CN110085510B - 一种多层单晶硅薄膜的制备方法 - Google Patents

一种多层单晶硅薄膜的制备方法 Download PDF

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CN110085510B
CN110085510B CN201810075920.8A CN201810075920A CN110085510B CN 110085510 B CN110085510 B CN 110085510B CN 201810075920 A CN201810075920 A CN 201810075920A CN 110085510 B CN110085510 B CN 110085510B
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党启森
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SHENYANG SILICON TECHNOLOGY CO LTD
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Abstract

一种多层单晶硅薄膜的制备方法,依次按照下述要求制备多层单晶硅薄膜:①首先,取两片表面洁净的单晶硅片采用等离子激活技术处理硅片表面后,进行预键合;②将键合后的硅片,传送至在200‑300℃的温度退火炉内进行6‑10小时的退火,既防止了过渡区的产生又将此两片硅片完成彻底键合,③将退火后的键合片进行减薄处理以达到需求的目标厚度;④将减薄处理后的SOI片,重新按照一片单晶硅片与另一片单晶硅片再次进行①‑③的操作,得到多层单晶硅薄膜。本发明采用等离子激活技术处理过的硅片键合时预键合力大,退火后键合效果优良;各层界面无明显电阻过渡区;可以对各层单晶硅的厚度进行有效控制;其综合技术效果良好;具有较为巨大的经济价值和社会价值。

