CN109736077A - For spraying the liquor and preparation method that shine wall clothing anion function fibrous material - Google Patents
For spraying the liquor and preparation method that shine wall clothing anion function fibrous material Download PDFInfo
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- CN109736077A CN109736077A CN201811431451.5A CN201811431451A CN109736077A CN 109736077 A CN109736077 A CN 109736077A CN 201811431451 A CN201811431451 A CN 201811431451A CN 109736077 A CN109736077 A CN 109736077A
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Abstract
The invention discloses for spraying the liquor and preparation method that shine wall clothing anion function fibrous material, the liquor is for carrying out spray solarization to substrate before substrate weaving forming material, the substrate is fiber, and the liquor includes the component of following parts by weight: 200-300 parts of anion material, 20-50 parts of softener, 20-50 parts of finishing agent, 5-10 parts of mould inhibitor, 590-755 parts of deionized water;Its anion material includes the component of following parts by weight: 5-10 parts of 20-45 parts of germanite, 20-30 parts of tourmaline, placer 15-40 parts of seabed, 10-20 parts of hornblend, 10-30 parts of opal, 10-25 parts of pyrophillite, rare earth mixed processings are made.The present invention has release negative aeroion and far infrared function, can eliminate suspend aerial toxic and harmful gas and dust, inhibits bacterium mould and purification air;Also with the fungicidal properties of mould inhibitor, the practical value of wall clothing fibrous material is substantially increased.
Description
Technical field
The present invention relates to metope coating material technical fields, and in particular to shines wall clothing anion function fiber to for spraying
The liquor and preparation method of material.
Background technique
Paint or wallpaper is usually used in wall surfacing product, but traditional paint coating harmful substance contents are high, right
Human body harm is big, though having used water paint currently on the market, harmful substance contents are reduced, and existing national Specification is still
A certain amount of free formaldehyde is allowed, this still needs to occupy after divulging information after a period of time after making room wall plastering
Firmly, and wall pattern color is single, lacks aesthetic feeling;Although the application of wallpaper can enrich the pattern and color of wall, its cost
Greatly improve, and using will appear over time aging, discoloration, it is damaged after be not easy the problems such as repairing, meanwhile, gluing used in wallpaper
Agent contains formaldehyde more.Wall clothing is the third class Novel interior wall ornament materials occurred after the decorative material for internal wall such as paint, wallpaper,
It is process using wood fibre, natural fiber as primary raw material through special scientific technology, has beauty, is free of noxious volatile
The advantages that ingredient, texture is not strong, easy to crack, construction is convenient pollution-free, repairing is simple is a kind of environmentally friendly, green internal wall finishing
Material.
In environmental evaluation, air-anion concentration is listed in an important parameter for measuring air quality.It is fitted in air
When the toxic and harmful gas and dust that the anion of concentration is suspended in air elimination, inhibit bacterium mould and purification air,
And ecological environment long-lived to people's health, all has and its important role.
Requirement with people to environmental quality is higher and higher, and the superior of wall clothing, functionalization, environmental protection have become wall clothing
The inexorable trend of manufacturing enterprise's development.Therefore have collection release anion, release far infrared, purification air, eliminate the unusual smell, resist
The wall clothing material of the functions such as bacterium, mould proof has very big realistic meaning and application value.
Summary of the invention
To solve the above problems, the present invention is provided to spray liquor and the preparation of shining wall clothing anion function fibrous material
Method.
To achieve the above object, The technical solution adopted by the invention is as follows: shining wall clothing anion function fiber for spraying
The liquor of material, for the liquor for carrying out spray solarization to substrate before substrate weaving forming material, the substrate is fiber,
The liquor includes the component of following parts by weight: 200-300 parts of anion material, 20-50 parts of softener, finishing agent 20-50
Part, 5-10 parts of mould inhibitor, 590-755 parts of deionized water.
Further, the anion material includes the component of following parts by weight: 20-45 parts of germanite, tourmaline 20-30
Part, placer 15-40 parts of seabed, 10-20 parts of hornblend, 10-30 parts of opal, 10-25 parts of pyrophillite, 5-10 parts of rare earth, it is described
Anion material particle diameter be 400-500nm.
Further, the mould inhibitor is ammonium chloride.
Further, the fiber includes natural fiber and artificial synthetic fiber, and the natural fiber includes natural
Animal origin and natural plant fibre.
Further, the artificial synthetic fiber includes terylene, spandex, acrylic fibers, nylon, aramid fiber, polyvinyl, polypropylene fibre.
