CN109971246A - A kind of vegetable oil type printing ink and its manufacturing method - Google Patents
A kind of vegetable oil type printing ink and its manufacturing method Download PDFInfo
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- CN109971246A CN109971246A CN201711454206.1A CN201711454206A CN109971246A CN 109971246 A CN109971246 A CN 109971246A CN 201711454206 A CN201711454206 A CN 201711454206A CN 109971246 A CN109971246 A CN 109971246A
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- China
- Prior art keywords
- oil
- manufacturing
- catalyst
- stillingia
- ink
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/06—Printing inks based on fatty oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
- C09D11/104—Polyesters
- C09D11/105—Alkyd resins
Abstract
A kind of vegetable oil type printing ink of the invention is made of the raw material of following weight percent content: 35%~40% stillingia stand oil, 32%~42% refined soybean oil, 3%~6% purification tung oil, 13%~18% pigment, 3%~5% filler material, 1%~3% assisted resin, 0.5%~1% drier, 1%~3% micro mist wax, 0.5%~1% antioxidant and 0.5%~1% vanilla flavour concentrate.To link godied oil by developing Chinese catalpa oil, plant type ink formulations are formed, develops and has a safety feature, low to human body and environmental hazard and advantage of lower cost environment protecting plant oil type off-set oil ink.
Description
Technical field
The present invention relates to a kind of ink, specifically, be a kind of environment-friendly plant type ink suitable for printing and
Its manufacturing method.
Background technique
Ink is described blood for printing industry, this is apt.Carrier of the ink as color, itself
Effect is not only to be presented in various colors on various paper with fuller state, and more to take into account in printing process
Machine requirement, stablize printing machine can and the product of lasting printing high quality in the case where running at high speed.Therefore ink
Performance can be able to be vital with the operating role of normal table for printing machine.
Since China's national economy and social development, more harsh new environmental law is promulgated and enforced, " green printing " this
One concept is also more and more proposed, and has been done step-by-step in the printing of middle and primary schools' textbook.And it is based on green
Concepts such as " green, environmental protection " are deeply implemented the every aspect of printing, and then realized really comprehensive by the theory of printing
Green printing, undoubtedly meet what market and policy needed.Implementation energetically with country to green printing, environment-friendly ink
Also it has been to be concerned by more and more people.The target for realizing national elementary and high school textbook green printing all standing simultaneously, also to exert
Power realizes middle and primary schools' paper and teaches the green printing of auxiliary material.
For overwhelming majority printing enterprise, China due to being limited by factors such as prices, there is no newest using soya-bean ink etc.
Environment-friendlyink ink.Ink currently in use generally has sternly environment in volatile organic matter Ppolynuclear aromatic solvent, heavy metal etc.
Ghost image ring harmful substance, cause industrial waste such as recycled writing paper, resource reclaim etc. environmental protection aspect the problem of.If student is long
Phase contacts the printing product of the VOC containing high concentration, can cause greatly to damage to human body, especially nervous system.Therefore how to reduce
The content of VOC becomes the most important thing of various countries' Environment control in ink.For the barren rock after the emission problem of VOC, and printing
Oil-based ink be difficult to biodegrade and caused by contamination phenomenon, development environment friendly vegetable oil type printing ink be solve ask
One important measures of topic, simultaneously for the adjustment for promoting domestic vegetable fat industry, mitigate to non-renewable petroleum according to
Rely, drives the adjustment of agricultural planting structure, be all of great significance.
Summary of the invention
The main purpose of the present invention is to provide a kind of vegetable oil type printing ink and its manufacturing methods, develop Chinese catalpa oil and connect
Godied oil is tied, plant type ink formulations is formed, is had a safety feature to develop, and cost phase low to human body and environmental hazard
To lower environment protecting plant oil type off-set oil ink.
