CN107099997A - A kind of dressing liquid of Anion FIR Functional Pigment pillow - Google Patents

A kind of dressing liquid of Anion FIR Functional Pigment pillow Download PDF

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Publication number
CN107099997A
CN107099997A CN201710451377.2A CN201710451377A CN107099997A CN 107099997 A CN107099997 A CN 107099997A CN 201710451377 A CN201710451377 A CN 201710451377A CN 107099997 A CN107099997 A CN 107099997A
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CN
China
Prior art keywords
dressing liquid
anion
negative ion
nano
functional pigment
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710451377.2A
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Chinese (zh)
Inventor
张陈成
王海峰
瞿建刚
贾维妮
张小丽
戴香玲
成庆寿
王相林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
XINGHUA DADI BLUE SILK SPINNING CO Ltd
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XINGHUA DADI BLUE SILK SPINNING CO Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XINGHUA DADI BLUE SILK SPINNING CO Ltd filed Critical XINGHUA DADI BLUE SILK SPINNING CO Ltd
Priority to CN201710451377.2A priority Critical patent/CN107099997A/en
Publication of CN107099997A publication Critical patent/CN107099997A/en
Pending legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/80Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides
    • D06M11/82Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with boron or compounds thereof, e.g. borides with boron oxides; with boric, meta- or perboric acids or their salts, e.g. with borax
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/77Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof
    • D06M11/79Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with silicon or compounds thereof with silicon dioxide, silicic acids or their salts
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/83Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/50Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with organometallic compounds; with organic compounds containing boron, silicon, selenium or tellurium atoms
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/40Fibres of carbon

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)

Abstract

The invention belongs to ecological functions textile application technical field, specifically disclose a kind of dressing liquid of Anion FIR Functional Pigment pillow, the component of the nano-negative ion dressing liquid includes, ultra-fine negative ion powder, nano silicon, silane coupler, surfactant, water, its percentage by weight is:20‑40%:10‑15%:0.5%‑5%:1%‑3%:Surplus.The beneficial effects of the present invention are:1st, dressing liquid outward appearance light yellow clear liquid, pH5.0 6.0, the 200nm of particle diameter distribution 50, reaches Nano grade;2nd, postfinishing process is:Owf values are 3%, bath raio 1:10,40 DEG C of dipping temperature, the min of dip time 15,150 DEG C of baking temperature bakes the min of time 3;3rd, there is feasibility using collated composite fibre, in addition to heat storing and heat preserving effect, anion-generating capacity is 1800 ~ 3200/cm3, it is 4 μm 15 μm of far infrared that wavelength is launched under body temperature, with stimulating circulation, improve the functions such as indoor air quality, and easy to operate.

