CN109757264A - One planting fruit-trees moss removing agent - Google Patents
One planting fruit-trees moss removing agent Download PDFInfo
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- CN109757264A CN109757264A CN201910124781.8A CN201910124781A CN109757264A CN 109757264 A CN109757264 A CN 109757264A CN 201910124781 A CN201910124781 A CN 201910124781A CN 109757264 A CN109757264 A CN 109757264A
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/30—Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change
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Abstract
The invention discloses a planting fruit-trees moss removing agents, belong to planting technology field.The present invention pre-processes biogas slurry, recycling anaerobic bacteria therein, further inwardly hole is got through in breeding metabolism, form multi-pore structure, improve gas permeability and water penetration, remaining bacterial fibers play elicitation effect to moisture after sterilizing, vesica can be self-assembly of by meeting water, further increase water penetration and gas permeability；Addition has penetrant crystalline containing the sodium methyl silicate in silica reagent, improve hydrophobic effect, reduce humidity, destroy the growing environment of moss, the phenolic acid class antibacterial substance dissolved out to wheat bran processing is coordinated, and inhibits the growth of bacterium and fungi, while can provide certain drying property, humidity is controlled, the growth of moss is influenced.The present invention solves common at present bad to required water penetration, the balance of gas permeability of fruit tree root soil for moss removing agent used in fruit tree, causes except moss effect is undesirable, the common pesticides also larger problem of environmental pollution.
Description
Technical field
The present invention relates to planting technology fields, and in particular to a planting fruit-trees moss removing agent.
Background technique
Bryophyte is the general name of two class higher plant of tongue fur and moss, and the whole world has more than 2.3 ten thousand.Moss is that aquatic moss is planted
Object, color is emerald green, and growth is in water or the dark and damp place in land；Especially: market of farm produce fairground, scenic spot, courtyard, washing room etc., it is empty
Gas is moist, and the big place of humidity is easy growth moss, moss etc..Moss is that one kind has both zoogamy and agamic energy is fast
The algae bio of speed procreation, adapts to various growing environments and water condition, has stronger growth ability.In daily life
Dark and damp ground and common water pipe etc. are frequently seen moss growth, and moss road surface will affect pedestrian's trip, since moss is wet and slippery,
Pedestrian walks up to be easy to appear and slide into；Pipeline of drinking water in life does not clear up easily growth moss class for a long time yet and influences water quality.Danger
The moss of evil fruit tree has more than 20 kinds, they are all green from terrestrial plant of nourishing one's nature.The green plants body of moss is zoogamy
Gametophytic generation is to generate protonema through developing by spore germination.Plant is usually in lobate or has cauline leaf differentiation, is not had
Real vascular bundle construction, the cell structure of stem is uniform or the differentiation of slightly skin zone and axis, to support based on function, Ye Tongchang
For monolayer, cell only slightly has differentiating phenomenon, can directly absorb moisture content and nutrient.Rhizoid is made of unicellular, with fixation
Based on function, the effect for absorbing moisture content and nutrient is had concurrently.Moss grows nonparasitically upon another plant on fruit tree branch bar, overwintering with trophosome, annual
In 5-9 month, since how wet warmer climate is, generation sprawling is most fast, endangers also most serious.Not only seriously affect fruit yield and matter
Amount, and shorten fruit tree and produce the fruit time limit, cause the too early decline of fruit tree.Remove moss mode rely primarily on artificial removing,
Bioelectric detecting and chemical scavenging.Wherein, artificial reset mode is caught using artificial, not only time and effort consuming, and filamentous algae is easily
It seeks connections with and easily damages plant leaf blade when water plant growth, fishing, so that destroying the upgrowth situation of plant, and manually removing cannot
The moss spore and tissue of removing, so that rapid restoration ecosystem in the moss short time；And bioelectric detecting is then with algophagous animal
Mode remove moss, however algophagous size of animal launch it is limited, but also the effect of bioelectric detecting mode is not significant.And
The mode of chemical scavenging is then to inhibit the growth of algae using drug, has and saves manpower and elimination effect clear advantage, is
Remove the conventional means in moss mode.In the prior art, though thering is the agrotechnical department in part and tea grower to test with limewash, caustic soda
The chemical controls fruit tree tongue furs such as water, Bordeaux mixture, ferrous sulfate, green newborn copper, copper sulphate, plant ash leachate, difoltan, captan
Moss, but it is bad to the required water penetration of fruit tree root soil, the balance of gas permeability, cause except moss effect is undesirable.And this
A little medicaments and method are difficult to promote and apply due to being influenced by composite factors such as environmental protection, food safety, control efficiency, application costs.
With gradually showing for these drug side-effects, researcher in order to adapt to the demand of people, make drug it is small towards dosage,
Environmentally friendly direction at low cost, easy to use, safe is developed, and therefore, it is easy how to research and develop new excellent pesticide control and simplicity
Capable technical measures, it has also become there is an urgent need to and the art technical problem urgently to be solved.
