CN108373647A - A kind of UV ink and preparation method thereof - Google Patents

A kind of UV ink and preparation method thereof Download PDF

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Publication number
CN108373647A
CN108373647A CN201810489842.6A CN201810489842A CN108373647A CN 108373647 A CN108373647 A CN 108373647A CN 201810489842 A CN201810489842 A CN 201810489842A CN 108373647 A CN108373647 A CN 108373647A
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China
Prior art keywords
parts
ink
pigment
finished product
benzophenone
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CN201810489842.6A
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Inventor
陈晓朋
谭勇
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Chengdu De Gong Zhi Science And Technology Co Ltd
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Chengdu De Gong Zhi Science And Technology Co Ltd
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Priority to CN201810489842.6A priority Critical patent/CN108373647A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/101Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Inks, Pencil-Leads, Or Crayons (AREA)

Abstract

The invention discloses a kind of UV ink and preparation method thereof, belong to technical field of ink, which is mainly made of the component of following weight:40~55 parts of urethane acrylate, 5~10 parts of epoxy acrylate, 20~30 parts of activated monomer, 2~5 parts of benzophenone, 2~5 parts of triethanolamine, 2~4 parts of polyethylene wax, 5~10 parts of pigment, 2~3 parts of bentonite;The UV ink dry times are short, strong adhesive force, and water-fast and resistance to alcoholic strength can be good, and weatherability and stability are also preferable, and environmentally protective, have no irritating odor, and will not volatilize harmful substance.The preparation method is simple for process, and it is convenient to prepare, and production efficiency is high, the good product quality produced, and production cost is relatively low.

