CN109504553A - 一种汽车用玻璃清洁剂及其制备方法 - Google Patents
一种汽车用玻璃清洁剂及其制备方法 Download PDFInfo
- Publication number
- CN109504553A CN109504553A CN201811621304.4A CN201811621304A CN109504553A CN 109504553 A CN109504553 A CN 109504553A CN 201811621304 A CN201811621304 A CN 201811621304A CN 109504553 A CN109504553 A CN 109504553A
- Authority
- CN
- China
- Prior art keywords
- automotive glass
- detergent
- glass
- glass detergent
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000011521 glass Substances 0.000 title claims abstract description 122
- 239000003599 detergent Substances 0.000 title claims abstract description 81
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 24
- 239000002994 raw material Substances 0.000 claims abstract description 23
- 230000008014 freezing Effects 0.000 claims abstract description 14
- 238000007710 freezing Methods 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 14
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 12
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 11
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 10
- 238000005260 corrosion Methods 0.000 claims abstract description 10
- 230000007797 corrosion Effects 0.000 claims abstract description 10
- 239000003755 preservative agent Substances 0.000 claims abstract description 10
- 230000002335 preservative effect Effects 0.000 claims abstract description 10
- -1 corrosion inhibiter Substances 0.000 claims abstract description 8
- 239000000975 dye Substances 0.000 claims abstract description 7
- 239000003205 fragrance Substances 0.000 claims abstract description 7
- 239000003002 pH adjusting agent Substances 0.000 claims abstract description 7
- 239000007788 liquid Substances 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims description 15
- 238000003756 stirring Methods 0.000 claims description 12
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 8
- 150000002191 fatty alcohols Chemical class 0.000 claims description 5
- 238000005498 polishing Methods 0.000 claims description 5
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 5
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- 235000013877 carbamide Nutrition 0.000 claims description 4
