CN109457475A - 一种多功能整理剂 - Google Patents

一种多功能整理剂 Download PDF

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CN109457475A
CN109457475A CN201811195930.1A CN201811195930A CN109457475A CN 109457475 A CN109457475 A CN 109457475A CN 201811195930 A CN201811195930 A CN 201811195930A CN 109457475 A CN109457475 A CN 109457475A
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graphene oxide
finishing agent
acid
multifunction finishing
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CN109457475B (zh
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徐仕翀
张冬梅
李季
刘博�
李海波
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Jilin Normal University
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Abstract

本发明公开了一种多功能整理剂，其原料包括：壳聚糖、丝胶、二氧化钛水溶胶、芦荟苷、茶多酚、季铵盐、乙二胺四乙酸二酐、多元酸、葡萄糖、六(4‑氨基苯氧基)环三磷腈、聚磷酸铵、碳酸胍、氧化石墨烯、蒙脱土、氯化镁、鸡蛋蛋白、聚乙烯醇、偶联剂、醋酸、溶剂。本发明提出的多功能整理剂，其配方合理，整理后的织物抗菌性好，阻燃性能优异，且手感柔软、抗折皱、耐水洗。

Description

一种多功能整理剂
技术领域
本发明涉及纺织技术领域，尤其涉及一种多功能整理剂。
背景技术
棉织物因具有良好的吸湿性及一定的耐磨性，不易产生静电，透气性好等特点，被广泛用于服装、家居用品和各种产业用纺织品。随着生活水平的不断提高，人们不但要求棉织物具有保暖、舒适的基本性能，还要求棉织物具有免烫、抗菌、阻燃等特殊功能，但是棉织物也具有以下缺点：在服用过程中极易起皱，难以保持平整的外观，且其属于多孔材料，在使用过程中容易吸附菌类，发生霉变，同时其氧指数较低，在18％左右，属于易燃材料，这些缺点阻碍了棉织物的发展。
发明内容
基于背景技术存在的技术问题，本发明提出了一种多功能整理剂，其配方合理，整理后的织物抗菌性好，阻燃性能优异，且手感柔软、抗折皱、耐水洗。
本发明提出的一种多功能整理剂，其原料按重量份包括：壳聚糖0.05-0.2份、丝胶1-3.5份、二氧化钛水溶胶2-6份、芦荟苷0.05-0.5份、茶多酚0.01-0.1份、季铵盐0.5-2份、乙二胺四乙酸二酐0.15-0.7份、多元酸0.7-3.2份、葡萄糖0.5-2.5份、六(4-氨基苯氧基)环三磷腈2-7份、聚磷酸铵2-8.5份、碳酸胍3-6份、氧化石墨烯0.3-1.5份、蒙脱土0.5-2.8份、氯化镁0.05-0.2份、鸡蛋蛋白0.1-0.55份、聚乙烯醇0.5-2份、偶联剂0.1-0.3份、醋酸0.01-0.15份、溶剂100份。