Further, the liquor includes the component of following parts by weight: 210 parts of anion material, 50 parts of softener, whole
Manage 50 parts of agent, 8 parts of mould inhibitor, 682 parts of deionized water.
Further, the liquor includes the component of following parts by weight: 290 parts of anion material, 30 parts of softener, whole
Manage 30 parts of agent, 5 parts of mould inhibitor, 645 parts of deionized water.
The preparation method of wall clothing anion function fibrous material, uses the liquor, comprising the following steps:
Fiber pretreatment;
Prepare anion material: the grain diameter of anion material is 400-500nm;
By following parts by weight prepare liquor: 200-300 parts of anion material, 20-50 parts of softener, 20-50 parts of finishing agent,
5-10 parts of mould inhibitor, 590-755 parts of deionized water;
It is sprayed with liquor and shines fiber;
After the completion of spray is shone, 18-24h is balanced, then mixed well, fed intake, clot, weaving are twisted diameter 0.5mm-3mm's
Single count yarn;
By the blended bifilar or multi-strand yarns at diameter 1mm-6mm of each single count yarn obtained;
By obtained bifilar or multi-strand yarns cut into length be 0.5cm-3cm line segment to get wall clothing anion function
It can fibrous material.
Further, the anion material preparation method the following steps are included:
It is 20-45 parts of germanite, 20-30 parts of tourmaline, 15-40 parts of seabed placer, 10-20 parts of angle by parts by weight
Amphibole, 10-30 parts of opal, 10-25 parts of pyrophillite, the mixing of 5-10 parts of rare earth, after calcining 3-5h at 500-550 DEG C
It is cooled to room temperature, is ground into the particle that partial size is 30-60 μm;
Be added the stirring of suitable deionized water be made after 50% suspension adjusted with the NaOH solution that concentration is 10% it is outstanding
Supernatant liquid PH to 8, then carries out microwave treatment 1.5-2.5h, microwave power 400-500W, and magnetic force vibrates 0.5-1h, frequency of oscillation
For 300-500Hz;
Suspension PH to 6 is adjusted with the HCl solution that concentration is 10%;Then microwave treatment 1.5-2.5h, microwave power are
400-500W, sonic oscillation 1-2h, frequency of oscillation 20-30KHz;
The NaHCO for being 15% with concentration3Solution is neutralized to neutrality, is then centrifuged under the revolving speed of 1500-2000r/min
18-24h is stood after 20-30min;
Filtering, drying carry out secondary clacining after removing moisture removal to moisture content≤1%, and calcination temperature is 600-650 DEG C, calcining
Time is 2-3h, and being milled to grain diameter after being cooled to room temperature under the revolving speed of 13000-15000r/min is 400-500nm, i.e.,
Obtain anion material.
The application method of wall clothing anion function fibrous material, comprising the following steps:
Metope is handled it is clean, smooth, and with white water-borne priming paint back cover or apply one layer of basement membrane;
Wall clothing anion function fibrous material, water-soluble plant glue are mixed according to weight ratio 1:1-1:2, and in mixing
It discharges after mixing evenly in equipment;
By after mixing fibrous material and water according to weight ratio 1:3-1:5 be mixed and stirred for uniformly, be made wall clothing material
Material stands 30-50min;
The wall clothing material hand or trowel that are stirred are stained on wall and smeared out with trowel, it is applied, with a thickness of 2-
4mm;
After 24-48h, uneven or exposed metope is squirted with normal-temperature water, then is smoothed out with wall clothing material;
Receipts light is carried out along respective direction with trowel.
By the above-mentioned description of this invention it is found that compared with prior art, wall clothing anion function fiber of the invention
It is aerial can to eliminate suspension for material, release negative aeroion and far infrared function with germanite, seabed placer etc.
Toxic and harmful gas and dust inhibit bacterium mould and purification air;And the excellent absorption property with pyrophillite etc.;Also have
The fungicidal properties of mould inhibitor can greatly improve the practical value of wall clothing material.
Detailed description of the invention
Fig. 1 is the preparation method flow chart of wall clothing anion function fibrous material of the present invention;
Fig. 2 is the preparation method process for the anion material that the present invention is used to prepare wall clothing anion function fibrous material
Figure;
Fig. 3 is the application method flow chart of wall clothing anion function fibrous material of the present invention.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, is clearly and completely retouched to the technical solution in the present invention
It states, it is clear that the described embodiments are merely a part of the embodiments of the present invention, instead of all the embodiments.