- 229930182470 glycoside Natural products 0.000 claims description 4
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 claims description 4
- 239000004094 surface-active agent Substances 0.000 claims description 4
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001450 anions Chemical class 0.000 claims description 3
- 239000003795 chemical substances by application Substances 0.000 claims description 3
- 238000001914 filtration Methods 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 239000000243 solution Substances 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 239000004711 α-olefin Substances 0.000 claims description 3
- DNIAPMSPPWPWGF-GSVOUGTGSA-N (R)-(-)-Propylene glycol Chemical compound C[C@@H](O)CO DNIAPMSPPWPWGF-GSVOUGTGSA-N 0.000 claims description 2
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims description 2
- MFKRHJVUCZRDTF-UHFFFAOYSA-N 3-methoxy-3-methylbutan-1-ol Chemical compound COC(C)(C)CCO MFKRHJVUCZRDTF-UHFFFAOYSA-N 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 2
- QRUDEWIWKLJBPS-UHFFFAOYSA-N benzotriazole Chemical compound C1=CC=C2N[N][N]C2=C1 QRUDEWIWKLJBPS-UHFFFAOYSA-N 0.000 claims description 2
- 239000012964 benzotriazole Substances 0.000 claims description 2
- 229910021538 borax Inorganic materials 0.000 claims description 2
- 150000001732 carboxylic acid derivatives Chemical class 0.000 claims description 2
- 235000019441 ethanol Nutrition 0.000 claims description 2
- 108700019599 monomethylolglycine Proteins 0.000 claims description 2
- 235000010241 potassium sorbate Nutrition 0.000 claims description 2
- 239000004302 potassium sorbate Substances 0.000 claims description 2
- 229940069338 potassium sorbate Drugs 0.000 claims description 2
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 2
- 235000010234 sodium benzoate Nutrition 0.000 claims description 2
- 239000004299 sodium benzoate Substances 0.000 claims description 2
- 229940101011 sodium hydroxymethylglycinate Drugs 0.000 claims description 2
- 235000010288 sodium nitrite Nutrition 0.000 claims description 2
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 2
- 239000004328 sodium tetraborate Substances 0.000 claims description 2