优选地，所述壳聚糖为香兰醛改性壳聚糖、聚乙二醇改性壳聚糖中的一种或者两种的混合物。
优选地，所述二氧化钛水溶胶的固含量为3-5.8wt％。
优选地，所述季铵盐为双十八烷基二甲基氯化铵、缩水甘油三甲基氯化铵、4-氨基-十二烷基氯化吡啶、4-(1-萘酰)氨基-十二烷基溴化吡啶中的一种或者多种的混合物。
优选地，所述多元酸为环戊烷四羧酸、环己烷六羧酸、柠檬酸、马来酸、植酸、3，3′，4，4′-二苯甲酮四羧酸、5-苯甲酰苹果酸-1，2，4-苯三甲酸中的一种或者多种的混合物。
优选地，所述氧化石墨烯为改性氧化石墨烯；所述改性氧化石墨烯按照以下工艺进行制备：将硼酸、季戊四醇、带水剂和水混合，升温至60-75℃，反应3-8h，反应结束后过滤、烘干得到物料A；在冰水浴条件下，将三聚氰氯加入丙酮中，调节pH值为5-6，加入物料A，搅拌反应2-5h，反应结束后静置、过滤、干燥得到物料B；将物料B加入1，4-二氧六环中，加入氨水，升温至80-90℃，反应3-4h，反应结束后静置、过滤、干燥得到物料C；将氧化石墨烯进行酰氯化，然后加入二甲基甲酰胺中，加入物料C混合均匀，在80-90℃下搅拌反应20-30h，反应结束后过滤、干燥得到所述改性氧化石墨烯。
优选地，在改性氧化石墨烯的制备过程中，所述带水剂为苯与甲苯的混合物。
优选地，在改性氧化石墨烯的制备过程中，所述氨水的浓度为1mol/L；硼酸、季戊四醇的摩尔比为2-2.3：1；三聚氰氯、物料A的摩尔比为2-2.5：1；物料B、氨水的摩尔体积比为1：4-4.5mol/L；氧化石墨烯、物料C的质量比为3-5：4-7。
优选地，所述偶联剂为偶联剂KH-310、γ-氨丙基三乙氧基硅烷、硅烷偶联剂KH-560、硅烷偶联剂KH-902中的一种或者多种的混合物。
优选地，所述溶剂为水、二甲基甲酰胺中的一种或者两种的混合物。
本发明所述多功能整理剂，其原料中，芦荟苷能改变织物的内部构象，提高其热稳定性和结晶度，与壳聚糖、二氧化钛水溶胶、茶多酚、季铵盐复配后具有协同作用，使整理后的织物具有优异的抗菌性和抗紫外线性能，且耐洗牢度好；壳聚糖与丝胶加入体系中，其中的氨基能与棉纤维发生反应，从而附着在棉织物上，使整理后的织物润湿性以及手感性好；氯化镁加入体系中，与偶联剂协同，提高了棉织物的防紫外线性能，其UPF值可达30+，同时使织物的柔软性得到一定的提升；多元酸与乙二胺四乙酸二酐配合加入体系中，并配合加入了聚乙烯醇和葡萄糖，一方面，多元酸和乙二胺四乙酸二酐能与棉纤维上的羟基基团发生交联反应，提高了织物的折皱回复角，经整理后的棉织物平整度等级高、手感柔软舒适、强力保留率高，同时聚乙烯醇在织物上形成了网状薄膜，有效的阻止了多元酸与织物内部纤维素的羟基所形成的酯键的断裂，提高了织物的耐水洗性，加入的葡萄糖能进入纤维内部，在不同的多元酸分子间形成了共价桥接，进一步提高了织物的折皱回复角，同时降低了因多元酸的加入引起的强力损失；六(4-氨基苯氧基)环三磷腈加入体系中，键合在织物的表面，在燃烧的过程中，会裂解生成具有淬灭效果的含磷碎片，与聚磷酸铵、碳酸胍、氧化石墨烯、蒙脱土和鸡蛋蛋白复配，发挥气相和凝聚相的协同作用，更易