Summary of the invention
The technical problems to be solved by the invention: moss removing agent used in fruit tree is directed to fruit tree root for common at present
Required water penetration, the balance of gas permeability of soil are bad, cause except moss effect it is undesirable, common pesticides also environmental pollution compared with
Big problem provides a planting fruit-trees moss removing agent.
In order to solve the above technical problems, the present invention is using technical solution as described below:
One planting fruit-trees moss removing agent, according to the mass fraction, including following component: 2 ~ 5 parts of zeolites, 12 ~ 20 parts of plant ash, 5 ~ 10 parts
Wheat bran processing material, further includes: 30 ~ 50 parts compound except tongue fur base-material, 12 ~ 20 parts of composite auxiliary materials.
The compound preparation method except tongue fur base-material, includes the following steps:
(1) it in 32 ~ 45 DEG C, takes biogas slurry 8 ~ 13:1:0.3 in mass ratio that sedimentation agent, flyash mixing is added, adjusts pH, protect
Temperature is stood, and filtering collects filtrate, obtains pretreatment biogas slurry, according to parts by weight, take 20 ~ 40 parts of natural colour sands, 40 ~ 60 parts of nutrition
Liquid, 1 ~ 3 part of pretreatment biogas slurry biogas slurry, 1 ~ 4 part of succinic acid mixing vibrate shaking table in 27 ~ 32 DEG C, and closed ferment at constant temperature blasts sky
Gas, in 28 ~ 32 DEG C, constant temperature incubation discharges, filtering, collects filter cake sterilizing, bio-modification color sand；
(2) according to parts by weight, successively take 50 ~ 70 parts of (N- amidino groups) dodecylacrylamides, 7 ~ 13 parts of macromole evocating agents,
1 ~ 4 part of additive mixing, in 35 ~ 45 DEG C, constant temperature stirring obtains block copolymer, block copolymer 1:4 in mass ratio ~ 8 is taken to be added
Bio-modification color sand is mixed to get compound place tongue fur base-material.
Sedimentation agent in the step (1): 5:1 ~ 3:0.2:0.01 in mass ratio takes aluminium polychloride, vulcanized sodium, wooden
Element, titanium dioxide mixing are to get sedimentation agent.
Nutrient solution in the step (1): 3 ~ 7:1:2:1:20 ~ 30 take casein, yeast extract, glucose, sugarcane in mass ratio
Sugar, water mixing are to get nutrient solution.
Additive in the step (2): 3 ~ 7:1:0.01 in mass ratio takes paracide, ferrocene, stannous octoate mixed
It closes to get additive.
Macromole evocating agent in the step (2): the taking polyethylene glycol of 4 ~ 8:3 in mass ratio diacrylate, poly- second two
Alcohol dioleate mixes to get macromole evocating agent.
The preparation of the composite auxiliary material: 3 ~ 5:1 in mass ratio takes snail shell, shrimp shell to pulverize and sieve, and takes sieving particle by matter
Amount is added bentonite, sodium chloride, water than 3:7 ~ 12:1:20 and is mixed, and obtains mixture, takes mixture 15 ~ 25:1 in mass ratio:
2 are added function nano material, are mixed containing silica reagent, in 35 ~ 48 DEG C of progress ultrasonications to get composite auxiliary material.
Described to contain silica reagent: 1:3 ~ 7 take sodium methyl silicate, trim,ethylchlorosilane mixing to get containing silica reagent in mass ratio.
The function nano material: 1:2 ~ 5 take nano-TiO in mass ratio2, Fe Nano-Powders mixing to get function nano material.
The wheat bran processing material: 1:12 ~ 18 take wheat bran, normal hexane mixing in mass ratio, and in 28 ~ 32 DEG C, ultrasonic treatment is obtained
Disperse materials take disperse materials to be centrifuged, and filter, and collect filter residue 1:8 in mass ratio ~ 12 and ethanol solution mixing is added, in 28 ~ 33 DEG C of ultrasounds
Wave assisted extraction, centrifugation are collected supernatant vacuum concentration and are expected to get wheat bran processing.
