CN109370099A - 一种pvc整版墙壁装饰膜 - Google Patents

一种pvc整版墙壁装饰膜 Download PDF

Info

Publication number
CN109370099A
CN109370099A CN201811019078.2A CN201811019078A CN109370099A CN 109370099 A CN109370099 A CN 109370099A CN 201811019078 A CN201811019078 A CN 201811019078A CN 109370099 A CN109370099 A CN 109370099A
Authority
CN
China
Prior art keywords
parts
pvc
nanometer
full page
wall fitting
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811019078.2A
Other languages
English (en)
Inventor
李永平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201811019078.2A priority Critical patent/CN109370099A/zh
Publication of CN109370099A publication Critical patent/CN109370099A/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2497/00—Characterised by the use of lignin-containing materials
    • C08J2497/02—Lignocellulosic material, e.g. wood, straw or bagasse
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/06—Pretreated ingredients and ingredients covered by the main groups C08K3/00 - C08K7/00
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/221—Oxides; Hydroxides of metals of rare earth metal
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/042—Graphene or derivatives, e.g. graphene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明所述一种PVC整版墙壁装饰膜，按照重量比，其原料组成为：PVC胶料100份，钛白粉10‑15份、增塑剂10‑30份、钛酸酯1‑2份、纳米碳酸钙2‑6份、钛酸钙3～5份、加工助剂6‑18份，所述加工助剂包括木质素纤维0.2‑0.4份，纳米火山泥2‑4份，氧化镧0.3‑0.6份，通过木质素纤维、纳米火山泥和氧化镧的加入，其韧性好，实现其超宽的特性，而且不易收缩，使用寿命长。

Description

一种PVC整版墙壁装饰膜
技术领域
本发明属于PVC技术领域，具体地说，涉及一种PVC整版墙壁装饰膜。
背景技术
聚氯乙烯英文简称PVC，随着PVC薄膜低毒、阻燃、耐寒、环保的优良性能，越来越得到广大的用途，广泛应用于证件、薄册、包装、箱包、服装、鞋类、汽车装璜等领域，发展到了日常生活领域中处处可见到PVC产品。由些可见，PVC薄膜的需求量越来越大。
PVC薄膜主要成份为聚氯乙烯，另有加入其他成分来增强其耐热性，韧性，延展性等。PVC薄膜是当今世界上深受喜爱、颇为流行并且也被广泛应用的一种合成材料。PVC薄膜的全球使用量在各种合成材料中高居第二。在可以生产三维表面膜的材料中，PVC薄膜是最适合的材料。
但是，PVC薄膜，尤其是装饰膜，在裁剪和使用时容易收缩，发生褶皱，影响美观，而且裁剪时，由于发生收缩，造成尺寸缩短。
发明内容
本发明克服了现有技术中的缺点，提供了一种PVC整版墙壁装饰膜，具有较好的延展性，而且实现装饰膜的零收缩，在裁剪和使用时均为零收缩。
为了解决上述技术问题，本发明是通过以下技术方案实现的：
一种PVC整版墙壁装饰膜，按照重量比，其原料组成为：PVC胶料100份，钛白粉10-15份、增塑剂10-30份、钛酸酯1-2份、纳米碳酸钙2-6份、钛酸钙3～5份、加工助剂6-18份，所述加工助剂包括木质素纤维0.2-0.4份，纳米火山泥2-4份，氧化镧0.3-0.6份。
进一步，所述增塑剂包括二乙二醇1-3份、草酸1-3份、柠檬酸2-5份、苯酐3-6份和苯甲酸4-8份。
进一步，所述加工助剂还包括竹纤维1-3份、改性氧化石墨烯溶液1-3份、纳米火山泥0.1-0.2份、硅石粉0.5-1份和纳米二氧化锑1-2份。
进一步，所述增塑剂包括二乙二醇2份、草酸2份、柠檬酸4份、苯酐4份和苯甲酸4份。
进一步，所述加工助剂包括木质素纤维0.3份，纳米火山泥3份，氧化镧0.5份、竹纤维2份、改性氧化石墨烯溶液2份、云母粉0.15份、硅石粉0.8份和纳米二氧化锑1.5份。
与现有技术相比，本发明的有益效果是：
本发明所述一种PVC整版墙壁装饰膜，按照重量比，其原料组成为：PVC胶料100份，钛白粉10-15份、增塑剂10-30份、钛酸酯1-2份、纳米碳酸钙2-6份、钛酸钙3～5份、加工助剂6-18份，所述加工助剂包括木质素纤维0.2-0.4份，纳米火山泥2-4份，氧化镧0.3-0.6份，通过木质素纤维、纳米火山泥和氧化镧的加入，其韧性好，实现其超宽的特性，而且不易收缩，使用寿命长。
具体实施方式
以下对本发明的优选实施例进行说明，应当理解，此处所描述的优选实施例仅用于说明和解释本发明，并不用于限定本发明。
一种PVC整版墙壁装饰膜，按照重量比，其原料组成为：PVC胶料100份，钛白粉12份、增塑剂16份、钛酸酯1-2份、纳米碳酸钙4份、钛酸钙4份、加工助剂10.25份，增塑剂包括二乙二醇2份、草酸2份、柠檬酸4份、苯酐4份和苯甲酸4份，加工助剂包括木质素纤维0.3份，纳米火山泥3份，氧化镧0.5份、竹纤维2份、改性氧化石墨烯溶液2份、云母粉0.15份、硅石粉0.8份和纳米二氧化锑1.5份，木质素纤维、竹纤维和云母粉增强其延展性，以实现超宽软玻璃的制备，纳米二氧化锑使其不易收缩，而且提高最终薄膜产品的耐老化性能。
各项指标如下表：
最后应说明的是：以上仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换，但是凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (5)