- YTPLMLYBLZKORZ-UHFFFAOYSA-N Thiophene Chemical compound C=1C=CSC=1 YTPLMLYBLZKORZ-UHFFFAOYSA-N 0.000 claims 2
- DDSZZGMTDFBTAT-UHFFFAOYSA-N 2-methyl-2,3-dihydro-1,3-oxazole Chemical compound CC1NC=CO1 DDSZZGMTDFBTAT-UHFFFAOYSA-N 0.000 claims 1
- WJIUUKVQXQFABS-RGMNGODLSA-N C(C(=O)O)(=O)O.C(CC)N[C@@H](CCO)C(=O)O Chemical compound C(C(=O)O)(=O)O.C(CC)N[C@@H](CCO)C(=O)O WJIUUKVQXQFABS-RGMNGODLSA-N 0.000 claims 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 claims 1
- 150000004985 diamines Chemical class 0.000 claims 1
- 229930192474 thiophene Natural products 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 13
- 238000004140 cleaning Methods 0.000 abstract description 5
- 238000000034 method Methods 0.000 abstract description 4
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- 230000000977 initiatory effect Effects 0.000 abstract 1
- 238000012360 testing method Methods 0.000 description 25
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 10
- 229910001335 Galvanized steel Inorganic materials 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- 229910052802 copper Inorganic materials 0.000 description 10
- 239000010949 copper Substances 0.000 description 10
- 230000003628 erosive effect Effects 0.000 description 10
- 239000008397 galvanized steel Substances 0.000 description 10
- 230000009972 noncorrosive effect Effects 0.000 description 10
- 229920001800 Shellac Polymers 0.000 description 5
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 5
- 239000004208 shellac Substances 0.000 description 5
- 229940113147 shellac Drugs 0.000 description 5
- 235000013874 shellac Nutrition 0.000 description 5
- WHUUTDBJXJRKMK-VKHMYHEASA-N L-glutamic acid Chemical compound OC(=O)[C@@H](N)CCC(O)=O WHUUTDBJXJRKMK-VKHMYHEASA-N 0.000 description 4
- 229960002989 glutamic acid Drugs 0.000 description 4
- WHUUTDBJXJRKMK-UHFFFAOYSA-N Glutamic acid Natural products OC(=O)C(N)CCC(O)=O WHUUTDBJXJRKMK-UHFFFAOYSA-N 0.000 description 3
- WDJHALXBUFZDSR-UHFFFAOYSA-N acetoacetic acid Chemical compound CC(=O)CC(O)=O WDJHALXBUFZDSR-UHFFFAOYSA-N 0.000 description 3
- 235000013922 glutamic acid Nutrition 0.000 description 3
- 239000004220 glutamic acid Substances 0.000 description 3
- 108010053481 Antifreeze Proteins Proteins 0.000 description 2