The present invention is compared with other methods, and advantageous effects are:
(1) present invention first carries out flocculating setting to biogas slurry, removes wherein macromolecular impurity and heavy metal, cooperates in alkalinization
After the metal oxide component of flyash kills the part bacterial strain in biogas slurry, by pretreatment biogas slurry and naturally adopts sand etc. and mix
It closes and is sealed by fermentation culture and aerobic culture, the gap for naturally adopting sand itself can be handled, in fermentation process, pre-process biogas slurry
In anaerobic bacteria mass propagation, the small organic molecule that the macromolecular nutrition Biodegradable in nutrient solution generates can be with moisture penetration
It is anaerobic environment inside sand because naturally adopting, and there is moisture and small molecule into inside natural colour sand, and after switching to aerobic culture
Organic matter can be used as nutrient source, and may make anaerobic bacteria, further inwardly hole is got through in breeding metabolism, thus can form porous knot
Structure improves gas permeability and water penetration, and its hole very little, can obstruct the impurity such as spoilage organisms and pass through, and can effectively adjust internal ventilative
Water permeability realizes interior humidity and gas regulation, and remaining bacterial fibers can also play elicitation effect, institute to moisture after sterilizing
Block copolymer processed have it is amphiphilic, meet water can be self-assembly of vesica, the carbon dioxide that can be generated by usage tree root respiration
It is stimulated, is reacted with the amidine group in block copolymer, be allowed to take charge, local like charges is caused to increase, occurred mutual
Repel, so that the vesica internal cavities volume formed increases, also can further improve water penetration and gas permeability, inhibits moss raw
It is long；
(2) what the present invention added has penetrant crystalline containing the sodium methyl silicate in silica reagent, the silanol group in molecular structure
The silanol group that can be generated with silicate components such as zeolites reacts dehydrated crosslinking, realizes that " anti-capillary effect " forms excellent hydrophobic
Layer improves hydrophobic effect, reduces humidity, destroys the growing environment of moss, and trim,ethylchlorosilane and humid air or water act on,
It can produce the acidity that HCl improves soil constituent, and moss hobby is grown in meta-alkalescence soil, and it is saline and alkaline that soil can be made to occur
Change, thus the growth of moss, the TiO in function nano material can be inhibited with the acid-base property of balanced soil2Ingredient can provide photocatalysis
Effect, under illumination condition, converts CO for organic matter contained by moss2And H2O carries out it under the illumination that moss is liked
Inhibit, block copolymer component can also be stimulated to expand, is mutually exclusive, excessive group of subdivided gap raising water penetration, and nanometer Fe
Under the package of other ingredients, autoxidation slowly occurs and generates anion, and handles wheat bran dissolved out phenolic acid class bateriostatics
Matter is coordinated, and the growth of bacterium and fungi is inhibited, while can provide certain drying property, controls humidity, influences the growth of moss；
(3) conditions such as light, hygrophilous, meta-alkalescence soil needed for the present invention makes full use of moss growth conditions, destroy its growth ring
Border, and cooperate the inhibition to bacterial fungus, to achieve the effect that efficiently to remove moss, the present invention is free of pesticide and high toxicity chemicals
Matter, environmental sound.
Specific embodiment
Wheat bran processing material: 1:12 ~ 18 take wheat bran, normal hexane mixing in mass ratio, in 28 ~ 32 DEG C, with 50 ~ 65kHz frequency
It is ultrasonically treated 40 ~ 60min, obtains disperse materials, takes disperse materials in centrifuge, 12 ~ 20min is centrifuged with 3000 ~ 4000 r/min, takes out
Filter collects filter residue 1:8 in mass ratio ~ 12 and the ethanol solution mixing that volume fraction is 70% is added, assists in 28 ~ 33 DEG C of ultrasonic waves
After extracting 40 ~ 60min, it is centrifuged 12 ~ 20min with 3000 ~ 4000 r/min, supernatant is collected in 40 ~ 60 DEG C and is concentrated in vacuo to original
Expect to get wheat bran processing the 25 ~ 45% of volume.
Sedimentation agent: 5:1 ~ 3:0.2:0.01 in mass ratio takes aluminium polychloride, vulcanized sodium, lignin, titanium dioxide mixing,
Up to sedimentation agent.
Nutrient solution: 3 ~ 7:1:2:1:20 ~ 30 take casein, yeast extract, glucose, sucrose, water mixing to get battalion in mass ratio
Nutrient solution.
Additive: 3 ~ 7:1:0.01 in mass ratio takes paracide, ferrocene, stannous octoate mixing to get additive.
Macromole evocating agent: the taking polyethylene glycol of 4 ~ 8:3 in mass ratio diacrylate, glycol dioleate mixing,
Up to macromole evocating agent.
Containing silica reagent: 1:3 ~ 7 take sodium methyl silicate, trim,ethylchlorosilane mixing to get organosilicon in mass ratio.
Function nano material: 1:2 ~ 5 take nano-TiO in mass ratio2, Fe Nano-Powders mixing to get function nano material.
