CN109467482A - The production method of the potassium phosphite a great number of elements Water soluble fertilizer of one planting fruit-trees - Google Patents

The production method of the potassium phosphite a great number of elements Water soluble fertilizer of one planting fruit-trees Download PDF

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Publication number
CN109467482A
CN109467482A CN201910022575.6A CN201910022575A CN109467482A CN 109467482 A CN109467482 A CN 109467482A CN 201910022575 A CN201910022575 A CN 201910022575A CN 109467482 A CN109467482 A CN 109467482A
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parts
potassium
great number
water soluble
soluble fertilizer
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林明
林珊
印华亮
吴君茂
李友德
梁家英
杨颜吉
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Sino-Linchem International Lnc
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Sino-Linchem International Lnc
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B17/00Other phosphatic fertilisers, e.g. soft rock phosphates, bone meal

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses the potassium phosphite a great number of elements Water soluble fertilizers and its production method of a planting fruit-trees, its raw material proportioning are as follows: phosphorous acid or 21-69 parts of potassium phosphite, phosphoric acid or 3.5-6 parts of phosphate, 8-41 parts of potassium hydroxide, 6-9 parts of nitrogenous fertilizer, middle microelement 2-30 parts, 5-20 parts of compound amino acid, 0.01-0.3 parts of plant growth regulator.Its production method is mainly weighed including raw material, and (2) raw material is mixed;(3) it in PH and adjusts;(4) microelement in addition;(5) performance measurement;(6) freeze: (7) product adjusts the potassium phosphite a great number of elements Water soluble fertilizer that fruit tree can be obtained.Product obtained by the present invention is detected by a great number of elements Water soluble fertilizer national sector standard NY1107-2010, N P and K a great number of elements total content be greater than 500g/L, overcome previous potassium phosphite aqueous solution by a great number of elements Water soluble fertilizer national sector standard NY1107-2010 detect when because+trivalent phosphorus can not be detected, 500g/L is not achieved in the total nutrient content of product the problem of.

Description

The production method of the potassium phosphite a great number of elements Water soluble fertilizer of one planting fruit-trees
Technical field
The invention belongs to technical field of inorganic chemical industry, and in particular to the potassium phosphite a great number of elements Water soluble fertilizer of a planting fruit-trees Production method.
Background technique
Water-soluble fertilizer has a great number of elements water-soluble fertilizer, moderate-element water-soluble fertilizer, trace element water-soluble fertilizer, contains amino acid Water-soluble fertilizer, containing humic acid water-soluble fertilizer, organic water-soluble fertilizer etc..It is a kind of quick action fertilizer, good water solubility, without residue can To completely dissolve in water, can be directly absorbed and utilized by the root system of crop and blade face.Using liquid manure with applying, with water band fertilizer, realize Water-fertilizer integral, its effective absorptivity are higher by common chemical fertilizer more than one times, reach 80%-90%;And fertilizer efficiency is fast, can solve The nutritional need of high-yield crop fast growing period.Cooperating drip irrigation system water requirement is only the 30% of common chemical fertilizer, and fertilising operation Almost human cost manually can not be greatly saved.Traditional compound fertilizer easily cause fertilizer loss, water eutrophication, It is serious to destroy soil texture, nutrient imbalance etc., and water-soluble fertilizer avoids lacking for conventional composite fertilizer as novel environment-friendly fertilizer Point, and it is easy to use, it can spray, rush and apply, and can be used in combination with being sprayed to fill, it can be with soil pouring or soilless cultivation, Water soluble fertilizer Expect the whole nutrients needed containing plant growth, can satisfy the purpose of peasant's increasing both production and income, crop can also be improved Quality, the physiological disease for reducing crop.There are more and more clay fertilizer experts, agricultural technology extension expert, means of agricultural production dealer The importance of water soluble fertilizer is recognized with peasant.Water-soluble fertilizer has more than 10,000 kinds in Ministry of Agriculture's registration product, water-soluble fertilizer product Meet the requirement of " low-carbon energy-saving, high-efficiency environment friendly " with application technique, therefore development prospect is very wide, a piece of light of future.
Potassium phosphite aqueous solution, is a kind of high-quality water-soluble fertilizer, and phosphorus has absorbability, mobility with the presence of 3+ phosphonium ion Feature, potassium phosphite+trivalent can be faster than+5 valence of phosphorus of phosphoric acid state by xylem and bast Bidirectional transporting, infiltration rate, With good promoting root growth, promote stem tuber, rush fruit effect.3+ phosphonium ion in plant in conductive process, have been demonstrated to epidemic disease bacterium, The fungal diseases such as downy mildew and b powder bacterium and bacterium have good inhibitory effect, and induction crop generates disease fungus and virus Lasting immunity.After crop applying potassium phosphite, it can be absorbed by plant leaf blade, root system, be transported in plant body, it is straight to play it Connect sterilizing function, while starting Defense response system, when pathogen people invades plant, stimulation plant generate plant alexin to Generate disease resistance.When pathogen invasion, pathogen can be invaded by potassium phosphite, be brought under control pathogen part, at this time Pathogen is also recognized by plant cell, and so that potassium phosphite starting system of defense is generated plant and resist element and PR protein, directly Attack pathogen is connect, and alert news can be issued and appeal other not yet affected cell starting systems of defense, then increases polysaccharide Add additional protein to reinforce cell wall, such pathogen will be suppressed or be killed by the reaction of plant.Potassium phosphite Resistant effect be a kind of acquired disease-resistant SAR of systematicness, also known as disease-resistant ISR of induced systemic, belong to generalization and give birth to One kind of object prevention and treatment prevents and treats epidemic disease using potassium phosphite, can reduce pesticide so potassium phosphite has the performance of plant protection It uses, maintains the ecological balance, it is ensured that agriculture sustainable development is the preferred raw materials for producing green non-pollution agricultural product.
