CN100376638C - Decorative coating material and construction material - Google Patents
Decorative coating material and construction material Download PDFInfo
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- CN100376638C CN100376638C CNB2005101030575A CN200510103057A CN100376638C CN 100376638 C CN100376638 C CN 100376638C CN B2005101030575 A CNB2005101030575 A CN B2005101030575A CN 200510103057 A CN200510103057 A CN 200510103057A CN 100376638 C CN100376638 C CN 100376638C
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Abstract
The object of the invention is to impart bright appearance to a coating material containing transparent aggregates such as feldspar, white marble, or glass beads in a high ratio, to enhance its texture. This decorative coating material contains a binder (A), grainy transparent aggregates (B) having an average particle diameter of 0.05 to 5 mm, flaky transparent aggregates (C) having an average particle diameter of 0.1 to 8 mm, and a pearl gloss pigment (D) having an average particle diameter of 1 to 600 [mu]m as essential components, wherein 100 pts.wt. of the solid content of the binder (A) is mixed with 100 to 4,000 pts.wt. of the particulate transparent aggregates (B), 1 to 500 pts.wt. of the flaky transparent aggregates (C), and 0.1 to 200 pts.wt. of the pearl gloss pigment (D). It is desirable that the weight ratio of the flaky transparent aggregates (C) : the pearl gloss pigment (D) is 1:0.05 to 1:5.
Description
Technical field
The present invention relates to novel decorative painting material and ornamental building materials.
Background technology
In the past, the material as the inside and outside wall of decorative constructure etc. uses the coating material that has cooperated natural aggregate or artificial aggregate in tackiness agents such as synthetic resin emulsion mostly.For example, in the fair 2-40702 communique of spy (patent documentation 1), disclose by the tackiness agent that forms the water white transparency tunicle and painted aggregate and transparent aggregate coating material combination, that can form the decorative pattern of lithotome style.The coating material of this patent documentation 1 is a purpose with the pattern effect of deepening to be shown by painted aggregate, has cooperated transparent aggregates such as feldspar, Mirabilitum crystallina, granulated glass sphere complementaryly.
To this, open the coating material of the transparent aggregate that discloses the feldspar that contains more amount, Mirabilitum crystallina, granulated glass sphere etc. in the 2003-231862 communique (patent documentation 2) the spy.In this patent documentation 2, in order to improve formed transparent feel of filming and texture, it is 20～75 weight % that the containing ratio of transparent aggregate in the solids component of coating material is set at.Yet, by filming that such coating material obtains,, be difficult to obtain the finished product effect of briliancy sense though can give to a certain degree transparent feel, from the texture of integral body, also have room for improvement.
As the method for in containing the coating material of aggregate, giving the briliancy sense, be well known that in coating material, to cooperate mica.For example, open the decoration coating material that discloses the painted aggregate, size 150～3.5 purpose micas and the synthetic resin emulsion that contain about particle diameter 1～200 μ m in the 2001-3002 communique (patent documentation 3) the spy.In this patent documentation 3, put down in writing by the effect that cooperates with mica and given the briliancy sense, can form decorative pattern with thick and heavy sense close with lithotome.
[patent documentation 1] special fair 2-40702 communique
[patent documentation 2] spy opens the 2003-231862 communique
[patent documentation 3] spy opens the 2001-3002 communique
Summary of the invention
In the coating material that contains transparent aggregates such as a high proportion of feldspar, Mirabilitum crystallina, granulated glass sphere,, can expect to improve the briliancy sense by as above-mentioned patent documentation 3, having cooperated mica.Yet in such coating material, even in fact cooperated mica to a certain degree, mica has visually been buried in formed filming, and is difficult to obtain by cooperating mica to improve the effect of briliancy sense.
The present invention proposes in view of the above problems.The objective of the invention is to give the briliancy sense, and improve its texture the coating material that contains transparent aggregates such as a high proportion of feldspar, Mirabilitum crystallina, granulated glass sphere.
