CN110123674A - A kind of smoothing toner and preparation method thereof containing oil and fat of sacha inchi microcapsules - Google Patents
A kind of smoothing toner and preparation method thereof containing oil and fat of sacha inchi microcapsules Download PDFInfo
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- CN110123674A CN110123674A CN201910423998.9A CN201910423998A CN110123674A CN 110123674 A CN110123674 A CN 110123674A CN 201910423998 A CN201910423998 A CN 201910423998A CN 110123674 A CN110123674 A CN 110123674A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/11—Encapsulated compositions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/345—Alcohols containing more than one hydroxy group
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/735—Mucopolysaccharides, e.g. hyaluronic acid; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
- A61K8/922—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof of vegetable origin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/04—Topical preparations for affording protection against sunlight or other radiation; Topical sun tanning preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/02—Preparations for care of the skin for chemically bleaching or whitening the skin
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
- A61Q19/08—Anti-ageing preparations
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/41—Particular ingredients further characterized by their size
- A61K2800/413—Nanosized, i.e. having sizes below 100 nm
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/56—Compounds, absorbed onto or entrapped into a solid carrier, e.g. encapsulated perfumes, inclusion compounds, sustained release forms
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Abstract
The present invention provides a kind of smoothing toner and preparation method thereof containing oil and fat of sacha inchi microcapsules.The smoothing toner containing oil and fat of sacha inchi microcapsules, in parts by weight, its raw material includes: 100-160 parts of distilled water, 3-5 parts of 1,3-BDOs, 4-6 parts of polyethylene glycol -32,2-4 parts of methyl gluceths -20,3-14 parts of moisturizer, 0.1-6 parts of antioxidants, 0.5-3 portions of preservatives and 2-8 parts of oil and fat of sacha inchi microcapsules.Using the present invention containing a few days after oil and fat of sacha inchi microcapsules smoothing toner after, can have apparent soft and moist skin, have and highlight skin, enhance the effect of skin elasticity, smoothing toner obtained by the present invention is nontoxic, and no sensitization, non-stimulated, use is safe.
Description
Technical field
The invention belongs to cosmetic fields, are related to a kind of toner, specifically a kind of to contain oil and fat of sacha inchi microcapsules
Smoothing toner and oil and fat of sacha inchi microcapsules smoothing toner preparation method.
Background technique
Smoothing toner refers to relatively mild toner of the pH close to 7.There is soft cutin, i.e., removal aging cutin is to make flesh
The moist softness of skin, improves the effect of the low and deep deficient gloss of skin and elasticity, while also preventing melanin from being formed, moistens soft skin, put down
Weigh skin acid-base property, reaches the effect of maintaining skin kilter.It is suitble to the skin of stemness and Combination to use.
Oil and fat of sacha inchi is a kind of vegetable fat extracted from the kernel of South America oil Calamus plant, unsaturated fatty acid
Content it is higher, while there are also a variety of lipids such as vitamin E, polyphenol and sterol to be used as active constituent, with whitening, moisturizing, dispels
It the effects of spot, anti-oxidant, anti-aging, is added in cosmetics as cosmetic material, will necessarily there is great benefit to skin.
Microcapsules technology is that some gaseous states or the substance of liquid are solidified into solid one kind newly by some way
The technology of type.In general, microcapsules are made of material core material two parts of shell i.e. wall material and internal cladding.Most micro- glue
Capsule in spherical, wall material mainly pass through certain equipment carry out a series of physical and chemical reaction by natural polymer or
Some inorganic matters are prepared.The partial size of most of microcapsules is all extremely small, and microcapsules play the role of very big in life.Therefore
Enhanced convenience in use, cost is also more cheap, is formed by microcapsules and can protect core material and avoids contact to oxygen, from
And oxidation deterioration, or because outside environmental elements cause to go bad, and influence shelf life.
Pale according to the skin of Nails, ruddy glossy always women praise highly the fashion of pursuit, then beautiful
White, moisturizing or the functional smoothing toner such as anti-oxidant emerge one after another on the market.Previous decades, people are covered using physics mostly
Technology such as " whitening powder " has the function that surface modification, a kind of with strong points, the often companion but skin state changes
With the appearance of some other skin problems, such as dry skin, it is easy for causing the obscure tarnish of skin, skin early ageing,
The problems such as pigment deposition.
Summary of the invention
It is an object of the present invention to provide a kind of smoothing toner and preparation method thereof containing oil and fat of sacha inchi microcapsules, to solve U.S. rattan
The technical issues of fruit oil is unstable, volatile and application range is by limitation.