Description

A kind of UV ink and preparation method thereof
Technical field
The invention belongs to technical field of ink, and in particular to a kind of UV ink and preparation method thereof.
Background technology
Currently, the ink in market is mainly solvent borne ink, printed to glass and ceramic system by modes such as silk-screen printings Then product surface carries out high-temperature baking by decoration firing line and is cured, hardening time is long, can not accomplish instantaneous solidification, ink Contain benezene material in material, there is strong volatility and penetrating odor, can cause damages to health, and existing ink Adhesive force, water resistance, resistance to alcoholic strength, weatherability are all poor, cannot meet the use demand of people.
Invention content
Embodiment of the present invention is designed to provide a kind of UV ink, can instantaneous solidification, can preferably improve The above problem.
Another of embodiment of the present invention is designed to provide a kind of preparation method of UV ink, simple for process, raw Production is convenient, and production efficiency is high, the good product quality produced.
What embodiments of the present invention were realized in:
Embodiments of the present invention provide a kind of UV ink, are mainly made of the component of following weight:Poly- ammonia 40~55 parts of ester acrylate, 5~10 parts of epoxy acrylate, 20~30 parts of activated monomer, 2~5 parts of benzophenone, three ethyl alcohol 2~5 parts of amine, 2~4 parts of polyethylene wax, 5~10 parts of pigment, 2~3 parts of bentonite.
Further, which is mainly made of the component of following weight:40 parts of urethane acrylate, ring 10 parts of oxypropylene acid fat, 20 parts of activated monomer, 2 parts of benzophenone, 2 parts of triethanolamine, 2 parts of polyethylene wax, 5 parts of pigment, swelling 2 parts of soil
Further, which is mainly made of the component of following weight:55 parts of urethane acrylate, ring 5 parts of oxypropylene acid fat, 20 parts of activated monomer, 5 parts of benzophenone, 5 parts of triethanolamine, 4 parts of polyethylene wax, 10 parts of pigment, swelling 3 parts of soil.
Further, which is mainly made of the component of following weight:45 parts of urethane acrylate, ring 8 parts of oxypropylene acid fat, 25 parts of activated monomer, 3 parts of benzophenone, 3 parts of triethanolamine, 3 parts of polyethylene wax, 8 parts of pigment, bentonite 2 parts.
Further, the activated monomer is alkoxy acrylic ester, tripropylene glycol diacrylate, trimethylolpropane tris One or more of acrylate or hexanediyl ester.
Further, the pigment uses organic high temperature-resistant pigment.
Embodiments of the present invention additionally provide a kind of preparation method of UV ink, include the following steps:
S1:Urethane acrylate, epoxy acrylate, polyethylene wax and activated monomer are added in the first dispersion cylinder It carries out pre-dispersed;
S2:Pigment is added in the second dispersion cylinder and carries out pre-dispersed, reuses the first grinder to the pigment after dispersion It is ground, the pigment after grinding is added in the first dispersion cylinder;
S3:Benzophenone, triethanolamine and bentonite are added in the first dispersion cylinder successively, then use dispersion machine pair Solution, which is stirred, is made semi-finished product;
S4:Semi-finished product are ground using the second grinder to obtain finished product UV ink.
Further, in S3 steps, the mixed solution in the first dispersion cylinder is heated to 40~50 DEG C, and stir 20~ 30min。
Further, in S4 steps, semi-finished product is heated to 50~60 DEG C and are ground again.
Further, in S4 steps, the fineness of grind of UV ink is 1~3 μm.
Beneficial effects of the present invention are:
The UV ink that embodiment of the present invention provides, drying time is short, strong adhesive force, and water-fast and resistance to alcoholic strength can be good, weather-proof Property and stability are also preferable and environmentally protective, have no irritating odor, will not volatilize harmful substance.
The preparation method for the UV ink that embodiment of the present invention provides, simple for process, it is convenient to prepare, and production efficiency is high, The good product quality produced, production cost are relatively low.
Specific implementation mode
To keep the purpose, technical scheme and advantage of embodiment of the present invention clearer, below to embodiment of the present invention In technical solution be clearly and completely described, it is clear that described embodiment is some embodiments of the invention, Rather than whole embodiment.
Embodiment 1
The embodiment of the present invention 1 provides a kind of UV ink, is mainly made of the component of following weight:Polyurethane third 40 parts of olefin(e) acid ester, 10 parts of epoxy acrylate, 20 parts of alkoxy acrylic ester, 2 parts of benzophenone, 2 parts of triethanolamine, polyethylene 2 parts of wax, 5 parts of pigment, 2 parts of bentonite.
The preparation method of the UV ink is as follows:
S1:Urethane acrylate, epoxy acrylate, polyethylene wax and alkoxy acrylic ester are pressed into above-mentioned parts by weight It is pre-dispersed to be added to progress in the first dispersion cylinder;
S2:Pigment is added in the second dispersion cylinder and carries out pre-dispersed, reuses the first grinder to the pigment after dispersion It is ground, the pigment after grinding is added to by above-mentioned parts by weight in the first dispersion cylinder;
S3:Benzophenone, triethanolamine and bentonite are added to by above-mentioned parts by weight in the first dispersion cylinder successively, then Solution is heated to 40 DEG C, dispersion machine is reused and 20min is stirred to solution, to which semi-finished product be made;
S4:Semi-finished product are ground using the second grinder to obtain finished product UV ink.
It should be noted that needing semi-finished product being heated to 50 DEG C in step S4, before grinding, then it is ground again, it will Semi-finished product are ground to 3 μm or so and can be obtained finished product UV ink, test to finished product UV ink, are wrapped after the assay was approved Dress.
The test performance of the UV ink of the present embodiment is as shown in table 1:
Table 1
Embodiment 2
The embodiment of the present invention 2 provides a kind of UV ink, is mainly made of the component of following weight:Polyurethane third 55 parts of olefin(e) acid ester, 5 parts of epoxy acrylate, 20 parts of trimethylolpropane trimethacrylate, 5 parts of benzophenone, triethanolamine 5 Part, 4 parts of polyethylene wax, 10 parts of pigment, 3 parts of bentonite.