In order to achieve the above object, the inventor etc. have carried out studying meticulously, the result expects: with the granular transparent aggregate of tackiness agent, median size 0.05～5mm, add specific aggregate pigment etc. and be decorative painting material that must composition, and then the ornamental building materials that obtain by this decorative painting material, thereby finished the present invention.
That is, the present invention has following feature:
1. decorative painting material, it is characterized in that, with tackiness agent (A), median size is that the pearly pigment (D) of granular transparent aggregate (B), the transparent aggregate of median size 0.1～8mm flakey (C) and median size 1～600 μ m of 0.05～5mm is a neccessary composition, and, for solids component 100 weight parts of described tackiness agent (A), contain described granular transparent aggregate (B) 100～4000 weight parts, the transparent aggregate of described flakey (C) 1～500 weight part and described pearly pigment (D) 0.1～200 weight part.
2. the decorative painting material described in the claim 1 is characterized in that, the weight ratio of transparent aggregate of described flakey (C) and described pearly pigment (D) is 1: 0.05～1: 5.
3. decorative painting material, it is characterized in that, with tackiness agent (A), median size is that granular transparent aggregate (B) and the median size of 0.05～5mm is that 0.1～8mm flakey interference of light aggregate (E) is a neccessary composition, and, for solids component 100 weight parts of described tackiness agent (A), contain described granular transparent aggregate (B) 100～4000 weight parts and described flakey interference of light aggregate (E) 1～500 weight part.
4. ornamental building materials is characterized in that, are by the decorative painting material forming slabbing described in the claim 1～3 any one is obtained.
5. coating process is characterized in that, any one described decorative painting material that base material is applied in above-mentioned 1～3 carries out trowelling processing.
The present invention given contain a high proportion of transparent aggregate the decorative painting material with the briliancy sense, can improve its texture.Decorative painting material of the present invention is a kind of trowelling material processed that is particularly suitable for.Also have, decorative painting material of the present invention can be configured as sheet in advance and use as ornamental building materials, just can bring into play more stable film performance with these ornamental building materials.
Embodiment
Illustrate below and implement best mode of the present invention.
As the tackiness agent in the coating material of the present invention (A) (hereinafter referred to as " composition (A) "), can use various tackiness agents such as water soluble resin, water-dispersed resin, the solvable type resin of solvent, no-solvent type resin, non-aqueous dispersion type resin, powdex, perhaps use by they compound tackiness agents etc.These also can be the materials with activity of cross-linking reaction.Also having, for the not special restriction of the form of composition (A), can be any of single-liquid type, two-pack type.What be particularly suitable for the present invention's use is water soluble resin and/or water-dispersed resin.As operable resin kind, can exemplify out Mierocrystalline cellulose, polyvinyl alcohol, ethenoid resin, vinyl acetate resin, vibrin, Synolac, vinyl chloride resin, Resins, epoxy, silicone resin, acrylic resin, carbamate resins, acrylic acid or the like silicone resin, fluoro-resin etc., perhaps their compound system etc.
The second-order transition temperature of composition (A) can suitably be set, and is generally about-50～50 ℃.When using water-dispersed resin as composition (A), if second-order transition temperature is set in-50～30 ℃ (and then-40～10 ℃), just can cut down the combined amount of film coalescence aid etc., can obtain being suitable for the coating material of the low VOC (VOC) of interior trim processing usefulness.
Granular transparent aggregate (B) in the coating material of the present invention (hereinafter referred to as " composition (B) ") is to give the filming with the composition of transparent feel of formation.Because in the present invention, such composition (B) contains with higher proportion, can show main to be the pattern effect with transparent feel of keynote in vain.As composition (B),, just have no particular limits so long as can bring into play the material of such effect.At this, the composition among the present invention (B) is to have difform material with composition described later (C).