To which in order to realize above-mentioned purpose, a kind of vegetable oil type printing ink provided by the invention is by following heavy
The raw material of amount degree is made: 35%~40% stillingia stand oil, 32%~42% refined soybean oil, 3%~6% essence
Tung oil processed, 13%~18% pigment, 3%~5% filler material, 1%~3% assisted resin, 0.5%~1% drier, 1%~
3% micro mist wax, 0.5%~1% antioxidant and 0.5%~1% vanilla flavour concentrate.
An embodiment according to the present invention, assisted resin is soybean oil modified isophthalic alcohol acid resin, for improving
Link stuff hydrophily.
The present invention provides a kind of manufacturing method of plant type printing ink comprising step:
The refined soybean oil of corrresponding quality score is added in ceramic cylinder S100, in 65~70 DEG C of progress heating water baths, then
Antioxidant is added in refined soybean oil；
S200 sequentially adds purification tung oil and stillingia stand oil, is dispersed with high speed shear dispersion emulsifying machine；
Pigment, filler material, micro mist wax, assisted resin, drier and vanilla flavour concentrate are sequentially added after S300 is uniform, are passed through
Blender carries out dispersion stirring 0.5h；
The 10mm bead of the weight such as S400 addition and raw material total amount, is uniformly dispersed, after stirring 3~4h always, isolates glass
Glass pearl is prepared into the plant type printing ink.
An embodiment according to the present invention, the preparation of stillingia stand oil in the step S200, including step S210: by Chinese catalpa
Oil and the catalyst of corresponding amount are added in the three-necked flask equipped with air set pipe and thermometer, and three-necked flask is placed in digital display heating
In the electric jacket of magnetic stirring apparatus, rotary-vane vaccum pump is connected, control keeps 0.5h at vacuum degree 0.095MPa, quickly rises
Temperature removes electric jacket after reaching predetermined soaking time to required temperature, so that stillingia stand oil is at vacuum degree 0.095MPa
It is cooled to room temperature.
Preferably, the catalyst in the step S210 is anthraquinone catalyst and/or sulphur Raney nickel.
Preferably, the required holding temperature in the step S210 is 320 DEG C.
Preferably, the mixing speed of the blender in the step S210 is 300r/min.
Preferably, the soaking time in the step S210 is 4h.
Preferably, the mass fraction of catalyst is 6% anthraquinone catalyst and 0.5% sulphur Raney nickel.
An embodiment according to the present invention, the step S200 further comprise step S220: recycling catalyst, by Chinese catalpa oil
Godied oil 3000r/min be centrifuged 0.5h, take upper layer oil be filtered by vacuum godied oil stays in bottle,suction, take lower layer's catalyst
It is filtered by vacuum with oil mixture is polymerize under the flushing of oily ether, takes out filter paper dried recovered catalyst.
Specific embodiment
Claim according to the present invention and specification disclosure of that, technical solution of the present invention literary institute specific as follows
It states.
A kind of vegetable oil type printing ink is made of the raw material of following weight percent content: the polymerization of 35%~40% Chinese catalpa oil
Oil, 32%~42% refined soybean oil, 3%~6% purification tung oil, 13%~18% pigment, 3%~5% filler material, 1%~
3% assisted resin, 0.5%~1% drier, 1%~3% micro mist wax, 0.5%~1% antioxidant and 0.5%~1%
Vanilla flavour concentrate.
Wherein, drier is cobalt naphthenate drier.
Wherein, assisted resin is soybean oil modified isophthalic alcohol acid resin, for improving link stuff hydrophily.
Wherein, filler material is calcene.
Wherein, pigment is selected from environment friendly inorganic pigment, respectively titanium yellow, titanium chromium palm fibre, iron zinc chrome palm fibre, siderochrome be black, cobalt green,
Cobalt blue, copper-chrome black, compound titan yellow and composite titanium are one or more of red.