生成不燃性气体，在气相稀释可燃性气体浓度，明显减短了续燃时间，同时促进了织物纤维素的脱水成炭，二者共同作用发挥高效的阻燃作用，且处理后织物的白度、断裂强度以及撕破强力下降小；优选方式，改性氧化石墨烯的制备过程中，首先以硼酸、季戊四醇为原料，控制反应的条件，使硼酸、季戊四醇发生了反应，得到了含羟基的硼化物物料A，之后以物料A为原料，使其与三聚氰氯进行反应，通过控制反应的条件，使物料A中的羟基与三聚氰氯中的氯发生了反应，从而将两分子三聚氰氯结合为一体，得到了物料B，物料B与氨水混合，控制反应的条件，氨水与物料B中剩余的氯发生了反应，得到了含氨基的物料C，与酰氯化的氧化石墨烯作用，通过酰氯与氨基的作用，将物料C结合到了氧化石墨烯的表面，得到了改性氧化石墨烯，将其作为整理剂的原料，其能通过改性氧化石墨烯表面未反应的羧基与氨基与棉纤维的羟基发生作用，从而键合到了棉纤维的表面，且覆盖率高，一方面，与六(4-氨基苯氧基)环三磷腈、聚磷酸铵、碳酸胍、蒙脱土和鸡蛋蛋白配合，发挥磷、氮、硼的协同作用，赋予处理后的织物优异的阻燃性，一方面，降低了织物表面的电阻值，改善了织物的抗静电性；同时茶多酚的加入将氧化石墨烯未反应的含氧官能团脱出，进一步提高了织物的阻燃性。
具体实施方式
下面，通过具体实施例对本发明的技术方案进行详细说明。
实施例1
本发明提出的一种多功能整理剂，其原料按重量份包括：壳聚糖0.2份、丝胶1份、二氧化钛水溶胶6份、芦荟苷0.05份、茶多酚0.1份、季铵盐0.5份、乙二胺四乙酸二酐0.7份、多元酸0.7份、葡萄糖2.5份、六(4-氨基苯氧基)环三磷腈2份、聚磷酸铵8.5份、碳酸胍3份、氧化石墨烯1.5份、蒙脱土0.5份、氯化镁0.2份、鸡蛋蛋白0.1份、聚乙烯醇2份、偶联剂0.1份、醋酸0.15份、溶剂100份。
实施例2
本发明提出的一种多功能整理剂，其原料按重量份包括：壳聚糖0.05份、丝胶3.5份、二氧化钛水溶胶2份、芦荟苷0.5份、茶多酚0.01份、季铵盐2份、乙二胺四乙酸二酐0.15份、多元酸3.2份、葡萄糖0.5份、六(4-氨基苯氧基)环三磷腈7份、聚磷酸铵2份、碳酸胍6份、氧化石墨烯0.3份、蒙脱土2.8份、氯化镁0.05份、鸡蛋蛋白0.55份、聚乙烯醇0.5份、偶联剂0.3份、醋酸0.01份、溶剂100份。
实施例3
本发明提出的一种多功能整理剂，其原料按重量份包括：壳聚糖0.17份、丝胶1.7份、二氧化钛水溶胶5.6份、芦荟苷0.2份、茶多酚0.08份、季铵盐1份、乙二胺四乙酸二酐0.6份、多元酸1份、葡萄糖2.3份、六(4-氨基苯氧基)环三磷腈3.2份、聚磷酸铵8份、碳酸胍3.8份、氧化石墨烯1.3份、蒙脱土0.7份、氯化镁0.17份、鸡蛋蛋白0.2份、聚乙烯醇1.7份、偶联剂0.18份、醋酸0.1份、溶剂100份；
其中，所述壳聚糖为香兰醛改性壳聚糖；
所述二氧化钛水溶胶的固含量为3wt％；
所述季铵盐为双十八烷基二甲基氯化铵；
所述多元酸为环戊烷四羧酸；
所述氧化石墨烯为改性氧化石墨烯；所述改性氧化石墨烯按照以下工艺进行制备：将硼酸、季戊四醇、带水剂和水混合，升温至60℃，反应8h，反应结束后过滤、烘干得到物料A；在冰水浴条件下，将三聚氰氯加入丙酮中，调节pH值为5，加入物料A，搅拌反应5h，反应结束后静置、过滤、干燥得到物料B；将物料B加入1,4-二氧六环中，加入氨水，升温至80℃，反应4h，反应结束后静置、过滤、干燥得到物料C；将氧化石墨烯进行酰氯化，然后加入二甲基甲酰胺中，加入物料C混合均匀，在80℃下搅拌反应30h，反应结束后过滤、干燥得到所述改性氧化石墨烯；
