CN109181890B - 一种免擦拭洗车液及其制备方法 - Google Patents
一种免擦拭洗车液及其制备方法 Download PDFInfo
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Abstract
本发明涉及车用洗涤试剂技术领域,尤其是一种免擦拭洗车液及其制备方法,为W1/O/W2型乳液,由A、B两相混合而成;A相为W1/O型乳液,占免擦拭洗车液总质量的15%;A相各组分的质量占A相总质量的比分别为:固体粉剂7.2‑9.6%,表面活性剂3‑9%,溶剂4‑15%,杀菌剂0.2%,余量为水;B相为W2水相,B相各组分的质量占免擦拭洗车液总质量的比分别为:表面活性剂16~31%,杀菌剂0.2%,助剂2%,余量为水。本发明采用W1/O/W2微胶囊技术,利用粉体颗粒高压喷淋冲击漆面,可以有效去除漆表面的氧化交通膜。
Description
技术领域
本发明涉及车用洗涤试剂技术领域,具体领域为一种免擦拭洗车液。
背景技术
无刷免擦拭洗是一种无接触高压喷淋清洗手段,广泛应用于大型运输车辆、工程车辆和无规则形状的车辆,这些类型的车辆由于体积庞大或形状的无规则性,无法使用常规的有刷清洗设备,只能采用高压喷淋的设备进行清洗。另外,由于车辆体积庞大,洗完车后无法采用风冷吹干,携带水渍的车体更加容易再度遭受污染且容易锈蚀。
目前,全世界普遍采用强酸、强碱性清洗剂去除车身表面上的污垢和交通膜。清洗剂主要由有机酸或无机酸、有机碱和无机碱、螯合剂、渗透剂、金属缓蚀剂及表面活性剂等组成,用于清洗车身的泥垢、虫胶,及其因有害气体、酸雨、紫外线的侵蚀而形成的氧化交通膜。
由于中国很多地区的工业污染较为严重,汽车行驶一段时间后,车身静电吸附刹车时飞溅的铁粉,灰尘以及受到大气中各种有害气体、酸雨、紫外线的伤害和侵蚀,会在漆面上形成一层坚硬粗糙的氧化膜,采用有刷或海绵和洗涤剂相配合,可以轻松把该交通膜擦拭干净,然而仅仅采用免擦拭高压喷淋的方式很难有效清除这种交通膜。
而且,由于无规则和体积庞大,这些特殊形状的车辆借助热风机很难把车身残留的积水吹拂干净。现有的免擦拭技术通常加入水溶性的聚醚改性有机硅表面活性剂以实现斥水效果,快速去除车漆上的大部分水分。但由于其亲水的性质,大部分活性成分会被水携带走,很难发挥有效驱水作用。
另外,强酸、强碱洗涤液会损伤洗车机械的橡胶密封件,也会给车体带来很大的损伤,比如会使车漆失色、风挡玻璃发花,透视度下降,橡胶密封胶条硬化、失色,加速老化,也会使塑料变得失色、发脆。
发明内容
本发明的目的在于提供一种免擦拭洗车液及其制备方法,以解决现有技术中免擦拭高压喷淋的方式很难有效清除氧化交通膜、试剂中的活性成分易被携带走、洗涤液易损伤车体等问题。
在无刷擦拭的状态下,为了在高压喷淋中获得良好的交通油膜去除率,利用水包油包水(W1/O/W2)乳液技术,把氧化铝和氧化锆纳米粉体包裹在油包水乳液中,然后靠表面活性剂和纳米粉体对污垢、油脂和交通膜进行有效地清洗和去除。
水包油包水(W1/O/W2)复合乳液技术的制作采用二步法,首先把含有纳米粉体的油包水的乳化体配制出来,然后再分散在第二水相中去,它是初级乳化再乳化的过程。
该复合乳液组合物包括表面活性剂、固体粉剂、溶剂、杀菌剂和其它助剂。
(1)表面活性剂
采用不同的表面活性剂进行复配,会产生意想不到的协同作用,在产品中起到乳化粉体包裹和清洁作用。
该复合乳液组合物研制的第一步骤是油包水(W1/O)乳液制定,对纳米粉体进行有效的包裹。油包水(W1/O)乳化液是由油、水和乳化剂混合形成的。体系的形态是水以小液滴的形式分散于油中。水相是内相或分散相,含有粉体,油是外相或分散介质。使乳化液尽可能稳定的根本途径是在油、水界面上形成聚密膜,以大幅度降低界面张力,增加界面膜强度,防止水相液珠的聚并。采用失水山梨糖醇脂肪酸酯(SPAN80)和失水山梨醇单油酸酯聚氧乙烯醚(TWEEN80)复配,或者采用不同HLB值的脂肪醇聚氧乙烯醚进行复配,如脂肪醇聚氧乙烯醚3(AEO3)和脂肪醇聚氧乙烯醚9(AEO9)的复配,都获得了良好的油包水稳定作用。