Modern agriculture cost of labor is more and more expensive, and water-fertilizer integral, medicine fertilizer integration are increasingly welcome by people, sub- Potassium phosphate be exactly it is a integrate water-fertilizer integral and the integrated quality product of medicine fertilizer, but in existing many fertilizer agricultures If the liquid product of this phosphorous acid sylvite is sold in money shop, there is the liquid product that must meet phosphorous acid sylvite fertilizer to put on record card National fertilizer management requirement, according to the regulation of a great number of elements water-soluble fertilizer national sector standard NY1107-2010, Nitrogen-and Phosphorus-containing potassium A great number of elements water-soluble fertilizer put on record and must meet N P and K total content and reach 500g/L or more, minimum two kinds of a great number of elements contents are every Kind reaching 40g/L or more, the liquid product kind of conventional phosphorous acid sylvite mainly has a 0-400-430 on the market, 0-460-420, 0-550-280,0-525-270 etc., and do not measured according to the potassium phosphite product trivalent phosphorus of NY1107-2010 standard by national standard inspection The requirement of 500g/L is not achieved in next, the total nutrient content of product, and many fertilizer means of agricultural productions shop can not sell the liquid of this phosphorous acid sylvite Body product.
Summary of the invention
In order to solve in potassium phosphite liquid product+trivalent phosphorus can not be detected by national sector standard, the total nutrition of product contains Amount is not achieved the requirement of the 500g/L of NY1107-2010 standard, can not sell this potassium phosphite down to many fertilizer means of agricultural productions shop The problem of liquid product, the potassium phosphite that the present invention provides a kind of fruit tree that can reach NY1107-2010 standard requirements are largely first The production method of plain Water soluble fertilizer.
The purpose of the present invention is what is realized by the following technical solutions:
The potassium phosphite a great number of elements Water soluble fertilizer of one planting fruit-trees, raw material proportioning are as follows: phosphorous acid or potassium phosphite 21-69 Part, phosphoric acid or 3.5-6 parts of phosphate, 8-41 parts of potassium hydroxide, 3-9 parts of nitrogenous fertilizer, middle microelement 2-30 parts, compound amino acid 0- 15 parts, 0-15 parts of humic acid, 0-10 parts of algae essence, 0.01-0.3 parts of plant growth regulator.
As a preferred option of the technical scheme, the proportion of the Water soluble fertilizer is phosphorous acid or 30-60 parts of potassium phosphite, phosphoric acid or phosphoric acid 3.5-6 parts of potassium, 20-41 parts of potassium hydroxide, 6-9 parts of nitrogenous fertilizer, middle microelement 5-20 parts, 1-6 parts of compound amino acid, humic acid 2- 8 parts, 1-6 parts of algae essence, 0.01-0.15 parts of plant growth regulator, preferred, the described humic acid selects potassium fulvate.
As a preferred option of the technical scheme, the phosphoric acid is common phosphoric acid or polyphosphoric acids, is preferably polyphosphoric acids;The phosphorus Hydrochlorate is potassium phosphate or potassium polyphosphate, is preferably potassium polyphosphate.
As a preferred option of the technical scheme, the middle microelement is calcium, magnesium, zinc, boron, manganese, copper, molybdenum and iron and its chemical combination Object, dosage are respectively 0.3-2.0 parts of zinc, 0.3-2.0 parts of boron, 0.3-1.5 parts of manganese, 0.3-1.5 parts of iron, 0.3-1.0 parts of copper, molybdenum 0.2-0.9 parts, 0.3-1.0 parts of calcium, 0.3-1.0 parts of magnesium.
Microelement is zinc, boron, manganese, iron, copper, molybdenum, calcium, magnesium, is respectively derived from zinc sulfate, is instant in the moderate-element Eight Boratex of boron or four water, manganese sulfate, ferrous sulfate, copper sulphate, ammonium molybdate, calcium nitrate, magnesium sulfate;Or it uses with EDTA chela Conjunction form provides, such as EDTA-Zn, EDTA-B, EDTA-Mn, EDTA-Fe, EDTA-Cu, EDTA-Mo, EDTA-Ca, EDTA- Mg。
As a preferred option of the technical scheme, the plant growth regulator be compound sodium nitrophenolate, diethyl aminoethyl hexanoate (DA-6) and ethephon (CEPHA),2-(chloroethyl) phosphonic acid, Dosage is compound sodium nitrophenolate 0.10-0.25 parts, 0.01-0.1 parts of diethyl aminoethyl hexanoate (DA-6), 0.01-0.1 parts of ethephon (CEPHA),2-(chloroethyl) phosphonic acid.
As a preferred option of the technical scheme, the content of potassium is in 300-500g/L in the water-soluble fertilizer product, and the content of nitrogen is in 2- 10g/L, Meso- and micro-nutrients calcium, magnesium, zinc, boron, manganese, copper, zinc, molybdenum, iron total content in 2-30g/L, every sample micro battalion Constituent content is supported between 0.2-5g/L, pH value is between 5-9, and for the specific gravity of liquid product between 1.30-1.55, N P and K is big Secondary element total content is greater than 500g/L, and the total phosphorus content of+trivalent phosphorus Zhan is 60-90%.
The production method of the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree of the invention, includes the following steps,
(1) it weighs: weighing phosphorous acid, phosphoric acid, potassium hydroxide, nitrogenous fertilizer by raw material weight proportioning of soup processed,
(2) stir: weighed phosphorous acid is added in water, and the weight ratio of phosphorous acid and water is 1-3:1, is stirred for adding The potassium hydroxide of total weight 50-80% is stirred for that phosphoric acid is added;The potassium hydroxide of total weight 20-40% is added after dissolution; It is stirred for addition nitrogenous fertilizer,
(3) it neutralizes: adding the solution in the potassium hydroxide regulating step (2) of surplus again to PH between 5-9;
(4) middle microelement, compound amino acid, humic acid, sea microelement in addition: are weighed respectively by weight ratio again Algae essence, is added in the solution in step (3), and dissolution is sufficiently stirred and is uniformly mixed;
(5) measure: pH value and specific gravity in determination step (4), control PH between 5-9, specific gravity 1.30-1.55 it Between;
(6) it freezes: the solution measured being placed on -10 DEG C or less and carries out 6-30 hour of freezing;
(7) product is adjusted: the product in step (6) being taken out, restores room temperature, adds plant growth regulator and filled Divide dissolution mixing, so that product generates the potassium phosphite a great number of elements Water soluble fertilizer that fruit tree can be obtained without floccule.
