CN105462115A - 一种装饰用pvc膜 - Google Patents

一种装饰用pvc膜 Download PDF

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CN105462115A
CN105462115A CN201510979718.4A CN201510979718A CN105462115A CN 105462115 A CN105462115 A CN 105462115A CN 201510979718 A CN201510979718 A CN 201510979718A CN 105462115 A CN105462115 A CN 105462115A
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庄启明
庄启飞
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Huangshan Haotai Plastic Co Ltd
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Abstract

本发明公开了一种装饰用PVC膜，由以下重量份原料组成：PVC440树脂粉、纳米碳化钛、壳聚糖接枝聚丙烯酸、聚氧乙烯山梨醇酐单硬脂酸酯、钛酸四丁酯、硬脂酸乙酯、正十八醇、二(三乙醇胺)钛酸二异丙酯、饱和脂肪醇多元羧酸酯、偏锑酸钠、铬酸锌、增塑剂、稳定剂、抗氧化剂。本发明通过配方的合理组合，所得的PVC薄膜具有抗老化、韧性高，热稳定性、阻燃性好的优点。同时，还具有耐酸碱腐蚀的特点。

Description

一种装饰用PVC膜
技术领域
本发明涉及一种装饰用PVC膜，属于PVC材料领域。
背景技术
一般PVC薄膜是由PVC树脂、稳定剂、润滑剂、改性剂等成分组成的，物料混合均匀后定量加入螺槽，有螺杆动力向前输送，机筒的加热作用和螺杆的剪切作用使物料塑化熔融，从螺槽到口模型腔截面积逐渐减小，因而在螺杆动力作用下形成一定的背压，使PVC材料成型。
目前，市场上的普通装饰用PVC膜，表面毛糙、没有光洁度且单层PVC薄膜大多不抗老化、易受光氧化和韧性低，热稳定性差、阻燃性差，不耐酸碱腐蚀等问题的彰显。如果应用到其它装饰材料，如壁纸中，会使得产品的各方面性能大大降低。
发明内容
本发明目的是提供一种热稳定性能强、抗氧化剂强、阻燃性好、抗老化的装饰用PVC膜。
本发明的方案如下：一种装饰用PVC膜，由以下重量份原料组成：PVC440树脂粉150-200份、纳米碳化钛5-12份、壳聚糖接枝聚丙烯酸2-8份、聚氧乙烯山梨醇酐单硬脂酸酯0.2-0.7份、钛酸四丁酯0.6-2份、硬脂酸乙酯0.5-3份、正十八醇1-2份、二(三乙醇胺)钛酸二异丙酯0.4-1.1份、饱和脂肪醇多元羧酸酯0.1-0.5份、偏锑酸钠1-3份、铬酸锌1-3份、增塑剂0.2-0.5份、稳定剂0.3-1份、抗氧化剂0.2-0.8份。
一种装饰用PVC膜，由以下重量份原料组成：PVC440树脂粉180份、纳米碳化钛8份、壳聚糖接枝聚丙烯酸6份、聚氧乙烯山梨醇酐单硬脂酸酯0.5份、钛酸四丁酯1份、硬脂酸乙酯2份、正十八醇1.5份、二(三乙醇胺)钛酸二异丙酯0.6份、饱和脂肪醇多元羧酸酯0.2份、偏锑酸钠2份、铬酸锌1.5份、增塑剂0.3份、稳定剂0.6份、抗氧化剂0.5份。
一种装饰用PVC膜，由以下重量份原料组成：PVC440树脂粉170份、纳米碳化钛10份、壳聚糖接枝聚丙烯酸5份、聚氧乙烯山梨醇酐单硬脂酸酯0.3份、钛酸四丁酯1.2份、硬脂酸乙酯1.6份、正十八醇1.8份、二(三乙醇胺)钛酸二异丙酯0.7份、饱和脂肪醇多元羧酸酯0.2份、偏锑酸钠1.6份、铬酸锌2.5份、增塑剂0.4份、稳定剂0.6份、抗氧化剂0.3份。
一种装饰用PVC膜，由以下重量份原料组成：PVC440树脂粉200份、纳米碳化钛9份、壳聚糖接枝聚丙烯酸7份、聚氧乙烯山梨醇酐单硬脂酸酯0.3份、钛酸四丁酯1.8份、硬脂酸乙酯2.1份、正十八醇1份、二(三乙醇胺)钛酸二异丙酯0.5份、饱和脂肪醇多元羧酸酯0.1份、偏锑酸钠3份、铬酸锌2份、增塑剂0.4份、稳定剂0.8份、抗氧化剂0.5份。
