CN110050313B - 氧化锌压敏电阻及其制造方法 - Google Patents
氧化锌压敏电阻及其制造方法 Download PDFInfo
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- CN110050313B CN110050313B CN201780075326.2A CN201780075326A CN110050313B CN 110050313 B CN110050313 B CN 110050313B CN 201780075326 A CN201780075326 A CN 201780075326A CN 110050313 B CN110050313 B CN 110050313B
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- zinc oxide
- varistor
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- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 title claims abstract description 295
- 239000011787 zinc oxide Substances 0.000 title claims abstract description 112
- 238000004519 manufacturing process Methods 0.000 title claims description 30
- 239000002245 particle Substances 0.000 claims abstract description 87
- 239000013078 crystal Substances 0.000 claims abstract description 29
- 239000000654 additive Substances 0.000 claims abstract description 20
- 230000000996 additive effect Effects 0.000 claims abstract description 16
- 238000004438 BET method Methods 0.000 claims abstract description 9
- 239000002243 precursor Substances 0.000 claims description 67
- 238000005245 sintering Methods 0.000 claims description 40
- 239000000843 powder Substances 0.000 claims description 33
- 238000000034 method Methods 0.000 claims description 32
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 28
- UOURRHZRLGCVDA-UHFFFAOYSA-D pentazinc;dicarbonate;hexahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[Zn+2].[O-]C([O-])=O.[O-]C([O-])=O UOURRHZRLGCVDA-UHFFFAOYSA-D 0.000 claims description 24
- 230000001186 cumulative effect Effects 0.000 claims description 19
- 239000011572 manganese Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 12
- 238000002441 X-ray diffraction Methods 0.000 claims description 11
- 239000002002 slurry Substances 0.000 claims description 11
- 229910052777 Praseodymium Inorganic materials 0.000 claims description 10
- 229910052797 bismuth Inorganic materials 0.000 claims description 10
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 9
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 9
- 229910017052 cobalt Inorganic materials 0.000 claims description 9
- 239000010941 cobalt Substances 0.000 claims description 9
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 9
- 229910052748 manganese Inorganic materials 0.000 claims description 9
- 229910052759 nickel Inorganic materials 0.000 claims description 9
- PUDIUYLPXJFUGB-UHFFFAOYSA-N praseodymium atom Chemical compound [Pr] PUDIUYLPXJFUGB-UHFFFAOYSA-N 0.000 claims description 9
- 229910052723 transition metal Inorganic materials 0.000 claims description 9
- 238000000790 scattering method Methods 0.000 claims description 8
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 5
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910052796 boron Inorganic materials 0.000 claims description 5
- 239000011575 calcium Substances 0.000 claims description 5
- 229910052791 calcium Inorganic materials 0.000 claims description 5
- FMRLDPWIRHBCCC-UHFFFAOYSA-L Zinc carbonate Chemical compound [Zn+2].[O-]C([O-])=O FMRLDPWIRHBCCC-UHFFFAOYSA-L 0.000 claims description 4
- 239000011667 zinc carbonate Substances 0.000 claims description 4
- 235000004416 zinc carbonate Nutrition 0.000 claims description 4
- 229910000010 zinc carbonate Inorganic materials 0.000 claims description 4
- 239000002994 raw material Substances 0.000 abstract description 21
- 238000010438 heat treatment Methods 0.000 description 40
- 230000015572 biosynthetic process Effects 0.000 description 35
- 238000003786 synthesis reaction Methods 0.000 description 34
- 230000000052 comparative effect Effects 0.000 description 25
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 17
- 239000001099 ammonium carbonate Substances 0.000 description 17
- 235000012501 ammonium carbonate Nutrition 0.000 description 17
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 15
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 description 14
- 239000000047 product Substances 0.000 description 14
- 239000000243 solution Substances 0.000 description 14
- 238000011156 evaluation Methods 0.000 description 10
- 239000011701 zinc Substances 0.000 description 10
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 10
- ONDPHDOFVYQSGI-UHFFFAOYSA-N zinc nitrate Chemical compound [Zn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ONDPHDOFVYQSGI-UHFFFAOYSA-N 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 9
- 230000018044 dehydration Effects 0.000 description 9
- 238000006297 dehydration reaction Methods 0.000 description 9
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- 230000002829 reductive effect Effects 0.000 description 9
- 229910052725 zinc Inorganic materials 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 7
- 239000002253 acid Substances 0.000 description 7
- 238000012856 packing Methods 0.000 description 7
- 235000017557 sodium bicarbonate Nutrition 0.000 description 7
- 229910000030 sodium bicarbonate Inorganic materials 0.000 description 7
- 239000013585 weight reducing agent Substances 0.000 description 7
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 238000000280 densification Methods 0.000 description 6
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- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 5
- 230000002159 abnormal effect Effects 0.000 description 5
- 238000004458 analytical method Methods 0.000 description 5
- 239000007864 aqueous solution Substances 0.000 description 5
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- 239000007788 liquid Substances 0.000 description 5
- 239000011592 zinc chloride Substances 0.000 description 5
- 235000005074 zinc chloride Nutrition 0.000 description 5
- 241000220317 Rosa Species 0.000 description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000001513 hot isostatic pressing Methods 0.000 description 4
- 238000009766 low-temperature sintering Methods 0.000 description 4