The production method of the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree of the invention, includes the following steps,
(1) it weighs: weighing potassium phosphite, phosphoric acid or phosphate, potassium hydroxide, nitrogenous fertilizer by raw material weight proportioning of soup processed,
(2) it stirs: by stirring addition phosphoric acid or phosphate, nitrogenous fertilizer in the weighed potassium phosphite in step (1);
(3) it neutralizes: reusing the solution in potassium hydroxide regulating step (2) to PH between 5-9;
(4) middle microelement, compound amino acid, humic acid, sea microelement in addition: are weighed respectively by weight ratio again Algae finishing enters in the solution in step (3), and dissolution is sufficiently stirred and is uniformly mixed;
(5) measure: pH value and specific gravity in determination step (4), control PH between 5-9, specific gravity 1.35-1.55 it Between;
(6) it freezes: the solution measured being placed on -10 DEG C or less and carries out 6-30 hour of freezing;
(7) product is adjusted: the product in step (6) being taken out, restores room temperature, adds plant growth regulator and filled Divide dissolution mixing, so that product generates the potassium phosphite a great number of elements Water soluble fertilizer that fruit tree can be obtained without floccule.
As a preferred option of the technical scheme, the nitrogenous fertilizer is ammonium salt or nitrate.
Product of the invention is suitable for the links of planting fruit trees growth, for different growth periods, dosage of applying fertilizer It is adjusted.Suitable fruit tree has citrus, shaddock, cumquat, passion fruit etc..
The algae essence used in the present invention sells product for city, can directly carry out the purchasing of raw materials.Algae essence, which removes, contains alginic acid Outside, also contain plant indispensable element nitrogen (N), phosphorus (P), potassium (K), calcium (Ca), magnesium (Mg), sulphur (S), iron (Fe), manganese (Mn), copper (Cu), zinc (Zn), molybdenum (Mo), boron (B) etc.;18 kinds of gal4 amino acids being also directly absorbed and utilized containing plant and to plant The plant growth substance (auxin, the basic element of cell division, gibberellin etc.) that physiology course has a significant impact;It is sprouted with promotion seed Hair improves germination percentage;Promote plant root system development, is conducive to plant absorption moisture, nutrient;Promote suction of the plant to microelement It receives, promotes bud differentiation, improve fruit-setting rate, enhance plant stress-resistance performance, improve crop yield, improve quality of agricultural product etc. and make With.
The invention has the following advantages:
1, product obtained by the present invention is detected by a great number of elements Water soluble fertilizer national sector standard NY1107-2010, N P and K A great number of elements total content is greater than 500g/L, overcomes previous potassium phosphite aqueous solution by a great number of elements Water soluble fertilizer national sector standard NY1107-2010 detect when because+trivalent phosphorus can not be detected, 500g/L is not achieved in the total nutrient content of product the problem of.
2, the content of the phosphorous acid in product of the present invention is high, i.e., the ratio that+trivalent phosphorus occupies phosphorus total amount is high, and+5 valence phosphorus occupy The ratio of phosphorus total amount is low, ensure that product to fungal disease and the good inhibitory effect of bacterium.
3, product potassium content obtained by the present invention is still very high, makes the existing bacteriostasis of product, but can to crops control shoot, The strong tip promotes bud differentiation, and swollen fruit is mature ahead of time, improves yield, and improving quality etc. has obvious action.
4, a variety of middle and trace elements needed for the addition of product obtained by present invention crops;Crop centering, micro can be supplemented The demand of element reduces crop and nutritional deficiency symptom occurs, such as phenomena such as yellowing leaf, deformity, leaflet, fallen flowers, dehiscent fruit.
5, compound amino acid, humic acid, algae essence and a small amount of plant growth regulator have also been fused in product of the present invention, When for applying fruit trees with fertilizer, can not only absorption of the root system to nutrient, while being adjustable plant growth, promote cauline leaf growth, Hestening rooting and flower_bud formation;It is used in term, flower and fruit protecting can also be played the role of, promote fruit maturation.
Specific embodiment
Son makees further detail explanation to implementation steps of the invention combined with specific embodiments below, in favor of clearer Clear understanding the object, technical solutions and advantages of the present invention.It is necessarily pointed out that specific implementation discussed below Mode is served only for the further explanation carried out to the present invention, should not be understood as limiting the scope of the invention, the field Person skilled in the art can make some nonessential modifications and adaptations according to aforementioned present invention content.
Embodiment 1
The potassium phosphite a great number of elements Water soluble fertilizer of one planting fruit-trees, raw material proportioning and parts by weight are as follows: 32 parts of phosphorous acid, more 6 parts of polyphosphoric acid, 37 parts of potassium hydroxide, 4 parts of nitrogenous fertilizer (potassium nitrate), middle microelement is 1.5 parts of EDTA-Zn, EDTA-B 1.5 Part, 0.8 part of EDTA-Mn, 1 part of EDTA-Fe, 0.6 part of EDTA-Cu, 0.2 part of EDTA-Mo, 0.8 part of EDTA-Ca and EDTA- 0.8 part of Mg, 2 parts of compound amino acid, 4 parts of potassium fulvate, 3 parts of algae essence, 0.10 part of compound sodium nitrophenolate, diethyl aminoethyl hexanoate (DA-6) 0.05 Part, 0.05 part of ethephon (CEPHA),2-(chloroethyl) phosphonic acid.