In order to achieve the above object, the present invention provides a kind of smoothing toner containing oil and fat of sacha inchi microcapsules, feature exists
In in parts by weight, raw material includes: 100-160 parts of distilled water, 3-5 parts of 1,3-BDOs, 4-6 parts of polyethylene glycol -32,2-
4 parts of methyl gluceth -20,3-14 part moisturizer, 0.1-6 parts of antioxidants, 0.5-3 portions of preservatives and 2-8 parts of U.S. rattan fruits
Oil microcapsule.
Preferably, the moisturizer is made of Sodium Hyaluronate, propylene glycol and glycerol.It is highly preferred that described is transparent
The mass ratio of matter acid sodium, propylene glycol and glycerol is 0.5-1.5:0.5-1.5:1, most preferably 1:1:1.
Preferably, the antioxidant is made of tocopherol and di-tert-butyl cresol.It is highly preferred that the tocopherol
It is 0.5-1.5:1, most preferably 1:1 with di-tert-butyl cresol mass ratio.
Preferably, the preservative is made of sodium benzoate and p-hydroxybenzoate.It is highly preferred that the fertility
Phenol and di-tert-butyl cresol mass ratio are 0.5-1.5:1, most preferably 1:1.
Preferably, the raw material of the smoothing toner containing oil and fat of sacha inchi microcapsules also includes 0.05-0.15 parts of essence.
Preferably, the essence is general daily chemical essence.
Preferably, the raw material of the smoothing toner containing oil and fat of sacha inchi microcapsules also includes pigment etc..
Preferably, the partial size of the oil and fat of sacha inchi microcapsules is 40nm-60nm.
Preferably, in parts by weight, the raw material for preparing of the oil and fat of sacha inchi microcapsules includes: 2-15 parts of oil and fat of sacha inchi,
0.5-1 parts of emulsifier, 0.2-5 parts of assistant for emulsifying agent, 0.5-1 parts and water 100-160 parts of preservative.
It is highly preferred that the emulsifier is made of Span-80 and Tween-80, the Span-80 and Tween-80
Mass ratio be 1:1-3.
It is highly preferred that the assistant for emulsifying agent be hexadecanol, 1,3-BDO any one.
Preferably, the preparation method of the oil and fat of sacha inchi microcapsules includes:
Step 1: 2-15 parts of oil and fat of sacha inchi, 0.5-1 parts of emulsifiers and 0.2-5 parts of assistant for emulsifying agents are placed in container, with
300-900r/min rate homogenization obtains stable oil-based system；
Step 2: 0.5-1 portions of preservatives being dissolved in 100-160 parts of water, water phase is obtained；
Step 3: being 65-85 DEG C in temperature range, resulting water phase is added in resulting oil-based system, control is added
Speed is 0.5-1.5mL/min, forms emulsification system；
Step 4: the calcium chloride solution that 10-15 parts of concentration are 3.0mol/l-4.5mol/l being added drop-wise in emulsification system, is controlled
Bath temperature processed is 65-80 DEG C of emulsification 0.8-1h；
Step 5: the sodium carbonate liquor that 10-15 parts of concentration are 0.9mol/l-1.4mol/l is added drop-wise to the resulting cream of step 4
In change system, after completion of dropwise addition, 6-24h is stood, by filtering, drying obtains oil and fat of sacha inchi microscapsule powder.
The present invention also provides the preparation methods of the above-mentioned smoothing toner containing oil and fat of sacha inchi microcapsules, which is characterized in that
Include:
Step 1: weighing 100-160 parts of distilled water, 3-5 parts of 1,3-BDOs, 4-6 parts of polyethylene glycol -32,2-4 part methyl
Glucitol polyethers -20,3-14 part moisturizer, 0.1-6 parts of antioxidants, 0.5-3 portions of preservatives and the 2-8 parts of micro- glue of oil and fat of sacha inchi
Capsule；The moisturizer is Sodium Hyaluronate, propylene glycol and glycerol mixture, and the antioxidant is tocopherol and two tertiary fourths
Base cresols mixture；The preservative is the mixture of sodium benzoate and p-hydroxybenzoate；
Step 2: 3-14 parts of moisturizer being dissolved in 80-130 parts of distilled water, under the continuously stirring of 300-400rpm
Even mixing 15-25min；
Step 3: 0.1-6 parts of antioxidants being added in remaining distilled water, 40-60 DEG C are heated to, in 400-
600rpm's continuously stirs 10-40min；
Step 4: the resulting mixture of step 3 is added in the resulting mixture of step 2, it is continuous in 500-700rpm
The lower uniformly mixing of stirring, is added 0.5-3 parts of preservative mixing, the glacial acetic acid solution for being 4-6% with mass percent concentration later
PH to 5.5-6.5 is adjusted, is cooled to 15-30 DEG C；
Step 5: 2-8 parts of oil and fat of sacha inchi microcapsules, 3-5 part 1,3- fourth two is added in resulting mixture in step 4
Alcohol, 4-6 parts of polyethylene glycol -32,2-4 part methyl gluceths -20, the uniform mixing under the continuously stirring of 450-650rpm,
Until the dispersion of oil and fat of sacha inchi uniform microcapsule, the NaOH solution for being then 6-10% with mass percent concentration adjusts pH and is
5-6 stands 1-4h to get smoothing toner.
