CN109279620A - 一种金属掺杂edi型磷酸锌分子筛及其合成方法 - Google Patents
一种金属掺杂edi型磷酸锌分子筛及其合成方法 Download PDFInfo
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- CN109279620A CN109279620A CN201811197948.5A CN201811197948A CN109279620A CN 109279620 A CN109279620 A CN 109279620A CN 201811197948 A CN201811197948 A CN 201811197948A CN 109279620 A CN109279620 A CN 109279620A
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- Prior art keywords
- molecular sieve
- metal
- edi
- doped
- phosphoric acid
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- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 239000002808 molecular sieve Substances 0.000 title claims abstract description 61
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 title claims abstract description 44
- 229910000147 aluminium phosphate Inorganic materials 0.000 title claims abstract description 23
- 238000010189 synthetic method Methods 0.000 title claims abstract description 10
- 239000011701 zinc Substances 0.000 claims abstract description 43
- LRXTYHSAJDENHV-UHFFFAOYSA-H zinc phosphate Chemical compound [Zn+2].[Zn+2].[Zn+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O LRXTYHSAJDENHV-UHFFFAOYSA-H 0.000 claims abstract description 25
- 229910000165 zinc phosphate Inorganic materials 0.000 claims abstract description 24
- 229910052751 metal Inorganic materials 0.000 claims abstract description 18
- 239000002184 metal Substances 0.000 claims abstract description 18
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 claims abstract description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000002425 crystallisation Methods 0.000 claims abstract description 10
- 230000008025 crystallization Effects 0.000 claims abstract description 10
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 9
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 9
- 239000011574 phosphorus Substances 0.000 claims abstract description 9
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 claims abstract description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical group [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910052725 zinc Inorganic materials 0.000 claims abstract description 8
- ISIJQEHRDSCQIU-UHFFFAOYSA-N tert-butyl 2,7-diazaspiro[4.5]decane-7-carboxylate Chemical compound C1N(C(=O)OC(C)(C)C)CCCC11CNCC1 ISIJQEHRDSCQIU-UHFFFAOYSA-N 0.000 claims abstract description 7
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004246 zinc acetate Substances 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims description 19
- 239000013078 crystal Substances 0.000 claims description 18
- 238000003756 stirring Methods 0.000 claims description 14
- 230000005291 magnetic effect Effects 0.000 claims description 12
- 229910001868 water Inorganic materials 0.000 claims description 11
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 9
- 239000000047 product Substances 0.000 claims description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 7
- 239000003960 organic solvent Substances 0.000 claims description 7
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 claims description 6
- 238000013019 agitation Methods 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- OJMIONKXNSYLSR-UHFFFAOYSA-N phosphorous acid Chemical compound OP(O)O OJMIONKXNSYLSR-UHFFFAOYSA-N 0.000 claims description 5
- 238000000926 separation method Methods 0.000 claims description 5
- 239000012265 solid product Substances 0.000 claims description 5
- 238000005406 washing Methods 0.000 claims description 5
- 150000001868 cobalt Chemical class 0.000 claims description 4
- 150000002815 nickel Chemical class 0.000 claims description 4
- 229910052759 nickel Inorganic materials 0.000 claims description 4
- 229910021586 Nickel(II) chloride Inorganic materials 0.000 claims description 3
- 229940011182 cobalt acetate Drugs 0.000 claims description 3
- QAHREYKOYSIQPH-UHFFFAOYSA-L cobalt(II) acetate Chemical group [Co+2].CC([O-])=O.CC([O-])=O QAHREYKOYSIQPH-UHFFFAOYSA-L 0.000 claims description 3
- QMMRZOWCJAIUJA-UHFFFAOYSA-L nickel dichloride Chemical group Cl[Ni]Cl QMMRZOWCJAIUJA-UHFFFAOYSA-L 0.000 claims description 3
- 239000011592 zinc chloride Substances 0.000 claims description 3
- 235000005074 zinc chloride Nutrition 0.000 claims description 3
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims description 2
- 239000008187 granular material Substances 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 6
- 239000012535 impurity Substances 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 5
- 230000005290 antiferromagnetic effect Effects 0.000 abstract description 4
- 150000002739 metals Chemical class 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 3
- 238000009415 formwork Methods 0.000 abstract description 3
- 239000008367 deionised water Substances 0.000 abstract description 2
- 229910021641 deionized water Inorganic materials 0.000 abstract description 2
- 238000001027 hydrothermal synthesis Methods 0.000 abstract description 2
- 150000002500 ions Chemical class 0.000 abstract description 2
- -1 iron cobalt nickel salt ion Chemical class 0.000 abstract description 2
- 238000003760 magnetic stirring Methods 0.000 abstract description 2
- 239000012046 mixed solvent Substances 0.000 abstract description 2
- 239000002904 solvent Substances 0.000 abstract description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 10
- 150000001875 compounds Chemical class 0.000 description 9
- 238000010586 diagram Methods 0.000 description 8
- 125000004429 atom Chemical group 0.000 description 7
- 229910019142 PO4 Inorganic materials 0.000 description 5