The compound preparation method except tongue fur base-material, includes the following steps:
(1) in 32 ~ 45 DEG C, take biogas slurry 8 ~ 13:1:0.3 in mass ratio that sedimentation agent, flyash mixing is added, with 500 ~ 800r/min
40 ~ 60min is stirred, pH to 7.5 ~ 8.0 is adjusted with the NaOH solution that mass fraction is 20%, keeps the temperature and stand 20 ~ 45min, filtering,
Collect filtrate, obtain pretreatment biogas slurry, according to parts by weight, take 20 ~ 40 parts of partial sizes be 1.3 ~ 3.2cm spherical natural colour sand, 40 ~
60 portions of nutrient solutions, 1 ~ 3 part of pretreatment biogas slurry biogas slurry, 1 ~ 4 part of succinic acid are mixed in fermentor, in 27 ~ 32 DEG C, with 180 ~ 220r/
Min vibrates shaking table, and closed ferment at constant temperature opens fermentor, air is blasted with 70 ~ 100mL/min rate, in 28 ~ 32 after 2 ~ 4 days
DEG C, it constant temperature incubation 2 ~ 4 days, discharges, filtering collects filter cake in 110 ~ 121 DEG C of 15 ~ 25min of insulated sterilizing, bio-modification color sand；
(2) according to parts by weight, successively take 50 ~ 70 parts of (N- amidino groups) dodecylacrylamides, 7 ~ 13 parts of macromole evocating agents,
1 ~ 4 part of additive is mixed in reaction kettle, in 35 ~ 45 DEG C, after stirring 1 ~ 3h with 700 ~ 1000r/min constant temperature, obtains block copolymer,
Take block copolymer 1:4 in mass ratio ~ 8 that the mixing of bio-modification color sand is added, with 450 ~ 800r/min, 40 ~ 60min of magnetic agitation,
Up to compound place tongue fur base-material.
The preparation of composite auxiliary material: 3 ~ 5:1 in mass ratio takes snail shell, shrimp shell to crush in pulverizer, crosses 150 meshes, took
Sieve particle 3:7 ~ 12:1:20 in mass ratio be added bentonite, sodium chloride, water mixing, with 500 ~ 800r/min magnetic agitation 40 ~
60min obtains mixture, takes mixture 15 ~ 25:1:2 in mass ratio that function nano material is added, mixes containing silica reagent, with 700 ~
1000r/min 1 ~ 3h of magnetic agitation, in 35 ~ 48 DEG C of 25 ~ 40min of progress ultrasonication to get composite auxiliary material.
One planting fruit-trees moss removing agent, according to the mass fraction, including following component: 2 ~ 5 parts of zeolites, 12 ~ 20 parts of plant ash, 5 ~
10 parts of wheat bran processing material, 30 ~ 50 parts compound remove tongue fur base-material, 12 ~ 20 parts of composite auxiliary materials.
The preparation method of one planting fruit-trees moss removing agent, includes the following steps:
Including following component (1) according to the mass fraction: 2 ~ 5 parts of zeolites, 12 ~ 20 parts of plant ash, 5 ~ 10 parts of wheat bran processing material, 30 ~
50 parts compound except tongue fur base-material, 12 ~ 20 parts of composite auxiliary materials.
(2) prior to 27 ~ 32 DEG C, take plant ash, wheat bran processing material, it is compound mixed except tongue fur base-material in reaction kettle, with 500 ~
800r/min 40 ~ 60min of magnetic agitation is warming up to 45 ~ 65 DEG C, composite auxiliary material, zeolite mixing is added, with 700 ~ 1000r/min
40 ~ 60min of magnetic agitation, cooled to room temperature is to get fruit tree moss removing agent.
The application method of one planting fruit-trees moss removing agent: 2 ~ 4kg/m is pressed2This fruit tree moss removing agent is coated on moss
Around fruit tree tree root, and using tree root as the center of circle, radius is in the border circular areas of 0.08 ~ 0.15m.
Embodiment 1
Wheat bran processing material: 1:12 in mass ratio takes wheat bran, normal hexane mixing, in 28 DEG C, handle 40min with 50kHz frequency ultrasound,
Disperse materials are obtained, take disperse materials in centrifuge, 12min is centrifuged with 3000r/min, is filtered, filter residue 1:8 in mass ratio is collected and body is added
The ethanol solution that fraction is 70% mixes, and after 28 DEG C of ultrasonic wave assisted extraction 40min, is centrifuged 12min with 3000r/min, receives
Collect supernatant and is concentrated in vacuo to the 25% of original volume in 40 DEG C to get wheat bran processing material.
Sedimentation agent: 5:1:0.2:0.01 in mass ratio takes aluminium polychloride, vulcanized sodium, lignin, titanium dioxide mixing, i.e.,
Obtain sedimentation agent.
Nutrient solution: 3:1:2:1:20 in mass ratio takes casein, yeast extract, glucose, sucrose, water mixing to get nutrient solution.
Additive: 3:1:0.01 in mass ratio takes paracide, ferrocene, stannous octoate mixing to get additive.
Macromole evocating agent: 4:3 taking polyethylene glycol diacrylate, glycol dioleate mixing in mass ratio, i.e.,
Obtain macromole evocating agent.
Containing silica reagent: 1:3 in mass ratio takes sodium methyl silicate, trim,ethylchlorosilane mixing to get organosilicon.
Function nano material: 1:2 takes nano-TiO in mass ratio2, Fe Nano-Powders mixing to get function nano material.