进一步，所述的增塑剂为磷酸三(2-氯乙基)酯、酞酸双(2-乙基己基)酯、二苯甲酸二聚丙二醇酯、己二酸二异壬酯中的任意一种或多种。
进一步，所述的稳定剂为双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯、二丁基二硫代氨基甲酸镍、2-丙烯酸环己基酯、2-乙氧基乙基丙烯酸脂、3-丙烯酰氧-2-甲基丙烯酸羟丙酯中的一种或多种。
进一步，所述的抗氧化剂为N，N'-六次甲基双—3(3，5二叔丁基-4羟基苯基)丙酰胺、4，4'-二叔辛基二苯胺、二亚磷酸双十八酯季戊四醇酯、二亚磷酸双十八酯、季戊四醇酯中的一种或多种。
一种装饰用PVC膜的生产方法，步骤如下：
（1）将各原料放置到高速混合机中进行混合，高速混合机每工作40-60min就停止，然后静置10-20min，重复3-4次；
（2）将混合充分的原料直接送入到挤塑机，挤压得到PVC膜；
（3）将步骤（2）得到的PVC膜过纯水池进行冷却，即可得装饰用PVC膜。
本发明各个工艺参数之间存在相互作用的关系，确保制造而成的PVC膜的塑化非常均匀，增加了PVC膜产品的柔韧性能，使得PVC膜产品变得牢固，延长了PVC膜产品的使用寿命。通过这些配方的合理组合，所得的PVC薄膜具有抗老化、韧性高，热稳定性、阻燃性好的优点。同时，还具有耐酸碱腐蚀的特点。
具体实施方式
下面结合实施例对本发明做进一步说明。
实施例1
一种装饰用PVC膜，由以下重量份原料组成：PVC440树脂粉180份、纳米碳化钛8份、壳聚糖接枝聚丙烯酸6份、聚氧乙烯山梨醇酐单硬脂酸酯0.5份、钛酸四丁酯1份、硬脂酸乙酯2份、正十八醇1.5份、二(三乙醇胺)钛酸二异丙酯0.6份、饱和脂肪醇多元羧酸酯0.2份、偏锑酸钠2份、铬酸锌1.5份、磷酸三(2-氯乙基)酯0.3份、双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯0.6份、N，N'-六次甲基双—3(3，5二叔丁基-4羟基苯基)丙酰胺0.5份。
生产方法，步骤如下：
（1）将各原料放置到高速混合机中进行混合，高速混合机每工作52min就停止，然后静置16min，重复4次；
（2）将混合充分的原料直接送入到挤塑机，挤压得到PVC膜；
（3）将步骤（2）得到的PVC膜过纯水池进行冷却，即可得装饰用PVC膜。
实施例2
一种装饰用PVC膜，由以下重量份原料组成：PVC440树脂粉170份、纳米碳化钛10份、壳聚糖接枝聚丙烯酸5份、聚氧乙烯山梨醇酐单硬脂酸酯0.3份、钛酸四丁酯1.2份、硬脂酸乙酯1.6份、正十八醇1.8份、二(三乙醇胺)钛酸二异丙酯0.7份、饱和脂肪醇多元羧酸酯0.2份、偏锑酸钠1.6份、铬酸锌2.5份、酞酸双(2-乙基己基)酯0.4份、2-乙氧基乙基丙烯酸脂0.6份、4，4'-二叔辛基二苯胺0.3份。
生产方法同实施例1。
实施例3
一种装饰用PVC膜，由以下重量份原料组成：PVC440树脂粉200份、纳米碳化钛9份、壳聚糖接枝聚丙烯酸7份、聚氧乙烯山梨醇酐单硬脂酸酯0.3份、钛酸四丁酯1.8份、硬脂酸乙酯2.1份、正十八醇1份、二(三乙醇胺)钛酸二异丙酯0.5份、饱和脂肪醇多元羧酸酯0.1份、偏锑酸钠3份、铬酸锌2份、己二酸二异壬酯0.4份、3-丙烯酰氧-2-甲基丙烯酸羟丙酯0.8份、季戊四醇酯0.5份。
生产方法同实施例1。
将上述实施例1-3所得的PVC复合薄膜进行进行拉伸强度（Mpa）测试、自熄时间测试、紫外光照射2500h后伸长率保持率(%)测试与断裂伸长率(%)测试，拉伸强度测试按照GB/T528-1998标准测试，断裂伸长率测试按照国家标准GB3923-83测试，结果见下表。在下表中，还对从市场上购得的常规壁纸用PVC薄膜也进行了相应测试。
拉伸强度 断裂伸长率 自熄时间 紫外光照射2500h 后伸长率
实施例1 71 371 7.9 98.2
实施例2 68 362 7.8 97.8
实施例3 62 358 7.1 97.5
常规PVC薄膜 46 310 14.1 91.3
尽管上文对本发明的具体实施方式给予了详细描述和说明，但是应该指明的是，我们可以依据本发明的构想对上述实施方式进行各种等效改变和修改，其所产生的功能作用仍未超出说明书所涵盖的精神时，均应在本发明的保护范围之内。