As the composition among the present invention (B), with light transmission rate 3% or the material of more (preferred 3～50%, more preferably 10～30%) be advisable.By having used such composition (B), just obtain the transparent feel and the texture of appropriateness in the filming of formation easily.Be meant the value of the whole light penetrations that obtain with turbidometer at this said light transmission rate.This mensuration is that the sample of composition (B) is filled in the transparent glass pond that inner thickness is 5mm, after slowly water being filled into then, by vibration the bubble removal in the pond is carried out again.But as sample, selecting particle diameter for use is the material of 0.5～1.0mm.
As the object lesson of such composition (B), can exemplify out feldspar, silica sand, silica, Mirabilitum crystallina, granulated glass sphere etc.Wherein, Mirabilitum crystallina etc. is particularly suitable for the present invention.
The median size of composition (B) is generally 0.05～5mm, preferred 0.1～2mm.When composition (B) was too small, filming was easy to generate crackle; When composition (B) was excessive, the concavo-convex change on surface is big, and was unfavorable for pattern effect and texture.As composition (B),, be that the material of 0.3～1.5mm is exactly suitable as long as use particle diameter to surpass 0.2mm and be less than or equal to 2mm, median size from pattern effect.At this, the median size of composition (B) is by adopting JIS Z8801-1: calculate the value that the mean value of its weight distribution obtains after the metallic sieve of 2000 defineds sieves.
With respect to solids component 100 weight parts of composition (A), composition (B) mixes with the ratio of 100～4000 weight parts, preferred 2002000 weight parts usually.If composition (B), just can be given filming with the transparent feel of appropriateness of formation by such blending ratio mixing.When if composition (B) is less than 100 weight parts, just be difficult to obtain transparent feel and the texture brought by composition (B).And composition (B) is during more than 4000 weight parts, and the ratio of relative tackiness agent tails off, form film in just be easy to generate bad situations such as composition (B) comes off.
The transparent aggregate of flakey among the present invention (C) (hereinafter referred to as " composition (C) ") is a kind ofly film with the neccessary composition of briliancy sense in order to give forming.Such composition (C) so long as on lepidiod thickness direction, have the transparency material get final product.At this, flakey of the present invention is meant the flat pattern of the minor axis of 5 times or more times (preferred 10 times or more times) with thickness.Minor axis is generally 1: 1 with the ratio of major diameter～about 1: 5.
Concrete composition (C) can exemplify out white mica, synthetic mica, silicon oxide fragment, glass fragment, resin chips etc., wherein is preferred with the white mica.
The median size of composition (C) is generally 0.1～8mm, preferred 0.5～5mm.If the median size of composition (C) in this scope, suits to briliancy sense, the texture of filming that forms.As composition (C), especially preferable particle size is the material of 1～5mm in 0.9mm～8mm, median size.At this, the median size of composition (C) be with mentioned component (B) similarly by adopting JIS Z8801-1: calculate the value that the mean value of its weight distribution obtains after the metallic sieve of 2000 defineds sieves.
The mean thickness of composition (C) is generally 1～500 μ m, preferred 5～200 μ m.Mean thickness described here is to try to achieve by the mean value of for example calculating the value of measuring with milscale.
With respect to solids component 100 weight parts of composition (A), the blending ratio of composition (C) is 1～500 weight part normally, preferred 5～100 weight parts.When composition (C) was less than 1 weight part, filming of formation can not obtain sufficient briliancy sense.When composition (C) than 500 weight parts more for a long time, the easy whole texture of damage.
In coating material of the present invention,, can fully manifest briliancy sense by cooperating mentioned component (C) to produce by containing pearly pigment (D) (hereinafter referred to as " composition (D) ").The pearly pigment that uses among the present invention be meant high refractive index flakey as thin as a wafer (mean thickness be generally be equal to or greater than 0.05 μ m and less than 1 μ m), make the incident light multipath reflection and present nacreous material.Concrete composition (D) can use the material of be covered metal or metal oxide on matrixes such as white mica, synthetic mica, silica chips or glass fragment.Wherein, contained metal in metal or metal oxide can be enumerated titanium, iron, aluminium, zinc, tin, zirconium, cobalt, nickel, gold and silver etc.At this, the mean thickness of composition (D) can be tried to achieve by electron microscope observation.