The preparation method of the UV ink is as follows:
S1:By urethane acrylate, epoxy acrylate, polyethylene wax and trimethylolpropane trimethacrylate by upper State parts by weight be added in the first dispersion cylinder carry out it is pre-dispersed;
S2:Pigment is added in the second dispersion cylinder and carries out pre-dispersed, reuses the first grinder to the pigment after dispersion It is ground, the pigment after grinding is added to by above-mentioned parts by weight in the first dispersion cylinder;
S3:Benzophenone, triethanolamine and bentonite are added to by above-mentioned parts by weight in the first dispersion cylinder successively, then Solution is heated to 50 DEG C, dispersion machine is reused and 30min is stirred to solution, to which semi-finished product be made;
S4:Semi-finished product are ground using the second grinder to obtain finished product UV ink.
It should be noted that needing semi-finished product being heated to 60 DEG C in step S4, before grinding, then it is ground again, it will Semi-finished product are ground to 1 μm or so and can be obtained finished product UV ink, test to finished product UV ink, are wrapped after the assay was approved Dress.
The test performance of the UV ink of the present embodiment is as shown in table 2:
Table 2
Embodiment 3
The embodiment of the present invention 3 provides a kind of UV ink, is mainly made of the component of following weight:Polyurethane third 45 parts of olefin(e) acid ester, 8 parts of epoxy acrylate, 25 parts of hexanediyl ester, 3 parts of benzophenone, 3 parts of triethanolamine, poly- second 3 parts of alkene wax, 8 parts of pigment, 2 parts of bentonite.
The preparation method of the UV ink is as follows:
S1:Urethane acrylate, epoxy acrylate, polyethylene wax and hexanediyl ester are pressed into above-mentioned weight It is pre-dispersed that part is added to progress in the first dispersion cylinder;
S2:Pigment is added in the second dispersion cylinder and carries out pre-dispersed, reuses the first grinder to the pigment after dispersion It is ground, the pigment after grinding is added to by above-mentioned parts by weight in the first dispersion cylinder;
S3:Benzophenone, triethanolamine and bentonite are added to by above-mentioned parts by weight in the first dispersion cylinder successively, then Solution is heated to 45 DEG C, dispersion machine is reused and 25min is stirred to solution, to which semi-finished product be made;
S4:Semi-finished product are ground using the second grinder to obtain finished product UV ink.
It should be noted that needing semi-finished product being heated to 55 DEG C in step S4, before grinding, then it is ground again, it will Semi-finished product are ground to 2 μm or so and can be obtained finished product UV ink, test to finished product UV ink, are wrapped after the assay was approved Dress.
The test performance of the UV ink of the present embodiment is as shown in table 3:
Table 3
Embodiment 4
The embodiment of the present invention 4 provides a kind of UV ink, is mainly made of the component of following weight:Polyurethane third 42 parts of olefin(e) acid ester, 6 parts of epoxy acrylate, 28 parts of tripropylene glycol diacrylate, 4 parts of benzophenone, 3 parts of triethanolamine, poly- second 4 parts of alkene wax, 6 parts of pigment, 2 parts of bentonite.
The preparation method of the UV ink is as follows:
S1:Urethane acrylate, epoxy acrylate, polyethylene wax and tripropylene glycol diacrylate are pressed into above-mentioned weight It is pre-dispersed that part is added to progress in the first dispersion cylinder;
S2:Pigment is added in the second dispersion cylinder and carries out pre-dispersed, reuses the first grinder to the pigment after dispersion It is ground, the pigment after grinding is added to by above-mentioned parts by weight in the first dispersion cylinder;
S3:Benzophenone, triethanolamine and bentonite are added to by above-mentioned parts by weight in the first dispersion cylinder successively, then Solution is heated to 40 DEG C, dispersion machine is reused and 30min is stirred to solution, to which semi-finished product be made;
S4:Semi-finished product are ground using the second grinder to obtain finished product UV ink.
It should be noted that needing semi-finished product being heated to 60 DEG C in step S4, before grinding, then it is ground again, it will Semi-finished product are ground to 3 μm or so and can be obtained finished product UV ink, test to finished product UV ink, are wrapped after the assay was approved Dress.
The test performance of the UV ink of the present embodiment is as shown in table 4:
Table 4
Embodiment 5
The embodiment of the present invention 4 provides a kind of UV ink, is mainly made of the component of following weight:Polyurethane third 50 parts of olefin(e) acid ester, 9 parts of epoxy acrylate, 26 parts of activated monomer, 3 parts of benzophenone, 3 parts of triethanolamine, 4 parts of polyethylene wax, 8 parts of pigment, 2 parts of bentonite.
The preparation method of the UV ink is as follows:
S1:Urethane acrylate, epoxy acrylate, polyethylene wax and the above-mentioned parts by weight of activated monomer are added to It is carried out in one dispersion cylinder pre-dispersed;
It should be noted that in the present embodiment, activated monomer uses trimethylolpropane trimethacrylate and hexylene glycol two Acrylate presses 1:1~1:2 parts by weight are mixed.
S2:Pigment is added in the second dispersion cylinder and carries out pre-dispersed, reuses the first grinder to the pigment after dispersion It is ground, the pigment after grinding is added to by above-mentioned parts by weight in the first dispersion cylinder;
S3:Benzophenone, triethanolamine and bentonite are added to by above-mentioned parts by weight in the first dispersion cylinder successively, then Solution is heated to 50 DEG C, dispersion machine is reused and 20min is stirred to solution, to which semi-finished product be made;
S4:Semi-finished product are ground using the second grinder to obtain finished product UV ink.
It should be noted that needing semi-finished product being heated to 60 DEG C in step S4, before grinding, then it is ground again, it will Semi-finished product are ground to 2 μm or so and can be obtained finished product UV ink, test to finished product UV ink, are wrapped after the assay was approved Dress.
The test performance of the UV ink of the present embodiment is as shown in table 5:
Table 5
The present invention is not limited to above-mentioned optional embodiment, based on the embodiment in the present invention, ordinary skill The every other embodiment that personnel are obtained without creative efforts belongs to the model that the present invention protects It encloses.