Oil and fat of sacha inchi microcapsules in oil and fat of sacha inchi microcapsules smoothing toner of the invention include core material and wall material two parts, with
Oil and fat of sacha inchi is core material, using calcium carbonate as wall material.The mass ratio 1-1.5:1 of the core material and wall material.
After cleaning skin, the present invention is gently beaten in into skin in face containing oil and fat of sacha inchi microcapsules skin softening water droplet,
Daily 2-3 suboptimum.
Compared with prior art, the beneficial effects of the present invention are:
The present invention is applied in smoothing toner using oil and fat of sacha inchi microcapsules as a kind of cosmetic material, is had to skin nursing
The a series of effect such as whitening spot-removing, anti-aging, and there is good replenishing water and preserving moisture, the effect of nourishes rough skin.Use this hair
After the bright microcapsules smoothing toner containing oil and fat of sacha inchi after a few days, there can be apparent soft and moist skin, have and highlight skin, enhance skin
The effect of elastic force, the present invention obtained by smoothing toner it is nontoxic, no sensitization, non-stimulated, use is safe.
For the present invention since oily phase raw material uses oil and fat of sacha inchi, the content of oil and fat of sacha inchi unsaturated fatty acid is higher, is applied to
The effects of better whitening, moisturizing, sun-proof, nti-freckle are had in cosmetics.Due to a variety of lipids such as containing as active constituent, tool
There is anti-aging, anti-oxidant, functions of detumescence, relieving inflammation increases skin repair ability, enhancing skin barrier effect, and control skin moisture is lost
Effect enables the skin to keep moistening for height.
One kind that the present invention obtains contains oil and fat of sacha inchi microcapsules smoothing toner, due to making its stability using microcapsules technology
It is fabulous, the rate of release of vegetable oil is controlled, and impart the higher use value of vegetable oil, the broader scope of application etc.
A series of effects different from simple vegetable oil.
The present invention contains the smoothing toner of oil and fat of sacha inchi microcapsules, is assembled using oil and fat of sacha inchi microcapsules and other raw materials, makes
The smoothing toner is obtained, it is not only very good in replenishing water and preserving moisture and the anti-oxidant aspect of smoothing wrinkle, but also lightening the stain, keep skin moist
Very well, modern is met to the deeper pursuit of skin.The soft of different skin quality is exactly suitble to according to the exploitation of the type of skin
Skin water, therefore, develop it is a kind of have both moisturizing, the smoothing toner that moisturizing, anti-aging are integrated has very extensive application prospect
And market prospects.
Microcapsules Size of the invention is minimum, and the microcapsules of this Nano grade are easier to make percutaneous absorption, is applied to change
In cosmetic, wherein effective component infiltration is made to improve skin anti-aging ability in skin.
Detailed description of the invention
Fig. 1 is the grain size distribution of 2 gained oil and fat of sacha inchi microcapsules smoothing toner of embodiment.
Specific embodiment
Present invention will be further explained below with reference to specific examples.It should be understood that these embodiments are merely to illustrate the present invention
Rather than it limits the scope of the invention.In addition, it should also be understood that, after reading the content taught by the present invention, those skilled in the art
Member can make various changes or modifications the present invention, and such equivalent forms equally fall within the application the appended claims and limited
Range.
Used each raw material is commercial product in following embodiment.
