 | 一种汽油的处理方法 |
CN2016109211755 | 2016-10-21 | ||
CN201610922006.3A CN107974292B (zh) | 2016-10-21 | 2016-10-21 | 一种汽油的处理方法 |
CN201610921955X | 2016-10-21 | ||
PCT/CN2017/000634 WO2018072343A1 (zh) | 2016-10-21 | 2017-10-20 | 一种汽油的处理方法 |
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CN115722261B (zh) * | 2021-08-31 | 2024-05-24 | 中国石油化工股份有限公司 | 降低汽油中苯含量和硫含量的含磷催化剂及其制备方法和应用 |
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CN104479738A (zh) * | 2014-12-16 | 2015-04-01 | 西安石油大学 | 一种催化裂化汽油深度脱硫组合工艺 |
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CN1268720C (zh) | 2002-10-10 | 2006-08-09 | 中国石油化工股份有限公司 | 一种芳构化催化剂及清洁汽油生产工艺 |
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