HLB值的选择是油包水乳化体系最为重要的环节,有助于提高乳化体系的稳定。该油包水(W1/O)乳液HLB值一般都控制在3-8之间。在该油包水(W1/O)配方体系中,如果选用失水山梨糖醇脂肪酸酯(SPAN80)和TWEEN80复配,失水山梨糖醇脂肪酸酯(SPAN80)的使用量是3-6%,优先考虑使用量是3.1-3.5%;失水山梨醇单油酸酯聚氧乙烯醚(TWEEN80)的使用量是0.1-3%,优先考虑使用量是0.2-1.6%;如果选用脂肪醇聚氧乙烯醚3(AEO3)和脂肪醇聚氧乙烯醚9(AEO9)复配,脂肪醇聚氧乙烯醚3(AEO3)的使用量是3-6%,优先考虑使用量是3.1-3.8%;脂肪醇聚氧乙烯醚3(AEO9)的使用量是0.1-2%,优先考虑使用量是0.2-0.5%。
为了增加油包水(W1/O)乳液的稳定性,也可加入悬浮稳定剂和电解质,如加入0.5%的硬脂酸镁。
该水包油包水(W1/O/W2)复合乳液组合物研制的第二步骤是水包油(O/W2)乳液制造。就是把第一步骤的油包水(W1/O)乳液当成油相,用阴离子和两性离子表面活性剂形成水包油乳液。采用脂肪醇聚氧乙烯醚硫酸钠(AES)与十二烷基二甲基氧化胺进行复配,或采用十二烷基硫酸钠(K12)与椰子油脂肪酸二乙醇酰胺(6501)复配,能够保证产品具有良好的清洁性和发泡稳定性。
在该水包油(O/W2)乳液中,如果选用脂肪醇聚氧乙烯醚硫酸钠(AES)和十二烷基二甲基氧化胺复配,脂肪醇聚氧乙烯醚硫酸钠(AES)的使用量是15-25%,优先考虑使用量是19-24%;十二烷基二甲基氧化胺的使用量是1-6%,优先考虑使用量是4-5%;如果选用十二烷基硫酸钠(K12)和椰子油脂肪酸二乙醇酰胺(6501)复配十二烷基硫酸钠(K12)的使用量是15-25%,优先考虑使用量是18-23%,椰子油脂肪酸二乙醇酰胺(6501)的使用量是3-6%,优先考虑使用量是3-5%。
(2)溶剂
在该水包油包水(W1/O/W2)复合乳液组合物中,油脂的选择对体系的粘度、体系连续相的配伍性、固体颗粒的分散和配方的稳定性都有着至关重要的影响。在实验的过程中,发明人发现在油包水(W1/O)乳液的体系里,弱极性溶剂更有利于粉体的分散。可以选择的弱极性溶剂很多,但从环保的角度出发,采用了一种挥发性的异构十二烷,这是一种安全环保的高度支链化的合成烃类产品。除了起到分散粉体颗粒的作用,同时对漆面交通膜有着良好的清洁促进作用。也可以选择其他挥发度适中的弱极性溶剂,馏程在150-250℃的烷烃溶剂较为合适。
在该油包水(W1/O)乳液中,溶剂的使用量是4-15%,优先考虑使用量是5-8%。
(3)粉剂
固体粉剂是提高漆面交通膜去除率的关键点。发明人发现具有微米尺寸的氧化铝和氧化锆,在该水包油包水(W1/O/W2)复合乳液组合物中,具有高效率的悬浮稳定和清洁性协同作用。同时,经高压喷淋在车体表面,可以获得惊人的污垢、油脂和交通膜去除效率。
一般来说,粉体在配方中的占有比例高些,清洁率会相应提高,但一般粉体颗粒超过10%左右或更高时,由于强烈的吸附作用,使得乳化剂消耗率非常高。在试验的过程中,发明人发现氧化铝和氧化锆,在油包水乳液中氧化铝达到6.4%左右的容量、氧化锆达到2.13%左右的容量,有着良好的污垢、油脂和交通膜去除率。氧化铝和氧化锆可以是颗粒形状可以是球形、棱形,平均粒径在1-2微米,油包水可以保持良好的污垢、油脂和交通膜去除率。
纳米硅酸铝粉体具有三维空间的网状的连续结构,具有良好的增稠,触变和分散功能。在油包水的乳液体系中,选用10-50纳米的硅酸铝粉体加入该体系中的水相中,可以提高粉体的分散性和悬浮稳定性。
本发明提供如下具体技术方案:
一种免擦拭洗车液,为W1/O/W2型乳液,由A、B两相混合而成;其中,A相为W1/O型乳液,占免擦拭洗车液总质量的15%;A相各组分的质量占A相总质量的比分别为:固体粉剂7.2-9.6%,表面活性剂3-9%,溶剂4~15%,杀菌剂0.2%,余量为水;
B相为W2水相,B相各组分的质量占免擦拭洗车液总质量的比分别为:表面活性剂16~31%,杀菌剂0.2%,助剂2%,余量为水。