A kind of manufacturing method of plant type printing ink comprising step:
The refined soybean oil of corrresponding quality score is added in ceramic cylinder S100, in 65~70 DEG C of progress heating water baths, then
Antioxidant is added in refined soybean oil；
S200 sequentially adds purification tung oil and stillingia stand oil, is dispersed with high speed shear dispersion emulsifying machine；
Pigment, filler material, micro mist wax, assisted resin, drier and vanilla flavour concentrate are sequentially added after S300 is uniform, are passed through
Blender carries out dispersion stirring 0.5h；
The 10mm bead of the weight such as S400 addition and raw material total amount, is uniformly dispersed, after stirring 3~4h always, isolates glass
Glass pearl is prepared into the plant type printing ink.
Wherein, in the step S200 stillingia stand oil preparation, including step S210: by Chinese catalpa oil and corresponding amount catalysis
Agent is added in the three-necked flask equipped with air set pipe and thermometer, and three-necked flask is placed in the electric heating of digital display heating magnetic stirring apparatus
In set, rotary-vane vaccum pump is connected, control keeps 0.5h at vacuum degree 0.095MPa, is rapidly heated to required temperature, reaches
After predetermined soaking time, electric jacket is removed, so that stillingia stand oil is cooled to room temperature at vacuum degree 0.095MPa.
Preferably, the catalyst in the step S210 is anthraquinone catalyst and/or sulphur Raney nickel.
Preferably, the required holding temperature in the step S210 is 320 DEG C.
Preferably, the mixing speed of the blender in the step S210 is 300r/min.
Preferably, the soaking time in the step S210 is 4h.
Preferably, the mass fraction of catalyst is 6% anthraquinone catalyst and 0.5% sulphur Raney nickel.
Wherein, the step S200 further comprises step S220: recycling catalyst, by stillingia stand oil in 3000r/
Min be centrifuged 0.5h, take upper layer oil be filtered by vacuum godied oil stays in bottle,suction, take lower layer's catalyst with polymerize oil mixture
It is filtered by vacuum under the flushing of oily ether, takes out filter paper dried recovered catalyst.
Embodiment 1
(1) refined soybean oil that mass fraction is 37% is added in ceramic cylinder, in 68 DEG C of progress heating water baths, then will
0.5% antioxidant is added in refined soybean oil；
(2) 4% purification tung oil and 40% stillingia stand oil are sequentially added, is dispersed with high speed shear dispersion emulsifying machine；
(3) uniformly after sequentially add 13% pigment, 3% filler material, 0.5% micro mist wax, 1% assisted resin, 0.5% urge
Dry agent and 0.5% vanilla flavour concentrate carry out dispersion stirring 0.5h by blender；
(4) the 10mm bead with weights such as raw material total amounts is added, is uniformly dispersed, after stirring 3~4h always, isolates glass
Glass pearl is prepared into the plant type printing ink.
Wherein, in the step (2) stillingia stand oil preparation, by the Chinese catalpa 80g oil and 6% anthraquinone catalyst be added dress
In the three-necked flask for having air set pipe and thermometer, three-necked flask is placed in the electric jacket of digital display heating magnetic stirring apparatus, is stirred
Mix speed be 300r/min, connect rotary-vane vaccum pump, control keep 0.5h at vacuum degree 0.095MPa, be rapidly heated to
Required temperature, holding temperature are 320 DEG C, after reaching predetermined soaking time 4h, electric jacket are removed, so that stillingia stand oil is true
Room temperature is cooled under reciprocal of duty cycle 0.095MPa.
The fixed speed of made ink is 45min, slamp value 30mm, and viscosity is that (400rpm, 32 DEG C) is 14.
The measurement of the fixed speed of plant type printing ink obtained is referring to QB570-1983；The measurement of ink fluidity is joined
According to GB/T14624.3-1993；The measurement of ink viscosity is referring to GB/T14624.5-1993.