The compound preparation method except tongue fur base-material, includes the following steps:
(1) it in 32 DEG C, takes biogas slurry 8:1:0.3 in mass ratio that sedimentation agent, flyash mixing is added, 40min is stirred with 500r/min,
PH to 7.5 is adjusted with the NaOH solution that mass fraction is 20%, heat preservation stands 20min, and filtering collects filtrate, must pre-process natural pond
Liquid, according to parts by weight, take 20 parts of partial sizes be the spherical natural colour sand of 1.3cm, 40 portions of nutrient solutions, 1 part of pretreatment biogas slurry biogas slurry,
1 part of succinic acid is mixed in fermentor, in 27 DEG C, vibrates shaking table with 180r/min, and closed ferment at constant temperature opened fermentor after 2 days,
Air is blasted with 70mL/min rate, in 28 DEG C, constant temperature incubation 2 days, is discharged, filtering collects filter cake in 110 DEG C of insulated sterilizings
15min, bio-modification color sand；
(2) according to parts by weight, successively take 50 parts of (N- amidino groups) dodecylacrylamides, 7 parts of macromole evocating agents, 1 part add
Add agent to mix in reaction kettle, in 35 DEG C, after stirring 1h with 700r/min constant temperature, obtains block copolymer, take block copolymer by matter
The mixing of bio-modification color sand is added than 1:4 in amount, with 450r/min magnetic agitation 40min to get compound place tongue fur base-material.
The preparation of composite auxiliary material: 3:1 in mass ratio takes snail shell, shrimp shell to crush in pulverizer, crosses 150 meshes, takes sieving
Bentonite, sodium chloride, water mixing is added in particle 3:7:1:20 in mass ratio, with 500r/min magnetic agitation 40min, must mix
Material takes mixture 15:1:2 in mass ratio that function nano material is added, mixes containing silica reagent, with 700r/min magnetic agitation 1h, in
42 DEG C of progress ultrasonication 25min are to get composite auxiliary material.
One planting fruit-trees moss removing agent, according to the mass fraction, including following component: 2 parts of zeolites, 12 parts of plant ash, 5 parts of wheat bran
Processing material, 30 parts it is compound remove tongue fur base-material, 12 parts of composite auxiliary materials.
The preparation method of one planting fruit-trees moss removing agent, includes the following steps:
Including following component (1) according to the mass fraction: 2 parts of zeolites, 12 parts of plant ash, 5 parts of wheat bran processing material, 30 parts compound remove
Tongue fur base-material, 12 parts of composite auxiliary materials.
(2) prior to 27 DEG C, plant ash, wheat bran processing material, the compound tongue fur base-material that removes is taken to mix in reaction kettle, with 500r/min magnetic
Power stirs 40min, is warming up to 45 DEG C, composite auxiliary material, zeolite mixing is added, with 700r/min magnetic agitation 40min, natural cooling
To room temperature to get fruit tree moss removing agent.
The application method of one planting fruit-trees moss removing agent: 2kg/m is pressed2This fruit tree moss removing agent is coated on the fruit with moss
It sets around tree root, and using tree root as the center of circle, radius is in the border circular areas of 0.08m.
Embodiment 2
Wheat bran processing material: 1:18 in mass ratio takes wheat bran, normal hexane mixing, in 32 DEG C, handle 60min with 65kHz frequency ultrasound,
Disperse materials are obtained, take disperse materials in centrifuge, 20min is centrifuged with 4000 r/min, filters, filter residue 1:12 in mass ratio is collected and is added
The ethanol solution that volume fraction is 70% mixes, after 33 DEG C of ultrasonic wave assisted extraction 60min, with 4000 r/min centrifugation
20min collects supernatant and is concentrated in vacuo to the 45% of original volume in 60 DEG C to get wheat bran processing material.
Sedimentation agent: 5:2:0.2:0.01 in mass ratio takes aluminium polychloride, vulcanized sodium, lignin, titanium dioxide mixing, i.e.,
Obtain sedimentation agent.
Nutrient solution: 7:1:2:1:30 in mass ratio takes casein, yeast extract, glucose, sucrose, water mixing to get nutrient solution.
Additive: 5:1:0.01 in mass ratio takes paracide, ferrocene, stannous octoate mixing to get additive.
Macromole evocating agent: 7:3 taking polyethylene glycol diacrylate, glycol dioleate mixing in mass ratio, i.e.,
Obtain macromole evocating agent.
Containing silica reagent: 1:7 in mass ratio takes sodium methyl silicate, trim,ethylchlorosilane mixing to get organosilicon.
Function nano material: 1:5 takes nano-TiO in mass ratio2, Fe Nano-Powders mixing to get function nano material.
