CN109280289A - 一种零收缩装饰膜 - Google Patents

一种零收缩装饰膜 Download PDF

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CN109280289A
CN109280289A CN201811018748.9A CN201811018748A CN109280289A CN 109280289 A CN109280289 A CN 109280289A CN 201811018748 A CN201811018748 A CN 201811018748A CN 109280289 A CN109280289 A CN 109280289A
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李永平
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    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
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Abstract

本发明所述一种零收缩装饰膜，按照重量比，其原料组成为：PVC胶料100份，锌粉6‑12份、环氧大豆油2‑3份、纳米碳酸钙2‑6份、钛白粉5‑10份、色料2‑6份、增塑剂20‑40份、镉钡锌复合稳定剂2～4份，加工助剂20‑40份，其通过配方，尤其是加工助剂的加入，使装饰膜零收缩，延长装饰膜的使用寿命。

Description

一种零收缩装饰膜
技术领域
本发明属于PVC技术领域，具体地说，涉及一种零收缩装饰膜。
背景技术
聚氯乙烯英文简称PVC，随着PVC薄膜低毒、阻燃、耐寒、环保的优良性能，越来越得到广大的用途，广泛应用于证件、薄册、包装、箱包、服装、鞋类、汽车装璜等领域，发展到了日常生活领域中处处可见到PVC产品。由些可见，PVC薄膜的需求量越来越大。
PVC薄膜主要成份为聚氯乙烯，另有加入其他成分来增强其耐热性，韧性，延展性等。PVC薄膜是当今世界上深受喜爱、颇为流行并且也被广泛应用的一种合成材料。PVC薄膜的全球使用量在各种合成材料中高居第二。在可以生产三维表面膜的材料中，PVC薄膜是最适合的材料。
但是，PVC薄膜，尤其是装饰膜，在裁剪和使用时容易收缩，发生褶皱，影响美观，而且裁剪时，由于发生收缩，造成尺寸缩短。
发明内容
本发明克服了现有技术中的缺点，提供了一种零收缩装饰膜，实现装饰膜的零收缩，在裁剪和使用时均为零收缩。
为了解决上述技术问题，本发明是通过以下技术方案实现的：
一种零收缩装饰膜，按照重量比，其原料组成为：PVC胶料100份，锌粉6-12份、环氧大豆油2-3份、纳米碳酸钙2-6份、钛白粉5-10份、色料2-6份、增塑剂20-40份、镉钡锌复合稳定剂2～4份，加工助剂20-40份。
进一步，所述增塑剂为乙二醇10-30份，石墨烯2-4份，甲壳素2-6份和乙酸酐5-10份。
进一步，所述加工助剂为马来酸酐0.8-1.2份，金属锑2-4份，纳米二氧化锑1-2份，果酸2-5份，冰醋酸3-6份，稀土氧化物15-25份，氧化石墨烯2-4份。
进一步，所述氧化石墨烯的改性剂为丝肽，所述石墨烯与丝肽的质量比为1：1.5。
进一步，所述增塑剂为乙二醇20份，石墨烯3份，甲壳素4份和乙酸酐6份。
进一步，所述加工助剂为马来酸酐1份，金属锑3份，纳米二氧化锑1.5份，果酸4份，冰醋酸4份，稀土氧化物21份，氧化石墨烯3份。
与现有技术相比，本发明的有益效果是：
本发明所述一种零收缩装饰膜，按照重量比，其原料组成为：PVC胶料100份，锌粉6-12份、环氧大豆油2-3份、纳米碳酸钙2-6份、钛白粉5-10份、色料2-6份、增塑剂20-40份、镉钡锌复合稳定剂2～4份，加工助剂20-40份，其通过配方，尤其是加工助剂的加入，使装饰膜零收缩，延长装饰膜的使用寿命。
具体实施方式
以下对本发明的优选实施例进行说明，应当理解，此处所描述的优选实施例仅用于说明和解释本发明，并不用于限定本发明。
一种零收缩装饰膜，按照重量比，其原料组成为：PVC胶料100份，锌粉8份、环氧大豆油2.5份、纳米碳酸钙4份、钛白粉7份、色料4份、增塑剂33份、镉钡锌复合稳定剂3份，加工助剂37.5份。
增塑剂为乙二醇20份，石墨烯3份，甲壳素4份和乙酸酐6份，加工助剂为马来酸酐1份，金属锑3份，纳米二氧化锑1.5份，果酸4份，冰醋酸4份，稀土氧化物21份，氧化石墨烯3份，氧化石墨烯的改性剂为丝肽，石墨烯与丝肽的质量比为1：1.5，氧化石墨烯的加入，降低其冷脆性，而且减小收缩，纳米二氧化锑提高最终薄膜产品的耐老化性能。
各项指标如下表：
最后应说明的是：以上仅为本发明的优选实施例而已，并不用于限制本发明，尽管参照实施例对本发明进行了详细的说明，对于本领域的技术人员来说，其依然可以对前述各实施例所记载的技术方案进行修改，或者对其中部分技术特征进行等同替换，但是凡在本发明的精神和原则之内，所作的任何修改、等同替换、改进等，均应包含在本发明的保护范围之内。