- 230000002528 anti-freeze Effects 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- RBTBFTRPCNLSDE-UHFFFAOYSA-N 3,7-bis(dimethylamino)phenothiazin-5-ium Chemical compound C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 RBTBFTRPCNLSDE-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000207199 Citrus Species 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 150000001413 amino acids Chemical group 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 235000020971 citrus fruits Nutrition 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 235000013305 food Nutrition 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 239000000383 hazardous chemical Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 229940087305 limonene Drugs 0.000 description 1
- 235000001510 limonene Nutrition 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 229960000907 methylthioninium chloride Drugs 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N n-Butanol Substances CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 235000013599 spices Nutrition 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 238000009602 toxicology test Methods 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/83—Mixtures of non-ionic with anionic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/04—Water-soluble compounds
- C11D3/046—Salts
- C11D3/048—Nitrates or nitrites
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/18—Hydrocarbons
- C11D3/185—Hydrocarbons cyclic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2041—Dihydric alcohols
- C11D3/2044—Dihydric alcohols linear
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2068—Ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/28—Heterocyclic compounds containing nitrogen in the ring
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/30—Amines; Substituted amines ; Quaternized amines
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/32—Amides; Substituted amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/40—Dyes ; Pigments
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/008—Polymeric surface-active agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/14—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aliphatic hydrocarbons or mono-alcohols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/28—Sulfonation products derived from fatty acids or their derivatives, e.g. esters, amides
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
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Abstract
本发明提供了一种汽车用玻璃清洁剂及其制备方法，所述玻璃清洁剂的原料包括溶剂、阴离子表面活性剂、非离子表面活性剂、香料、助剂、防腐剂、缓蚀剂、染料、pH调节剂和水。现有的车用玻璃清洁剂中，使用了大量的易燃液体作为溶剂，它们的闪点低，很容易挥发，这样的玻璃清洁剂在生产、贮藏、运输以及使用过程中，极易引发火灾或爆炸事故。为解决这一问题，本发明采用高闪点、低残留的原料进行复配，在产品闪点高于61℃，冰点低于‑8℃的前提下，达到有效清洁玻璃，无腐蚀、低残留无留痕的效果。
Description
技术领域
本发明属于硬表面清洁领域，特别涉及一种汽车用玻璃清洁剂及其制备方法。
背景技术
危险品所引发的火灾或爆炸事件时有发生，严重危害着广大消费者的生命安全和财产安全。闪点是指加热闪点杯中的试样时所逸出的蒸汽在火焰的存在下能瞬间闪火时的最低温度。闪点是衡量易燃液体火灾危险性的一项重要参数，闪点越低，危险性越大；一般低于61℃的货物运输需要办理危险品运输许可证。现有的车用玻璃清洁剂中使用了大量的易燃液体作溶剂，它们的闪点低，很容易挥发，在车用玻璃清洁剂生产、贮藏、运输以及使用过程中，极易引发火灾或爆炸事故。
发明内容
针对上述存在的问题，本发明的目的是提供一种汽车用玻璃清洁剂及其制备方法。其中采用高闪点低残留的原料复配，在产品闪点高于61℃的前提下，达到清洁玻璃，无腐蚀、低残留无留痕的效果。
本发明的目的是通过以下技术方案实现的：
一种汽车用玻璃清洁剂，其闪点高于61℃，冰点低于-8℃；制备所述清洁剂的原料包括溶剂、助剂、阴离子表面活性剂、非离子表面活性剂、香料、助剂、防腐剂、缓蚀剂、染料、pH调节剂和水，所述各原料的重量分数比为：
溶剂 1-50
助剂 0.1-6
阴离子表面活性剂 0.01-1
非离子表面活性剂 0.01-1
香料 0.01-0.5
防腐剂 0.01-0.5
缓蚀剂 0.01-0.1
染料 0.01-0.5
pH调节剂 0.01-1.0
水 补齐至100。
进一步的，所述溶剂包括乙二醇、碳酰二胺、乙醇、丙二醇甲醚和3-甲氧基-3-甲基-1-丁醇。
进一步的，所述助剂包括碳酰二胺、谷氨酸二乙酸四钠。
进一步的，所述阴离子表面活性剂包括脂肪醇聚氧乙烯醚硫酸盐（可以是2EO、或3EO）、α-烯烃磺酸钠、脂肪醇聚氧乙烯（9）醚羧酸钠。
进一步的，所述非离子表面活性剂包括烷基糖苷、脂肪醇聚氧乙烯醚（7EO或者9EO或者5～6EO）。
进一步的，所述防腐剂包括苯甲酸钠、山梨酸钾、N－羟甲基甘氨酸钠、5-氯-2-甲基-4-异噻唑啉-3-酮 (CMI) 和 2-甲基-4-异噻唑啉-3-酮。
进一步的，所述缓蚀剂包括亚硝酸钠、硼砂、苯并三氮唑，三者复配使用可用于缓释金属材料。
进一步的，所述香料包括D-柠烯。
本发明的另一方面：
上述汽车用玻璃清洁剂的制备方法，包括以下步骤：
A）按照上述的重量分数比，将阴离子表面活性剂用水预溶成一定比例的溶液，所述水的用量为总水量的5-15%；
B）在化料釜中加入占总水量40-60%的水，搅拌中依次加入步骤（A）中预溶后的阴离子表面活性剂溶液、非离子表面活性剂和助剂，完全搅拌溶解；
C）再依次加入溶剂、防腐剂和缓蚀剂，搅拌均匀后加入pH调节剂调pH至6.5-10；
D）最后加入色素，补齐余水搅拌，过滤即得到所述的汽车用玻璃清洁剂。
本发明相比现有技术的有益效果为：
1、本发明所述的汽车用玻璃清洁剂，采用的主表面活性剂为乙氧基化烷基硫酸钠（AES）、脂肪醇聚氧乙烯醚（AEO）、α-烯烃磺酸钠（AOS）和烷基糖苷（APG），使体系在保证去污力的同时更加温和，且配伍性较好；
2、本发明所述的汽车用玻璃清洁剂中，添加的非离子表面活性剂烷基糖苷，其表面张力低、湿润力强、去污力强、泡沫丰富细腻、配伍性强、无毒、无害、对金属、塑料无刺激，生物降解迅速彻底，关键在硬表面使用后不留痕，使得所述汽车用玻璃清洁剂达到低残留无留痕的效果；
3、本发明所述的汽车用玻璃清洁剂中，添加3-甲氧基-3-甲基-1-丁醇作为溶剂，其分子中同时拥有羟基和甲氧基，这使它在分子内和分子间形成很强的氢键，并显示出两亲性，既溶于水又溶于油，能很好的清洁硬表面上的污渍，同时在毒物学测试的许多方面显示出很高的安全性，它的闪点是68℃；
4、本发明所述的汽车用玻璃清洁剂中，D-柠烯是多种水果(主要为柑橘类)、蔬菜及香料中存在的天然成分，人与大鼠经口摄入均可完全吸收D-柠烯，柠檬烯有非常好的渗透性，可以快速去除硬表面的污垢，原料本身为柠檬味液体加入配方中可给产品带来愉悦气味；