The compound preparation method except tongue fur base-material, includes the following steps:
(1) it in 45 DEG C, takes biogas slurry 13:1:0.3 in mass ratio that sedimentation agent, flyash mixing is added, is stirred with 800r/min
60min adjusts pH to 8.0 with the NaOH solution that mass fraction is 20%, and heat preservation stands 45min, and filtering collects filtrate, obtains pre- place
Biogas slurry is managed, according to parts by weight, taking 40 parts of partial sizes is spherical natural colour sand, the 60 portions of nutrient solutions, 3 parts of pretreatment biogas slurries of 3.2cm
Biogas slurry, 4 parts of succinic acids are mixed in fermentor, in 32 DEG C, vibrate shaking table with 220r/min, closed ferment at constant temperature opened hair after 4 days
Fermentation tank blasts air with 100mL/min rate, in 32 DEG C, constant temperature incubation 4 days, discharges, and filtering is collected filter cake and kept the temperature in 121 DEG C
Sterilize 25min, bio-modification color sand；
(2) according to parts by weight, successively take 70 parts of (N- amidino groups) dodecylacrylamides, 13 parts of macromole evocating agents, 4 parts add
Add agent to mix in reaction kettle, in 45 DEG C, after stirring 3h with 1000r/min constant temperature, obtains block copolymer, take block copolymer by matter
The mixing of bio-modification color sand is added than 1:8 in amount, with 800r/min magnetic agitation 60min to get compound place tongue fur base-material.
The preparation of composite auxiliary material: 5:1 in mass ratio takes snail shell, shrimp shell to crush in pulverizer, crosses 150 meshes, takes sieving
Bentonite, sodium chloride, water mixing is added in particle 3:12:1:20 in mass ratio, with 800r/min magnetic agitation 60min, must mix
Material takes mixture 25:1:2 in mass ratio that function nano material is added, mixes containing silica reagent, with 1000r/min magnetic agitation 3h, in
38 DEG C of progress ultrasonication 40min are to get composite auxiliary material.
One planting fruit-trees moss removing agent, according to the mass fraction, including following component: 5 parts of zeolites, 20 parts of plant ash, 10 portions of wheats
Bran processing material, 50 parts it is compound remove tongue fur base-material, 20 parts of composite auxiliary materials.
The preparation method of one planting fruit-trees moss removing agent, includes the following steps:
Including following component (1) according to the mass fraction: 5 parts of zeolites, 20 parts of plant ash, 10 parts of wheat bran processing material, 50 parts compound remove
Tongue fur base-material, 20 parts of composite auxiliary materials.
(2) prior to 32 DEG C, plant ash, wheat bran processing material, the compound tongue fur base-material that removes is taken to mix in reaction kettle, with 800r/min magnetic
Power stirs 60min, is warming up to 65 DEG C, and composite auxiliary material, zeolite mixing is added, naturally cold with 1000r/min magnetic agitation 60min
But to room temperature to get fruit tree moss removing agent.
The application method of one planting fruit-trees moss removing agent: 4kg/m is pressed2This fruit tree moss removing agent is coated on the fruit with moss
It sets around tree root, and using tree root as the center of circle, radius is in the border circular areas of 0.15m.
Embodiment 3
Wheat bran processing material: 1:15 in mass ratio takes wheat bran, normal hexane mixing, in 30 DEG C, handle 50min with 55kHz frequency ultrasound,
Disperse materials are obtained, take disperse materials in centrifuge, 15min is centrifuged with 3500 r/min, filters, filter residue 1:10 in mass ratio is collected and is added
The ethanol solution that volume fraction is 70% mixes, after 30 DEG C of ultrasonic wave assisted extraction 50min, with 3500 r/min centrifugation
15min collects supernatant and is concentrated in vacuo to the 35% of original volume in 50 DEG C to get wheat bran processing material.
Sedimentation agent: 5:3:0.2:0.01 in mass ratio takes aluminium polychloride, vulcanized sodium, lignin, titanium dioxide mixing, i.e.,
Obtain sedimentation agent.
Nutrient solution: 4:1:2:1:25 in mass ratio takes casein, yeast extract, glucose, sucrose, water mixing to get nutrient solution.
Additive: 5:1:0.01 in mass ratio takes paracide, ferrocene, stannous octoate mixing to get additive.
Macromole evocating agent: 8:3 taking polyethylene glycol diacrylate, glycol dioleate mixing in mass ratio, i.e.,
Obtain macromole evocating agent.
Containing silica reagent: 1:5 in mass ratio takes sodium methyl silicate, trim,ethylchlorosilane mixing to get organosilicon.
Function nano material: 1:3 takes nano-TiO in mass ratio2, Fe Nano-Powders mixing to get function nano material.
The compound preparation method except tongue fur base-material, includes the following steps:
(1) it in 35 DEG C, takes biogas slurry 10:1:0.3 in mass ratio that sedimentation agent, flyash mixing is added, is stirred with 600r/min
50min adjusts pH to 7.9 with the NaOH solution that mass fraction is 20%, and heat preservation stands 35min, and filtering collects filtrate, obtains pre- place
Biogas slurry is managed, according to parts by weight, taking 30 parts of partial sizes is spherical natural colour sand, the 50 portions of nutrient solutions, 2 parts of pretreatment biogas slurries of 2.2cm
Biogas slurry, 3 parts of succinic acids are mixed in fermentor, in 29 DEG C, vibrate shaking table with 200r/min, closed ferment at constant temperature opened hair after 3 days
Fermentation tank blasts air with 80mL/min rate, in 30 DEG C, constant temperature incubation 3 days, discharges, and filtering is collected filter cake and kept the temperature in 120 DEG C
Sterilize 20min, bio-modification color sand；
(2) according to parts by weight, successively take 60 parts of (N- amidino groups) dodecylacrylamides, 10 parts of macromole evocating agents, 3 parts add
Add agent to mix in reaction kettle, in 40 DEG C, after stirring 2h with 900r/min constant temperature, obtains block copolymer, take block copolymer by matter
The mixing of bio-modification color sand is added than 1:6 in amount, with 600r/min magnetic agitation 50min to get compound place tongue fur base-material.