Description

一种多层单晶硅薄膜的制备方法
技术领域
本发明涉及多层单晶硅薄膜的制备技术领域,特别提供了一种多层单晶硅薄膜的制备方法。
背景技术
现有技术中,申请号为201510460906.6和201510481429.1的中国专利申请文件披露了多层单晶硅薄膜的制备方法;但是其操作较为复杂,其技术效果仍不理想。仍有很多亟待解决的技术问题,例如:多层单晶硅薄膜产品的各层之间仍然存在较明显的电阻过渡区。
人们迫切希望获得一种技术效果优良的多层单晶硅薄膜。
发明内容
本发明的目是提供一种技术效果优良的多层单晶硅薄膜。
本发明一种多层单晶硅薄膜的制备方法,其特征在于:依次按照下述要求制备多层单晶硅薄膜:
①首先,取两片硅片Si-1,Si-2进行常规湿法清洗清洁表面,再在真空条件下(真空度<1Torr)采用等离子激活技术对表面进行5s-20s的处理以增强键合时预键合力,进行预键合;
②将完成预键合的硅片,从室温以5-10℃/min的速率升至200-300℃的恒定温度,在此温度下维持6-10小时退火,此温度下既防止过渡区的产生又可将两片硅片彻底键合在一起;
③对此键合片通过粗磨+精磨+抛光的处理方式对Si-2进行厚度上的减薄达到所需厚度要求;要求顶层Si-2剩余2-100um;
④将步骤③得到的SOI硅片视为整体Si-1,取一片新硅片Si-3视为 Si-2重复步骤①-③的操作,得到Si-1/Si-2/Si-3的多层SOI硅片;
⑤重复步骤④操作,得到所需层数的多层SOI硅片 (Si-1/Si-2/…/Si-n)。
附带说明:①在多层单晶硅薄膜的制备过程中,最高温度为300℃,在此温度下得到的多层SOI硅片界面不存在明显的过渡区;②所选硅片无特定要求,一般相邻的两层存在电阻率差异或掺杂类型差异,例如:Si-1为重掺片,Si-2为轻掺片。或Si-1为P型硅片,Si-2为N型硅片;③通过粗磨精磨抛光的方式进行顶层的减薄,能够使厚度被控制在2-100um;通常在Si-1上采用外延生长的方式不容易得到较厚的Si薄膜,而此方式能够较容易地停止在70um/60um/50um。
所述多层单晶硅薄膜的制备方法,优选要求保护的技术内容还有:
所述多层单晶硅薄膜的制备方法中,对硅片的厚度进行减薄处理以达到要求的方法具体是:先粗磨再精磨再化学机械抛光;所用设备为Disco 公司型号为8761的磨抛一体机,该设备是一台磨、抛一体机,该设备具有在线测量工具,可以停止在所需厚度(2-100um)。
采用等离子激活技术处理硅片表面以增强键合时预键合力和最终形成的键合力,取两片经过清洗预处理后的待键合硅片,将其准备键合的表面对准,在真空环境下(低真空)进行预键合动作
采用等离子激活技术处理硅片表面以增强键合时预键合力之前,对硅片表面进行湿法清洗,常规清洗顺序为:使用化学液SC1清洗→使用H2O 洗→使用化学液SC2清洗→使用H2O洗;其中所用化学液SC1的成分及配比为:NH4OH:H2O2:H2O=1:5:40;化学液SC2的成分及配比为:HCl:H2O=1:2:20; H2O为DI water。
将由两块硅片键合后的整体视为一个整体,再取一个硅片,并分别对其二者表面进行湿法清洗,然后等离子激活;之后将二者待键合表面相对,在真空环境下进行预键合;将预键合后的前述键合片在200-300℃的温度下进行6-10小时的退火将两片硅片彻底键合在一起;通过粗磨+精磨+化学机械抛光的处理方式进行厚度上的减薄,使其达到所需厚度的薄膜。
多层单晶硅薄膜的硅片层数为2-5层;这里的层数是优选,前述内容已经包含了2、3层;这一条实质重点保护4-30更多层。如果各层有自己的厚度要求,也可以分别详细规定。
2个单晶硅片、键合层;其中:单晶硅片键合前几何参数满足下述要求:单晶硅片满足:平整度TTV<1um,SFQR<0.3um,表面粗糙度Rms<0.5nm,厚度450um-750um,电阻率:0.01-1000ohm·cm。
进一步优选要求是:
多层单晶硅薄膜的硅片层数为2-5层;
2个单晶硅片、键合层;其中:单晶硅片满足下述要求:硅片类型:P 型或N型,相邻两层电阻率不同或掺杂类型不同。
本发明的优点是:键合时预键合力大,键合效果优良;界面无明显电阻过渡区;可以对各层单晶硅的厚度进行有效控制;其综合技术效果良好;具有较为巨大的经济价值和社会价值。
附图说明
图1为多层单晶硅薄膜的制备原理示意简图。
具体实施方式
附图1的附带说明:
1)Si-1/Si-2/Si-3/Si-n均代表一片表面洁净的单晶硅片;
2)Si-1/Si-2/Si-3/Si-n均代表按照一定目标厚度进行磨抛后的硅片。
实施例1
一种多层单晶硅薄膜的制备方法,其依次按照下述要求制备多层单晶硅薄膜:
①首先,取两片硅片Si-1,Si-2进行常规湿法清洗清洁表面,再在真空条件下(真空度<1Torr)采用等离子激活技术对表面进行5s-20s的处理以增强键合时预键合力,进行预键合;
②将完成预键合的硅片,从室温以5-10℃/min的速率升至200-300℃的恒定温度,在此温度下维持6-10小时退火,此温度下既防止过渡区的产生又可将两片硅片彻底键合在一起;
③对此键合片通过粗磨+精磨+抛光的处理方式对Si-2进行厚度上的减薄达到所需厚度要求;要求顶层Si-2剩余2-100um;
④将步骤③得到的SOI硅片视为整体Si-1,取一片新硅片Si-3视为 Si-2重复步骤①-③的操作,得到Si-1/Si-2/Si-3的多层SOI硅片;
⑤重复步骤④操作,得到所需层数的多层SOI硅片 (Si-1/Si-2/…/Si-n)。
附带说明:①在多层单晶硅薄膜的制备过程中,最高温度为300℃,在此温度下得到的多层SOI硅片界面不存在明显的过渡区;②所选硅片无特定要求,一般相邻的两层存在电阻率差异或掺杂类型差异,例如:Si-1为重掺片,Si-2为轻掺片。或Si-1为P型硅片,Si-2为N型硅片;③通过粗磨精磨抛光的方式进行顶层的减薄,能够使厚度被控制在2-100um;通常在Si-1上采用外延生长的方式不容易得到较厚的Si薄膜,而此方式能够较容易地停止在70um/60um/50um。
所述多层单晶硅薄膜的制备方法中还有下述补充要求内容:
对硅片的厚度进行减薄处理以达到要求的方法具体是:先粗磨再精磨再化学机械抛光;所用设备为Disco公司型号为8761的磨抛一体机,该设备是一台磨、抛一体机,该设备具有在线测量工具,可以停止在所需厚度 (即2-100um)。
采用等离子激活技术处理硅片表面以增强键合时预键合力和最终形成的键合力,取两片经过清洗预处理后的待键合硅片,将其准备键合的表面对准,在真空环境下(低真空)进行预键合动作。
采用等离子激活技术处理硅片表面以增强键合时预键合力之前,对硅片表面进行湿法清洗,常规清洗顺序为:使用化学液SC1清洗→使用H2O 洗→使用化学液SC2清洗→使用H2O洗;其中所用化学液SC1的成分及配比为:NH4OH:H2O2:H2O=1:5:40;化学液SC2的成分及配比为:HCl:H2O=1:2:20; H2O为DI water。
将由两块硅片键合后的整体视为一个整体,再取一个硅片,并分别对其二者表面进行湿法清洗,然后等离子激活;之后将二者待键合表面相对,在真空环境下进行预键合;将预键合后的前述键合片在200-300℃的温度下进行6-10小时的退火将两片硅片彻底键合在一起;通过粗磨+精磨+化学机械抛光的处理方式进行厚度上的减薄,使其达到所需厚度的薄膜。
多层单晶硅薄膜的硅片层数为2-5层;
2个单晶硅片、键合层;其中:单晶硅片键合前几何参数满足下述要求:单晶硅片满足:平整度TTV<1um,SFQR<0.3um,表面粗糙度Rms<0.5nm,厚度450um-750um,电阻率:0.01-1000ohm·cm。单晶硅片满足下述要求:硅片类型:P型或N型,相邻两层电阻率不同或掺杂类型不同。
本实施例键合时预键合力大,键合效果优良;界面无明显电阻过渡区;可以对各层单晶硅的厚度进行有效控制;其综合技术效果良好;具有较为巨大的经济价值和社会价值。

