CN109401110A - 一种超耐变形的pvc卷材 - Google Patents

一种超耐变形的pvc卷材 Download PDF

Info

Publication number
CN109401110A
CN109401110A CN201811018664.5A CN201811018664A CN109401110A CN 109401110 A CN109401110 A CN 109401110A CN 201811018664 A CN201811018664 A CN 201811018664A CN 109401110 A CN109401110 A CN 109401110A
Authority
CN
China
Prior art keywords
parts
super
pvc
deformation resistant
roll material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811018664.5A
Other languages
English (en)
Inventor
李永平
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to CN201811018664.5A priority Critical patent/CN109401110A/zh
Publication of CN109401110A publication Critical patent/CN109401110A/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18—Manufacture of films or sheets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/18—Layered products comprising a layer of synthetic resin characterised by the use of special additives
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B32B27/304—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers comprising vinyl halide (co)polymers, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54—Yield strength; Tensile strength
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/558—Impact strength, toughness
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/582—Tearability
    • B32B2307/5825—Tear resistant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/50—Properties of the layers or laminate having particular mechanical properties
    • B32B2307/584—Scratch resistance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/732—Dimensional properties
    • B32B2307/734—Dimensional stability
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2491/00—Characterised by the use of oils, fats or waxes; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
    • C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/08—Metals
    • C08K2003/0893—Zinc
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/38—Boron-containing compounds
    • C08K2003/387—Borates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C08K3/042—Graphene or derivatives, e.g. graphene oxides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/34—Silicon-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C08K7/26—Silicon- containing compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Laminated Bodies (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

本发明所述一种超耐变形的PVC卷材，由多层超透薄膜贴合而成，按照重量份数，每层原料组成为：PVC胶料100份，锌粉5‑10份、环氧大豆油5‑10份、增塑剂10‑30份、镉钡锌复合稳定剂2～5份，加工助剂20‑50份，其通过所述配比原料的加入，得到超耐变形的PVC卷材，而且零收缩，在裁剪和使用时均为零收缩。

Description

一种超耐变形的PVC卷材
技术领域
本发明属于PVC技术领域，具体地说，涉及一种超耐变形的PVC卷材。
背景技术
聚氯乙烯英文简称PVC，随着PVC薄膜低毒、阻燃、耐寒、环保的优良性能，越来越得到广大的用途，广泛应用于证件、薄册、包装、箱包、服装、鞋类、汽车装璜等领域，发展到了日常生活领域中处处可见到PVC产品。由些可见，PVC 薄膜的需求量越来越大。
PVC薄膜主要成份为聚氯乙烯，另有加入其他成分来增强其耐热性，韧性，延展性等。PVC薄膜是当今世界上深受喜爱、颇为流行并且也被广泛应用的一种合成材料。PVC薄膜的全球使用量在各种合成材料中高居第二。在可以生产三维表面膜的材料中，PVC薄膜是最适合的材料。
为了满足人们的需要，目前一般采用PVC装饰膜来替代原有装饰材料表面的自然纹路，一般将多层薄膜贴合在一起，表面为装饰层，但是现有的贴合效率低，贴合效果差。
但是，PVC薄膜，尤其是超透薄膜，在裁剪和使用时容易收缩，发生褶皱，影响美观，而且裁剪时，由于发生收缩，造成尺寸缩短，而且超透薄膜不耐磨，容易撕裂。
发明内容
本发明克服了现有技术中的缺点，提供了一种超耐变形的PVC卷材，得到多层贴合的超透薄膜的原料及配比，而且零收缩，在裁剪和使用时均为零收缩。
为了解决上述技术问题，本发明是通过以下技术方案实现的：
一种超耐变形的PVC卷材，由多层超透薄膜贴合而成，按照重量份数，每层原料组成为：PVC胶料100份，锌粉5-10份、环氧大豆油5-10份、增塑剂 10-30份、镉钡锌复合稳定剂2～5份，加工助剂20-50份。
进一步，所述增塑剂包括石墨烯1-2份，硼酸锌5-10份、水玻璃2-5份、煤精3-7份、苯酐3-6份。
进一步，所述加工助剂包括：硬脂酸锌2-4份、硅藻土3-6份、高岭土4-8 份、富勒烯3-6份、氧化铝10-15份、玻璃粉2-6份、椰子纤维粉4-8份和蒙脱石粉2-4份。
进一步，所述增塑剂包括石墨烯1.5份，硼酸锌8份、水玻璃4份、煤精5 份、苯酐5份。
进一步，所述加工助剂包括：硬脂酸锌3份、硅藻土4份、高岭土6份、富勒烯4份、氧化铝12份、玻璃粉5份、椰子纤维粉5.5份和蒙脱石粉3.5份。
与现有技术相比，本发明的有益效果是：
本发明所述一种超耐变形的PVC卷材，由多层超透薄膜贴合而成，按照重量份数，每层原料组成为：PVC胶料100份，锌粉5-10份、环氧大豆油5-10 份、增塑剂10-30份、镉钡锌复合稳定剂2～5份，加工助剂20-50份，其通过所述配比原料的加入，得到超耐变形的PVC卷材，而且零收缩，在裁剪和使用时均为零收缩。
具体实施方式
以下对本发明的优选实施例进行说明，应当理解，此处所描述的优选实施例仅用于说明和解释本发明，并不用于限定本发明。
一种超耐变形的PVC卷材，由多层超透薄膜贴合而成，按照重量份数，每层原料组成为：PVC胶料100份，锌粉8份、环氧大豆油7份、增塑剂23.5份、镉钡锌复合稳定剂4份，加工助剂43份。
增塑剂包括石墨烯1.5份，硼酸锌8份、水玻璃4份、煤精5份、苯酐5份，苯酐和石墨烯的加入，使其延展性更好，硼酸锌、水玻璃和煤精使其高温流动性更好。
加工助剂包括：硬脂酸锌3份、硅藻土4份、高岭土6份、富勒烯4份、氧化铝12份、玻璃粉5份、椰子纤维粉5.5份和蒙脱石粉3.5份，富勒烯和椰子纤维粉增加PVC超透薄膜的韧性，硅藻土、高岭土和蒙脱石粉使其不易变形，不易收缩。
其配方和配比，实现多层超透薄膜的贴合。
各项指标如下表：
最后应说明的是：以上仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换，但是凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (5)