Embodiment 2
(1) refined soybean oil that mass fraction is 32% is added in ceramic cylinder, in 68 DEG C of progress heating water baths, then will
1% antioxidant is added in refined soybean oil；
(2) 6% purification tung oil and 35% stillingia stand oil are sequentially added, is dispersed with high speed shear dispersion emulsifying machine；
(3) uniformly after sequentially add 15% pigment, 5% filler material, 1% micro mist wax, 3% assisted resin, 1% drier
With 1% vanilla flavour concentrate, dispersion stirring 0.5h is carried out by blender；
(4) the 10mm bead with weights such as raw material total amounts is added, is uniformly dispersed, after stirring 4h always, isolates glass
Pearl is prepared into the plant type printing ink.
Wherein, in the step (2) stillingia stand oil preparation, by the Chinese catalpa 80g oil and 1% sulphur Raney nickel be added dress
In the three-necked flask for having air set pipe and thermometer, three-necked flask is placed in the electric jacket of digital display heating magnetic stirring apparatus, is stirred
Mix speed be 300r/min, connect rotary-vane vaccum pump, control keep 0.5h at vacuum degree 0.095MPa, be rapidly heated to
Required temperature, holding temperature are 320 DEG C, after reaching predetermined soaking time 4h, electric jacket are removed, so that stillingia stand oil is true
Room temperature is cooled under reciprocal of duty cycle 0.095MPa.
The fixed speed of made ink is 50min, slamp value 28mm, and viscosity is that (400rpm, 32 DEG C) is 16.
Embodiment 3
(1) refined soybean oil that mass fraction is 42% is added in ceramic cylinder, in 70 DEG C of progress heating water baths, then will
0.5% antioxidant is added in refined soybean oil；
(2) 3% purification tung oil and 36% stillingia stand oil are sequentially added, is dispersed with high speed shear dispersion emulsifying machine；
(3) uniformly after sequentially add 13% pigment, 3% filler material, 0.5% micro mist wax, 1% assisted resin, 0.5% urge
Dry agent and 0.5% vanilla flavour concentrate carry out dispersion stirring 0.5h by blender；
(4) the 10mm bead with weights such as raw material total amounts is added, is uniformly dispersed, after stirring 4h always, isolates glass
Pearl is prepared into the plant type printing ink.
Wherein, in the step (2) stillingia stand oil preparation, by the Chinese catalpa 80g oil and 6% anthraquinone catalyst and 0.5% sulphur
Raney nickel is added in the three-necked flask equipped with air set pipe and thermometer, and three-necked flask is placed in digital display heating magnetic stirring apparatus
Electric jacket in, mixing speed 300r/min, connect rotary-vane vaccum pump, control kept at vacuum degree 0.095MPa
0.5h is rapidly heated to required temperature, and holding temperature is 320 DEG C, after reaching predetermined soaking time 4h, removes electric jacket, so that
Stillingia stand oil is cooled to room temperature at vacuum degree 0.095MPa.
The fixed speed of made ink is 35min, slamp value 32mm, and viscosity is that (400rpm, 32 DEG C) is 15.
Above content is enumerating for specific embodiments of the present invention, for the equipment and structure of wherein not detailed description, is answered
When being interpreted as that the existing common apparatus in this field and universal method is taken to be practiced.
The above embodiment of the present invention is only to illustrate that technical solution of the present invention is used simultaneously, only the column of technical solution of the present invention
It lifts, the technical solution and its protection scope being not intended to restrict the invention.Using equivalent technologies mean, equivalent apparatus etc. to this
The improvement of technical solution disclosed in invention claims and specification is considered to be without departing from the claims in the present invention
Range disclosed in book and specification.
Claims (10)
1. a kind of vegetable oil type prints ink, which is characterized in that be made of the raw material of following weight percent content: 35%~
40% stillingia stand oil, 32%~42% refined soybean oil, 3%~6% purification tung oil, 13%~18% pigment, 3%~5%
Filler material, 1%~3% assisted resin, 0.5%~1% drier, 1%~3% micro mist wax, 0.5%~1% antioxidant with
And 0.5%~1% vanilla flavour concentrate.