Description

A kind of dressing liquid of Anion FIR Functional Pigment pillow
Technical field
The invention belongs to ecological functions textile application technical field, and in particular to a kind of Anion FIR Functional Pigment The dressing liquid of pillow.
Background technology
Because textile is in a kind of human contact's time at most and the closest material, with living standards of the people Raising, health turn into the people pay close attention to mostly important topic.Therefore, many enterprises all are making great efforts to develop various different work( Can and not same-action textile, wherein Far-Infrared Health Textiles be at present both at home and abroad the function textile of popular research it One.Far-Infrared Health Textiles generally refer to a kind of fabric produced using the fuel factor and physical therapy function of far infrared Product, the health properties such as the thermal property having with it is good, stimulate circulation, enhance metabolism, dispelling fatigue, and without pair Effect, it is easy to use the features such as, demand of the people to health is met, with the good market demand and development prospect.Separately Outside, far-infrared textiles have with high content of technology, the characteristics of added value is high, and producing this product can bring certain for enterprise Benefit, can more promote the development of textile industry.What the research of this research new function type pillow was exactly carried out under this demand.
The content of the invention
Goal of the invention:It is an object of the invention to provide a kind of dressing liquid of Anion FIR Functional Pigment pillow, it is utilized The activation of negative ion powder realizes cleaning postfinishing process, promotes the development of following textile ecological dyeing.
Technical scheme:The present invention provides a kind of dressing liquid of Anion FIR Functional Pigment pillow, the nano-negative ion The component of dressing liquid includes, ultra-fine negative ion powder, nano silicon, silane coupler, surfactant, water, its weight hundred Point ratio is:20-40%:10-15%:0.5%-5%:1%-3%:Surplus.
The technical program, the ultra-fine negative ion powder is the compound of tourmaline or tourmaline and rare earth.
The technical program, the fiber is far-infrared polyester fiber and activated carbon fiber blend fibre, its blending rate For:1:0.1-0.3.
The technical program, prepared nano-negative ion dressing liquid dilutes 5-12 times, and now concentration is in 1%-5%, normal temperature Lower utilize soaks-rolling-aftertreatment technology dried, obtains the sample of nano-negative ion dressing liquid processing.
The technical program, the ultrasonic disperse at room temperature is well mixed, and pH value is 5.0-6.0, and particle diameter distribution is 50- 200nm。
It is used as optimization:The particulate footpath of negative ion far-infrared is about averagely 80-120nm, shows that particle reaches nanometer in solution Rank.It is used as optimization:Finishing agent consumption is to △ m(The difference of fiber weight before and after experiment)Influence:With nanometer finishing agent consumption Increase, the adsorbance of finishing agent is consequently increased in fiber, that is, far infrared transmissivity is accordingly improved.When finishing agent is used After owf is measured more than 3%, the change of adsorbance is basically unchanged, therefore, and finishing agent consumption is 3%, carries out subsequent experimental.It is used as optimization: Arrange influence of the temperature to △ m:With the increase of bath temperature, the adsorbance of finishing agent increases therewith, when temperature is more than 40 DEG C Afterwards, adsorptive value is held essentially constant, therefore arrangement temperature takes 40 DEG C.It is used as optimization:Influence of the bath raio to △ m:It is certain in owf values Under conditions of, the increase of bath raio means to respond the reduction of volumetric concentration, and when bath raio is smaller, finish solution can not be to fiber Fully wetting.When bath raio is more than 1:10, adsorptive value is basically unchanged, therefore bath raio takes 1:10, carry out subsequent experimental.It is used as optimization: Influence of the dip time to △ m:With the increase of dip time, the adsorbance of finishing agent increases therewith, has served as after 15min, should The change of value is not fairly obvious, therefore, and dip time takes 15min, carries out subsequent experimental.It is used as optimization:Baking temperature is to △ m's Influence:With the increase of baking temperature, the adsorbance of finishing agent increases therewith, when temperature is more than 135 DEG C, the change of the value It is smaller, therefore follow-up baking temperature selects 130 DEG C.
Compared with prior art, a kind of beneficial effect of the dressing liquid of Anion FIR Functional Pigment pillow of the invention exists In:1st, dressing liquid outward appearance light yellow clear liquid, pH5.0-6.0, particle diameter distribution 50-200nm, reaches Nano grade;2nd, it is rear whole Science and engineering skill is:Owf values are 3%, bath raio 1:10,40 DEG C of dipping temperature, the min of dip time 15,150 DEG C of baking temperature, when baking Between 3 min;3rd, there is feasibility using collated composite fibre, in addition to heat storing and heat preserving effect, anion-generating capacity is 1800 ~ 3200/cm3, it is 4 μm -15 μm of far infrared that wavelength is launched under body temperature, with stimulating circulation, improve The functions such as indoor air quality, and it is easy to operate;4th, the composite fibre of collated liquid processing has preferable compression performance And heat-insulating property.