The production method of the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree of the invention, includes the following steps,
(1) it weighs: weighing phosphorous acid, polyphosphoric acids, potassium hydroxide, nitrogenous fertilizer by raw material weight proportioning of soup processed;
(2) stir: 32 parts of weighed phosphorous acid are dissolved in 21 parts of water with container, and the endothermic reaction occurs;Weigh hydroxide 25 parts of potassium is slowly added in said vesse while stirring, and exothermic reaction occurs;6 parts of 85% phosphoric acid is weighed slowly to be added while stirring It in said vesse, then weighs 10.0 parts of potassium hydroxide and is slowly added in said vesse while stirring, exothermic reaction occurs, is stirred for Add nitrogenous fertilizer;
(3) it neutralizes: constantly monitoring solution pH value, then add molten in 2.0 parts of surplus of potassium hydroxide regulating step (2) Liquid to pH value stops that potassium hydroxide is added when solution pH value reaches 7;
(4) addition in microelement: weigh respectively by weight ratio again middle microelement, compound amino acid, potassium fulvate, Algae essence is added in the solution in step (3), is sufficiently stirred and is completely dissolved and is uniformly mixed using product;
(5) measure: the pH value in determination step (4) is 7.5, and surveying specific gravity is 1.5, is in brownish black uniform liquid;
(6) it freezes: the solution measured being placed on -10 DEG C or less and carries out 10 hours of freezing;
(7) product is adjusted: the product in step (6) being taken out, observation product is taken out and does not crystallize also without generating wadding Shape object, product do not have any variation, restore room temperature, add load weighted plant growth regulator and carry out sufficiently dissolution mixing, So that product generates the potassium phosphite a great number of elements Water soluble fertilizer that fruit tree can be obtained without floccule.
Detection: by the potassium phosphite a great number of elements Water soluble fertilizer produced by a great number of elements water-soluble fertilizer national sector standard The regulation of NY1107-2010 is detected, phosphorous (in terms of phosphorus pentoxide) 55g/L, contains potassium (in terms of potassium oxide) 434g/L, is closed Meter a great number of elements phosphorus potassium total content reaches 517g/L, is greater than 500g/L, meets a great number of elements water-soluble fertilizer national sector standard It is required that meanwhile, it measures by phosphorous acid detection method containing the+total phosphorus content of trivalent phosphorus (in terms of phosphorus pentoxide) 411g/L, Zhan 88.1%.Wherein the content of nitrogen is in 2-10g/L, Meso- and micro-nutrients calcium, magnesium, zinc, boron, manganese, copper, zinc, molybdenum, iron total content In 2-30g/L, every sample Meso- and micro-nutrients content is between 0.5-5g/L.
Embodiment 2
The potassium phosphite a great number of elements Water soluble fertilizer of one planting fruit-trees, raw material proportioning and parts by weight are as follows: 45.5 parts of phosphorous acid, 3.5 parts of polyphosphoric acids, 37 parts of potassium hydroxide, 3 parts of nitrogenous fertilizer (potassium nitrate), middle microelement is 2.0 parts of zinc sulfate, instant boron 0.3 Part, 1.0 parts of manganese sulfate, 1.0 parts of ferrous sulfate, 0.3 part of copper sulphate, 0..3 parts of ammonium molybdate, 1.0 parts of calcium nitrate and magnesium sulfate 0.3 Part, 1 part of compound amino acid, 2 parts of potassium fulvate, 2 parts of algae essence, 0.25 part of compound sodium nitrophenolate, 0.02 part of diethyl aminoethyl hexanoate (DA-6), ethylene 0.03 part of benefit.
The production method of the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree of the invention, includes the following steps,
(1) it weighs: weighing phosphorous acid, polyphosphoric acids, potassium hydroxide, nitrogenous fertilizer by raw material weight proportioning of soup processed;
(2) stir: weighed phosphorous acid 45.5g is dissolved in 20 parts of water with container, and the endothermic reaction occurs;Weigh hydroxide 15 parts of potassium is slowly added in said vesse while stirring, and exothermic reaction occurs;3.5 parts of 115% polyphosphoric acids slow sides are weighed to stir It mixes side to be added in said vesse, then weighs 21 parts of potassium hydroxide and be slowly added in said vesse while stirring, exothermic reaction occurs, It is stirred for addition nitrogenous fertilizer;
(3) it neutralizes: constantly monitoring solution pH value, then add the solution in 6 parts of surplus of potassium hydroxide regulating step (2) To pH value, stop that potassium hydroxide is added when solution pH value reaches 7 or so;
(4) addition in microelement: weigh respectively by weight ratio again middle microelement, compound amino acid, potassium fulvate, Algae essence is added in the solution in step (3), is sufficiently stirred and is completely dissolved and is uniformly mixed using product;
(5) measure: the pH value in determination step (4) is 6.0, and surveying specific gravity is 1.55, is in brownish black uniform liquid;
(6) it freezes: the solution measured being placed on -10 DEG C or less and carries out 20 hours of freezing;
(7) product is adjusted: the product in step (6) being taken out, observation product is taken out and does not crystallize also without generating wadding Shape object, product do not have any variation, restore room temperature, add load weighted plant growth regulator and carry out sufficiently dissolution mixing, So that product generates the potassium phosphite a great number of elements Water soluble fertilizer that fruit tree can be obtained without floccule.
Detection: by the potassium phosphite a great number of elements Water soluble fertilizer produced by a great number of elements water-soluble fertilizer national sector standard The regulation of NY1107-2010 is detected, phosphorous (in terms of phosphorus pentoxide) 45g/L, contains potassium (in terms of potassium oxide) 442g/L, is closed Meter a great number of elements phosphorus potassium total content reaches 504g/L, is greater than 500g/L, meets a great number of elements water-soluble fertilizer national sector standard It is required that meanwhile, it measures by phosphorous acid detection method containing the+total phosphorus content of trivalent phosphorus (in terms of phosphorus pentoxide) 604g/L, Zhan 93.0%.The content of nitrogen in 2-10g/L, Meso- and micro-nutrients calcium, magnesium, zinc, boron, manganese, copper, zinc, molybdenum, iron total content in 2- 30g/L, every sample Meso- and micro-nutrients content is between 0.5-5g/L.