1.一种超耐变形的PVC卷材，其特征在于，由多层超透薄膜贴合而成，按照重量份数，每层原料组成为：PVC胶料100份，锌粉5-10份、环氧大豆油5-10份、增塑剂10-30份、镉钡锌复合稳定剂2～5份，加工助剂20-50份。
2.根据权利要求1所述一种超耐变形的PVC卷材，其特征在于，所述增塑剂包括石墨烯1-2份，硼酸锌5-10份、水玻璃2-5份、煤精3-7份、苯酐3-6份。
3.根据权利要求2所述一种超耐变形的PVC卷材，其特征在于，所述加工助剂包括：硬脂酸锌2-4份、硅藻土3-6份、高岭土4-8份、富勒烯3-6份、氧化铝10-15份、玻璃粉2-6份、椰子纤维粉4-8份和蒙脱石粉2-4份。
4.根据权利要求3所述一种超耐变形的PVC卷材，其特征在于，所述增塑剂包括石墨烯1.5份，硼酸锌8份、水玻璃4份、煤精5份、苯酐5份。
5.根据权利要求4所述一种超耐变形的PVC卷材，其特征在于，所述加工助剂包括：硬脂酸锌3份、硅藻土4份、高岭土6份、富勒烯4份、氧化铝12份、玻璃粉5份、椰子纤维粉5.5份和蒙脱石粉3.5份。
CN201811018664.5A 2018-09-03 2018-09-03 一种超耐变形的pvc卷材 Withdrawn CN109401110A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811018664.5A CN109401110A (zh) 2018-09-03 2018-09-03 一种超耐变形的pvc卷材

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811018664.5A CN109401110A (zh) 2018-09-03 2018-09-03 一种超耐变形的pvc卷材

Publications (1)

Publication Number Publication Date
CN109401110A true CN109401110A (zh) 2019-03-01

Family

ID=65463748

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811018664.5A Withdrawn CN109401110A (zh) 2018-09-03 2018-09-03 一种超耐变形的pvc卷材

Country Status (1)

Country Link
CN (1) CN109401110A (zh)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102924844A (zh) * 2012-10-09 2013-02-13 李永平 一种超透pvc膜及其制备方法
CN103205066A (zh) * 2012-01-14 2013-07-17 广州市雄星塑料制品有限公司 耐高温且不易收缩的电工膜
CN106827346A (zh) * 2017-01-21 2017-06-13 江苏大海塑料股份有限公司 一种覆合彩绘软玻璃及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103205066A (zh) * 2012-01-14 2013-07-17 广州市雄星塑料制品有限公司 耐高温且不易收缩的电工膜
CN102924844A (zh) * 2012-10-09 2013-02-13 李永平 一种超透pvc膜及其制备方法
CN106827346A (zh) * 2017-01-21 2017-06-13 江苏大海塑料股份有限公司 一种覆合彩绘软玻璃及其制备方法

Similar Documents

Publication Publication Date Title
AU2010332128A8 (en) Methods of imparting conductivity to materials used in composite article fabrication & materials thereof
CN107974231B (zh) 胶黏剂、其制备方法及囊体材料
CN104452460A (zh) 一种低透气高防水性能涂布内衬纸及其生产工艺
CN102774104B (zh) 印膜直镀开窗复合包装膜及其制备方法
CN105670173A (zh) 一种耐油抗静电聚氯乙烯管材
CN103469423A (zh) 一种隔热消防布料的制作工艺
CN106336574A (zh) 一种bopp薄膜
CN103665917A (zh) 一种新型塑料配方
CN109383104A (zh) 一种多层贴合超透薄膜处理方法
CN109401110A (zh) 一种超耐变形的pvc卷材
CN109385022A (zh) 一种多层贴合超透薄膜
CN109280289A (zh) 一种零收缩装饰膜
CN109370099A (zh) 一种pvc整版墙壁装饰膜
CN204674139U (zh) 一种汽车贴膜
CN109337233A (zh) 一种零收缩地板膜
CN103122212A (zh) 水性氟硅涂料
CN103319823A (zh) 一种石墨烯纳米复合材料
CN109280290A (zh) 一种聚氯乙烯pvc超透薄膜
CN104945736A (zh) 一种高性能的bopp消光膜
CN203831881U (zh) 一种玻璃贴膜
CN109354792A (zh) 一种零收缩超宽超透薄膜
CN109354791A (zh) 一种pvc卷材超宽多层复合方法
CN109401112A (zh) 一种多层贴合软玻璃
CN109401111A (zh) 一种高性能压延复合材料定型方法
CN109370088A (zh) 一种无收缩超透薄膜

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20190301