The present invention is also indeterminate by the mechanism of action that gradation composition (D) tells on, and following consideration is roughly arranged.
Generally, in the coating material that contains painted aggregate etc., during gradation composition (C), reveal the briliancy sense by the luminous reflectance effect of composition (C).Yet, when in the coating material that contains a high proportion of composition (B), having cooperated composition (C), because the light transmission of composition (B) has reduced the luminous reflectance effect of composition (C).The result is that visually composition (C) has been buried, and can not be improved the effect of briliancy sense fully.
Relative therewith, except gradation composition (B), composition (C), also cooperated composition (D) among the present invention.Consider that in the present invention this composition (D) becomes the material of having strengthened composition (C) in table, the effect of vicinity, the inside performance luminous reflectance of composition (C).Especially, add man-hour carrying out trowelling, composition (C) and composition (D) are arranged along coated surface and are become easily, make that effect of the present invention is remarkable.
The median size of composition (D) the preferably median size than composition (C) is little, is generally 1～600 μ m, preferred 1～180 μ m, more preferably 5～80 μ m.If the scope of the median size sd so of composition (D) is filmed for the briliancy sense for giving forming, suit.At this, the median size of composition (D) is the value of 50% particle diameter measured by the centrifugal type particle size distribution device.
With respect to solids component 100 weight parts of composition (A), the blending ratio of composition (D) is 0.1～200 weight part normally, preferred 0.5～100 weight part, more preferably 1～50 weight part.And then the present invention wishes that composition (C) and composition (D) are that 1: 0.05～1: 5 (preferred 1: 0.1～1: 2, more preferably 1: 0.2～1: 1.5) merges use with weight ratio.By such composition (D) that mixed, can obtain sufficient briliancy sense.When composition (D) is very few, can only obtain lacking filming of briliancy sense; And composition (D) may damage the texture of being brought by composition (B) and composition (C) too much the time.
Among the present invention, replace mentioned component (C), composition (D), also can give the filming of formation with the briliancy sense by the flakey interference of light aggregate (E) (hereinafter referred to as " composition (E) ") that contains median size 0.1～8mm.As such composition (E), so long as the flakey shape, have the interference of light, just can use various materials, for example can use the different resin lamination of specific refractory power become 2 layers or more multi-layered diaphragm, by embossing processing etc. form micro concavo-convex diaphragm, fixed the diaphragm of hyaloplasmic spheres such as glass sphere or on these, implemented material of metal evaporation etc.Such composition can be the material that has the interference of light and the transparency concurrently.At this, mentioned component (C) is not the material with interference of light usually, and this point is and the different place of composition (E).
The median size of composition (E) is generally 0.1～8mm, preferred 0.2～3mm.If the median size of composition (E) in this scope, suits to briliancy sense, the texture of filming that forms.At this, the median size of composition (E) be with mentioned component (B) similarly by adopting JIS Z8801-1: calculate the value that the mean value of its weight distribution obtains after the metallic sieve of 2000 defineds sieves.
The mean thickness of composition (E) is generally 1～500 μ m, preferred 5～200 μ m.Mean thickness described here is to try to achieve by the mean value of for example calculating the value of measuring with milscale.
With respect to solids component 100 weight parts of composition (A), the blending ratio of composition (E) is 1～500 weight part normally, preferred 5～100 weight parts.When composition (E) was less than 1 weight part, filming of formation can not obtain sufficient briliancy sense; And composition (E) is during more than 500 weight parts, easily the whole texture of damage.
When in coating material of the present invention, having used such composition (E), as required,, also can improve the briliancy sense of filming, texture of formation etc. by using any in mentioned component * (C), the composition (D) or both being merged use.