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 239000000919 ceramic Substances 0.000 description 3
- 238000001816 cooling Methods 0.000 description 3
- 239000002537 cosmetic Substances 0.000 description 3
- 238000011049 filling Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 238000000967 suction filtration Methods 0.000 description 3
- XIOUDVJTOYVRTB-UHFFFAOYSA-N 1-(1-adamantyl)-3-aminothiourea Chemical compound C1C(C2)CC3CC2CC1(NC(=S)NN)C3 XIOUDVJTOYVRTB-UHFFFAOYSA-N 0.000 description 2
- 230000005653 Brownian motion process Effects 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical group [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 description 2
- 230000001133 acceleration Effects 0.000 description 2
- 230000004888 barrier function Effects 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 238000005537 brownian motion Methods 0.000 description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000006243 chemical reaction Methods 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 230000003247 decreasing effect Effects 0.000 description 2
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- 230000000694 effects Effects 0.000 description 2
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- 238000005755 formation reaction Methods 0.000 description 2
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- 229910052763 palladium Inorganic materials 0.000 description 2
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- 238000004321 preservation Methods 0.000 description 2
- 239000011164 primary particle Substances 0.000 description 2
- 238000005477 sputtering target Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- -1 zinc carboxylate salt Chemical class 0.000 description 2
- 238000007088 Archimedes method Methods 0.000 description 1
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- 238000005169 Debye-Scherrer Methods 0.000 description 1
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- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 238000005311 autocorrelation function Methods 0.000 description 1
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- 238000005469 granulation Methods 0.000 description 1
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- C04B35/453—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on oxide ceramics based on zinc, tin, or bismuth oxides or solid solutions thereof with other oxides, e.g. zincates, stannates or bismuthates
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- C04B35/622—Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/626—Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
- C04B35/62605—Treating the starting powders individually or as mixtures
- C04B35/62645—Thermal treatment of powders or mixtures thereof other than sintering
- C04B35/62675—Thermal treatment of powders or mixtures thereof other than sintering characterised by the treatment temperature
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- H01B1/00—Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
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- H01C7/00—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material
- H01C7/10—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material voltage responsive, i.e. varistors
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- H01C7/10—Non-adjustable resistors formed as one or more layers or coatings; Non-adjustable resistors made from powdered conducting material or powdered semi-conducting material with or without insulating material voltage responsive, i.e. varistors
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PCT/JP2017/043953 WO2018105689A1 (ja) | 2016-12-07 | 2017-12-07 | 酸化亜鉛バリスタおよびその製造方法 |
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JPS58124204A (ja) * | 1982-01-21 | 1983-07-23 | 株式会社東芝 | 非直線抵抗体の製造方法 |
JPS6046005A (ja) * | 1983-08-24 | 1985-03-12 | 株式会社富士電機総合研究所 | 電圧非直線抵抗体 |
JP2001220136A (ja) * | 2000-02-09 | 2001-08-14 | Hakusui Tech Co Ltd | 酸化亜鉛微粒子の製造方法 |
CN101531507A (zh) * | 2009-04-10 | 2009-09-16 | 孙丹峰 | 高能型氧化锌压敏电阻复合粉体及该压敏电阻的制造方法 |
CN102290176A (zh) * | 2011-06-08 | 2011-12-21 | 上海大学 | 一种直流氧化锌压敏电阻片及其制备方法 |
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JPS5617410A (en) | 1979-07-24 | 1981-02-19 | Toshiba Corp | Thyristor converter |
JPH0685363B2 (ja) * | 1991-09-30 | 1994-10-26 | ソマール株式会社 | 高電圧用バリスタ及びその製造方法 |
JP2003119080A (ja) | 2001-10-09 | 2003-04-23 | Nippon Soken Inc | セラミック素子の製造方法 |
JP5010183B2 (ja) | 2005-06-02 | 2012-08-29 | 株式会社 資生堂 | 崩壊性酸化亜鉛粉体の製造方法 |
JP5150111B2 (ja) * | 2007-03-05 | 2013-02-20 | 株式会社東芝 | ZnOバリスター粉末 |
US8399092B2 (en) * | 2009-10-07 | 2013-03-19 | Sakai Chemical Industry Co., Ltd. | Zinc oxide particle having high bulk density, method for producing it, exoergic filler, exoergic resin composition, exoergic grease and exoergic coating composition |
JP5617410B2 (ja) * | 2010-07-23 | 2014-11-05 | 堺化学工業株式会社 | 酸化亜鉛粒子、樹脂組成物、グリース、塗料組成物及び化粧料 |
JP5993703B2 (ja) * | 2012-02-17 | 2016-09-14 | 住友化学株式会社 | 酸化亜鉛系粉末の製造方法 |
JP2015038014A (ja) | 2013-07-19 | 2015-02-26 | パナソニック株式会社 | 薄片状粉末、薄片状粉末の製造方法および薄片状粉末を含有する化粧品 |
JP6754288B2 (ja) * | 2016-12-07 | 2020-09-09 | Jfeミネラル株式会社 | 高強度で熱伝導率の低い酸化亜鉛焼結体作製用酸化亜鉛粉末 |
JP7169776B2 (ja) * | 2018-06-06 | 2022-11-11 | Koa株式会社 | 酸化亜鉛バリスタおよびその製造方法 |
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Publication number | Priority date | Publication date | Assignee | Title |
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JPS58124204A (ja) * | 1982-01-21 | 1983-07-23 | 株式会社東芝 | 非直線抵抗体の製造方法 |
JPS6046005A (ja) * | 1983-08-24 | 1985-03-12 | 株式会社富士電機総合研究所 | 電圧非直線抵抗体 |
JP2001220136A (ja) * | 2000-02-09 | 2001-08-14 | Hakusui Tech Co Ltd | 酸化亜鉛微粒子の製造方法 |
CN101531507A (zh) * | 2009-04-10 | 2009-09-16 | 孙丹峰 | 高能型氧化锌压敏电阻复合粉体及该压敏电阻的制造方法 |
CN102290176A (zh) * | 2011-06-08 | 2011-12-21 | 上海大学 | 一种直流氧化锌压敏电阻片及其制备方法 |
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DE112017006173T5 (de) | 2019-08-22 |
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