The information of the specification and manufacturer of various raw materials or reagent used in the present invention is as follows:
1,3-BDO analyzes pure, Sinopharm Chemical Reagent Co., Ltd.；
Polyethylene glycol -32；Analyze pure, Sinopharm Chemical Reagent Co., Ltd.；
Methyl gluceth -20 analyzes pure, Sinopharm Chemical Reagent Co., Ltd.；
Glycerol analyzes pure, Sinopharm Chemical Reagent Co., Ltd.；
Tocopherol, Shanghai Jia Chen Chemical Co., Ltd.；
P-hydroxybenzoate, Shanghai Jia Chen Chemical Co., Ltd.；
Flavoring rose essence, daily essence, Shanghai Yi Kesaiting fragrance Co., Ltd；
Oil and fat of sacha inchi, Yunnan Province Pu'er Lian Zhong living resources development corporation, Ltd.；
Tween-80 analyzes pure, Sinopharm Chemical Reagent Co., Ltd.；
Span-80 analyzes pure, Sinopharm Chemical Reagent Co., Ltd.；
Sodium benzoate analyzes pure, Sinopharm Chemical Reagent Co., Ltd.；
Sodium Hyaluronate, Shanghai Chemical Co., Ltd., Hang Seng；
Di-tert-butyl cresol, Shanghai Jia Chen Chemical Co., Ltd.；
NaOH analyzes pure, Sinopharm Chemical Reagent Co., Ltd.；
Glacial acetic acid analyzes pure, Sinopharm Chemical Reagent Co., Ltd.；
The model of instrument and equipment used in the present invention and the information of manufacturer are as follows:
Electronic balance, PL403, Mei Tele-support benefit Instrument Ltd.:
The electronic mulser of digital type high speed, T-25 type, German IKA Co., Ltd；
Constant temperature blender with magnetic force, 524G, Shanghai Mei Yingpu instrument and meter Manufacturing Co., Ltd；
Water bath chader, SHZ-B, Shanghai Bo Xun Industrial Co., Ltd.；
Laser particle analyzer, Nano-ZS, Malvern instrument (China) Co., Ltd；
Moisture of skin analyzer, AS-509, Guangzhou An Sen Electronic Science and Technology Co., Ltd..
Embodiment 1
A kind of smoothing toner containing oil and fat of sacha inchi microcapsules, in parts by weight, raw material include: 100 parts of distilled water；3 parts
1,3-BDO；3 parts of propylene glycol；3 parts of Sodium Hyaluronates；4 parts of polyethylene glycol -32；2 parts of methyl gluceths -20；2 parts
Oil and fat of sacha inchi microcapsules；3 parts of glycerol: 0.1 part of tocopherol；0.1 part of di-tert-butyl cresol；0.50 part of p-hydroxybenzoate；0.5
Part sodium benzoate；0.05 part of flavoring rose essence.
In parts by weight, the raw material for preparing of the oil and fat of sacha inchi microcapsules includes: 2 parts of oil and fat of sacha inchi, emulsifier 0.6
Part, 3 parts of assistant for emulsifying agent, 0.5 part and 100 parts of water of preservative.The emulsifier is the compound of Span-80 and Tween-80,
Span-80:Tween-80 is 1:1.The assistant for emulsifying agent is 1,3-BDO, and the preservative is P-hydroxybenzoic acid
Ester.
The oil and fat of sacha inchi microcapsules the preparation method comprises the following steps:
Step 1: 2 parts of oil and fat of sacha inchi, 0.6 part of emulsifier and 3 parts of assistant for emulsifying agents being placed in container, with 600r/min rate
Homogenization obtains stable oil-based system；
Step 2: 0.5 portion of preservative being dissolved in 100 parts of water, water phase is obtained；
Step 3: being 75 DEG C in temperature range, resulting water phase is added in resulting oil-based system, speed is added in control
Degree is 1mL/min, forms emulsification system；
Step 4: the calcium chloride solution that 10 parts of concentration are 3.0mol/l being added drop-wise in emulsification system, control bath temperature is
80 DEG C of emulsification 1h；
Step 5: the sodium carbonate liquor that 10 parts of concentration are 0.9mol/l being added drop-wise in the resulting emulsification system of step 4, is controlled
Drop rate processed is 0.8ml/min, after completion of dropwise addition, stands 6h, and by filtering, gained filter cake is washed repeatedly with distilled water, is controlled
Temperature processed is dried at 60 DEG C, obtains white oil and fat of sacha inchi microscapsule powder, partial size 40nm-60nm.The U.S. rattan fruit
Oil microcapsule calculates, wherein core material: wall material 1:1 in mass ratio using calcium carbonate as wall material using oil and fat of sacha inchi as core material.