Brief description of the drawings
Fig. 1 is that the present invention prepares nano-negative ion dressing liquid reaction equation;
Fig. 2 is that nano-negative ion dressing liquid of the present invention carries out particle diameter distribution test schematic diagram.
Embodiment
With reference to specific embodiment, the present invention is furture elucidated.
Embodiment
The dressing liquid of a kind of Anion FIR Functional Pigment pillow of the invention as depicted in figs. 1 and 2, the nanometer bear from The component of sub- dressing liquid includes, ultra-fine negative ion powder, nano silicon, silane coupler, surfactant, water, its weight Percentage is:20-40%:10-15%:0.5%-5%:1%-3%:Surplus.
It is further preferred that ultra-fine negative ion powder is the compound of tourmaline or tourmaline and rare earth;And the fiber For far-infrared polyester fiber and activated carbon fiber blend fibre, its blending rate is:1:0.1-0.3;And prepare nanometer bear from Sub- dressing liquid dilutes 5-12 times, and now concentration obtains nanometer and born using-rolling-aftertreatment technology dried is soaked under 1%-5%, normal temperature The sample of ion dressing liquid processing;And the ultrasonic disperse at room temperature is well mixed, pH value is 5.0-6.0, and particle diameter distribution is 50-200nm。
1st, the experimental section in the present invention is as follows:
1.1 experiment materials, instrument and reagent.
Experiment material:Polyester fiber, activated carbon fiber, butyl titanate, glacial acetic acid, silane coupler, dispersant etc.;
Laboratory apparatus:Padding machine (PB1), thermostat water bath(DSHL-300), baking oven(101AB-1), assay balance(Shimadzu AY220), nano particle size instrument(90plus Zeta), the warming instrument of flat-plate type fabric(YG606N)Deng;
1.2 experimental method
Nano titanic oxide sol is proportionally prepared using hydrothermal synthesis method, and according to percentage by weight(20~40%:10~ 15%:0.5%~5%:1%~3%:Surplus)Add through silane coupler modified ultra-fine anion powder, prepare nano-negative ion Dressing liquid, reaction equation is as shown in Figure 1;Then at room temperature by composite fibre wetness impregna-tion in dressing liquid, dried using-rolling-is soaked Aftertreatment technology, obtains the sample of nano-far-infrared processing.
Postfinishing process:Owf values are 3%, bath raio 1:10,40 DEG C of dipping temperature, the min of dip time 15, baking temperature 150 DEG C, bake the min of time 3.
2nd, performance test
2.1 particle diameter distribution
Particle diameter distribution test is carried out to nano-negative ion dressing liquid made from embodiment, as a result as shown in Figure 2:
Figure it is seen that the particulate footpath of anion finishing liquor is about averagely 80-120nm, show that particle reaches nanometer in solution Rank.
2.2 regains, compression performance, heat-insulating property test
Regain, compression performance, heat-insulating property test are carried out to functionalization pillow, 1 is the results are shown in Table.
Table 1
As a result the composite fibre handled by dressing liquid is shown, in conformality, fluffy sense, thickness persistence, hot wet migration energy It is all preferable, and because thermal resistance also increases therewith, the heat-insulating property of fiber is also accordingly improved.
2.3 far infrared performances
Far infrared radiation aptitude tests, the far infrared measured are carried out using Fourier's infrared tester to pillow made from embodiment Emissivity can launch the far infrared that wavelength is 4 μm -15 μm, meet state-set standard under body temperature 80% ~ 90%. Illustrate that the functionalization pillow through processing has preferable far infrared transmission performance, human body body immunity and Regenerated energy can be strengthened Power, expands capillary, improves microcirculation, enhances metabolism and blood flow.
2.4 anion emission values
Pillow made from embodiment is detected using IC-1000 test systems, anion-generating capacity 1800 ~ 3200/ cm3, illustrate that the pillow prepared has good negative ion releasing function, and negative ion concentration is set to >=2000 or 2100 (individual/cm3) it is the superlative degree, it is very pure and fresh or extremely favourable to health that its evaluation is expressed as air.
3rd, the conclusion that the present invention is drawn is as follows:(1)Dressing liquid outward appearance light yellow clear liquid, pH5.0-6.0, particle diameter distribution 50-200nm, reaches Nano grade;(2)Postfinishing process is:Owf values are 3%, bath raio 1:10,40 DEG C of dipping temperature, during dipping Between 15 min, 150 DEG C of baking temperature bakes the min of time 3;(3)The composite fibre handled through nano-negative ion finishing agent has Preferable compression performance and heat-insulating property, with higher anion concentration;(4)Had using collated composite fibre feasible Property, except outer with heat storing and heat preserving effect, also with stimulating circulation, improve the functions such as indoor air quality, and operate It is easy.
Described above is only the preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art For member, under the premise without departing from the principles of the invention, some improvement can also be made, these improvement also should be regarded as the present invention's Protection domain.