Embodiment 3
The potassium phosphite a great number of elements Water soluble fertilizer of one planting fruit-trees, raw material proportioning and parts by weight are as follows: 29 parts of phosphorous acid, general Logical phosphatase 79 part, 36 parts of potassium hydroxide, 4 parts of nitrogenous fertilizer (ammonium nitrate), middle microelement is EDTA-Zn2.0 parts, 2.0 parts of EDTA-B, 0.3 part of EDTA-Mn, 0.3 part of EDTA-Fe, 1.0 parts of EDTA-Cu, 0.2 part of EDTA-Mo, 0.3 part of EDTA-Ca and EDTA- Mg1.0 parts, 1 part of compound amino acid, 2 parts of potassium fulvate, 1 part of algae essence, 0.15 part of compound sodium nitrophenolate, diethyl aminoethyl hexanoate (DA-6) 0.01 Part, 0.1 part of ethephon (CEPHA),2-(chloroethyl) phosphonic acid.
The production method of the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree of the invention, includes the following steps,
(1) it weighs: weighing phosphorous acid, common phosphoric acid, potassium hydroxide, nitrogenous fertilizer by raw material weight proportioning of soup processed;
(2) stir: 29 parts of weighed phosphorous acid are dissolved in 20 parts of water with container, and the endothermic reaction occurs;Weigh hydroxide 16 parts of potassium is slowly added in said vesse while stirring, and exothermic reaction occurs;Weigh the slow side stirring of 3.5 parts of 85% common phosphoric acid Side is added in said vesse, then weighs 20 parts of potassium hydroxide and be slowly added in said vesse while stirring, and exothermic reaction occurs, then Stirring addition nitrogenous fertilizer;
(3) it neutralizes: constantly monitoring solution pH value, control solution to pH value is 7 or so;
(4) addition in microelement: weigh respectively by weight ratio again middle microelement, compound amino acid, potassium fulvate, Algae essence is added in the solution in step (3), is sufficiently stirred and is completely dissolved and is uniformly mixed using product;
(5) measure: the pH value in determination step (4) is 7.5, and surveying specific gravity is 1.47, is in brownish black uniform liquid;
(6) it freezes: the solution measured being placed on -10 DEG C or less and carries out 6 hours of freezing;
(7) product is adjusted: the product in step (6) being taken out, observation product is taken out and does not crystallize also without generating wadding Shape object, product do not have any variation, restore room temperature, add load weighted plant growth regulator and carry out sufficiently dissolution mixing, So that product generates the potassium phosphite a great number of elements Water soluble fertilizer that fruit tree can be obtained without floccule.
Detection: by the potassium phosphite a great number of elements Water soluble fertilizer produced by a great number of elements water-soluble fertilizer national sector standard The regulation of NY1107-2010 is detected, phosphorous (in terms of phosphorus pentoxide) 81g/L, contains potassium (in terms of potassium oxide) 433g/L, is closed Meter a great number of elements phosphorus potassium total content reaches 514g/L, is greater than 500g/L, meets a great number of elements water-soluble fertilizer national sector standard It is required that meanwhile, it measures by phosphorous acid detection method containing the+total phosphorus content of trivalent phosphorus (in terms of phosphorus pentoxide) 365g/L, Zhan 81.78%.The content of nitrogen in 2-10g/L, Meso- and micro-nutrients calcium, magnesium, zinc, boron, manganese, copper, zinc, molybdenum, iron total content exist 2-30g/L, every sample Meso- and micro-nutrients content is between 0.5-5g/L.
Embodiment 4
The potassium phosphite a great number of elements Water soluble fertilizer of one planting fruit-trees, raw material proportioning and parts by weight are as follows: 20 parts of phosphorous acid, more 16 parts of polyphosphoric acid, 28 parts of potassium hydroxide, 2 parts of nitrogenous fertilizer (ammonium nitrate), middle microelement is EDTA-Zn2.0 parts, EDTA-B 2.0 Part, 1.5 parts of EDTA-Mn, 1.5 parts of EDTA-Fe, 1.0 parts of EDTA-Cu, 0.24 part of EDTA-Mo, 1.0 parts of EDTA-Ca and EDTA-Mg1.0 parts, 1 part of compound amino acid, 2 parts of potassium fulvate, 1 part of algae essence, 0.1 part of compound sodium nitrophenolate, diethyl aminoethyl hexanoate (DA-6) 0.1 part, 0.01 part of ethephon (CEPHA),2-(chloroethyl) phosphonic acid.
The production method of the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree of the invention, includes the following steps,
(1) it weighs: weighing phosphorous acid, polyphosphoric acids, potassium hydroxide, nitrogenous fertilizer by raw material weight proportioning of soup processed,
(2) stir: 20 parts of weighed phosphorous acid are dissolved in 23 parts of water with container, and the endothermic reaction occurs;Weigh hydroxide 15 parts of potassium is slowly added in said vesse while stirring, and exothermic reaction occurs;Weigh 15 parts of 115% polyphosphoric acids slow side stirrings Side is added in said vesse, then weighs 12 parts of potassium hydroxide and be slowly added in said vesse while stirring, and exothermic reaction occurs, then Stirring addition nitrogenous fertilizer,
(3) it neutralizes: constantly monitoring solution pH value, then add the solution in 2 parts of surplus of potassium hydroxide regulating step (2) To pH value, stop that potassium hydroxide is added when solution pH value reaches 7 or so;
(4) addition in microelement: weigh respectively by weight ratio again middle microelement, compound amino acid, potassium fulvate, Algae essence is added in the solution in step (3), is sufficiently stirred and is completely dissolved and is uniformly mixed using product;
(5) measure: the pH value in determination step (4) is 7.8, and surveying specific gravity is 1.45, is in brownish black uniform liquid;
(6) it freezes: the solution measured being placed on -10 DEG C or less and carries out 30 hours of freezing;
(7) product is adjusted: the product in step (6) being taken out, observation product is taken out and does not crystallize also without generating wadding Shape object, product do not have any variation, restore room temperature, add load weighted plant growth regulator and carry out sufficiently dissolution mixing, So that product generates the potassium phosphite a great number of elements Water soluble fertilizer that fruit tree can be obtained without floccule.