本发明所述的免擦拭洗车液,所述A相中的固体粉剂包括氧化铝和氧化锆,其粒径为1~2微米。
本发明所述的免擦拭洗车液,所述A相中的固体粉剂还包括硅酸铝粉体,其粒径为10~50纳米。
本发明所述的免擦拭洗车液,所述A相W1/O型乳液的HLB值为3~8;所述A相中的表面活性剂为失水山梨糖醇脂肪酸酯(SPAN80)和(失水山梨醇单油酸酯聚氧乙烯醚TWEEN80)复配,或者采用不同HLB值的脂肪醇聚氧乙烯醚(AEO)复配。
本发明所述的免擦拭洗车液,当A相中的表面活性剂为失水山梨糖醇脂肪酸酯(SPAN80)和失水山梨醇单油酸酯聚氧乙烯醚(TWEEN80)复配时,失水山梨糖醇脂肪酸酯(SPAN80)用量为3-6%,优选为3.1-3.5%;失水山梨醇单油酸酯聚氧乙烯醚(TWEEN80)用量为0.1-3%,优选为0.2-1.6%;
如果选用脂肪醇聚氧乙烯醚9(AEO3)和脂肪醇聚氧乙烯醚9(AEO9)复配,脂肪醇聚氧乙烯醚3(AEO3)用量为3-6%,优选为3.1-3.8%;脂肪醇聚氧乙烯醚9(AEO9)用量为0.1-2%,优选为0.2-0.5%。
本发明所述的免擦拭洗车液,所述A相中的溶剂为异构十二烷。
本发明所述的免擦拭洗车液,所述B相中的助剂为金属缓蚀剂。
本发明所述的免擦拭洗车液,所述B相中的表面活性剂为脂肪醇聚氧乙烯醚硫酸钠(AES)与十二烷基二甲基氧化胺复配,或十二烷基硫酸钠(K12)与椰子油脂肪酸二乙醇酰胺(6501)复配。
本发明所述的免擦拭洗车液,当B相中的表面活性剂为脂肪醇聚氧乙烯醚硫酸钠(AES)与十二烷基二甲基氧化胺复配时,脂肪醇聚氧乙烯醚硫酸钠(AES)用量为15-25%,优选为19-24%;十二烷基二甲基氧化胺用量为1-6%,优选为4-5%;
当选用十二烷基硫酸钠(K12)和椰子油脂肪酸二乙醇酰胺(6501)复配时,十二烷基硫酸钠(K12)用量为15-25%,优选为18-23%;椰子油脂肪酸二乙醇酰胺(6501)用量为3-6%,优选为3-5%。
本发明任一所述的免擦拭洗车液的制备方法,包括以下步骤:
(1)制备A相油包水W1/O乳液:首先把氧化铝和氧化锆粉体、纳米硅酸铝、硬脂酸镁和水倒入容器中,搅拌混合均匀,形成水相;然后把异构十二烷溶剂和非离子复合乳化剂在另外一个容器中搅拌均匀,形成油相;然后在搅拌的状态下,以点滴的输入方式,把水相缓缓混入油相;调和搅拌速度不低于600转/分钟,对于混合液体适当剪切处理,可以获得更加稳定的油包水乳液,剪切速度不低于1000转/分钟;
(2)制备W1/O/W2型乳液:把表面活性剂、杀菌剂、金属缓蚀剂与水混合均匀,完全溶解得B相,然后在搅拌的状态下,缓缓倒入上一步骤预制的A相油包水乳液,搅拌速度不低于600转/分钟。
与现有技术相比,本发明的有益效果是:
(1)摈弃国际上强酸、强碱的传统免擦拭清洗思路,采用含有固体粉体的中性乳液,不会伤害车漆挡风玻璃、也不会伤害比较脆弱的橡胶密封胶条和塑料机部件,具有卓越的交通膜去除率。
(2)固体粉剂是提高漆面污垢、油脂和交通膜去除率的关键点。发明人发现具有微米尺寸的软质的氧化铝和硬质的氧化锆和纳米尺寸的硅酸铝粉,在该免擦拭清洗剂组分中具有高效率的悬浮稳定和清洁性协同作用。经高压喷淋在车体表面,可以获得惊人的污垢、油脂和交通膜去除效率。
(3)采用特殊的油包水(W1/O)乳液制作工艺,对微米粒径的氧化铝、氧化锆进行有效的包裹。我们采用失水山梨糖醇脂肪酸酯(SPAN80)和失水山梨醇单油酸酯聚氧乙烯醚(TWEEN80)复配,或者采用不同HLB值的脂肪醇聚氧乙烯醚进行复配,如脂肪醇聚氧乙烯醚3(AEO3)和脂肪醇聚氧乙烯醚9(AEO9)的复配,都获得了良好的油包水稳定作用。
(4)利用水包油包水(W1/O/W2)复合乳液技术,既能形成长期稳定的复合乳液,又能拥有超强的清洁率,去除车漆表面上的污垢、油脂和交通膜。
具体实施方式
下面将对本发明实施例中的技术方案进行清楚、完整地描述,显然,所描述的实施例仅仅是本发明一部分实施例,而不是全部的实施例。基于本发明中的实施例,本领域普通技术人员在没有做出创造性劳动前提下所获得的所有其他实施例,都属于本发明保护的范围。