2. vegetable oil type according to claim 1 prints ink, which is characterized in that assisted resin is soybean oil modified isophthalic
Diformazan alkyd resin.
3. a kind of manufacturing method of vegetable oil type printing ink as claimed in claim 1 or 2, which is characterized in that comprising steps of
The refined soybean oil of corrresponding quality score is added in ceramic cylinder S100, in 65~70 DEG C of progress heating water baths, then will resist
Oxidant is added in refined soybean oil；
S200 sequentially adds purification tung oil and stillingia stand oil, is dispersed with high speed shear dispersion emulsifying machine；
Pigment, filler material, micro mist wax, assisted resin, drier and vanilla flavour concentrate are sequentially added after S300 is uniform, pass through blender
Carry out dispersion stirring 0.5h；
The 10mm bead of the weight such as S400 addition and raw material total amount, is uniformly dispersed, after stirring 3~4h always, isolates bead,
It is prepared into the plant type printing ink.
4. manufacturing method according to claim 3, which is characterized in that the preparation of stillingia stand oil in the step S200,
Including step S210: the catalyst of Chinese catalpa oil and corresponding amount being added in the three-necked flask equipped with air set pipe and thermometer, three
Mouth flask is placed in the electric jacket of digital display heating magnetic stirring apparatus, connects rotary-vane vaccum pump, is controlled in vacuum degree 0.095MPa
Lower holding 0.5h, is rapidly heated to required temperature, after reaching predetermined soaking time, removes electric jacket, so that stillingia stand oil exists
Room temperature is cooled under vacuum degree 0.095MPa.
5. manufacturing method according to claim 4, which is characterized in that the catalyst in the step S210 is anthraquinone catalysis
Agent and/or sulphur Raney nickel.
6. manufacturing method according to claim 5, which is characterized in that the required holding temperature in the step S210 is
320℃。
7. manufacturing method according to claim 6, which is characterized in that the mixing speed of the blender in the step S210
For 300r/min.
8. manufacturing method according to claim 7, which is characterized in that the soaking time in the step S210 is 4h.
9. manufacturing method according to claim 8, which is characterized in that the mass fraction of catalyst is 6% anthraquinone catalyst
With 0.5% sulphur Raney nickel.
10. manufacturing method according to claim 9, which is characterized in that the step S200 further comprises step S220:
Recycle catalyst, by stillingia stand oil 3000r/min be centrifuged 0.5h, take upper layer oil be filtered by vacuum godied oil stays in bottle,suction
In, take lower layer's catalyst with polymerize oil mixture under the flushing of oily ether and be filtered by vacuum, take out filter paper dried recovered catalyst.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711454206.1A CN109971246A (en) | 2017-12-28 | 2017-12-28 | A kind of vegetable oil type printing ink and its manufacturing method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711454206.1A CN109971246A (en) | 2017-12-28 | 2017-12-28 | A kind of vegetable oil type printing ink and its manufacturing method |
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| Publication Number | Publication Date |
|---|---|
| CN109971246A true CN109971246A (en) | 2019-07-05 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711454206.1A Pending CN109971246A (en) | 2017-12-28 | 2017-12-28 | A kind of vegetable oil type printing ink and its manufacturing method |
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| CN (1) | CN109971246A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112300624A (en) * | 2020-11-05 | 2021-02-02 | 合肥杏花印务股份有限公司 | Formula and preparation method of ink for green printing |
-
2017
- 2017-12-28 CN CN201711454206.1A patent/CN109971246A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112300624A (en) * | 2020-11-05 | 2021-02-02 | 合肥杏花印务股份有限公司 | Formula and preparation method of ink for green printing |
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Application publication date: 20190705 |