Specific embodiment one
Wall clothing anion function fibrous material, preparation method includes the following steps:
S1: fiber pretreatment,
S2: being 20-45 parts of germanite, 20-30 parts of tourmaline, 15-40 parts of seabed placer, 10-20 parts by parts by weight
Hornblend, 10-30 parts of opal, 10-25 parts of pyrophillite, 5-10 parts rare earth mixing, calcine 3- at 500-550 DEG C
It is cooled to room temperature after 5h, is ground into the particle that partial size is 30-60 μm;The suspension that suitable deionized water stirring is made 50% is added
Suspension PH to 8 is adjusted with the NaOH solution that concentration is 10% after liquid, then carries out microwave treatment 1.5-2.5h, microwave power is
400-500W, magnetic force vibrate 0.5-1h, frequency of oscillation 300-500Hz;Suspension PH is adjusted with the HCl solution that concentration is 10%
To 6;Then microwave treatment 1.5-2.5h, microwave power 400-500W, sonic oscillation 1-2h, frequency of oscillation 20-30KHz;
The NaHCO for being 15% with concentration3Solution is neutralized to neutrality, after being then centrifuged 20-30min under the revolving speed of 1500-2000r/min
Stand 18-24h;Filtering, drying carry out secondary clacining after removing moisture removal to moisture content≤1%, and calcination temperature is 600-650 DEG C,
Calcination time is 2-3h, and being milled to grain diameter after being cooled to room temperature under the revolving speed of 13000-15000r/min is 400-
500nm to get anion material,
S3: liquor: 210 parts of anion material, 50 parts of softener, 50 parts of finishing agent, mould inhibitor 8 is prepared by following parts by weight
Part, 682 parts of deionized water,
S4: being sprayed with liquor and shine fiber,
S5: balance 20h, it then mixed well, fed intake, clot, weaving are twisted single count yarn of diameter 1mm;
S6: by the blended bifilar yarn at diameter 2mm of each list count yarn made from S5;
S7: bifilar yarn made from S6 is cut into the line segment that length is 1cm.
A kind of wall clothing nano-negative ion functional fibre material and preparation method thereof provided in this embodiment is suitable for soft
The metope (such as bedroom metope) of the more demanding area of compliance, fungicidal properties, anion burst size relatively small (10-25 ㎡) is applied
Work.Its actual effect is as shown in Table 1.
Table one:
According to functional fibre prepared by preparation method of the wall clothing provided in this embodiment with anion function fibrous material
Material, application method the following steps are included:
S1 ': metope is handled it is clean, smooth, and with white water-borne priming paint back cover or apply one layer of basement membrane;
S2 ': wall clothing anion function fibrous material, water-soluble plant glue are mixed according to weight ratio 1:1, and in mixing
It discharges after mixing evenly in equipment;
S3 ': by after mixing fibrous material and water according to weight ratio 1:3 be mixed and stirred for uniformly, be made wall clothing material
Material stands 35min;
S4 ': the wall clothing material hand or trowel that are stirred being stained on wall and smeared out with trowel, applied, with a thickness of
4mm;
After S5 ': 40h, uneven or exposed metope is squirted with normal-temperature water, then with wall clothing material obtained in step 3
Material smoothes out;
S6 ': receipts light is carried out along respective direction with trowel.
As shown in Table 1, wall clothing anion function fibrous material and preparation method provided in this embodiment, by certain
The anion material of weight ratio, softener, finishing agent, mould inhibitor, deionized water are mixed and made into liquor, then with liquor to fiber
Spray solarization is carried out, makes fibrous material obtained that not only there is release negative aeroion and far infrared function, can eliminate and be suspended in
Toxic and harmful gas and dust in air inhibit bacterium mould and purification air;Compliance also with higher and mould proof effect
Fruit can satisfy the demand such as bedroom to negative ion concentration, compliance and anti-mold effect etc., substantially increase wall clothing material
The practical value of material.