Claims (10)

1. a kind of UV ink, which is characterized in that be mainly made of the component of following weight:Urethane acrylate 40~ 55 parts, 5~10 parts of epoxy acrylate, 20~30 parts of activated monomer, 2~5 parts of benzophenone, 2~5 parts of triethanolamine, poly- second 2~4 parts of alkene wax, 5~10 parts of pigment, 2~3 parts of bentonite.
2. UV ink according to claim 1, which is characterized in that be mainly made of the component of following weight:It is poly- 40 parts of urethane acrylate, 10 parts of epoxy acrylate, 20 parts of activated monomer, 2 parts of benzophenone, 2 parts of triethanolamine, polyethylene 2 parts of wax, 5 parts of pigment, 2 parts of bentonite.
3. UV ink according to claim 1, which is characterized in that be mainly made of the component of following weight:It is poly- 55 parts of urethane acrylate, 5 parts of epoxy acrylate, 20 parts of activated monomer, 5 parts of benzophenone, 5 parts of triethanolamine, polyethylene 4 parts of wax, 10 parts of pigment, 3 parts of bentonite.
4. UV ink according to claim 1, which is characterized in that be mainly made of the component of following weight:It is poly- 45 parts of urethane acrylate, 8 parts of epoxy acrylate, 25 parts of activated monomer, 3 parts of benzophenone, 3 parts of triethanolamine, polyethylene 3 parts of wax, 8 parts of pigment, 2 parts of bentonite.
5. UV ink according to claim 1, which is characterized in that the activated monomer is alkoxy acrylic ester, 3 third One or more of glycol diacrylate, trimethylolpropane trimethacrylate or hexanediyl ester.
6. UV ink according to claim 1, which is characterized in that the pigment uses organic high temperature-resistant pigment.
7. a kind of preparation method of UV ink, which is characterized in that include the following steps:
S1:Urethane acrylate, epoxy acrylate, polyethylene wax and activated monomer are added in the first dispersion cylinder and carried out It is pre-dispersed;
S2:Pigment is added in the second dispersion cylinder carry out it is pre-dispersed, reuse the first grinder to after dispersion pigment carry out Grinding, the pigment after grinding is added in the first dispersion cylinder;
S3:Benzophenone, triethanolamine and bentonite are added in the first dispersion cylinder successively, then use dispersion machine to solution It is stirred and semi-finished product is made;
S4:Semi-finished product are ground using the second grinder to obtain finished product UV ink.
8. the preparation method of UV ink according to claim 7, which is characterized in that, will be in the first dispersion cylinder in S3 steps Mixed solution be heated to 40~50 DEG C, and stir 20~30min.
9. the preparation method of UV ink according to claim 7, which is characterized in that in S4 steps, semi-finished product are heated to 50~60 DEG C are ground again.
10. the preparation method of UV ink according to claim 7, which is characterized in that in S4 steps, the grinding of UV ink is thin Degree is 1~3 μm.
CN201810489842.6A 2018-05-21 2018-05-21 A kind of UV ink and preparation method thereof Pending CN108373647A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109605933A (en) * 2018-12-17 2019-04-12 安徽本色印刷有限公司 A kind of UV printing plate drying unit and its printing process
CN113402925A (en) * 2021-06-23 2021-09-17 亚化(福建)油墨科技有限公司 Preparation process of quick-drying wear-resistant environment-friendly composite water-based ink

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CN103342921A (en) * 2013-07-29 2013-10-09 中国科学院化学研究所 Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate
CN104845442A (en) * 2015-05-05 2015-08-19 杭州科望特种油墨有限公司 Ink with ultraviolet curing type water drop effects and method for producing products with water drop effects

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CN1896156A (en) * 2006-06-23 2007-01-17 中国乐凯胶片集团公司 Ultraviolet light-curing sand vein ink
WO2013037277A1 (en) * 2011-09-14 2013-03-21 中国科学院化学研究所 Uv-curable ink for direct plate making by ink-jet printing with preparation method and application therefor
CN103342921A (en) * 2013-07-29 2013-10-09 中国科学院化学研究所 Ink with high hiding rate for ink-jet printing and application thereof to preparation of flexible plate
CN104845442A (en) * 2015-05-05 2015-08-19 杭州科望特种油墨有限公司 Ink with ultraviolet curing type water drop effects and method for producing products with water drop effects

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109605933A (en) * 2018-12-17 2019-04-12 安徽本色印刷有限公司 A kind of UV printing plate drying unit and its printing process
CN113402925A (en) * 2021-06-23 2021-09-17 亚化(福建)油墨科技有限公司 Preparation process of quick-drying wear-resistant environment-friendly composite water-based ink

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