The above-mentioned smoothing toner containing oil and fat of sacha inchi microcapsules the preparation method comprises the following steps:
Step 1: weighing 100 parts of distilled water；3 parts of 1,3-BDO；3 parts of propylene glycol；3 parts of Sodium Hyaluronates；4 parts of poly- second
Glycol -32；2 parts of methyl gluceths -20；2 parts of oil and fat of sacha inchi microcapsules；3 parts of glycerol: 0.1 part of tocopherol；0.1 part of two uncle
Butyl cresols；0.50 part of p-hydroxybenzoate；0.5 part of sodium benzoate；0.05 part of flavoring rose essence；By Sodium Hyaluronate, the third two
Pure and mild glycerol mixes in proportion, obtains 9 parts of Sodium Hyaluronates, propylene glycol and glycerol mixture, as moisturizer, by tocopherol and
Di-tert-butyl cresol is mixed to get 0.2 part of tocopherol and di-tert-butyl cresol mixture in proportion, as antioxidant, by benzene first
Sour sodium and p-hydroxybenzoate mix in proportion, obtain the mixture of 1 part of sodium benzoate and p-hydroxybenzoate, as anti-
Rotten agent；
Step 2: 9 parts of moisturizer being dissolved in 80 parts of distilled water, the uniform mixing under the continuously stirring of 400rpm
15min；
Step 3: 0.2 part of antioxidant being added in remaining distilled water, 50 DEG C are heated to, in the continuous of 400rpm
Stir 10min；
Step 4: the resulting mixture of step 3 being added in the resulting mixture of step 2, in the case where 500pm is continuously stirred
Uniformly mixing, is added 1 part of preservative mixing later, adjusts pH to 6, drop with the glacial acetic acid solution that mass percent concentration is 5%
Temperature is to 25 DEG C；
Step 5: addition 2 parts of oil and fat of sacha inchi microcapsules, 3 parts of 1,3-BDOs in resulting mixture in step 4,4 parts
Polyethylene glycol -32,2 part methyl gluceth -20,0.05 part flavoring rose essence, it is uniformly mixed under the continuously stirring of 450rpm
It closes, this process continues 2h, is then 8% with mass percent concentration until the dispersion of oil and fat of sacha inchi uniform microcapsule
It is 5.5 that NaOH solution, which adjusts pH, stands 3h to get smoothing toner.
Embodiment 2
A kind of smoothing toner containing oil and fat of sacha inchi microcapsules, in parts by weight, raw material include: 130 parts of distilled water；4 parts
1,3-BDO；4 parts of propylene glycol；4 parts of Sodium Hyaluronates；5 parts of polyethylene glycol -32；3 parts of methyl gluceths -20；4 parts
Oil and fat of sacha inchi microcapsules；3 parts of glycerol: 0.2 part of tocopherol；0.2 part of di-tert-butyl cresol；0.8 part of p-hydroxybenzoate；0.8
Part sodium benzoate；0.08 part of flavoring rose essence.
In parts by weight, the raw material for preparing of the oil and fat of sacha inchi microcapsules includes: 4 parts of oil and fat of sacha inchi, emulsifier 0.8
Part, 4 parts of assistant for emulsifying agent, 0.75 part and 130 parts of water of preservative.The emulsifier is the compounding of Span-80 and Tween-80
Object, Span-80:Tween-80 1:1.The assistant for emulsifying agent is 1,3- butanediol, and the preservative is para hydroxybenzene first
Acid esters.
The oil and fat of sacha inchi microcapsules the preparation method comprises the following steps:
Step 1: 4 parts of oil and fat of sacha inchi, 0.8 part of emulsifier and 4 parts of assistant for emulsifying agents being placed in container, with 600r/min speed
Rate homogenization obtains stable oil-based system；
Step 2: 0.75 portion of preservative being dissolved in 130 parts of water, water phase is obtained；
Step 3: being 75 DEG C in temperature range, resulting water phase is added in resulting oil-based system, speed is added in control
Degree is 1mL/min, forms emulsification system；
Step 4: the calcium chloride solution that 12.5 parts of concentration are 3.75mol/l being added drop-wise in emulsification system, water-bath temperature is controlled
Degree is 80 DEG C of emulsification 1h；
Step 5: the sodium carbonate liquor that 12.5 parts of concentration are 1.18mol/l is added drop-wise in the resulting emulsification system of step 4,
Control drop rate is 0.8ml/min, after completion of dropwise addition, stands 12h, and by filtering, gained filter cake is washed repeatedly with distilled water,
Control temperature is dried at 60 DEG C, obtains white oil and fat of sacha inchi microscapsule powder, as shown in Figure 1, partial size is 40nm-60nm.
The oil and fat of sacha inchi microcapsules calculate, wherein core material: wall material in mass ratio using calcium carbonate as wall material using oil and fat of sacha inchi as core material
1.2:1.
