CN109463394B - 一种石墨烯驱蚊助剂及制备石墨烯驱蚊面料的方法 - Google Patents

一种石墨烯驱蚊助剂及制备石墨烯驱蚊面料的方法 Download PDF

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CN109463394B
CN109463394B CN201811557174.2A CN201811557174A CN109463394B CN 109463394 B CN109463394 B CN 109463394B CN 201811557174 A CN201811557174 A CN 201811557174A CN 109463394 B CN109463394 B CN 109463394B
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沙嫣
沙晓林
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Nantong Qiangsheng Graphene Technology Co ltd
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Abstract

本发明提供了一种石墨烯驱蚊助剂及制备石墨烯驱蚊面料的方法，所示石墨烯驱蚊助剂包括以下质量含量的各组分：1‑10％石墨烯、润湿渗透剂1‑20％、粘合剂2‑8％、有机溶剂10‑30％、余量为水。将面料反复浸轧在石墨烯驱蚊助剂中，浸轧后的面料再经过脱水、烘干、烘焙即得所述石墨烯驱蚊面料。本发明采用的石墨烯来源于矿物质绿色环保对人体无害，将其应用在面料上可以有效防蚊，保护人体健康。制得的面料对蚊子的驱避率高达92％，且水洗10次后驱避率仍高达72％，可以达到国家标准A级。