5、由于我国北方冬季温度较低，一款高闪点、防冻型玻璃水很有必要，本发明所述的汽车用玻璃清洁剂中，采用包括丙二醇甲醚、碳酰二胺、乙二醇在内的原料作为溶剂，可有效降低产品的冰点和闪点；
6、Dissolvine GL-47-S（谷氨酸二乙酸四钠）是由食品级天然氨基酸盐左旋谷氨酸钠（MSG）制成。使用这种生物基原材料作为助剂，能够保证谷氨酸二乙酸四钠（GLDA）中一半以上的碳都是生物基的，这种天然氨基酸结构使它很容易被细菌识别为食物，从而使其易于生物降解；另外，该原料对于硬水金属离子（如Ca2+）而言是一种很强的螯合剂，它能够增强清洁剂配方的随软化性、清洁能力和稳定性；
7、本发明所述的汽车用玻璃清洁剂中，所用的染料为亚甲基蓝，其为指示剂，在次体系中不仅可作为染料，亦可来监控产品的pH值；
8、本发明所述的汽车用玻璃清洁剂为高闪点产品（闪点>61℃），利于安全生产、贮藏、运输以及使用，有效降低火灾、爆炸等事故的发生率。
附图说明
图1为实施例1所述汽车用玻璃清洁剂去污能力测试图；
图2为实施例2所述汽车用玻璃清洁剂去污能力测试图；
图3为实施例3所述汽车用玻璃清洁剂去污能力测试图；
图4为实施例4所述汽车用玻璃清洁剂去污能力测试图；
图5为实施例6所述汽车用玻璃清洁剂去污能力测试图。
具体实施方式
实施例1
本实施例提供了一种汽车用玻璃清洁剂，所述清洁剂的各原料重量份数比如表1中1#所示。
所述汽车用玻璃清洁剂的制备方法为：
A）按照表1-1#中所述的重量分数比，将阴离子表面活性剂用水预溶成一定比例的溶液，所述水的用量为总水量的5-15%；
B）在化料釜中加入占总水量40-60%的水，搅拌中依次加入步骤（A）中预溶后的阴离子表面活性剂溶液、非离子表面活性剂和助剂，完全搅拌溶解；
C）再依次加入溶剂、防腐剂和缓蚀剂，搅拌均匀后加入pH调节剂调pH至6.5-10；
D）最后加入色素，补齐余水搅拌，过滤即得到所述的防冻型汽车用玻璃清洁剂。
所述汽车用玻璃清洁剂的冰点为-40℃，闪点为65℃。
分别检测所述汽车用玻璃清洁剂的去污力和腐蚀性：
（1）去污力：依据GB/T 23436这一标准来对所述玻璃清洁剂进行了测试，经测试，如图1所示，其对车玻璃上的污渍去污效果良好，无残留。
（2）腐蚀性：依据GB/T 23436标准，分别利用所述玻璃清洁剂对铝片、铜片、镀锌钢板进行了腐蚀性测试。测试结果所述玻璃清洁剂为对三种材质均无腐蚀性。
表1 汽车用玻璃清洁剂的原料配比。
表2 汽车用玻璃清洁剂的原料配比。
实施例2
本实施例提供了另一种汽车用玻璃清洁剂，所述清洁剂的各原料重量份数比如表1中2#所示。所述玻璃清洁剂的制备方法参见实施例1。
所述汽车用玻璃清洁剂的冰点为-42℃，闪点为65℃。
分别检测所述汽车用玻璃清洁剂的去污力和腐蚀性：
（1）去污力：依据GB/T 23436这一标准来对所述玻璃清洁剂进行了测试，经测试，如图2所示，其对车玻璃上的污渍去污效果良好，无残留。
（2）腐蚀性：依据GB/T 23436标准，分别利用所述玻璃清洁剂对铝片、铜片、镀锌钢板进行了腐蚀性测试。测试结果所述玻璃清洁剂为对三种材质均无腐蚀性。
实施例3
本实施例提供了另一种汽车用玻璃清洁剂，所述清洁剂的各原料重量份数比如表1中3#所示。所述玻璃清洁剂的制备方法参见实施例1。
所述汽车用玻璃清洁剂的冰点为-43℃，闪点为66℃。
分别检测所述汽车用玻璃清洁剂的去污力和腐蚀性：
（1）去污力：依据GB/T 23436这一标准来对所述玻璃清洁剂进行了测试，经测试，如图3所示，其对车玻璃上的污渍去污效果良好，无残留。
（2）腐蚀性：依据GB/T 23436标准，分别利用所述玻璃清洁剂对铝片、铜片、镀锌钢板进行了腐蚀性测试。测试结果所述玻璃清洁剂为对三种材质均无腐蚀性。
实施例4
本实施例提供了另一种汽车用玻璃清洁剂，所述清洁剂的各原料重量份数比如表1中4#所示。所述玻璃清洁剂的制备方法参见实施例1。
所述汽车用玻璃清洁剂的冰点为-45℃，闪点为68℃。
分别检测所述汽车用玻璃清洁剂的去污力和腐蚀性：
（1）去污力：依据GB/T 23436这一标准来对所述玻璃清洁剂进行了测试，经测试，如图4所示，其对车玻璃上的污渍去污效果良好，无残留。
（2）腐蚀性：依据GB/T 23436标准，分别利用所述玻璃清洁剂对铝片、铜片、镀锌钢板进行了腐蚀性测试。测试结果所述玻璃清洁剂为对三种材质均无腐蚀性。
实施例5
本实施例提供了另一种汽车用玻璃清洁剂，所述清洁剂的各原料重量份数比如表1中5#所示。所述玻璃清洁剂的制备方法参见实施例1。
所述汽车用玻璃清洁剂的冰点为-46℃，闪点为70℃。
分别检测所述汽车用玻璃清洁剂的去污力和腐蚀性：
（1）去污力：依据GB/T 23436这一标准来对所述玻璃清洁剂进行了测试，经测试，其对车玻璃上的污渍去污效果良好，无残留。
（2）腐蚀性：依据GB/T 23436标准，分别利用所述玻璃清洁剂对铝片、铜片、镀锌钢板进行了腐蚀性测试。测试结果所述玻璃清洁剂为对三种材质均无腐蚀性。
实施例6
本实施例提供了另一种汽车用玻璃清洁剂，所述清洁剂的各原料重量份数比如表2中6#所示。所述玻璃清洁剂的制备方法参见实施例1。
所述汽车用玻璃清洁剂的冰点为-8℃，闪点为66℃。