The above-mentioned smoothing toner containing oil and fat of sacha inchi microcapsules the preparation method comprises the following steps:
Step 1: weighing 130 parts of distilled water；4 parts of 1,3-BDO；4 parts of propylene glycol；4 parts of Sodium Hyaluronates；5 parts of poly- second
Glycol -32；3 parts of methyl gluceths -20；4 parts of oil and fat of sacha inchi microcapsules；3 parts of glycerol: 0.2 part of tocopherol；0.2 part of two uncle
Butyl cresols；0.8 part of p-hydroxybenzoate；0.8 part of sodium benzoate；0.08 part of flavoring rose essence；
Sodium Hyaluronate, propylene glycol and glycerol are mixed in proportion, it is mixed to obtain 11 parts of Sodium Hyaluronates, propylene glycol and glycerol
Object is closed, as moisturizer；
Tocopherol and di-tert-butyl cresol are mixed to get 0.4 part of tocopherol and di-tert-butyl cresol mixture in proportion,
As antioxidant；
Sodium benzoate and p-hydroxybenzoate are mixed in proportion, obtain 1.6 parts of sodium benzoates and P-hydroxybenzoic acid
The mixture of ester, as preservative；
Step 2: 11 parts of moisturizer being dissolved in 100 parts of distilled water, the uniform mixing under the continuously stirring of 400rpm
15min；
Step 3: 0.4 part of antioxidant being added in remaining distilled water, 50 DEG C are heated to, in the continuous of 400rpm
Stir 10min；
Step 4: the resulting mixture of step 3 being added in the resulting mixture of step 2, in the case where 500pm is continuously stirred
Uniformly mixing, is added 1.6 parts of preservative mixing later, adjusts pH to 6 with the glacial acetic acid solution that mass percent concentration is 5%,
It is cooled to 25 DEG C；
Step 5: addition 4 parts of oil and fat of sacha inchi microcapsules, 4 parts of 1,3- butanediols in resulting mixture in step 4,5 parts
Polyethylene glycol -32,3 part methyl gluceth -20,0.08 part flavoring rose essence, it is uniformly mixed under the continuously stirring of 450rpm
It closes, this process continues 2h, is then 8% with mass percent concentration until the dispersion of oil and fat of sacha inchi uniform microcapsule
It is 5.5 that NaOH solution, which adjusts pH, stands 3h to get smoothing toner.
Embodiment 3
A kind of smoothing toner containing oil and fat of sacha inchi microcapsules, in parts by weight, raw material include: 160 parts of distilled water；5 parts
1,3-BDO；5 parts of propylene glycol；5 parts of Sodium Hyaluronates；6 parts of polyethylene glycol -32；4 parts of methyl gluceths -20；8 parts
Oil and fat of sacha inchi microcapsules；4 parts of glycerol: 0.3 part of tocopherol；0.3 part of di-tert-butyl cresol；1 part of p-hydroxybenzoate；1 part of benzene
Sodium formate；0.1 part of flavoring rose essence.
In parts by weight, the raw material for preparing of the oil and fat of sacha inchi microcapsules includes: 8 parts of oil and fat of sacha inchi, and 1 part of emulsifier,
5 parts of assistant for emulsifying agent, 1 part and 160 parts of water of preservative.The emulsifier is the compound of Span-80 and Tween-80, Span-
80:Tween-80 is 1:1.The assistant for emulsifying agent is 1,3-BDO, and the preservative is p-hydroxybenzoate.
The oil and fat of sacha inchi microcapsules the preparation method comprises the following steps:
Step 1: 8 parts of oil and fat of sacha inchi, 1 part of emulsifier and 5 parts of assistant for emulsifying agents being placed in container, with 600r/min rate
Homogenization obtains stable oil-based system；
Step 2: 1 portion of preservative being dissolved in 160 parts of water, water phase is obtained；
Step 3: being 75 DEG C in temperature range, resulting water phase is added in resulting oil-based system, speed is added in control
Degree is 1mL/min, forms emulsification system；
Step 4: the calcium chloride solution that 15 parts of concentration are 4.5mol/l being added drop-wise in emulsification system, control bath temperature is
80 DEG C of emulsification 1h；
Step 5: the sodium carbonate liquor that 15 parts of concentration are 1.41mol/l being added drop-wise in the resulting emulsification system of step 4, is controlled
Drop rate processed is 0.8ml/min, after completion of dropwise addition, is stood for 24 hours, and by filtering, gained filter cake is washed repeatedly with distilled water, is controlled
Temperature processed is dried at 60 DEG C, obtains white oil and fat of sacha inchi microscapsule powder, partial size 40nm-60nm.The U.S. rattan fruit
Oil microcapsule calculates, wherein core material: wall material 1.5:1 in mass ratio using calcium carbonate as wall material using oil and fat of sacha inchi as core material.