Claims (6)

1.一种零收缩装饰膜，其特征在于，按照重量比，其原料组成为：PVC胶料100份，锌粉6-12份、环氧大豆油2-3份、纳米碳酸钙2-6份、钛白粉5-10份、色料2-6份、增塑剂20-40份、镉钡锌复合稳定剂2～4份，加工助剂20-40份。
2.根据权利要求1所述一种零收缩装饰膜，其特征在于，所述增塑剂为乙二醇10-30份，石墨烯2-4份，甲壳素2-6份和乙酸酐5-10份。
3.根据权利要求2所述一种零收缩装饰膜，其特征在于，所述加工助剂为马来酸酐0.8-1.2份，金属锑2-4份，纳米二氧化锑1-2份，果酸2-5份，冰醋酸3-6份，稀土氧化物15-25份，氧化石墨烯2-4份。
4.根据权利要求3所述一种零收缩装饰膜，其特征在于，所述氧化石墨烯的改性剂为丝肽，所述石墨烯与丝肽的质量比为1：1.5。
5.根据权利要求4所述一种零收缩装饰膜，其特征在于，所述增塑剂为乙二醇20份，石墨烯3份，甲壳素4份和乙酸酐6份。
6.根据权利要求5所述一种零收缩装饰膜，其特征在于，所述加工助剂为马来酸酐1份，金属锑3份，纳米二氧化锑1.5份，果酸4份，冰醋酸4份，稀土氧化物21份，氧化石墨烯3份。
CN201811018748.9A 2018-09-03 2018-09-03 一种零收缩装饰膜 Withdrawn CN109280289A (zh)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2032179B1 (en) * 2022-06-15 2023-12-21 Zhejiang Xidamen New Mat Co Ltd Method for preparing inorganic component reinforced high-weather-resistance pvc film

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103059473A (zh) * 2013-01-09 2013-04-24 浙江明士达新材料有限公司 一种超宽环保装饰膜材料及其制备工艺
CN105440492A (zh) * 2015-12-17 2016-03-30 东莞市悠悠美居家居制造有限公司 一种高柔软高抗压聚氯乙烯片材及其制备方法
CN106280131A (zh) * 2016-08-31 2017-01-04 黄山豪泰塑胶有限公司 一种耐热阻燃的pvc装饰膜及其制备方法和应用
CN107841071A (zh) * 2018-01-08 2018-03-27 金华观瑞科技有限公司 一种pvc装饰膜

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103059473A (zh) * 2013-01-09 2013-04-24 浙江明士达新材料有限公司 一种超宽环保装饰膜材料及其制备工艺
CN105440492A (zh) * 2015-12-17 2016-03-30 东莞市悠悠美居家居制造有限公司 一种高柔软高抗压聚氯乙烯片材及其制备方法
CN106280131A (zh) * 2016-08-31 2017-01-04 黄山豪泰塑胶有限公司 一种耐热阻燃的pvc装饰膜及其制备方法和应用
CN107841071A (zh) * 2018-01-08 2018-03-27 金华观瑞科技有限公司 一种pvc装饰膜

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2032179B1 (en) * 2022-06-15 2023-12-21 Zhejiang Xidamen New Mat Co Ltd Method for preparing inorganic component reinforced high-weather-resistance pvc film

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Application publication date: 20190129