Specific embodiment two
Wall clothing anion function fibrous material, preparation method includes the following steps:
S01: fiber pretreatment,
S02: being 20-45 parts of germanite, 20-30 parts of tourmaline, 15-40 parts of seabed placer, 10-20 parts by parts by weight
Hornblend, 10-30 parts of opal, 10-25 parts of pyrophillite, 5-10 parts rare earth mixing, calcine 3- at 500-550 DEG C
It is cooled to room temperature after 5h, is ground into the particle that partial size is 30-60 μm;The suspension that suitable deionized water stirring is made 50% is added
Suspension PH to 8 is adjusted with the NaOH solution that concentration is 10% after liquid, then carries out microwave treatment 1.5-2.5h, microwave power is
400-500W, magnetic force vibrate 0.5-1h, frequency of oscillation 300-500Hz;Suspension PH is adjusted with the HCl solution that concentration is 10%
To 6;Then microwave treatment 1.5-2.5h, microwave power 400-500W, sonic oscillation 1-2h, frequency of oscillation 20-30KHz;
The NaHCO for being 15% with concentration3Solution is neutralized to neutrality, after being then centrifuged 20-30min under the revolving speed of 1500-2000r/min
Stand 18-24h;Filtering, drying carry out secondary clacining after removing moisture removal to moisture content≤1%, and calcination temperature is 600-650 DEG C,
Calcination time is 2-3h, and being milled to grain diameter after being cooled to room temperature under the revolving speed of 13000-15000r/min is 400-
500nm to get anion material,
S03: liquor: 290 parts of anion material, 30 parts of softener, 30 parts of finishing agent, mould inhibitor is prepared by following parts by weight
5 parts, 645 parts of deionized water,
S04: being sprayed with liquor and shine fiber,
S05: balance for 24 hours, is then mixed well, is fed intake, clot, weaving are twisted single count yarn of diameter 2mm;
S06: by the blended multi-strand yarns at diameter 6mm of each list count yarn made from S5;
S07: bifilar yarn made from S6 is cut into the line segment that length is 2cm.
A kind of wall clothing nano-negative ion functional fibre material and preparation method thereof provided in this embodiment is suitable for soft
Compliance, fungicidal properties, anion burst size require metope (such as public place of entertainment wall of slightly lower area relatively large (30-50 ㎡)
Face) construction.Its actual effect is as shown in Table 2.
Table two:
According to functional fibre prepared by preparation method of the wall clothing provided in this embodiment with anion function fibrous material
Material, application method the following steps are included:
S01 ': metope is handled it is clean, smooth, and with white water-borne priming paint back cover or apply one layer of basement membrane;
S02 ': wall clothing anion function fibrous material, water-soluble plant glue are mixed according to weight ratio 1:2, and mixed
It discharges after mixing evenly in material equipment;
S03 ': by after mixing fibrous material and water according to weight ratio 1:5 be mixed and stirred for uniformly, be made wall clothing material
Material stands 50min;
S04 ': the wall clothing material hand or trowel that are stirred being stained on wall and smeared out with trowel, applied, with a thickness of
3mm;
After S05 ': 30h, uneven or exposed metope is squirted with normal-temperature water, then with wall clothing obtained in step 3
Material smoothes out;
S06 ': receipts light is carried out along respective direction with trowel.
As shown in Table 2, wall clothing anion function fibrous material and preparation method provided in this embodiment, by certain
The anion material of weight ratio, softener, finishing agent, mould inhibitor, deionized water are mixed and made into liquor, then with liquor to fiber
Spray solarization is carried out, makes fibrous material obtained that not only there is release negative aeroion and far infrared function, can eliminate and be suspended in
Toxic and harmful gas and dust in air inhibit bacterium mould and purification air;Although compliance and anti-mold effect more one
As, it also can satisfy the general requirement such as public place of entertainment to negative ion concentration, compliance and anti-mold effect, substantially increase wall
The practical value of clothing material.
It is appreciated that the present invention is described by some embodiments, and what those skilled in the art knew, it is not taking off
In the case where from the spirit and scope of the present invention, various changes or equivalence replacement can be carried out to these features and embodiment.Separately
Outside, under the teachings of the present invention, can modify to these features and embodiment with adapt to particular situation and material without
The spirit and scope of the present invention can be detached from.Therefore, the present invention is not limited to the particular embodiment disclosed, and is fallen with
Embodiment within the scope of claims hereof belong to the present invention protect in the range of.
Claims (10)
1. for spraying the liquor for shining wall clothing anion function fibrous material, it is characterised in that: the liquor is spun for substrate
It is made into before fibrous material and spray solarization is carried out to substrate, the substrate is fiber, and the liquor includes the component of following parts by weight:
200-300 parts of anion material, 20-50 parts of softener, 20-50 parts of finishing agent, 5-10 parts of mould inhibitor, deionized water 590-755
Part.
2. according to claim 1 for spraying the liquor for shining wall clothing anion function fibrous material, it is characterised in that: institute
The anion material stated includes the component of following parts by weight: 20-45 parts of germanite, 20-30 parts of tourmaline, placer 15-40 parts of seabed,
10-20 parts of hornblend, 10-30 parts of opal, 10-25 parts of pyrophillite, 5-10 parts of rare earth, the particle of the anion material is straight
Diameter is 400-500nm.
3. according to claim 1 for spraying the liquor for shining wall clothing anion function fibrous material, it is characterised in that: institute
The mould inhibitor stated is ammonium chloride.