制作程序
以下实施例均按此制作工艺实施。
一种免擦拭洗车液,其制备方法包括以下步骤:
(1)制备A相油包水W1/O乳液:首先把氧化铝和氧化锆粉体、纳米硅酸铝、硬脂酸镁和水倒入容器中,搅拌混合均匀,形成水相;然后把异构十二烷溶剂和非离子复合乳化剂在另外一个容器中搅拌均匀,形成油相;然后在搅拌的状态下,以点滴的输入方式,把水相缓缓混入油相;调和搅拌速度不低于600转/分钟,对于混合液体采用均质乳化机做适当剪切处理,可以获得更加稳定的油包水乳液,剪切速度不低于1000转/分钟;
(2)制备W1/O/W2型乳液:把表面活性剂、杀菌剂、金属缓蚀剂与水混合均匀,完全溶解得B相,然后在搅拌的状态下,缓缓倒入上一步骤预制的A相油包水乳液,搅拌速度不低于600转/分钟。
以下列出不同比例的氧化铝和氧化锆的实施例和不同比例的表面活性剂的复合物的实施例。
氧化铝和氧化锆不同添加量试验实例
实施例1
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例2
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例3
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例4
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例5
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例6
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例7
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例8
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
试验结果
调整实施例1-8中的氧化铝和氧化锆的用量,其余组分含量及制备方法均保持不变。并将制得的洗车液进行性能对比。具体结果见表1。
表1含氧化铝及氧化锆免擦拭洗车液试验数据
并将A相中的固体粉剂调整为氧化铝,其余组分含量及制备方法均保持不变。将制得的洗车液进行性能对比。具体结果见表2。
表2含氧化铝免擦拭洗车液试验数据
结论:经过实验室多次测试,固体粉体仅仅采用氧化铝时,漆面喷淋清洁率不会超过53%,当固体粉体采用氧化铝和氧化锆复配并辅以纳米硅酸铝时,该水包油包水(W1/O/W2)复合乳液中含有6.4%的氧化铝和2.13%的氧化锆时,清洁率可达到90%以上,同时也发现粉体的用量继续提高后,清洁率并没有明显提高。
以下为表面活性剂不同添加量的实施例:
实施例9
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例10
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例11
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例12
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例13
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例14
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例15
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
实施例16
其具体组分含量为:
A相油包水W1/O乳液:
W1/O/W2型乳液:
试验结果:
调整实施例9-16中的表面活性剂用量,其余组分含量及制备方法均保持不变。并将制得的洗车液进行性能对比。具体结果见表3。
表3表面活性剂不同含量的试验数据
注:十二烷基二甲基氧化胺简称氧化胺。