Description

一种石墨烯驱蚊助剂及制备石墨烯驱蚊面料的方法
技术领域
本发明涉及一种石墨烯驱蚊助剂及制备石墨烯驱蚊面料的方法，属于纺织技术领域。
背景技术
现阶段驱蚊面料一般有两种，一种在基布层和面料层之间做驱蚊夹层，一种是由驱蚊液处理后的纤维编织而成。其中，驱蚊液中一般都含有合成趋避剂，如DEET(N,N—二乙基间甲苯甲酰胺)，这类趋避剂会对人体健康产生不良影响，如可以引发神经系统疾病、脑病和皮肤病等。
发明内容
针对现有技术的不足，本发明提供了一种石墨烯驱蚊助剂及制备石墨烯驱蚊面料的方法。
本发明的目的是通过以下技术方案实现的：
本发明提供了一种石墨烯驱蚊助剂，包括以下质量含量的各组分：1-10％石墨烯、润湿渗透剂1-20％、粘合剂2-8％、有机溶剂10-30％、余量为水。
优选地，所述石墨烯为氧化石墨烯、改性石墨烯、还原石墨烯中的一种或几种。
优选地，所述石墨烯采用氧化还原法、机械剥离法、化学气相沉积法或电化学剥离法制备。
优选地，所述石墨烯厚度为0.3-10nm，比表面积为450-800m2/g。
优选地，所述润湿渗透剂为阴离子、阳离子或非离子表面活性剂中的至少一种。
优选地，所述粘合剂为硅烷偶联剂、环氧树脂、硅油、水性聚氨酯中的至少一种；
所述有机溶剂为乙醇、丙酮、四氢呋喃中的至少一种
本发明提供了一种石墨烯驱蚊助剂的制备方法，所述石墨烯驱蚊助剂的制备方法包括以下步骤：
(1)称取各组分备用；
(2)将石墨烯与水混合配成溶液，并移至反应釜中；
(3)将粘合剂、润湿渗透剂、有机溶剂加入上述反应釜中，在30-60℃温度下高速搅拌20-80min得到成品。
本发明提供了一种石墨烯驱蚊面料的制备方法，包括以下步骤：
将面料反复浸轧在权利要求1所述的石墨烯驱蚊助剂中，浸轧后的面料再经过脱水、烘干、烘焙即得所述石墨烯驱蚊面料。
优选地，所述面料为梭织面料或者针织面料。
优选地，制备所述面料的纤维包括天然纤维、黏胶纤维、丙纶纤维、涤纶纤维、锦纶纤维、石墨烯锦纶纤维、石墨烯涤纶纤维、石墨烯丙纶纤维中的一种或几种。
优选地，所述浸轧处理的轧余率为70％-90％。
优选地，所述烘干温度为40-80℃，时间为60-240min；所述烘焙温度为90-130℃，时间为2-5min。
与现有技术相比，本发明具有如下的有益效果：
(1)本发明所用石墨烯具有较强的驱蚊效果，而且石墨烯来源于矿物质绿色环保对人体无害，将其应用在面料上可以有效防蚊，保护人体健康。
(2)本发明的石墨烯驱蚊面料对蚊子的驱避率为92％，可以达到国家标准A级。
(3)本发明的石墨烯驱蚊面料水洗10次后，石墨烯驱蚊面料的驱避率为72％，依然可以达到国家标准A级。
具体实施方式
下面结合具体实施例对本发明进行详细说明。以下实施例将有助于本领域的技术人员进一步理解本发明，但不以任何形式限制本发明。应当指出的是，对本领域的普通技术人员来说，在不脱离本发明构思的前提下，还可以做出若干变化和改进。这些都属于本发明的保护范围。
实施例1
本实施例提供了一种石墨烯驱蚊面料的制备方法，包括以下步骤：
1、石墨烯驱蚊助剂的制备
1.1根据表1的各组分及质量百分含量称取原料备用；所述石墨烯为氧化石墨烯，采用氧化还原方法制备，石墨烯厚度为0.3nm，比表面积为450m2/g。
1.2将石墨烯与水混合配成溶液，并移至反应釜中；
1.3将粘合剂、润湿渗透剂、有机溶剂加入上述反应釜中，在30-60℃温度下高速搅拌20-80min得到成品；所述粘合剂为硅烷偶联剂，湿润渗透剂为非离子表面活性剂，有机溶剂为乙醇。
2、将天然纤维织造的针织面料反复浸轧在步骤1制备的石墨烯驱蚊助剂中，浸轧处理的轧余率为70％，浸轧后的面料再经过脱水、40℃烘干240min、130℃烘焙2min，即得所述石墨烯驱蚊面料。
实施例2
本实施例提供了一种石墨烯驱蚊面料的制备方法，包括以下步骤：
1、石墨烯驱蚊助剂的制备
1.1根据表1的各组分及质量百分含量称取原料备用；所述石墨烯为还原石墨烯，石墨烯厚度为5nm，比表面积为600m2/g。
1.2将石墨烯与水混合配成溶液，并移至反应釜中；
1.3将粘合剂、润湿渗透剂、有机溶剂加入上述反应釜中，在30-60℃温度下高速搅拌20-80min得到成品；所述粘合剂为环氧树脂，湿润渗透剂为阴离子表面活性剂，有机溶剂为丙酮。
2、将粘胶纤维织造的梭织面料反复浸轧在步骤1制备的石墨烯驱蚊助剂中，浸轧处理的轧余率为80％，浸轧后的面料再经过脱水、60℃烘干120min、80℃烘焙5min，即得所述石墨烯驱蚊面料。
实施例3
本实施例提供了一种石墨烯驱蚊面料的制备方法，包括以下步骤：
1、石墨烯驱蚊助剂的制备
1.1根据表1的各组分及质量百分含量称取原料备用；所述石墨烯为氧化石墨烯，石墨烯厚度为10nm，比表面积为800m2/g。
1.2将石墨烯与水混合配成溶液，并移至反应釜中；
1.3将粘合剂、润湿渗透剂、有机溶剂加入上述反应釜中，在30-60℃温度下高速搅拌20-80min得到成品；所述粘合剂为水性聚氨酯，湿润渗透剂为阴离子表面活性剂，有机溶剂为四氢呋喃。
2、将石墨烯锦纶纤维织造的针织面料反复浸轧在步骤1制备的石墨烯驱蚊助剂中，浸轧处理的轧余率为90％，浸轧后的面料再经过脱水、80℃烘干60min、100℃烘焙3min，即得所述石墨烯驱蚊面料。
实施例4
本实施例提供了一种石墨烯驱蚊面料的制备方法，包括以下步骤：
1、石墨烯驱蚊助剂的制备
1.1根据表1的各组分及质量百分含量称取原料备用；所述石墨烯为氧化石墨烯，石墨烯厚度为5nm，比表面积为600m2/g。
1.2将石墨烯与水混合配成溶液，并移至反应釜中；
1.3将粘合剂、润湿渗透剂、有机溶剂加入上述反应釜中，在30-60℃温度下高速搅拌20-80min得到成品；所述粘合剂为水性聚氨酯，湿润渗透剂为阴离子表面活性剂，有机溶剂为四氢呋喃。
2、将锦纶纤维织造的针织面料反复浸轧在步骤1制备的石墨烯驱蚊助剂中，浸轧处理的轧余率为90％，浸轧后的面料再经过脱水、80℃烘干60min、100℃烘焙3min，即得所述石墨烯驱蚊面料。
实施例5
本实施例提供了一种石墨烯驱蚊面料的制备方法，包括以下步骤：
1、石墨烯驱蚊助剂的制备
1.1根据表1的各组分及质量百分含量称取原料备用；所述石墨烯为改性石墨烯，石墨烯厚度为5nm，比表面积为600m2/g。
1.2将石墨烯与水混合配成溶液，并移至反应釜中；
1.3将粘合剂、润湿渗透剂、有机溶剂加入上述反应釜中，在30-60℃温度下高速搅拌20-80min得到成品；所述粘合剂为硅油，湿润渗透剂为阳离子表面活性剂，有机溶剂为乙醇。
2、将石墨烯涤纶纤维织造的针织面料反复浸轧在步骤1制备的石墨烯驱蚊助剂中，浸轧处理的轧余率为90％，浸轧后的面料再经过脱水、80℃烘干60min、100℃烘焙3min，即得所述石墨烯驱蚊面料。
对比例1-5
本对比例与实施例1的方法基本相同，不同之处仅在于：所述石墨烯驱蚊助剂的各组分含量如表1所示。
表1
Figure BDA0001912265510000041
Figure BDA0001912265510000051
效果验证：
将各实施例和对比例制备的石墨烯驱蚊面料进行驱蚊效果测定，测定方法为：测定结果如表2所示。
表2
Figure BDA0001912265510000052
Figure BDA0001912265510000061
以上对本发明的具体实施例进行了描述。需要理解的是，本发明并不局限于上述特定实施方式，本领域技术人员可以在权利要求的范围内做出各种变化或修改，这并不影响本发明的实质内容。在不冲突的情况下，本申请的实施例和实施例中的特征可以任意相互组合。