Claims (8)

1.一种装饰用PVC膜，其特征在于，由以下重量份原料组成：PVC440树脂粉150-200份、纳米碳化钛5-12份、壳聚糖接枝聚丙烯酸2-8份、聚氧乙烯山梨醇酐单硬脂酸酯0.2-0.7份、钛酸四丁酯0.6-2份、硬脂酸乙酯0.5-3份、正十八醇1-2份、二(三乙醇胺)钛酸二异丙酯0.4-1.1份、饱和脂肪醇多元羧酸酯0.1-0.5份、偏锑酸钠1-3份、铬酸锌1-3份、增塑剂0.2-0.5份、稳定剂0.3-1份、抗氧化剂0.2-0.8份。
2.根据权利要求1所述的一种装饰用PVC膜，其特征在于，由以下重量份原料组成：PVC440树脂粉180份、纳米碳化钛8份、壳聚糖接枝聚丙烯酸6份、聚氧乙烯山梨醇酐单硬脂酸酯0.5份、钛酸四丁酯1份、硬脂酸乙酯2份、正十八醇1.5份、二(三乙醇胺)钛酸二异丙酯0.6份、饱和脂肪醇多元羧酸酯0.2份、偏锑酸钠2份、铬酸锌1.5份、增塑剂0.3份、稳定剂0.6份、抗氧化剂0.5份。
3.根据权利要求1所述的一种装饰用PVC膜，其特征在于，由以下重量份原料组成：PVC440树脂粉170份、纳米碳化钛10份、壳聚糖接枝聚丙烯酸5份、聚氧乙烯山梨醇酐单硬脂酸酯0.3份、钛酸四丁酯1.2份、硬脂酸乙酯1.6份、正十八醇1.8份、二(三乙醇胺)钛酸二异丙酯0.7份、饱和脂肪醇多元羧酸酯0.2份、偏锑酸钠1.6份、铬酸锌2.5份、增塑剂0.4份、稳定剂0.6份、抗氧化剂0.3份。
4.根据权利要求1所述的一种装饰用PVC膜，其特征在于，由以下重量份原料组成：PVC440树脂粉200份、纳米碳化钛9份、壳聚糖接枝聚丙烯酸7份、聚氧乙烯山梨醇酐单硬脂酸酯0.3份、钛酸四丁酯1.8份、硬脂酸乙酯2.1份、正十八醇1份、二(三乙醇胺)钛酸二异丙酯0.5份、饱和脂肪醇多元羧酸酯0.1份、偏锑酸钠3份、铬酸锌2份、增塑剂0.4份、稳定剂0.8份、填充剂0.6份、抗氧化剂0.5份。
5.根据权利要求1述的一种装饰用PVC膜，其特征在于，所述的增塑剂为磷酸三(2-氯乙基)酯、酞酸双(2-乙基己基)酯、二苯甲酸二聚丙二醇酯、己二酸二异壬酯中的任意一种或多种。
6.根据权利要求1述的一种装饰用PVC膜，其特征在于，所述的稳定剂为双(2,2,6,6-四甲基-4-哌啶基)癸二酸酯、二丁基二硫代氨基甲酸镍、2-丙烯酸环己基酯、2-乙氧基乙基丙烯酸脂、3-丙烯酰氧-2-甲基丙烯酸羟丙酯中的一种或多种。
7.根据权利要求1述的一种装饰用PVC膜，其特征在于，所述的抗氧化剂为N，N'-六次甲基双—3(3，5二叔丁基-4羟基苯基)丙酰胺、4，4'-二叔辛基二苯胺、二亚磷酸双十八酯季戊四醇酯、二亚磷酸双十八酯、季戊四醇酯中的一种或多种。
8.根据权利要求1-7中任一权利要求所述的一种装饰用PVC膜的生产方法，其特征在于，步骤如下：