Coating material of the present invention can also can become phase-splitting to mix by mentioned component is come uniform mixing manufacturing with known method as required with operable other in common coating material.As such composition, can exemplify out tinting pigment, filler pigment, tackifier, film coalescence aid, leveling agent, softening agent, frostproofer, pH adjustment agent, thinner, sanitas, mould inhibitor, anti-algae agent, antiseptic-germicide, dispersion agent, defoamer, UV light absorber, oxidation inhibitor, photostabilizer, fiber, catalyzer, linking agent etc.
Also have,, also can mix with the aggregate outside mentioned component (B), composition (C), the composition (E) as long as in the scope of not damaging effect of the present invention.As such aggregate, can use artificial aggregates such as the natural aggregate such as crushed material of for example lithotome, lithotome and painted aggregate, in addition, aluminum oxide fragment, shell sheet, tinsel, sheet rubber, plastic sheet, wood chip etc. or be coated with material of look etc. on these surface.By having cooperated such aggregate, just can adjust and form the form and aspect film, texture etc.Also has the pattern effect that also can have been strengthened.Aggregate described herein is normally opaque, neither possess the material of the interference of light.
The use level of such aggregate is preferably lacked than the total weight of composition (B) and composition (C) (or composition (B) and composition (E)), and specifically, getting this, to add up to weight be 1 o'clock, and the ratio of aggregate is wished 0.5 or still less (preferably 0.2 or still less).
Decorative painting material of the present invention mainly is that the surface decoration material that can be used as buildings and civil structure thing etc. uses.The base material that can be suitable for can exemplify out plasterboard, glued board, concrete, mortar, ceramic tile, mix fibre cement plate, cement calcium silicate board, slag cement pearlite board, asbestos cement plate, ALC plate, wallboard, extrusion molding plate, steel plate, plastic plate etc.The surface treatment (for example, cover material, surfacing, stopping composition, putty etc.) of some can have been implemented in the surface of these base materials, also can be to have formed material of filming or the material that has pasted wallpaper etc.When carrying out surface treatment such as cover material, preferably the form and aspect of cover material are set for and decorative painting material look altogether.
As the coating process of coating material of the present invention, can adopt known method, for example can be trowelling, spraying, roller coat, brushing etc.
Wherein, the present invention is so that method for processing serves as preferred on the face being coated with trowel.By such method, with trowel when being coated with face and smoothening, mentioned component (C), composition (D), composition (E) etc. are arranged along coated surface and are become easy, just can bring into play effect of the present invention to greatest extent.As trowel, can use for example metal trowel, wooden trowel etc.At this, coating material is being coated to when (joining and being coated with) on the base material, use trowel to be fine certainly, but also can use other method, for example spraying, roller coat etc.
The not special restriction of coating amount during for application can suitably be set, usually with 0.5～8kg/m
2(preferred 1～5kg/m
2) about be advisable.
When application,, can appropriateness adjust the viscosity of coating material by dilutions such as waters.Dilution ratio is generally about 0～10 weight %.Solids component during application is generally about 60～90 weight %.
The application of coating material of the present invention and drying get final product under normal temperature (about 5～40 ℃) usually.After the application, also can be coated with face and form various ridge designs with processing such as roller, trowel, hairbrush, comb, bamboo clappers.When carrying out drying at normal temperatures, coating after drying 24 hours or time of drying more of a specified duration to be arranged on usually, just cured coating film can be formed.At this, the drying of coating material also can at high temperature be carried out as required.
With coating material of the present invention form film after, also can be as required varnish coating and hydrophobizing agent etc. again.Wherein, can exemplify out acrylic resin class coating, carbamate resins class coating, epoxy resin coating, acrylic acid or the like silicone resin class coating, fluorine type resin coating etc. as varnish colour.Such varnish colour also can be adjusted bright-coloured degree by cooperating flatting agent.Also have, as long as do not hinder effect of the present invention, also can be painted.As hydrophobizing agent, can use with alkoxysilane compound containing trialkylsilyl group in molecular structure and silicone resin etc. to be material of main component etc.