The above-mentioned smoothing toner containing oil and fat of sacha inchi microcapsules the preparation method comprises the following steps:
Step 1: weighing 160 parts of distilled water；5 parts of 1,3-BDO；5 parts of propylene glycol；5 parts of Sodium Hyaluronates；6 parts of poly- second
Glycol -32；4 parts of methyl gluceths -20；8 parts of oil and fat of sacha inchi microcapsules；4 parts of glycerol: 0.3 part of tocopherol；0.3 part of two uncle
Butyl cresols；1 part of p-hydroxybenzoate；1 part of sodium benzoate；0.1 part of flavoring rose essence；
Sodium Hyaluronate, propylene glycol and glycerol are mixed in proportion, it is mixed to obtain 14 parts of Sodium Hyaluronates, propylene glycol and glycerol
Object is closed, as moisturizer；
Tocopherol and di-tert-butyl cresol are mixed to get 0.6 part of tocopherol and di-tert-butyl cresol mixture in proportion,
As antioxidant；
Sodium benzoate and p-hydroxybenzoate are mixed in proportion, obtain 2 parts of sodium benzoates and p-hydroxybenzoate
Mixture, as preservative；
Step 2: 14 parts of moisturizer being dissolved in 130 parts of distilled water, the uniform mixing under the continuously stirring of 400rpm
15min；
Step 3: 0.6 part of antioxidant being added in remaining distilled water, 50 DEG C are heated to, in the continuous of 400rpm
Stir 10min；
Step 4: the resulting mixture of step 3 being added in the resulting mixture of step 2, in the case where 500pm is continuously stirred
Uniformly mixing, is added 2 parts of preservative mixing later, adjusts pH to 6, drop with the glacial acetic acid solution that mass percent concentration is 5%
Temperature is to 25 DEG C；
Step 5: addition 8 parts of oil and fat of sacha inchi microcapsules, 5 parts of 1,3- butanediols in resulting mixture in step 4,6 parts
Polyethylene glycol -32,4 part methyl gluceth -20,0.1 part flavoring rose essence, the uniform mixing under the continuously stirring of 450rpm,
This process continues 2h, and until the dispersion of oil and fat of sacha inchi uniform microcapsule, the NaOH for being then 8% with mass percent concentration is molten
It is 5.5 that liquid, which adjusts pH, stands 3h to get smoothing toner.
Above-mentioned resulting oil and fat of sacha inchi microcapsules smoothing toner is in simple and elegant white, is suitable as skin care maintenance, has whitening, protects
It is wet, it is wrinkle resistant and other effects, it easily absorbs, security performance is high, is suitable for various skin quality.
The moistening effect of the oil and fat of sacha inchi microcapsules smoothing toner of case study on implementation 1-3 is tested.
Test method: selecting 20-50 years old 60 people, and men and women is fifty-fifty, health, rule of life, no skin disease, and random point
It is 3 groups, every group of 20 people.Testing environment temperature is 25 DEG C, and the moisture content of right face is measured in the environment that relative humidity is 60%.
2 square centimeters of square Experimental Area is drawn as skin test zone in right face.Subject is cleaning flesh
After skin, skin surface moisture is wiped, 1g oil and fat of sacha inchi microcapsules smoothing toner is taken to be applied to facial skin.It is measured using moisture of skin
Instrument measures 2 hours right face skin water content after smearing oil and fat of sacha inchi microcapsules smoothing toner respectively, and records result.Concrete outcome is shown in
Following table.
Oil and fat of sacha inchi microcapsules smoothing toner moistening effect test result table:
| Skin moisture content, % | |
| Embodiment 1 | 42.5 |
| Embodiment 2 | 43.3 |
| Embodiment 3 | 45.2 |
Above-described is only one embodiment of the present invention, for those of ordinary skill in the art, not
Under the premise of the disengaging present invention makes structure, several deformations and transformation can also be made, these are all within the scope of protection of the present invention.
Claims (10)
1. a kind of smoothing toner containing oil and fat of sacha inchi microcapsules, which is characterized in that in parts by weight, raw material includes: 100-160
Part distilled water, 3-5 parts of 1,3-BDOs, 4-6 parts of polyethylene glycol -32,2-4 part methyl gluceth -20,3-14 part moisturizings
Agent, 0.1-6 parts of antioxidants, 0.5-3 portions of preservatives and 2-8 parts of oil and fat of sacha inchi microcapsules.
2. the smoothing toner as described in claim 1 containing oil and fat of sacha inchi microcapsules, which is characterized in that the moisturizer is by saturating
Bright matter acid sodium, propylene glycol and glycerol composition.
3. the smoothing toner as described in claim 1 containing oil and fat of sacha inchi microcapsules, which is characterized in that the antioxidant by
Tocopherol and di-tert-butyl cresol composition.
4. the smoothing toner as described in claim 1 containing oil and fat of sacha inchi microcapsules, which is characterized in that the preservative is by benzene
Sodium formate and p-hydroxybenzoate composition.