1.一种PVC整版墙壁装饰膜，其特征在于，按照重量比，其原料组成为：PVC胶料100份，钛白粉10-15份、增塑剂10-30份、钛酸酯1-2份、纳米碳酸钙2-6份、钛酸钙3～5份、加工助剂6-18份，所述加工助剂包括木质素纤维0.2-0.4份，纳米火山泥2-4份，氧化镧0.3-0.6份。
2.根据权利要求1所述一种PVC整版墙壁装饰膜，其特征在于，所述增塑剂包括二乙二醇1-3份、草酸1-3份、柠檬酸2-5份、苯酐3-6份和苯甲酸4-8份。
3.根据权利要求2所述一种PVC整版墙壁装饰膜，其特征在于，所述加工助剂还包括竹纤维1-3份、改性氧化石墨烯溶液1-3份、云母粉0.1-0.2份、硅石粉0.5-1份和纳米二氧化锑1-2份。
4.根据权利要求3所述一种PVC整版墙壁装饰膜，其特征在于，所述增塑剂包括二乙二醇2份、草酸2份、柠檬酸4份、苯酐4份和苯甲酸4份。
5.根据权利要求4所述一种PVC整版墙壁装饰膜，其特征在于，所述加工助剂包括木质素纤维0.3份，纳米火山泥3份，氧化镧0.5份、竹纤维2份、改性氧化石墨烯溶液2份、云母粉0.15份、硅石粉0.8份和纳米二氧化锑1.5份。
CN201811019078.2A 2018-09-03 2018-09-03 一种pvc整版墙壁装饰膜 Withdrawn CN109370099A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811019078.2A CN109370099A (zh) 2018-09-03 2018-09-03 一种pvc整版墙壁装饰膜

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811019078.2A CN109370099A (zh) 2018-09-03 2018-09-03 一种pvc整版墙壁装饰膜

Publications (1)

Publication Number Publication Date
CN109370099A true CN109370099A (zh) 2019-02-22

Family

ID=65404211

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811019078.2A Withdrawn CN109370099A (zh) 2018-09-03 2018-09-03 一种pvc整版墙壁装饰膜

Country Status (1)

Country Link
CN (1) CN109370099A (zh)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114133680A (zh) * 2021-12-02 2022-03-04 湖南湘鹤集团电缆科技股份有限公司 一种pvc材料及其用于电线或电缆的制备方法、用途

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103029311A (zh) * 2012-12-12 2013-04-10 浙江博泰塑胶有限公司 一种半硬质pvc装饰膜片
CN103059473A (zh) * 2013-01-09 2013-04-24 浙江明士达新材料有限公司 一种超宽环保装饰膜材料及其制备工艺
CN105462115A (zh) * 2015-12-24 2016-04-06 黄山豪泰塑胶有限公司 一种装饰用pvc膜

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103029311A (zh) * 2012-12-12 2013-04-10 浙江博泰塑胶有限公司 一种半硬质pvc装饰膜片
CN103059473A (zh) * 2013-01-09 2013-04-24 浙江明士达新材料有限公司 一种超宽环保装饰膜材料及其制备工艺
CN105462115A (zh) * 2015-12-24 2016-04-06 黄山豪泰塑胶有限公司 一种装饰用pvc膜

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114133680A (zh) * 2021-12-02 2022-03-04 湖南湘鹤集团电缆科技股份有限公司 一种pvc材料及其用于电线或电缆的制备方法、用途

Similar Documents

Publication Publication Date Title
JP2018517654A5 (zh)
WO2017197933A3 (zh) 一种高性能玻璃纤维组合物及其玻璃纤维和复合材料
CN109370099A (zh) 一种pvc整版墙壁装饰膜
CN113861824B (zh) 一种艺术涂料及其制备方法和应用
CN103709571B (zh) 一种光扩散改性pmma材料及其制备方法
CN106084918A (zh) 一种多功能环保涂料
CN109337233A (zh) 一种零收缩地板膜
CN206011913U (zh) 一种具有双重防火功能的广告材料布
CN107841064A (zh) 一种pvc台布塑料及其制备方法
CN109280289A (zh) 一种零收缩装饰膜
CN204674139U (zh) 一种汽车贴膜
CN103321045A (zh) 一种竹纤维织物上浆专用组合物
CN109385022A (zh) 一种多层贴合超透薄膜
AR017508A1 (es) Metodo para producir una suspension acuosa con alto contenido de solidos de carbonato de calcio resistente a acidos, y suspension asi producida para uso enla fabricacion de papel
CN109401110A (zh) 一种超耐变形的pvc卷材
CN109354792A (zh) 一种零收缩超宽超透薄膜
CN202601253U (zh) 透明双色扁线
CN105778930A (zh) 一种环保阻燃剂
CN104945736A (zh) 一种高性能的bopp消光膜
CN105256422A (zh) 一种悬垂挺括混纺纤维
CN109294112A (zh) 一种微收缩超透薄膜
CN103897296A (zh) 低成本阻燃pvc改性塑料组合物
CN109370103A (zh) 一种零收缩的超透薄膜
CN109280290A (zh) 一种聚氯乙烯pvc超透薄膜
CN210062269U (zh) 一种卫生用品的防静电阻燃复合纸

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20190222