在改性氧化石墨烯的制备过程中，所述带水剂为苯与甲苯的混合物；所述氨水的浓度为1mol/L；硼酸、季戊四醇的摩尔比为2：1；三聚氰氯、物料A的摩尔比为2.5：1；物料B、氨水的摩尔体积比为1：4mol/L；氧化石墨烯、物料C的质量比为5：4；
所述偶联剂为γ-氨丙基三乙氧基硅烷、硅烷偶联剂KH-902的混合物；
所述溶剂为水。
实施例4
本发明提出的一种多功能整理剂，其原料按重量份包括：壳聚糖0.09份、丝胶3.3份、二氧化钛水溶胶3.5份、芦荟苷0.4份、茶多酚0.04份、季铵盐1.7份、乙二胺四乙酸二酐0.32份、多元酸3份、葡萄糖0.9份、六(4-氨基苯氧基)环三磷腈6.5份、聚磷酸铵4份、碳酸胍5.7份、氧化石墨烯0.6份、蒙脱土2.5份、氯化镁0.1份、鸡蛋蛋白0.42份、聚乙烯醇1份、偶联剂0.27份、醋酸0.06份、溶剂100份；
其中，所述壳聚糖为聚乙二醇改性壳聚糖；
所述二氧化钛水溶胶的固含量为5.8wt％；
所述季铵盐为缩水甘油三甲基氯化铵、4-(1-萘酰)氨基-十二烷基溴化吡啶的混合物；
所述多元酸为环己烷六羧酸、植酸、3,3′,4,4′-二苯甲酮四羧酸的混合物；
所述氧化石墨烯为改性氧化石墨烯；所述改性氧化石墨烯按照以下工艺进行制备：将硼酸、季戊四醇、带水剂和水混合，升温至75℃，反应3h，反应结束后过滤、烘干得到物料A；在冰水浴条件下，将三聚氰氯加入丙酮中，调节pH值为6，加入物料A，搅拌反应2h，反应结束后静置、过滤、干燥得到物料B；将物料B加入1,4-二氧六环中，加入氨水，升温至90℃，反应3h，反应结束后静置、过滤、干燥得到物料C；将氧化石墨烯进行酰氯化，然后加入二甲基甲酰胺中，加入物料C混合均匀，在90℃下搅拌反应20h，反应结束后过滤、干燥得到所述改性氧化石墨烯；
在改性氧化石墨烯的制备过程中，所述带水剂为苯与甲苯的混合物；所述氨水的浓度为1mol/L；硼酸、季戊四醇的摩尔比为2.3：1；三聚氰氯、物料A的摩尔比为2：1；物料B、氨水的摩尔体积比为1：4.5mol/L；氧化石墨烯、物料C的质量比为3：7；
所述偶联剂为偶联剂KH-310；
所述溶剂为二甲基甲酰胺。
实施例5
本发明提出的一种多功能整理剂，其原料按重量份包括：壳聚糖0.14份、丝胶2.7份、二氧化钛水溶胶4.3份、芦荟苷0.32份、茶多酚0.05份、季铵盐1.5份、乙二胺四乙酸二酐0.5份、多元酸2.4份、葡萄糖1.8份、六(4-氨基苯氧基)环三磷腈5.2份、聚磷酸铵6.3份、碳酸胍4.2份、氧化石墨烯1份、蒙脱土1.7份、氯化镁0.12份、鸡蛋蛋白0.35份、聚乙烯醇1.7份、偶联剂0.2份、醋酸0.1份、溶剂100份；
其中，所述壳聚糖为香兰醛改性壳聚糖、聚乙二醇改性壳聚糖的混合物，且香兰醛改性壳聚糖、聚乙二醇改性壳聚糖的重量比为3：2；
所述二氧化钛水溶胶的固含量为5wt％；
所述季铵盐为双十八烷基二甲基氯化铵、缩水甘油三甲基氯化铵、4-(1-萘酰)氨基-十二烷基溴化吡啶的混合物，且双十八烷基二甲基氯化铵、缩水甘油三甲基氯化铵、4-(1-萘酰)氨基-十二烷基溴化吡啶的重量比为3：5：1；