Detection: by the potassium phosphite a great number of elements Water soluble fertilizer produced by a great number of elements water-soluble fertilizer national sector standard The regulation of NY1107-2010 is detected, phosphorous (in terms of phosphorus pentoxide) 181g/L, contains potassium (in terms of potassium oxide) 333g/L, Total a great number of elements phosphorus potassium total content reaches 503g/L, is greater than 500g/L, meets a great number of elements water-soluble fertilizer national sector standard Requirement, meanwhile, measure by phosphorous acid detection method containing the+total phosphorus content of trivalent phosphorus (in terms of phosphorus pentoxide) 285g/L, Zhan 61.2%.The content of nitrogen in 2-10g/L, Meso- and micro-nutrients calcium, magnesium, zinc, boron, manganese, copper, molybdenum, iron total content in 2- 30g/L, every sample Meso- and micro-nutrients content is between 0.5-5g/L.
Embodiment 5
The potassium phosphite a great number of elements Water soluble fertilizer of one planting fruit-trees, raw material proportioning and parts by weight are as follows: potassium phosphite (0- 400-430) 50 parts, 10 parts of potassium polyphosphate, 17 parts of potassium hydroxide, 2 parts of nitrogenous fertilizer (ammonium nitrate), middle microelement is EDTA- Zn2.0 parts, 0.3 part of EDTA-B, 1.5 parts of EDTA-Mn, 1.5 parts of EDTA-Fe, 0.3 part of EDTA-Cu, 0.3 part of EDTA-Mo, 1.0 parts and EDTA-Mg0.2 parts of EDTA-Ca, 3 parts of compound amino acid, 2 parts of potassium fulvate, 2 parts of algae essence, compound sodium nitrophenolate 0.25 Part, 0.02 part of diethyl aminoethyl hexanoate (DA-6), 0.03 part of ethephon (CEPHA),2-(chloroethyl) phosphonic acid.
The production method of the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree of the invention, includes the following steps,
(1) it weighs: weighing potassium phosphite, potassium polyphosphate, potassium hydroxide, nitrogenous fertilizer by raw material weight proportioning of soup processed,
(2) it stirs: the weighed potassium phosphite in step (1) is placed in 250 milliliters of containers, be stirred for addition poly Potassium phosphate, nitrogenous fertilizer;
(3) it neutralizes: reusing potassium hydroxide and be slowly added in said vesse while stirring, exothermic reaction occurs, and constantly Solution pH value is monitored, solution pH value stops that potassium hydroxide is added when reaching 7 or so;
(4) middle microelement, compound amino acid, humic acid, sea microelement in addition: are weighed respectively by weight ratio again Algae finishing enters in the solution in step (3), is sufficiently stirred and is completely dissolved, and is uniformly mixed;
(5) measure: pH value and specific gravity in determination step (4), surveying pH value is 7.5, and surveying specific gravity is 1.4, equal in brownish black Even liquid;
(6) it freezes: the solution measured being placed on -10 DEG C or less and carries out 10 hours of freezing;
(7) product is adjusted: the product in step (6) being taken out, observation product is taken out and does not crystallize also without generating wadding Shape object, product do not have any variation, restore room temperature, add load weighted plant growth regulator and carry out sufficiently dissolution mixing, So that product generates the potassium phosphite a great number of elements Water soluble fertilizer that fruit tree can be obtained without floccule.
Detection: by the potassium phosphite a great number of elements Water soluble fertilizer produced by a great number of elements water-soluble fertilizer national sector standard The regulation of NY1107-2010 is detected, phosphorous (in terms of phosphorus pentoxide) 116g/L, contains potassium (in terms of potassium oxide) 388g/L, Total a great number of elements phosphorus potassium total content reaches 505g/L, is greater than 500g/L, meets a great number of elements water-soluble fertilizer national sector standard Requirement, meanwhile, measure by phosphorous acid detection method containing the+total phosphorus content of trivalent phosphorus (in terms of phosphorus pentoxide) 186g/L, Zhan 61.5%.The content of nitrogen in 2-10g/L, Meso- and micro-nutrients calcium, magnesium, zinc, boron, manganese, copper, molybdenum, iron total content in 2- 30g/L, every sample Meso- and micro-nutrients content is between 0.5-5g/L.
Embodiment 6
The potassium phosphite a great number of elements Water soluble fertilizer of one planting fruit-trees, raw material proportioning and parts by weight are as follows: potassium phosphite (0- 400-430) 67.5 parts, 7.2 parts of polyphosphoric acids, 11.5 parts of potassium hydroxide, 2 parts of nitrogenous fertilizer (ammonium nitrate), in EDTA chelated forms Microelement is 2.0 parts of zinc sulfate, 1.5 parts of instant boron, 0.8 part of manganese sulfate, 1 part of ferrous sulfate, 0.7 part of copper sulphate, ammonium molybdate 0.06 part, 0.7 part of calcium nitrate and 0.8 part of magnesium sulfate, 1 part of compound amino acid, 2 parts of potassium fulvate, 1 part of algae essence, compound sodium nitrophenolate 0.1 part, 0.1 part of diethyl aminoethyl hexanoate (DA-6), 0.01 part of ethephon (CEPHA),2-(chloroethyl) phosphonic acid.
The production method of the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree of the invention, includes the following steps,
(1) it weighs: weighing potassium phosphite, potassium polyphosphate, potassium hydroxide, nitrogenous fertilizer by raw material weight proportioning of soup processed,
(2) it stirs: the weighed potassium phosphite in step (1) is placed in 250 milliliters of containers, be stirred for addition poly Phosphoric acid, nitrogenous fertilizer;
(3) it neutralizes: reusing potassium hydroxide and be slowly added in said vesse while stirring, exothermic reaction occurs, and constantly Solution pH value is monitored, solution pH value stops that potassium hydroxide is added when reaching 7.5;
(4) middle microelement, compound amino acid, humic acid, sea microelement in addition: are weighed respectively by weight ratio again Algae finishing enters in the solution in step (3), is sufficiently stirred and is completely dissolved, and is uniformly mixed;
(5) measure: pH value and specific gravity in determination step (4), surveying pH value is 7.5, and surveying specific gravity is 1.48, equal in brownish black Even liquid;
(6) it freezes: the solution measured being placed on -10 DEG C or less and carries out 6 hours of freezing;
(7) product is adjusted: the product in step (6) being taken out, observation product is taken out and does not crystallize also without generating wadding Shape object, product do not have any variation, restore room temperature, add load weighted plant growth regulator and carry out sufficiently dissolution mixing, So that product generates the potassium phosphite a great number of elements Water soluble fertilizer that fruit tree can be obtained without floccule.