Claims (9)

1.一种石墨烯驱蚊助剂，其特征在于，包括以下质量含量的各组分：1-10%石墨烯、润湿渗透剂1-20%、粘合剂2-8%、有机溶剂10-30%、余量为水；
所述润湿渗透剂为阴离子、阳离子或非离子表面活性剂中的至少一种。
2.根据权利要求1所述的石墨烯驱蚊助剂，其特征在于，所述石墨烯为氧化石墨烯、改性石墨烯、还原石墨烯中的一种或几种。
3.根据权利要求1所述的石墨烯驱蚊助剂，其特征在于，所述石墨烯采用氧化还原法、机械剥离法、化学气相沉积法或电化学剥离法制备。
4.根据权利要求2或3所述的石墨烯驱蚊助剂，其特征在于，所述石墨烯厚度为0.3-10nm，比表面积为450-800 m2/g。
5.根据权利要求1所述的石墨烯驱蚊助剂，其特征在于，所述粘合剂为硅烷偶联剂、环氧树脂、硅油、水性聚氨酯中的至少一种；
所述有机溶剂为乙醇、丙酮、四氢呋喃中的至少一种。
6.一种根据权利要求1所述的石墨烯驱蚊助剂的制备方法，其特征在于，包括以下步骤：
（1）称取各组分备用；
（2）将石墨烯与水混合配成溶液，并移至反应釜中；
（3）将粘合剂、润湿渗透剂、有机溶剂加入上述反应釜中，在30-60℃温度下高速搅拌20-80min得到成品。
7.一种石墨烯驱蚊面料的制备方法，其特征在于，包括以下步骤：
将面料反复浸轧在权利要求1所述的石墨烯驱蚊助剂中，浸轧后的面料再经过脱水、烘干、烘焙即得所述石墨烯驱蚊面料。
8.根据权利要求7所述的石墨烯驱蚊面料的制备方法，其特征在于，所述面料为梭织面料或者针织面料；
制备所述面料的纤维包括天然纤维、黏胶纤维、丙纶纤维、涤纶纤维、锦纶纤维、石墨烯锦纶纤维、石墨烯涤纶纤维、石墨烯丙纶纤维中的一种或几种。
9.根据权利要求7所述的石墨烯驱蚊面料的制备方法，其特征在于，所述浸轧处理的轧余率为70%-90%；
所述烘干温度为40-80℃，时间为60-240min；所述烘焙温度为90-130℃，时间为2-5min。
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