The preparation of composite auxiliary material: 4:1 in mass ratio takes snail shell, shrimp shell to crush in pulverizer, crosses 150 meshes, takes sieving
Bentonite, sodium chloride, water mixing is added in particle 3:10:1:20 in mass ratio, with 600r/min magnetic agitation 50min, must mix
Material takes mixture 20:1:2 in mass ratio that function nano material is added, mixes containing silica reagent, with 900r/min magnetic agitation 2h, in
45 DEG C of progress ultrasonication 30min are to get composite auxiliary material.
One planting fruit-trees moss removing agent, according to the mass fraction, including following component: 3 parts of zeolites, 15 parts of plant ash, 7 parts of wheat bran
Processing material, 40 parts it is compound remove tongue fur base-material, 19 parts of composite auxiliary materials.
The preparation method of one planting fruit-trees moss removing agent, includes the following steps:
Including following component (1) according to the mass fraction: 3 parts of zeolites, 19 parts of plant ash, 7 parts of wheat bran processing material, 40 parts compound remove
Tongue fur base-material, 15 parts of composite auxiliary materials.
(2) prior to 30 DEG C, plant ash, wheat bran processing material, the compound tongue fur base-material that removes is taken to mix in reaction kettle, with 600r/min magnetic
Power stirs 50min, is warming up to 55 DEG C, composite auxiliary material, zeolite mixing is added, with 800r/min magnetic agitation 50min, natural cooling
To room temperature to get fruit tree moss removing agent.
The application method of one planting fruit-trees moss removing agent: 3kg/m is pressed2This fruit tree moss removing agent is coated on the fruit with moss
It sets around tree root, and using tree root as the center of circle, radius is in the border circular areas of 0.12m.
Comparative example 1: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking compound except tongue fur base-material.
Comparative example 2: it is essentially identical with the preparation method of embodiment 1, it has only the difference is that lacking composite auxiliary material.
Comparative example 3: the moss removing agent of Kunming company production.
The moss removing agent that above-described embodiment is obtained with comparative example is detected, test material: the moss on fruit tree root, it is real
Design: 6 groups of processing of experimental design is tested, using the moss removing agent of embodiment and comparative example preparation, is handled, plot area 12m2,
Random district's groups arrangement, every minizone is every 20cm；Efficacy survey: the 30th day investigation drug effect after application, by 0 (no moss), 1 (1%~
10% slightly moss), 3 (11%~25% moss is somewhat green), 5 (26%~50% moss visual field is visible), 7 (51%~75%
Moss agglomeration), 9 (76%~100% moss is covered with) grade grade scales, Zai Qu inspection center detects whether it contains high toxicity object
Matter, there is that the results are shown in Table 1.
Table 1:
| Detection project | Embodiment 1 | Embodiment 2 | Embodiment 3 | Comparative example 1 | Comparative example 2 | Comparative example 3 |
| Moss preventive effect | 0 | 0 | 0 | 1 | 3 | 5 |
| High toxic material | Nothing | Nothing | Nothing | Nothing | Nothing | Have |
In summary, fruit tree of the invention is more preferable with moss removing agent effect as can be seen from Table 1, is worth of widely use, described above
Preferred mode only of the invention, is not intended to limit the invention, all within the spirits and principles of the present invention, made any
Modification, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.
Claims (10)
1. a planting fruit-trees moss removing agent, according to the mass fraction, including following component: 2 ~ 5 parts of zeolites, 12 ~ 20 parts of plant ash, 5 ~ 10
Part wheat bran processing material, which is characterized in that further include: 30 ~ 50 parts are compound except tongue fur base-material, 12 ~ 20 parts of composite auxiliary materials.
2. a planting fruit-trees moss removing agent according to claim 1, which is characterized in that the compound preparation side except tongue fur base-material
Method includes the following steps:
(1) it in 32 ~ 45 DEG C, takes biogas slurry 8 ~ 13:1:0.3 in mass ratio that sedimentation agent, flyash mixing is added, adjusts pH, protect
Temperature is stood, and filtering collects filtrate, obtains pretreatment biogas slurry, according to parts by weight, take 20 ~ 40 parts of natural colour sands, 40 ~ 60 parts of nutrition
Liquid, 1 ~ 3 part of pretreatment biogas slurry biogas slurry, 1 ~ 4 part of succinic acid mixing vibrate shaking table in 27 ~ 32 DEG C, and closed ferment at constant temperature blasts sky
Gas, in 28 ~ 32 DEG C, constant temperature incubation discharges, filtering, collects filter cake sterilizing, bio-modification color sand；
(2) according to parts by weight, successively take 50 ~ 70 parts of (N- amidino groups) dodecylacrylamides, 7 ~ 13 parts of macromole evocating agents,
1 ~ 4 part of additive mixing, in 35 ~ 45 DEG C, constant temperature stirring obtains block copolymer, block copolymer 1:4 in mass ratio ~ 8 is taken to be added
Bio-modification color sand is mixed to get compound place tongue fur base-material.