Detection: by the potassium phosphite a great number of elements Water soluble fertilizer produced by a great number of elements water-soluble fertilizer national sector standard The regulation of NY1107-2010 is detected, phosphorous (in terms of phosphorus pentoxide) 84g/L, contains potassium (in terms of potassium oxide) 412g/L, is closed Meter a great number of elements phosphorus potassium total content reaches 501g/L, is greater than 500g/L, meets a great number of elements water-soluble fertilizer national sector standard It is required that meanwhile, it measures by phosphorous acid detection method containing+261 grams per liter of trivalent phosphorus (in terms of phosphorus pentoxide), the total phosphorus content of Zhan 75.0%.The content of nitrogen in 2-10g/L, Meso- and micro-nutrients calcium, magnesium, zinc, boron, manganese, copper, molybdenum, iron total content in 2- 30g/L, every sample Meso- and micro-nutrients content is between 0.5-5g/L.
Embodiment 7
The potassium phosphite a great number of elements Water soluble fertilizer of one planting fruit-trees, raw material proportioning and parts by weight are as follows: 46 parts of potassium phosphite, 9.6 parts of potassium polyphosphate, 19 parts of potassium hydroxide, 2 parts of nitrogenous fertilizer (ammonium nitrate), middle microelement is EDTA-Zn0.3 parts, EDTA- B2.0 parts, 0.3 part of EDTA-Mn, 0.3 part of EDTA-Fe, 1.0 parts of EDTA-Cu, 0.06 part of EDTA-Mo, 0.3 part of EDTA-Ca With EDTA-Mg1.0 parts, 1 part of compound amino acid, 2 parts of potassium fulvate, 1 part of algae essence, 0.15 part of compound sodium nitrophenolate, diethyl aminoethyl hexanoate (DA- 6) 0.01 part, 0.1 part of ethephon (CEPHA),2-(chloroethyl) phosphonic acid.
The production method of the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree of the invention, includes the following steps,
(1) it weighs: weighing potassium phosphite, potassium polyphosphate, potassium hydroxide, nitrogenous fertilizer by raw material weight proportioning of soup processed,
(2) it stirs: the weighed potassium phosphite in step (1) is placed in 250 milliliters of containers, be stirred for addition poly Potassium phosphate, nitrogenous fertilizer;
(3) it neutralizes: reusing potassium hydroxide and be slowly added in said vesse while stirring, exothermic reaction occurs, and constantly Solution pH value is monitored, solution pH value reaches 7 or so stoppings and potassium hydroxide is added;
(4) middle microelement, compound amino acid, humic acid, sea microelement in addition: are weighed respectively by weight ratio again Algae finishing enters in the solution in step (3), is sufficiently stirred and is completely dissolved, and is uniformly mixed;
(5) measure: pH value and specific gravity in determination step (4), surveying pH value is 7.8, and surveying specific gravity is 1.4, equal in brownish black Even liquid;
(6) it freezes: the solution measured being placed on -10 DEG C or less and carries out 30 hours of freezing;
(7) product is adjusted: the product in step (6) being taken out, observation product is taken out and does not crystallize also without generating wadding Shape object, product do not have any variation, restore room temperature, add load weighted plant growth regulator and carry out sufficiently dissolution mixing, So that product generates the potassium phosphite a great number of elements Water soluble fertilizer that fruit tree can be obtained without floccule.
Detection: by the potassium phosphite a great number of elements Water soluble fertilizer produced by a great number of elements water-soluble fertilizer national sector standard The regulation of NY1107-2010 is detected, phosphorous (in terms of phosphorus pentoxide) 111g/L, contains potassium (in terms of potassium oxide) 390g/L, Total a great number of elements phosphorus potassium total content reaches 503g/L, is greater than 500g/L, meets a great number of elements water-soluble fertilizer national sector standard Requirement, meanwhile, measure by phosphorous acid detection method containing the+total phosphorus content of trivalent phosphorus (in terms of phosphorus pentoxide) 171g/L, Zhan 62.2%.The content of nitrogen in 2-10g/L, Meso- and micro-nutrients calcium, magnesium, zinc, boron, manganese, copper, molybdenum, iron total content in 2- 30g/L, every sample Meso- and micro-nutrients content is between 0.5-5g/L.
Two, experimental example
(1) Water soluble fertilizer produced by the invention is applied to the simulation experiments of citrus
2017, test carried out in Guangxi Mr. Lin Orange Producing base.Using packet mode, the fertilising of A group is all made of The compound fertilizer of traditional market, B group use Water soluble fertilizer of the invention, every group 30 plants.The mode and dosage of fertilising are all the same.
1 orange yield contrast table of table
Test item A group B group Growth rate
Average single plant fruiting number (a) 283 302 6.7%
Average single plant yield (kg) 38.54 43.25 12.22%
Total output (kg) 1156.21 1297.62 12.23%
Occur germ plant (strain) 2 0
The potassium phosphite a great number of elements Water soluble fertilizer of fruit tree produced by the invention, which improves orange yield, has facilitation, single Strain yield can be improved 10% or more, while have antibacterial, the effect of antibacterial.
(2) Water soluble fertilizer produced by the invention is applied to the simulation experiments of fertile mandarin orange
Mandarin orange production base is irrigated in Nanning Binyang County and is carried out in March, 2017.Experimental subjects is triennial plant Strain is divided into three groups, and every group 20 plants, the respectively fertilising of C group mainly uses traditional farmyard manure, and D group is compound using traditional market Fertilizer, E group use Water soluble fertilizer of the invention.The mode and dosage of fertilising are all the same.
Table 2 irrigates mandarin orange yield comparison table
Known to the contrast table above in yield: E group is for D group, output increased 9.67%, relative to C group, Output increased 30.76%.