结论:经过实验室多次测试,该水包油包水(W1/O/W2)复合乳液中,选用合适比例的表面活性剂进行复配,清洁率可达到90%以上。
A相(油包水(W1/O))选用SPAN80和TWEEN80复配,SPAN80的使用量是3-6%,TWEEN80的使用量是0.1-3%。与此同时,A相(油包水(W1/O))选用AEO3和AEO9复配,AEO3的使用量是3-6%,AEO9的使用量是0.1-2%。
B相中的表面活性剂选用脂肪醇聚氧乙烯醚硫酸钠AES与十二烷基二甲基氧化胺复配时,AES用量为15-25%,;十二烷基二甲基氧化胺用量为1-6%。B相中的表面活性剂选用K12和6501复配时,K12用量为15-25%;6501用量为3-6%。
尽管已经示出和描述了本发明的实施例,对于本领域的普通技术人员而言,可以理解在不脱离本发明的原理和精神的情况下可以对这些实施例进行多种变化、修改、替换和变型,本发明的范围由所附权利要求及其等同物限定。
Claims (6)
1.一种免擦拭洗车液,其特征在于:为W1/O/W2型乳液,由A、B两相混合而成;其中,A相为W1/O型乳液,占免擦拭洗车液总质量的15%;A相各组分的质量占A相总质量的比分别为:固体粉剂7.2-9.6%,表面活性剂3-9%,溶剂4~15%,杀菌剂0.2%,余量为水;所述A相中的固体粉剂包括氧化铝和氧化锆,其粒径为1~2微米;还包括硅酸铝粉体,其粒径为10~50纳米;
A相中的表面活性剂为失水山梨糖醇脂肪酸酯和失水山梨醇单油酸酯聚氧乙烯醚复配,失水山梨糖醇脂肪酸酯用量为3-6%,失水山梨醇单油酸酯聚氧乙烯醚用量为0.1-3%,或A相中的表面活性剂为脂肪醇聚氧乙烯(3)醚和脂肪醇聚氧乙烯(9)醚复配,脂肪醇聚氧乙烯(3)醚用量为3-6%,脂肪醇聚氧乙烯(9)醚用量为0.1-2%;
B相为W2水相,B相各组分的质量占免擦拭洗车液总质量的比分别为:表面活性剂16~31%,杀菌剂0.2%,助剂2%,余量为水;B相中的助剂为金属缓蚀剂;所述B相中的表面活性剂为脂肪醇聚氧乙烯醚硫酸钠与十二烷基二甲基氧化胺复配,或十二烷基硫酸钠与椰子油脂肪酸二乙醇酰胺复配。
2.根据权利要求1所述的免擦拭洗车液,其特征在于:所述A相W1/O型乳液的HLB值为3~8;所述A相中的表面活性剂为失水山梨糖醇脂肪酸酯和失水山梨醇单油酸酯聚氧乙烯醚复配。
3.根据权利要求2所述的免擦拭洗车液,其特征在于:A相中的表面活性剂为失水山梨糖醇脂肪酸酯和失水山梨醇单油酸酯聚氧乙烯醚复配,失水山梨糖醇脂肪酸酯用量为3.1-3.5%,失水山梨醇单油酸酯聚氧乙烯醚用量为0.2-1.6%,或选用脂肪醇聚氧乙烯(3)醚和脂肪醇聚氧乙烯(9)醚复配,脂肪醇聚氧乙烯(3)醚用量为3.1-3.8%,脂肪醇聚氧乙烯(9)醚用量为0.2-0.5%。
4.根据权利要求1所述的免擦拭洗车液,其特征在于:所述A相中的溶剂为异构十二烷。
5.根据权利要求1所述的免擦拭洗车液,其特征在于:B相中的表面活性剂为脂肪醇聚氧乙烯醚硫酸钠与十二烷基二甲基氧化胺复配,脂肪醇聚氧乙烯醚硫酸钠用量为15-25%,十二烷基二甲基氧化胺用量为1-6%,或选用十二烷基硫酸钠和椰子油脂肪酸二乙醇酰胺复配,十二烷基硫酸钠用量为15-25%,椰子油脂肪酸二乙醇酰胺用量为3-6%。
6.权利要求1-5任一所述的免擦拭洗车液的制备方法,其特征在于,包括以下步骤:
(1)制备A相油包水W1/O乳液:首先把氧化铝和氧化锆粉体、纳米硅酸铝、硬脂酸镁和水倒入容器中,搅拌混合均匀,形成水相;然后把异构十二烷溶剂和A相的表面活性剂在另外一个容器中搅拌均匀,形成油相;然后在搅拌的状态下,以点滴的输入方式,把水相缓缓混入油相;调和搅拌速度不低于600转/分钟,对于混合液体适当剪切处理,可以获得更加稳定的油包水乳液,剪切速度不低于1000转/分钟;
(2)制备W1/O/W2型乳液:把B相的表面活性剂、杀菌剂、金属缓蚀剂与水混合均匀,完全溶解得B相,然后在搅拌的状态下,缓缓倒入上一步骤预制的A相油包水乳液,搅拌速度不低于600转/分钟。
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