Method as applying such varnish colour and hydrophobizing agent etc. can adopt known method, for example, and spraying, roller coat, brushing etc.
The present invention also can be configured as sheet to above-mentioned decorative painting material in advance.Is decorative painting material forming of the present invention that flaky method can adopt known method, for example can use (i) that the decorative painting material is coated in the method on the supporter and (ii) the decorative painting material is poured into method of curing and demolding in the type frame etc.Building material surface after shaping also can apply varnish colour and hydrophobizing agent etc. as required.
As the supporter in the aforesaid method (i), can exemplify out weave cotton cloth, non-woven fabrics, ceramic paper, synthetic paper, woven fiber glass, screen cloth, plasterboard, glued board, slabstone, metal sheet etc.By having used such supporter, can fully guarantee the intensity of building materials.When on such supporter, applying the decorative painting material, can use for example spray gun, flow coating machine, roller coating machine etc.
As above-mentioned template in (ii), can use the template of making, or lay the template etc. of release paper by for example silicone resin, carbamate resins etc.When being the surface, just can on building material surface, give desired ridge design by the shape of adjusting the template inboard with the template.When being the building materials inner face,, can also improve the adhesive property of building materials if on this inner face, formed concavo-convexly with the template.
The method that in the above-mentioned method (ii), also can adopt spraying, smear, replacement such as reciprocating type, coating machine pours into.Also have, also can be the supporter lamination of passing the imperial examinations at the provincial level out at (i).When solidifying, also can implement heat treated.
If above so ornamental building materials are disposed with sheet-like formed thing when circulating, constructing after the working-yard of it being moved into buildings and civil structure thing etc. gets final product on various base materials again.When ornamental building materials are constructed, can be attached to it on the base material with binding agent, tackiness agent, adhesive tape, nail, drawing pin etc.In addition, also can fix with safety pin, fastener, track etc.In the construction of ornamental building materials, the problem such as disperse of the material due to when for example not having by spraying, the operability excellence, and since use be in advance factory be coated with membranization material, therefore film management easily, the film performance that can play stably.Thickness for ornamental building materials has no particular limits, and is generally about 0.5～8mm.
Embodiment
Come clearer and more definite feature of the present invention by the following embodiment that illustrates.
(embodiment 1)
Transparent aggregate 1, the 10 weight part pearly pigments of granular transparent aggregate 2, the 20 weight part flakeys of granular transparent aggregate 1,700 weight parts of the water-dispersed resin of 200 weight parts (solids component 100 weight parts) and 700 weight parts 1,400 weight parts waters, 10 weight part film coalescence aid, 5 weight part tackifier, 5 weight part defoamers are mixed, evenly stir by usual method and make coating material 1.
On the slabstone of 450mm * 300mm, with 0.3kg/m
2The basecoat material of coating amount application white, after dry 4 hours, the coating material 1 usefulness trowel that obtains with aforesaid method by 2kg/m
2The coating amount application, dry 48 hours.At this, the coating of coating material and drying are carried out under standard state (23 ℃ of temperature, relative humidity 50%) entirely.
The outward appearance of the test body that affirmation is obtained by above method, the result is that its finished product is a white tone, transparent feel and briliancy sense are all good.
The raw material that uses in the manufacturing of coating material is as follows.