5. the smoothing toner as described in claim 1 containing oil and fat of sacha inchi microcapsules, which is characterized in that described contains U.S. rattan fruit
The raw material of the smoothing toner of oil microcapsule also includes 0.05-0.15 parts of essence.
6. the smoothing toner as described in claim 1 containing oil and fat of sacha inchi microcapsules, which is characterized in that the oil and fat of sacha inchi is micro-
The partial size of capsule is 40nm-60nm.
7. the smoothing toner as described in claim 1 containing oil and fat of sacha inchi microcapsules, which is characterized in that in parts by weight, described
The raw materials for preparing of oil and fat of sacha inchi microcapsules include: 2-15 parts of oil and fat of sacha inchi, 0.5-1 parts of emulsifier, 0.2-5 parts of assistant for emulsifying agent,
0.5-1 parts and water 100-160 parts of preservative.
8. the smoothing toner as described in claim 1 containing oil and fat of sacha inchi microcapsules, which is characterized in that the emulsifier by
The mass ratio of Span-80 and Tween-80 composition, the Span-80 and Tween-80 are 1:1-3；The assistant for emulsifying agent is
Hexadecanol, 1,3-BDO any one.
9. the smoothing toner as described in claim 1 containing oil and fat of sacha inchi microcapsules, which is characterized in that the oil and fat of sacha inchi is micro-
The preparation method of capsule includes:
Step 1: 2-15 parts of oil and fat of sacha inchi, 0.5-1 parts of emulsifiers and 0.2-5 parts of assistant for emulsifying agents being placed in container, with 300-
900r/min rate homogenization obtains stable oil-based system；
Step 2: 0.5-1 portions of preservatives being dissolved in 100-160 parts of water, water phase is obtained；
Step 3: being 65-85 DEG C in temperature range, resulting water phase is added in resulting oil-based system, speed is added in control
For 0.5-1.5mL/min, emulsification system is formed；
Step 4: the calcium chloride solution that 10-15 parts of concentration are 3.0mol/l-4.5mol/l being added drop-wise in emulsification system, water is controlled
Bath temperature is 65-80 DEG C of emulsification 0.8-1h；
Step 5: the sodium carbonate liquor that 10-15 parts of concentration are 0.9mol/l-1.4mol/l is added drop-wise to the resulting emulsified body of step 4
In system, after completion of dropwise addition, 6-24h is stood, by filtering, drying obtains oil and fat of sacha inchi microscapsule powder.
10. the preparation method of the smoothing toner containing oil and fat of sacha inchi microcapsules described in claim 1 characterized by comprising
Step 1: weighing 100-160 parts of distilled water, 3-5 parts of 1,3-BDOs, 4-6 parts of polyethylene glycol -32,2-4 part methyls
Alcohol polyethers -20,3-14 part moisturizer, 0.1-6 parts of antioxidants, 0.5-3 portions of preservatives and 2-8 parts of oil and fat of sacha inchi microcapsules；Institute
The moisturizer stated is Sodium Hyaluronate, propylene glycol and glycerol mixture, and the antioxidant is tocopherol and di-t-butyl first
Phenol mixture；The preservative is the mixture of sodium benzoate and p-hydroxybenzoate；
Step 2: 3-14 parts of moisturizer are dissolved in 80-130 parts of distilled water, it is uniformly mixed under the continuously stirring of 300-400rpm
Close 15-25min；
Step 3: 0.1-6 parts of antioxidants being added in remaining distilled water, 40-60 DEG C are heated to, 400-600rpm's
Continuously stir 10-40min；
Step 4: the resulting mixture of step 3 being added in the resulting mixture of step 2, in the case where 500-700rpm is continuously stirred
Uniformly mixing, is added 0.5-3 parts of preservative mixing later, adjusts pH with the glacial acetic acid solution that mass percent concentration is 4-6%
To 5.5-6.5, it is cooled to 15-30 DEG C；
Step 5: 2-8 parts of oil and fat of sacha inchi microcapsules, 3-5 parts of 1,3-BDOs, 4-6 is added in resulting mixture in step 4
Part polyethylene glycol -32,2-4 part methyl gluceth -20, the uniform mixing under the continuously stirring of 450-650rpm, until beauty
Until rattan fruit oil microcapsule is evenly dispersed, it is 5-6 that the NaOH solution for being then 6-10% with mass percent concentration, which adjusts pH, quiet
1-4h is set to get smoothing toner.
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| CN110974711A (en) * | 2019-12-11 | 2020-04-10 | 上海应用技术大学 | Azelaic acid microcapsule and preparation method thereof |
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| CN112618420A (en) * | 2021-01-12 | 2021-04-09 | 上海应用技术大学 | Jojoba oil-loaded microcapsule and preparation method thereof |
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