3. a planting fruit-trees moss removing agent according to claim 2, which is characterized in that the sedimentation agent in the step (1): pressing matter
Amount takes aluminium polychloride, vulcanized sodium, lignin, titanium dioxide mixing to get sedimentation agent than 5:1 ~ 3:0.2:0.01.
4. a planting fruit-trees moss removing agent according to claim 2, which is characterized in that the nutrient solution in the step (1): pressing matter
Amount takes casein, yeast extract, glucose, sucrose, water mixing to get nutrient solution than 3 ~ 7:1:2:1:20 ~ 30.
5. a planting fruit-trees moss removing agent according to claim 2, which is characterized in that the additive in the step (2): pressing matter
Amount takes paracide, ferrocene, stannous octoate mixing to get additive than 3 ~ 7:1:0.01.
6. a planting fruit-trees moss removing agent according to claim 2, which is characterized in that the macromolecular in the step (2) causes
Agent: the taking polyethylene glycol of 4 ~ 8:3 in mass ratio diacrylate, glycol dioleate mixing are to get macromole evocating agent.
7. a planting fruit-trees moss removing agent according to claim 1, which is characterized in that the preparation of the composite auxiliary material: pressing quality
Take snail shell, shrimp shell to pulverize and sieve than 3 ~ 5:1, take sieving particle 3:7 ~ 12:1:20 in mass ratio be added bentonite, sodium chloride,
Water is mixed, and obtains mixture, takes mixture 15 ~ 25:1:2 in mass ratio that function nano material is added, is mixed containing silica reagent,
In 35 ~ 48 DEG C of progress ultrasonications to get composite auxiliary material.
8. a planting fruit-trees moss removing agent according to claim 7, which is characterized in that described to contain silica reagent: 1:3 ~ 7 in mass ratio
Take sodium methyl silicate, trim,ethylchlorosilane mixing to get containing silica reagent.
9. a planting fruit-trees moss removing agent according to claim 7, which is characterized in that the function nano material: 1:2 in mass ratio
~ 5 take nano-TiO2, Fe Nano-Powders mixing to get function nano material.
10. a planting fruit-trees moss removing agent according to claim 1, which is characterized in that the wheat bran processing material: in mass ratio 1:
12 ~ 18 take wheat bran, normal hexane mixing, and in 28 ~ 32 DEG C, ultrasonic treatment obtains disperse materials, disperse materials is taken to be centrifuged, and filters, and collect filter residue
Ethanol solution mixing is added in 1:8 in mass ratio ~ 12, and in 28 ~ 33 DEG C of ultrasonic wave assisted extractions, it is dense to collect supernatant vacuum for centrifugation
Contracting is expected to get wheat bran processing.
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| CN102763686A (en) * | 2012-07-25 | 2012-11-07 | 天津生机集团股份有限公司 | Composition for removing moss and preparation method of composition |
| KR20140056547A (en) * | 2012-10-29 | 2014-05-12 | 대한민국(농촌진흥청장) | Moss remover of citrus tree |
| CN104255790A (en) * | 2014-08-29 | 2015-01-07 | 周可幸 | Composition for removing moss |
| CN108002933A (en) * | 2016-10-29 | 2018-05-08 | 重庆市农业科学院 | Mandarin tree removes moss reagent |
| CN108576071A (en) * | 2018-05-31 | 2018-09-28 | 广西浪伏茶业股份有限公司 | A kind of control method of tea tree moss |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5009700A (en) * | 1990-07-26 | 1991-04-23 | Olin Corporation | Use of pyrithione for the control of moss |
| KR20090065005A (en) * | 2007-12-17 | 2009-06-22 | 그린스웰 주식회사 | Green moss washing agent composition for fruit tree and a preparation method thereof |
| CN102763686A (en) * | 2012-07-25 | 2012-11-07 | 天津生机集团股份有限公司 | Composition for removing moss and preparation method of composition |
| KR20140056547A (en) * | 2012-10-29 | 2014-05-12 | 대한민국(농촌진흥청장) | Moss remover of citrus tree |
| CN104255790A (en) * | 2014-08-29 | 2015-01-07 | 周可幸 | Composition for removing moss |
| CN108002933A (en) * | 2016-10-29 | 2018-05-08 | 重庆市农业科学院 | Mandarin tree removes moss reagent |
| CN108576071A (en) * | 2018-05-31 | 2018-09-28 | 广西浪伏茶业股份有限公司 | A kind of control method of tea tree moss |
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