（1）将各原料放置到高速混合机中进行混合，高速混合机每工作40-60min就停止，然后静置10-20min，重复3-4次；
（2）将混合充分的原料直接送入到挤塑机，挤压得到PVC膜；
（3）将步骤（2）得到的PVC膜过纯水池进行冷却，即可得装饰用PVC膜。
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106280131A (zh) * 2016-08-31 2017-01-04 黄山豪泰塑胶有限公司 一种耐热阻燃的pvc装饰膜及其制备方法和应用
CN106317703A (zh) * 2016-08-31 2017-01-11 黄山豪泰塑胶有限公司 一种pvc膜及其制备方法和应用
CN109370099A (zh) * 2018-09-03 2019-02-22 李永平 一种pvc整版墙壁装饰膜

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103029311A (zh) * 2012-12-12 2013-04-10 浙江博泰塑胶有限公司 一种半硬质pvc装饰膜片
CN103774814A (zh) * 2013-11-29 2014-05-07 淮北龙盘工贸有限责任公司 一种环保防水壁纸
CN104893144A (zh) * 2015-05-26 2015-09-09 苏州宏恒化工有限公司 一种壁纸专用的pvc树脂糊料及其制备方法

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103029311A (zh) * 2012-12-12 2013-04-10 浙江博泰塑胶有限公司 一种半硬质pvc装饰膜片
CN103774814A (zh) * 2013-11-29 2014-05-07 淮北龙盘工贸有限责任公司 一种环保防水壁纸
CN104893144A (zh) * 2015-05-26 2015-09-09 苏州宏恒化工有限公司 一种壁纸专用的pvc树脂糊料及其制备方法

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106280131A (zh) * 2016-08-31 2017-01-04 黄山豪泰塑胶有限公司 一种耐热阻燃的pvc装饰膜及其制备方法和应用
CN106317703A (zh) * 2016-08-31 2017-01-11 黄山豪泰塑胶有限公司 一种pvc膜及其制备方法和应用
CN109370099A (zh) * 2018-09-03 2019-02-22 李永平 一种pvc整版墙壁装饰膜

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