Claims (5)

1. a kind of dressing liquid of Anion FIR Functional Pigment pillow, it is characterised in that:The group of the nano-negative ion dressing liquid Dividing includes, ultra-fine negative ion powder, nano silicon, silane coupler, surfactant, water, and its percentage by weight is:20- 40%:10-15%:0.5%-5%:1%-3%:Surplus.
2. a kind of dressing liquid of Anion FIR Functional Pigment pillow according to claim 1, it is characterised in that:It is described super Thin negative ion powder is the compound of tourmaline or tourmaline and rare earth.
3. a kind of dressing liquid of Anion FIR Functional Pigment pillow according to claim 1, it is characterised in that:The fibre Tie up as far-infrared polyester fiber and activated carbon fiber blend fibre, its blending rate is:1:0.1-0.3.
4. a kind of dressing liquid of Anion FIR Functional Pigment pillow according to claim 1, it is characterised in that:It is prepared Nano-negative ion dressing liquid dilute 5-12 times, now concentration under 1%-5%, normal temperature using soaking-rolling-aftertreatment technology dried, Obtain the sample of nano-negative ion dressing liquid processing.
5. a kind of dressing liquid of Anion FIR Functional Pigment pillow according to claim 1, it is characterised in that:It is described Ultrasonic disperse is well mixed at room temperature, and pH value is 5.0-6.0, and particle diameter distribution is 50-200nm.
CN201710451377.2A 2017-06-15 2017-06-15 A kind of dressing liquid of Anion FIR Functional Pigment pillow Pending CN107099997A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107485243A (en) * 2017-09-22 2017-12-19 南通优棉濠晨纺织品有限公司 A kind of anion quilt and its manufacture method
CN108130721A (en) * 2017-12-20 2018-06-08 彭裕民 Weight reducing health care women's dress and preparation method thereof
CN108797101A (en) * 2018-07-09 2018-11-13 江苏阳光股份有限公司 A kind of preparation method of the warming dressing liquid of wool fabric
CN109736077A (en) * 2018-11-26 2019-05-10 福建省绿城环保科技有限公司 For spraying the liquor and preparation method that shine wall clothing anion function fibrous material
CN110331577A (en) * 2019-05-16 2019-10-15 苏州佰旺纺织有限公司 A kind of negative ion health fabric and its soaking agent and application
CN114108315A (en) * 2021-12-20 2022-03-01 江苏鑫缘丝绸科技有限公司 Finishing silk floss sheet and silk floss quilt prepared from same

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1730803A (en) * 2005-08-04 2006-02-08 东华大学 Nano functional textile finishing method
CN102488427A (en) * 2011-12-09 2012-06-13 水经(上海)生物科技有限公司 Anion sleeping-promoting health-care pillow core
CN104404676A (en) * 2014-11-05 2015-03-11 常熟市立丹纺织品有限公司 Polyester blended shell fabric
CN105420901A (en) * 2015-12-30 2016-03-23 无锡红豆居家服饰有限公司 Hodo fleece fabric with far infrared heating function
CN105696316A (en) * 2014-11-25 2016-06-22 江阴市长泾花园毛纺织有限公司 Preparation method of nanometer negative ion automobile interior decoration fabric
CN106149413A (en) * 2015-04-24 2016-11-23 储金中 A kind of preparation method of anion PRINTED FABRIC
CN106702726A (en) * 2017-01-17 2017-05-24 瑞投(上海)服饰科技有限公司 Winter fashion womenswear and preparation method thereof

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1730803A (en) * 2005-08-04 2006-02-08 东华大学 Nano functional textile finishing method
CN102488427A (en) * 2011-12-09 2012-06-13 水经(上海)生物科技有限公司 Anion sleeping-promoting health-care pillow core
CN104404676A (en) * 2014-11-05 2015-03-11 常熟市立丹纺织品有限公司 Polyester blended shell fabric
CN105696316A (en) * 2014-11-25 2016-06-22 江阴市长泾花园毛纺织有限公司 Preparation method of nanometer negative ion automobile interior decoration fabric
CN106149413A (en) * 2015-04-24 2016-11-23 储金中 A kind of preparation method of anion PRINTED FABRIC
CN105420901A (en) * 2015-12-30 2016-03-23 无锡红豆居家服饰有限公司 Hodo fleece fabric with far infrared heating function
CN106702726A (en) * 2017-01-17 2017-05-24 瑞投(上海)服饰科技有限公司 Winter fashion womenswear and preparation method thereof

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107485243A (en) * 2017-09-22 2017-12-19 南通优棉濠晨纺织品有限公司 A kind of anion quilt and its manufacture method
CN108130721A (en) * 2017-12-20 2018-06-08 彭裕民 Weight reducing health care women's dress and preparation method thereof
CN108130721B (en) * 2017-12-20 2020-06-16 湖北赛尚服饰集团有限公司 Slimming health-care women's dress and preparation method thereof
CN108797101A (en) * 2018-07-09 2018-11-13 江苏阳光股份有限公司 A kind of preparation method of the warming dressing liquid of wool fabric
CN109736077A (en) * 2018-11-26 2019-05-10 福建省绿城环保科技有限公司 For spraying the liquor and preparation method that shine wall clothing anion function fibrous material
CN110331577A (en) * 2019-05-16 2019-10-15 苏州佰旺纺织有限公司 A kind of negative ion health fabric and its soaking agent and application
CN114108315A (en) * 2021-12-20 2022-03-01 江苏鑫缘丝绸科技有限公司 Finishing silk floss sheet and silk floss quilt prepared from same
CN114108315B (en) * 2021-12-20 2024-03-08 江苏鑫缘丝绸科技有限公司 Finishing silk floss sheet and silk floss quilt prepared from same

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