- 229910052742 iron Inorganic materials 0.000 description 4
- 239000000843 powder Substances 0.000 description 4
- 238000002360 preparation method Methods 0.000 description 4
- 238000004088 simulation Methods 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 230000005343 Curie-Weiss law Effects 0.000 description 3
- 150000001336 alkenes Chemical class 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- IPCXNCATNBAPKW-UHFFFAOYSA-N zinc;hydrate Chemical compound O.[Zn] IPCXNCATNBAPKW-UHFFFAOYSA-N 0.000 description 3
- 229910021536 Zeolite Inorganic materials 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- ILRRQNADMUWWFW-UHFFFAOYSA-K aluminium phosphate Chemical compound O1[Al]2OP1(=O)O2 ILRRQNADMUWWFW-UHFFFAOYSA-K 0.000 description 2
- 230000005316 antiferromagnetic exchange Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000002050 diffraction method Methods 0.000 description 2
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000009616 inductively coupled plasma Methods 0.000 description 2
- 230000003993 interaction Effects 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 125000004437 phosphorous atom Chemical group 0.000 description 2
- 239000010457 zeolite Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229940001007 aluminium phosphate Drugs 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910021645 metal ion Inorganic materials 0.000 description 1
- 229910001463 metal phosphate Inorganic materials 0.000 description 1
- 238000004377 microelectronic Methods 0.000 description 1
- 239000012229 microporous material Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000005504 petroleum refining Methods 0.000 description 1
- OXHXATNDTXVKAU-UHFFFAOYSA-N phosphoric acid zinc Chemical class [Zn].OP(O)(O)=O OXHXATNDTXVKAU-UHFFFAOYSA-N 0.000 description 1
- 230000005622 photoelectricity Effects 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B37/00—Compounds having molecular sieve properties but not having base-exchange properties
- C01B37/002—Metallophosphates not containing aluminium, e.g. gallophosphates or silicogallophosphates
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B39/00—Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
- C01B39/54—Phosphates, e.g. APO or SAPO compounds
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/30—Particle morphology extending in three dimensions
- C01P2004/38—Particle morphology extending in three dimensions cube-like
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/61—Micrometer sized, i.e. from 1-100 micrometer
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2006/00—Physical properties of inorganic compounds
- C01P2006/42—Magnetic properties
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Geology (AREA)
- Materials Engineering (AREA)
- Silicates, Zeolites, And Molecular Sieves (AREA)
- Catalysts (AREA)
Abstract
Description
Claims (5)
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CN201811197948.5A CN109279620B (zh) | 2018-10-15 | 2018-10-15 | 一种金属掺杂edi型磷酸锌分子筛及其合成方法 |
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CN201811197948.5A CN109279620B (zh) | 2018-10-15 | 2018-10-15 | 一种金属掺杂edi型磷酸锌分子筛及其合成方法 |
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CN109279620A true CN109279620A (zh) | 2019-01-29 |
CN109279620B CN109279620B (zh) | 2022-01-28 |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5186814A (en) * | 1990-10-02 | 1993-02-16 | Uop | Hydrocarbon conversion processes using crystalline microporous zinc phosphate compositions |
CN101264897A (zh) * | 2008-04-15 | 2008-09-17 | 南开大学 | 一种有10元环和8元环交叉连接孔道的磷酸锌钴分子筛及合成方法 |
CN101570335A (zh) * | 2009-06-11 | 2009-11-04 | 南开大学 | 具有16元环孔道的磷酸锌钴分子筛及合成方法 |
US20170056442A1 (en) * | 2003-10-20 | 2017-03-02 | Framework Therapeutics, Llc | Zeolite molecular sieves for the removal of toxins |
CN107427821A (zh) * | 2015-02-20 | 2017-12-01 | 庄信万丰股份有限公司 | 双金属分子筛催化剂 |
-
2018
- 2018-10-15 CN CN201811197948.5A patent/CN109279620B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5186814A (en) * | 1990-10-02 | 1993-02-16 | Uop | Hydrocarbon conversion processes using crystalline microporous zinc phosphate compositions |
US20170056442A1 (en) * | 2003-10-20 | 2017-03-02 | Framework Therapeutics, Llc | Zeolite molecular sieves for the removal of toxins |
CN101264897A (zh) * | 2008-04-15 | 2008-09-17 | 南开大学 | 一种有10元环和8元环交叉连接孔道的磷酸锌钴分子筛及合成方法 |
CN101570335A (zh) * | 2009-06-11 | 2009-11-04 | 南开大学 | 具有16元环孔道的磷酸锌钴分子筛及合成方法 |
CN107427821A (zh) * | 2015-02-20 | 2017-12-01 | 庄信万丰股份有限公司 | 双金属分子筛催化剂 |
Non-Patent Citations (2)
Title |
---|
HARRISON, WTA: "[H3N(CH2)3NH3]0.5[ZnPO4], an organically templated zincophosphate analogue of the aluminosilicate zeolite edingtonite", 《ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE》 * |
王学雷等: "亚磷酸锌无机-有机杂化化合物的合成与结构表征", 《高等学校化学学报》 * |
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Inventor after: Wang Xuelei Inventor after: Zhuang Weibin Inventor after: Wang Ming Inventor after: Yang Shaobin Inventor after: Shen Ding Inventor after: Zhou Xiaoqian Inventor before: Wang Xuelei Inventor before: Zhuang Weibin Inventor before: Wang Ming Inventor before: Yang Shaobin Inventor before: Shen Ding Inventor before: Zhou Xiaoqian |
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Application publication date: 20190129 Assignee: Liaoning Sunshine Stone science and Technology Park Co.,Ltd. Assignor: LIAONING TECHNICAL University Contract record no.: X2023210000320 Denomination of invention: A metal doped EDI type zinc phosphate molecular sieve and its synthesis method Granted publication date: 20220128 License type: Common License Record date: 20231227 |