The potassium phosphite a great number of elements Water soluble fertilizer of fruit tree produced by the invention has facilitation to fertile mandarin orange also output increased, There is antibacterial, the effect of antibacterial simultaneously.

Claims (9)

1. the potassium phosphite a great number of elements Water soluble fertilizer of a planting fruit-trees, it is characterised in that: the Water soluble fertilizer raw material proportioning are as follows: phosphorous acid or 21-69 parts of potassium phosphite, phosphoric acid or 3.5-6 parts of phosphate, 8-41 parts of potassium hydroxide, 3-9 parts of nitrogenous fertilizer, middle microelement 2-30 Part, 0-15 parts of compound amino acid, 0-15 parts of humic acid, 0-10 parts of algae essence, 0.01-0.3 parts of plant growth regulator.
2. the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree according to claim 1, it is characterised in that: the Water soluble fertilizer is matched Than for phosphorous acid or 30-60 parts of potassium phosphite, phosphoric acid or 3.5-6 parts of potassium phosphate, 20-41 parts of potassium hydroxide, 6-9 parts of nitrogenous fertilizer, in 5-20 parts of microelement, 1-6 parts of compound amino acid, 2-8 parts of humic acid, 1-6 parts of algae essence, plant growth regulator 0.01- 0.15 part.
3. the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree according to claim 1, it is characterised in that: the phosphoric acid is general Logical phosphoric acid or polyphosphoric acids;The phosphate is potassium phosphate or potassium polyphosphate.
4. the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree according to any one of claims 1 to 3, it is characterised in that: described Middle microelement is calcium, magnesium, zinc, boron, manganese, copper, molybdenum and/or iron and its compound, and dosage is respectively 0.3-2.0 parts of zinc, boron 0.3-2.0 parts, 0.3-1.5 parts of manganese, 0..3-1.5 parts of iron, 0.3-1.0 parts of copper, 0.3-0.9 parts of molybdenum, 0.3-1.0 parts of calcium, magnesium 0.3- 1.0 part.
5. the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree according to any one of claims 1 to 3, it is characterised in that: described Plant growth regulator is compound sodium nitrophenolate, diethyl aminoethyl hexanoate (DA-6) and ethephon (CEPHA),2-(chloroethyl) phosphonic acid, and dosage is compound sodium nitrophenolate 0.10-0.25 parts, and amine is fresh 0.01-0.1 parts of ester (DA-6), 0.01-0.1 parts of ethephon (CEPHA),2-(chloroethyl) phosphonic acid.
6. the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree according to any one of claims 1 to 3, it is characterised in that: described The content of potassium is in 300-500g/L in water-soluble fertilizer product, the content of nitrogen in 2-10g/L, Meso- and micro-nutrients calcium, magnesium, zinc, boron, Manganese, copper, zinc, molybdenum, iron total content in 2-30g/L, every sample Meso- and micro-nutrients content is between 0.2-5g/L, and pH value is in 5- Between 9, for the specific gravity of liquid product between 1.30-1.55, N P and K a great number of elements total content is greater than 500g/L, and+trivalent phosphorus Zhan is total Phosphorus content is 60-90%.
7. the production method of the potassium phosphite a great number of elements Water soluble fertilizer of the fruit tree as described in claim 1-6 is any, feature exist In: include the following steps,
(1) it weighs: weighing phosphorous acid, phosphoric acid, potassium hydroxide, nitrogenous fertilizer by raw material weight proportioning of soup processed,
(2) stir: weighed phosphorous acid is added in water, and the weight ratio of phosphorous acid and water is 1-3:1, is stirred for addition gross weight The potassium hydroxide for measuring 50-80% is stirred for that phosphoric acid is added;The potassium hydroxide of total weight 20-40% is added after dissolution;It stirs again Addition nitrogenous fertilizer is mixed,
(3) it neutralizes: adding the solution in the potassium hydroxide regulating step (2) of surplus again to PH between 5-9;
(4) middle microelement, compound amino acid, humic acid, seaweed microelement in addition: are weighed respectively by weight ratio again Essence is added in the solution in step (3), and dissolution is sufficiently stirred and is uniformly mixed;
(5) measure: pH value and specific gravity in determination step (4) control PH between 5-9, and specific gravity is between 1.30-1.55;
(6) it freezes: the solution measured being placed on -10 DEG C or less and carries out 6-30 hour of freezing;
(7) product is adjusted: the product in step (6) being taken out, room temperature is restored, it is sufficiently molten to add plant growth regulator progress Solution mixing, so that product generates the potassium phosphite a great number of elements Water soluble fertilizer that fruit tree can be obtained without floccule.
8. the production method of the potassium phosphite a great number of elements Water soluble fertilizer of the fruit tree as described in claim 1-6 is any, feature exist In: include the following steps,
(1) it weighs: weighing potassium phosphite, phosphoric acid or phosphate, potassium hydroxide, nitrogenous fertilizer by raw material weight proportioning of soup processed,
(2) it stirs: by stirring addition phosphoric acid or phosphate, nitrogenous fertilizer in the weighed potassium phosphite in step (1);
(3) it neutralizes: reusing the solution in potassium hydroxide regulating step (2) to PH between 5-9;
(4) middle microelement, compound amino acid, humic acid, algae essence microelement in addition: are weighed respectively by weight ratio again It is added in the solution in step (3), dissolution is sufficiently stirred and is uniformly mixed;
(5) measure: pH value and specific gravity in determination step (4) control PH between 5-9, and specific gravity is between 1.35-1.55;
(6) it freezes: the solution measured being placed on -10 DEG C or less and carries out 6-30 hour of freezing;
(7) product is adjusted: the product in step (6) being taken out, room temperature is restored, it is sufficiently molten to add plant growth regulator progress Solution mixing, so that product generates the potassium phosphite a great number of elements Water soluble fertilizer that fruit tree can be obtained without floccule.
9. the production method of the potassium phosphite a great number of elements Water soluble fertilizer of fruit tree according to claim 7 or 8, feature exist In: the nitrogenous fertilizer is ammonium salt or nitrate.
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Application publication date: 20190315