Water-dispersed resin: acrylic resin latex (18 ℃ of solids component 50%, second-order transition temperatures)
Granular transparent aggregate 1: Mirabilitum crystallina (median size 0.3mm, light transmission rate 16%)
Granular transparent aggregate 2: Mirabilitum crystallina (median size 0.8mm, light transmission rate 16%)
The transparent aggregate 1 of flakey: white mica (median size 2mm, mean thickness 40 μ m)
The transparent aggregate 2 of flakey: white mica (median size 4mm, mean thickness 60 μ m)
Pearly pigment 1: titanium oxide lining mica (median size 30 μ m)
Pearly pigment 2: titanium oxide lining mica (median size 60 μ m)
Flakey interference of light aggregate: interference of light diaphragm (median size 0.5mm, mean thickness 50 μ m)
Opaque aggregate 1: painted silica sand (orange, median size 15 μ m)
Opaque aggregate 2: shell sheet (median size 3mm)
Film coalescence aid: 2,2,4-trimethylammonium-1,3-pentanediol mono isobutyrate
Tackifier: Natvosol powder
Defoamer: silicone defoamer (solids component 50 weight %)
Table 1
| Coating material 1 | Coating material 2 | Coating material 3 | Coating material 4 | Coating material 5 | Coating material 6 | Coating material 7 | Coating material 8 | Coating material 9 | Coating material 10 | Coating material 11 | Coating material 12 | |
| Water-dispersed resin | 200 | 200 | 200 | 200 | 200 | 200 | 200 | 200 | 200 | 200 | 200 | 200 |
| Granular transparent aggregate 1 | 700 | 700 | 700 | 700 | 700 | 700 | 700 | 700 | 700 | 700 | 700 | 700 |
| Granular transparent aggregate 2 | 700 | 700 | 700 | 700 | 700 | 700 | 700 | 700 | 700 | 700 | 700 | 700 |
| The transparent aggregate 1 of flakey | 20 | 10 | - | 80 | 20 | 20 | 22 | 22 | 22 | - | 15 | 20 |
| The transparent aggregate 2 of flakey | - | - | 20 | - | - | - | - | - | - | - | - | - |
| Pearly pigment 1 | 10 | 5 | - | 40 | 10 | 10 | 22 | 115 | 1 | - | 5 | - |
| Pearly pigment 2 | - | - | 10 | - | - | - | - | - | - | - | - | - |
| Flakey interference of light aggregate | - | - | - | - | - | - | - | - | - | 20 | 8 | - |
| Opaque aggregate 1 | - | - | - | - | 40 | - | 40 | 40 | 40 | 40 | 40 | - |
| Opaque aggregate 2 | - | - | - | - | - | 80 | - | - | - | - | - | - |
| Water | 400 | 400 | 400 | 400 | 400 | 400 | 400 | 400 | 400 | 400 | 400 | 400 |
| Film coalescence aid | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 | 10 |
| Tackifier | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 |
| Defoamer | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 | 5 |
Numeral in the table is a weight part
(embodiment 2～4)
Press the cooperation shown in the table 1 and make coating material 2～4, test with method similarly to Example 1.The result has obtained filming of white tone, and its transparent feel and briliancy sense are all good.
(embodiment 5)
Press the cooperation shown in the table 1 and make coating material 5, test with method similarly to Example 1.The result has obtained with the filming of some red white tones, and its transparent feel and briliancy sense are all good.
(embodiment 6)
Press the cooperation shown in the table 1 and make coating material 6, test with method similarly to Example 1.The result has obtained filming of white tone, and its transparent feel and briliancy sense are all good.And then the shell sheet has been given the aesthetic of strengthening.
(embodiment 7)
Press the cooperation shown in the table 1 and make coating material 7, test with method similarly to Example 1.The result has obtained with the filming of some red white tones, and its transparent feel and briliancy sense are all good.
(embodiment 8)
Press the cooperation shown in the table 1 and make coating material 8, test with method similarly to Example 1.The result has obtained with the filming of some red white tones, although transparent feel and briliancy sense are arranged, the texture of outward appearance is poor slightly.
(embodiment 9)
Press the cooperation shown in the table 1 and make coating material 9, test with method similarly to Example 1.The result has obtained with the filming of some red white tones, although transparent feel and briliancy sense are arranged, the briliancy sense is abundant slightly inadequately.
(embodiment 10)
Press the cooperation shown in the table 1 and make coating material 10, test with method similarly to Example 1.The result has obtained with the filming of some red white tones, and its transparent feel and briliancy sense are all good.