所述多元酸为环戊烷四羧酸、柠檬酸、马来酸、植酸、5-苯甲酰苹果酸-1,2,4-苯三甲酸的混合物；
所述氧化石墨烯为改性氧化石墨烯；所述改性氧化石墨烯按照以下工艺进行制备：将硼酸、季戊四醇、带水剂和水混合，升温至68℃，反应5h，反应结束后过滤、烘干得到物料A；在冰水浴条件下，将三聚氰氯加入丙酮中，调节pH值为5，加入物料A，搅拌反应3.8h，反应结束后静置、过滤、干燥得到物料B；将物料B加入1,4-二氧六环中，加入氨水，升温至85℃，反应3.7h，反应结束后静置、过滤、干燥得到物料C；将氧化石墨烯进行酰氯化，然后加入二甲基甲酰胺中，加入物料C混合均匀，在85℃下搅拌反应26h，反应结束后过滤、干燥得到所述改性氧化石墨烯；
在改性氧化石墨烯的制备过程中，所述带水剂为苯与甲苯的混合物；所述氨水的浓度为1mol/L；硼酸、季戊四醇的摩尔比为2.1：1；三聚氰氯、物料A的摩尔比为2.3：1；物料B、氨水的摩尔体积比为1：4.2mol/L；氧化石墨烯、物料C的质量比为4：5；
所述偶联剂为偶联剂KH-310、γ-氨丙基三乙氧基硅烷、硅烷偶联剂KH-560、硅烷偶联剂KH-902的混合物；
所述溶剂为水、二甲基甲酰胺的混合物，且水、二甲基甲酰胺的体积比为3：2。
实施例6
本发明提出的一种多功能整理剂，其原料按重量份包括：壳聚糖0.14份、丝胶2.7份、二氧化钛水溶胶4.3份、芦荟苷0.32份、茶多酚0.05份、季铵盐1.5份、乙二胺四乙酸二酐0.5份、多元酸2.4份、葡萄糖1.8份、六(4-氨基苯氧基)环三磷腈5.2份、聚磷酸铵6.3份、碳酸胍4.2份、氧化石墨烯1份、蒙脱土1.7份、氯化镁0.12份、鸡蛋蛋白0.35份、聚乙烯醇1.7份、偶联剂0.2份、醋酸0.1份、溶剂100份；
其中，所述壳聚糖为香兰醛改性壳聚糖、聚乙二醇改性壳聚糖的混合物，且香兰醛改性壳聚糖、聚乙二醇改性壳聚糖的重量比为3：2；
所述二氧化钛水溶胶的固含量为5wt％；
所述季铵盐为双十八烷基二甲基氯化铵、缩水甘油三甲基氯化铵、4-(1-萘酰)氨基-十二烷基溴化吡啶的混合物，且双十八烷基二甲基氯化铵、缩水甘油三甲基氯化铵、4-(1-萘酰)氨基-十二烷基溴化吡啶的重量比为3：5：1；
所述多元酸为环戊烷四羧酸、柠檬酸、马来酸、植酸、5-苯甲酰苹果酸-1,2,4-苯三甲酸的混合物；
所述偶联剂为偶联剂KH-310、γ-氨丙基三乙氧基硅烷、硅烷偶联剂KH-560、硅烷偶联剂KH-902的混合物；
所述溶剂为水、二甲基甲酰胺的混合物，且水、二甲基甲酰胺的体积比为3：2。
对比例1
一种织物整理剂，其原料按重量份包括：壳聚糖0.14份、丝胶2.7份、二氧化钛水溶胶4.3份、芦荟苷0.32份、茶多酚0.05份、季铵盐1.5份、乙二胺四乙酸二酐0.5份、多元酸2.4份、葡萄糖1.8份、六(4-氨基苯氧基)环三磷腈5.2份、聚磷酸铵6.3份、碳酸胍4.2份、蒙脱土1.7份、氯化镁0.12份、鸡蛋蛋白0.35份、聚乙烯醇1.7份、偶联剂0.2份、醋酸0.1份、溶剂100份；
其中，所述壳聚糖为香兰醛改性壳聚糖、聚乙二醇改性壳聚糖的混合物，且香兰醛改性壳聚糖、聚乙二醇改性壳聚糖的重量比为3：2；
所述二氧化钛水溶胶的固含量为5wt％；
所述季铵盐为双十八烷基二甲基氯化铵、缩水甘油三甲基氯化铵、4-(1-萘酰)氨基-十二烷基溴化吡啶的混合物，且双十八烷基二甲基氯化铵、缩水甘油三甲基氯化铵、4-(1-萘酰)氨基-十二烷基溴化吡啶的重量比为3：5：1；