Claims (7)

1.一种多层单晶硅薄膜的制备方法,其特征在于:依次按照下述要求制备多层单晶硅薄膜:
①首先,取两片硅片Si-1,Si-2进行常规湿法清洗清洁表面,再在真空度<1Torr的真空条件下采用等离子激活技术对表面进行5s-20s的处理以增强键合时预键合力,进行预键合;
②将完成预键合的硅片,从室温以5-10℃/min的速率升至200-300℃的恒定温度,在此温度下维持6-10小时退火;
③对此键合片通过粗磨+精磨+抛光的处理方式对Si-2进行厚度上的减薄达到所需厚度要求;要求顶层Si-2剩余2-100um;
④将步骤③得到的SOI硅片视为整体Si-1,取一片新硅片Si-3视为Si-2重复步骤①-③的操作,得到Si-1/Si-2/Si-3的多层SOI硅片;
⑤重复步骤④操作,得到所需层数的多层SOI硅片(Si-1/Si-2/…/Si-n)。
2.按照权利要求1所述多层单晶硅薄膜的制备方法,其特征在于:所述多层单晶硅薄膜的制备方法中,对硅片的厚度进行减薄处理以达到要求的方法具体是:先粗磨再精磨再化学机械抛光。
3.按照权利要求2所述多层单晶硅薄膜的制备方法,其特征在于:
采用等离子激活技术处理硅片表面以增强键合时预键合力和最终形成的键合力,取两片经过清洗预处理后的待键合硅片,将其准备键合的表面对准,在真空环境下进行预键合动作。
4.按照权利要求2所述多层单晶硅薄膜的制备方法,其特征在于:采用等离子激活技术处理硅片表面以增强键合时预键合力之前,对硅片表面进行湿法清洗,常规清洗顺序为:使用化学液SC1清洗→使用H2O洗→使用化学液SC2清洗→使用H2O洗;其中所用化学液SC1的成分及配比为:NH4OH:H2O2:H2O=1:5:40;化学液SC2的成分及配比为:HCl:H2O=1:2:20;H2O为DI water。
5.按照权利要求1-4其中之一所述多层单晶硅薄膜的制备方法,其特征在于:将由两块硅片键合后的整体视为一个整体,再取一个硅片,并分别对其二者表面进行湿法清洗,然后等离子激活;之后将二者待键合表面相对,在真空环境下进行预键合;将预键合后的前述键合片在200-300℃的温度下进行6-10小时的退火将两片硅片彻底键合在一起;通过粗磨+精磨+化学机械抛光的处理方式进行厚度上的减薄,使其达到所需厚度的薄膜。
6.按照权利要求5所述多层单晶硅薄膜的制备方法,其特征在于:
多层单晶硅薄膜的硅片层数为2-30层;
2个单晶硅片、键合层;其中:单晶硅片满足下述要求:单晶硅片满足:平整度TTV<1um,SFQR<0.3um,表面粗糙度Rms<0.5nm,厚度450um-750um,电阻率:0.01-1000ohm·cm。
7.按照权利要求6所述多层单晶硅薄膜的制备方法,其特征在于:
多层单晶硅薄膜的硅片层数为2-5层;
2个单晶硅片、键合层;其中:单晶硅片满足下述要求:硅片类型:P型或N型,相邻两层电阻率不同或掺杂类型不同。
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