(embodiment 11)
Press the cooperation shown in the table 1 and make coating material 11, test with method similarly to Example 1.The result has obtained with the filming of some red white tones, and its transparent feel and briliancy sense are all good.
(comparative example 1)
Press the cooperation shown in the table 1 and make coating material 12, test with method similarly to Example 1.The result is that comparative example 1 can not obtain the such finished product outward appearance of the foregoing description.
(embodiment 12)
In the template of having smeared releasing agent (vertical 300mm * horizontal 300mm * dark 2mm), pour into the coating material 1 of embodiment 1, make its cunning that flattens with trowel.Through 48 hours curing and demolding of 23 ℃, obtain sheet-like formed thing 1.The outward appearance of the shaping thing that obtains with aforesaid method is a white tone, and its transparent feel and briliancy sense are all good.Also have, on the wall on plasterboard basis, stick several pieces of sheet-like formed things 1, obtained stable ornamental wall with the acrylic resin tackiness agent.
Claims (4)
1. decorative painting material, it is characterized in that, with tackiness agent (A), median size is that the pearly pigment (D) of granular transparent aggregate (B), the transparent aggregate of median size 0.1～8mm flakey (C) and median size 1～600 μ m of 0.05～5mm is a neccessary composition, and, for solids component 100 weight parts of described tackiness agent (A), contain described granular transparent aggregate (B) 100～4000 weight parts, the transparent aggregate of described flakey (C) 1～500 weight part and described pearly pigment (D) 0.1～200 weight part.
2. the decorative painting material described in the claim 1 is characterized in that, the weight ratio of transparent aggregate of described flakey (C) and described pearly pigment (D) is 1: 0.05～1: 5.
3. decorative painting material, it is characterized in that, with tackiness agent (A), median size is that granular transparent aggregate (B) and the median size of 0.05～5mm is that 0.1～8mm flakey interference of light aggregate (E) is a neccessary composition, and, for solids component 100 weight parts of described tackiness agent (A), contain described granular transparent aggregate (B) 100～4000 weight parts and described flakey interference of light aggregate (E) 1～500 weight part.
4. ornamental building materials is characterized in that, are by the decorative painting material forming slabbing described in the claim 1～3 any one is obtained.
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| JP2004311450 | 2004-10-26 | ||
| JP2004311450 | 2004-10-26 | ||
| JP2005049848 | 2005-02-25 |
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| CN1766013A CN1766013A (en) | 2006-05-03 |
| CN100376638C true CN100376638C (en) | 2008-03-26 |
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| CNB2005101030575A Active CN100376638C (en) | 2004-10-26 | 2005-09-19 | Decorative coating material and construction material |
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| CN105504627B (en) * | 2016-01-12 | 2017-10-13 | 陈礼根 | Raw material and its manufacture method for preparing three-dimensional pattern pearly-lustre decorative panel |
| CN107099198B (en) * | 2016-02-22 | 2019-07-26 | 上海三银涂料科技股份有限公司 | Criticize scratch-type wall of sand texture coating and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1277230A (en) * | 1999-06-10 | 2000-12-20 | 菊水化学工业株式会社 | Decorative material composition |
| CN1279262A (en) * | 1999-06-30 | 2001-01-10 | 菊水化学工业株式会社 | Multiple coating materials for forming granite patterns |
| JP2003231862A (en) * | 2002-02-08 | 2003-08-19 | Kikusui Chemical Industries Co Ltd | Aggregate-containing coating material and metal panel coated with the same |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1277230A (en) * | 1999-06-10 | 2000-12-20 | 菊水化学工业株式会社 | Decorative material composition |
| CN1279262A (en) * | 1999-06-30 | 2001-01-10 | 菊水化学工业株式会社 | Multiple coating materials for forming granite patterns |
| JP2003231862A (en) * | 2002-02-08 | 2003-08-19 | Kikusui Chemical Industries Co Ltd | Aggregate-containing coating material and metal panel coated with the same |
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