所述多元酸为环戊烷四羧酸、柠檬酸、马来酸、植酸、5-苯甲酰苹果酸-1,2,4-苯三甲酸的混合物；
所述偶联剂为偶联剂KH-310、γ-氨丙基三乙氧基硅烷、硅烷偶联剂KH-560、硅烷偶联剂KH-902的混合物；
所述溶剂为水、二甲基甲酰胺的混合物，且水、二甲基甲酰胺的体积比为3：2。
利用本发明实施例1-6以及对比例1中的整理剂对棉织物进行两浸两轧整理，然后将浸轧后的织物在100℃下预烘3min，再在180℃下焙烘2min，经过标准水洗并烘干后进行测试。
以未整理的织物为对照样进行检测。
1、折皱回复角
按照AATCC 66-2008《织物折皱回复性：回复角法》使用M003A型折皱回复角测试仪(SDL Atlas公司)进行测定。试样尺寸为40mm×15mm，6经6纬，在温度(21±1)℃，相对湿度65％±2％条件下，至少平衡4h后进行测定。采用折皱回复角(经+纬)表征织物的折皱回复性能。
2、断裂强力测试
按照GB/T3923-1997《纺织品织物拉伸性能第1部分：断裂强力和断裂伸长率的测定条样法》测定，测定织物的径向断裂强力。所用试样有效宽度为50mm，隔距长度为100mm，测试3次取其平均值作为参考值。根据断裂强力计算织物的强为保留率。计算公式为：强力保留率(％)＝整理后织物断裂强力/原布断裂强力×100％。
3、防紫外性能测试
按照AATCC Test Method 183-1998标准进行测试，防紫外效果用紫外线防护因子(UPF)及UPF等级表示如下：UPF＜15不能标为防晒或防紫外线产品，UPF在15-24之间，为良好的防紫外线性能，UPF在25-39非常好的防紫外线性能，UPF≥40，非常优异的防紫外线性能。
4、燃烧性能测试
按GB/T 5455-1997《纺织品阻燃性能试验垂直法》，采用HD815A型织物阻燃性能测试仪对整理前后的织物进行垂直燃烧性能测试。
对实施例1-6以及对比例1中所述整理剂整理后的棉织物进行性能检测的结果如下表所示：
折皱回复角 强力保留率 UPF值 碳长 续燃时间 阴燃时间
实施例1 266° 95.67％ 47.8 11mm 0s 0s
实施例2 265° 96.53％ 49.4 8.5mm 0s 0s
实施例3 271° 95.5％ 52.5 8mm 0s 0s
实施例4 269° 96.9％ 54.7 7.3mm 0s 0s
实施例5 278° 97.1％ 59.6 6.5mm 0s 0s
实施例6 268° 96.7％ 51.3 8.3mm 0s 0s
对比例1 267° 96.5％ 51.2 11.9 5.8s 9.3s
对照样 121° 6.5 300 23.5 45
另外，对本发明实施例1-6以及对比例1中整理剂整理的棉织物的氧指数进行检测，实施例1-6以及对比例1的氧指数分别为41.3％、41.2％、43.5％、43.8％、44.5％、41.7％、36.1％；实施例1-6中的整理剂整理的棉织物对金黄色葡萄球菌、大肠杆菌、白色念珠菌、红色毛癣菌的抑菌率分别达到99.3％、99.7％、96.7％、99.2％以上，经10次洗涤后对金黄色葡萄球菌、大肠杆菌、白色念珠菌、红色毛癣菌的抑菌率仍达到89.99％以上。