分别检测所述汽车用玻璃清洁剂的去污力和腐蚀性：
（1）去污力：依据GB/T 23436这一标准来对所述玻璃清洁剂进行了测试，经测试，如图5所示，其对车玻璃上的污渍及虫胶去污效果良好，无残留。
（2）腐蚀性：依据GB/T 23436标准，分别利用所述玻璃清洁剂对铝片、铜片、镀锌钢板进行了腐蚀性测试。测试结果所述玻璃清洁剂为对三种材质均无腐蚀性。
实施例7
本实施例提供了另一种汽车用玻璃清洁剂，所述清洁剂的各原料重量份数比如表2中7#所示。所述玻璃清洁剂的制备方法参见实施例1。
所述汽车用玻璃清洁剂的冰点为-9℃，闪点为68℃。
分别检测所述汽车用玻璃清洁剂的去污力和腐蚀性：
（1）去污力：依据GB/T 23436这一标准来对所述玻璃清洁剂进行了测试，经测试，其对车玻璃上的污渍及虫胶去污效果良好，无残留。
（2）腐蚀性：依据GB/T 23436标准，分别利用所述玻璃清洁剂对铝片、铜片、镀锌钢板进行了腐蚀性测试。测试结果所述玻璃清洁剂为对三种材质均无腐蚀性。
实施例8
本实施例提供了另一种汽车用玻璃清洁剂，所述清洁剂的各原料重量份数比如表2中8#所示。所述玻璃清洁剂的制备方法参见实施例1。
所述汽车用玻璃清洁剂的冰点为-9℃，闪点为68℃。
分别检测所述汽车用玻璃清洁剂的去污力和腐蚀性：
（1）去污力：依据GB/T 23436这一标准来对所述玻璃清洁剂进行了测试，经测试，其对车玻璃上的污渍及虫胶去污效果良好，无残留。
（2）腐蚀性：依据GB/T 23436标准，分别利用所述玻璃清洁剂对铝片、铜片、镀锌钢板进行了腐蚀性测试。测试结果所述玻璃清洁剂为对三种材质均无腐蚀性。
实施例9
本实施例提供了另一种汽车用玻璃清洁剂，所述清洁剂的各原料重量份数比如表2中9#所示。所述玻璃清洁剂的制备方法参见实施例1。
所述汽车用玻璃清洁剂的冰点为-12℃，闪点为70℃。
分别检测所述汽车用玻璃清洁剂的去污力和腐蚀性：
（1）去污力：依据GB/T 23436这一标准来对所述玻璃清洁剂进行了测试，经测试，其对车玻璃上的污渍及虫胶去污效果良好，无残留。
（2）腐蚀性：依据GB/T 23436标准，分别利用所述玻璃清洁剂对铝片、铜片、镀锌钢板进行了腐蚀性测试。测试结果所述玻璃清洁剂为对三种材质均无腐蚀性。
实施例10
本实施例提供了另一种汽车用玻璃清洁剂，所述清洁剂的各原料重量份数比如表2中10#所示。所述玻璃清洁剂的制备方法参见实施例1。
所述汽车用玻璃清洁剂的冰点为-15℃，闪点为70℃。
分别检测所述汽车用玻璃清洁剂的去污力和腐蚀性：
（1）去污力：依据GB/T 23436这一标准来对所述玻璃清洁剂进行了测试，经测试，其对车玻璃上的污渍及虫胶去污效果良好，无残留。
（2）腐蚀性：依据GB/T 23436标准，分别利用所述玻璃清洁剂对铝片、铜片、镀锌钢板进行了腐蚀性测试。测试结果所述玻璃清洁剂为对三种材质均无腐蚀性。
Claims (9)
1.一种汽车用玻璃清洁剂，其特征在于，所述清洁剂的闪点高于61℃，冰点低于-8℃；制备所述清洁剂的原料包括溶剂、助剂、阴离子表面活性剂、非离子表面活性剂、香料、助剂、防腐剂、缓蚀剂、染料、pH调节剂和水，所述各原料的重量分数比为：
溶剂 1-50
助剂 0.1-6
阴离子表面活性剂 0.01-1
非离子表面活性剂 0.01-1
香料· 0.01-0.5
防腐剂 0.01-0.5
缓蚀剂 0.01-0.1
染料 0.01-0.5
pH调节剂 0.01-1.0
水 补齐至100。
2.根据权利要求1所述的汽车用玻璃清洁剂，其特征在于，所述溶剂包括乙二醇、碳酰二胺、乙醇、丙二醇甲醚和3-甲氧基-3-甲基-1-丁醇。
3.根据权利要求1所述的汽车用玻璃清洁剂，其特征在于，所述助剂包括碳酰二胺、谷氨酸二乙酸四钠。
4.根据权利要求1所述的汽车用玻璃清洁剂，其特征在于，所述阴离子表面活性剂包括脂肪醇聚氧乙烯醚硫酸盐、α-烯烃磺酸钠、脂肪醇聚氧乙烯（9）醚羧酸钠。
5.根据权利要求1所述的汽车用玻璃清洁剂，其特征在于，所述非离子表面活性剂包括烷基糖苷、脂肪醇聚氧乙烯醚。
6.根据权利要求1所述的汽车用玻璃清洁剂，其特征在于，所述防腐剂包括苯甲酸钠、山梨酸钾、N－羟甲基甘氨酸钠、5-氯-2-甲基-4-异噻唑啉-3-酮 (CMI) 和 2-甲基-4-异噻唑啉-3-酮。
7.根据权利要求1所述的汽车用玻璃清洁剂，其特征在于，所述缓蚀剂包括亚硝酸钠、硼砂、苯并三氮唑。
8.根据权利要求1所述的汽车用玻璃清洁剂，其特征在于，所述香料包括D-柠烯。
9.一种如权利要求1-8任一项所述的汽车用玻璃清洁剂的制备方法，其特征在于，所述制备方法包括以下步骤：
A）按照权利要求1所述的重量分数比，将阴离子表面活性剂用水预溶成一定比例的溶液，所述水的用量为总水量的5-15%；
B）在化料釜中加入占总水量40-60%的水，搅拌中依次加入步骤（A）中预溶后的阴离子表面活性剂溶液、非离子表面活性剂和助剂，完全搅拌溶解；
C）再依次加入溶剂、防腐剂和缓蚀剂，搅拌均匀后加入pH调节剂调pH至6.5-10；
D）最后加入色素，补齐余水搅拌，过滤即得到所述的汽车用玻璃清洁剂。
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