4. according to claim 1 for spraying the liquor for shining wall clothing anion function fibrous material, it is characterised in that: institute
The fiber stated includes natural fiber and artificial synthetic fiber, and the natural fiber includes that natural animal fibres and natural plants are fine
Dimension.
5. according to claim 4 for spraying the liquor for shining wall clothing anion function fibrous material, it is characterised in that: institute
The artificial synthetic fiber stated includes terylene, spandex, acrylic fibers, nylon, aramid fiber, polyvinyl, polypropylene fibre.
6. according to claim 1 for spraying the liquor for shining wall clothing anion function fibrous material described in any one of -5,
It is characterized by: the liquor includes the component of following parts by weight: 210 parts of anion material, 50 parts of softener, finishing agent 50
Part, 8 parts of mould inhibitor, 682 parts of deionized water.
7. according to claim 1 for spraying the liquor for shining wall clothing anion function fibrous material described in any one of -5,
It is characterized by: the liquor includes the component of following parts by weight: 290 parts of anion material, 30 parts of softener, finishing agent 30
Part, 5 parts of mould inhibitor, 645 parts of deionized water.
8. the wall clothing preparation method of anion function fibrous material, it is characterised in that: use liquid described in claim 1-7
Agent, comprising the following steps:
Step 1: fiber pretreatment;
Step 2: prepare anion material: the grain diameter of anion material is 400-500nm;
Step 3: liquor: 200-300 parts of anion material, 20-50 parts of softener, finishing agent 20-50 is prepared by following parts by weight
Part, 5-10 parts of mould inhibitor, 590-755 parts of deionized water;
Step 4: it is sprayed with liquor and shines fiber;
Step 5: after the completion of spray is shone, balancing 18-24h, is then mixed well, is fed intake, clot, weaving are twisted diameter 0.5mm-3mm
Single count yarn;
Step 6: by the blended bifilar or multi-strand yarns at diameter 1mm-6mm of each list count yarn made from step 5;
Step 7: bifilar made from step 6 or multi-strand yarns are cut into the line segment that length is 0.5cm-3cm to get wall clothing use
Anion function fibrous material.
9. the preparation method of wall clothing anion function fibrous material according to claim 8, it is characterised in that: described
The preparation method of anion material the following steps are included:
Step 1: being 20-45 parts of germanite, 20-30 parts of tourmaline, 15-40 parts of seabed placer, 10-20 parts by parts by weight
Hornblend, 10-30 parts of opal, 10-25 parts of pyrophillite, 5-10 parts rare earth mixing, calcine 3- at 500-550 DEG C
It is cooled to room temperature after 5h, is ground into the particle that partial size is 30-60 μm;
Step 2: it is added after 50% suspension is made in the stirring of suitable deionized water and is adjusted with the NaOH solution that concentration is 10%
Suspension PH to 8, then carries out microwave treatment 1.5-2.5h, microwave power 400-500W, and magnetic force vibrates 0.5-1h, oscillation frequency
Rate is 300-500Hz;
Step 3: suspension PH to 6 is adjusted with the HCl solution that concentration is 10%;Then microwave treatment 1.5-2.5h, microwave power
For 400-500W, sonic oscillation 1-2h, frequency of oscillation 20-30KHz;
Step 4: the NaHCO for being 15% with concentration3Solution is neutralized to neutrality, is then centrifuged under the revolving speed of 1500-2000r/min
18-24h is stood after 20-30min;
Step 5: filtering, drying carry out secondary clacining after removing moisture removal to moisture content≤1%, and calcination temperature is 600-650 DEG C,
Calcination time is 2-3h, and being milled to grain diameter after being cooled to room temperature under the revolving speed of 13000-15000r/min is 400-
500nm is to get anion material.
10. the wall clothing application method of anion function fibrous material, it is characterised in that: the following steps are included:
Step 1: metope is handled it is clean, smooth, and with white water-borne priming paint back cover or apply one layer of basement membrane;
Step 2: wall clothing anion function fibrous material, water-soluble plant glue are mixed according to weight ratio 1:1-1:2, and
It discharges after mixing evenly in mixing equipment;
Step 3: by after mixing fibrous material and water according to weight ratio 1:3-1:5 be mixed and stirred for uniformly, be made wall clothing
Material stands 30-50min;
Step 4: the wall clothing material hand or trowel that are stirred being stained on wall and smeared out with trowel, applied, with a thickness of 2-
4mm;
Step 5: after 24-48h, squirting uneven or exposed metope with normal-temperature water, then with wall clothing obtained in step 3
Material smoothes out;
Step 6: receipts light is carried out along respective direction with trowel.
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Application publication date: 20190510 |