以上所述，仅为本发明较佳的具体实施方式，但本发明的保护范围并不局限于此，任何熟悉本技术领域的技术人员在本发明揭露的技术范围内，根据本发明的技术方案及其发明构思加以等同替换或改变，都应涵盖在本发明的保护范围之内。

Claims (10)

1.一种多功能整理剂，其特征在于，其原料按重量份包括：壳聚糖0.05-0.2份、丝胶1-3.5份、二氧化钛水溶胶2-6份、芦荟苷0.05-0.5份、茶多酚0.01-0.1份、季铵盐0.5-2份、乙二胺四乙酸二酐0.15-0.7份、多元酸0.7-3.2份、葡萄糖0.5-2.5份、六(4-氨基苯氧基)环三磷腈2-7份、聚磷酸铵2-8.5份、碳酸胍3-6份、氧化石墨烯0.3-1.5份、蒙脱土0.5-2.8份、氯化镁0.05-0.2份、鸡蛋蛋白0.1-0.55份、聚乙烯醇0.5-2份、偶联剂0.1-0.3份、醋酸0.01-0.15份、溶剂100份。
2.根据权利要求1所述多功能整理剂，其特征在于，所述壳聚糖为香兰醛改性壳聚糖、聚乙二醇改性壳聚糖中的一种或者两种的混合物。
3.根据权利要求1或2所述多功能整理剂，其特征在于，所述二氧化钛水溶胶的固含量为3-5.8wt％。
4.根据权利要求1-3中任一项所述多功能整理剂，其特征在于，所述季铵盐为双十八烷基二甲基氯化铵、缩水甘油三甲基氯化铵、4-氨基-十二烷基氯化吡啶、4-(1-萘酰)氨基-十二烷基溴化吡啶中的一种或者多种的混合物。
5.根据权利要求1-4中任一项所述多功能整理剂，其特征在于，所述多元酸为环戊烷四羧酸、环己烷六羧酸、柠檬酸、马来酸、植酸、3，3′，4，4′-二苯甲酮四羧酸、5-苯甲酰苹果酸-1，2，4-苯三甲酸中的一种或者多种的混合物。
6.根据权利要求1-5中任一项所述多功能整理剂，其特征在于，所述氧化石墨烯为改性氧化石墨烯；所述改性氧化石墨烯按照以下工艺进行制备：将硼酸、季戊四醇、带水剂和水混合，升温至60-75℃，反应3-8h，反应结束后过滤、烘干得到物料A；在冰水浴条件下，将三聚氰氯加入丙酮中，调节pH值为5-6，加入物料A，搅拌反应2-5h，反应结束后静置、过滤、干燥得到物料B；将物料B加入1，4-二氧六环中，加入氨水，升温至80-90℃，反应3-4h，反应结束后静置、过滤、干燥得到物料C；将氧化石墨烯进行酰氯化，然后加入二甲基甲酰胺中，加入物料C混合均匀，在80-90℃下搅拌反应20-30h，反应结束后过滤、干燥得到所述改性氧化石墨烯。
7.根据权利要求6所述多功能整理剂，其特征在于，在改性氧化石墨烯的制备过程中，所述带水剂为苯与甲苯的混合物。
8.根据权利要求7或8所述多功能整理剂，其特征在于，在改性氧化石墨烯的制备过程中，所述氨水的浓度为1mol/L；硼酸、季戊四醇的摩尔比为2-2.3：1；三聚氰氯、物料A的摩尔比为2-2.5：1；物料B、氨水的摩尔体积比为1：4-4.5mol/L；氧化石墨烯、物料C的质量比为3-5：4-7。
9.根据权利要求1-8中任一项所述多功能整理剂，其特征在于，所述偶联剂为偶联剂KH-310、γ-氨丙基三乙氧基硅烷、硅烷偶联剂KH-560、硅烷偶联剂KH-902中的一种或者多种的混合物。
10.根据权利要求1-9中任一项所述多功能整理剂，其特征在于，所述溶剂为水、二甲基甲酰胺中的一种或者两种的混合物。
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