CN109071862A - 用于发泡包含聚苯乙烯的热塑性聚合物的Z-HFO-1336mzz发泡剂 - Google Patents

用于发泡包含聚苯乙烯的热塑性聚合物的Z-HFO-1336mzz发泡剂 Download PDF

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Publication number
CN109071862A
CN109071862A CN201780027495.9A CN201780027495A CN109071862A CN 109071862 A CN109071862 A CN 109071862A CN 201780027495 A CN201780027495 A CN 201780027495A CN 109071862 A CN109071862 A CN 109071862A
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CN
China
Prior art keywords
polystyrene
foaming agent
thermoplastic polymer
hfo
1336mzz
Prior art date
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Pending
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CN201780027495.9A
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English (en)
Chinese (zh)
Inventor
J.A.克里佐
M.L.罗宾
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EIDP Inc
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EI Du Pont de Nemours and Co
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Filing date
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Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to CN202510965567.0A priority Critical patent/CN120554701A/zh
Publication of CN109071862A publication Critical patent/CN109071862A/zh
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/143—Halogen containing compounds
    • C08J9/144—Halogen containing compounds containing carbon, halogen and hydrogen only
    • C08J9/146—Halogen containing compounds containing carbon, halogen and hydrogen only only fluorine as halogen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/0061—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof characterized by the use of several polymeric components
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/12—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent
    • C08J9/14—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a physical blowing agent organic
    • C08J9/149—Mixtures of blowing agents covered by more than one of the groups C08J9/141 - C08J9/143
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/08—Copolymers of styrene
    • C08L25/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2201/00—Foams characterised by the foaming process
    • C08J2201/02—Foams characterised by the foaming process characterised by mechanical pre- or post-treatments
    • C08J2201/03—Extrusion of the foamable blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/14—Saturated hydrocarbons, e.g. butane; Unspecified hydrocarbons
    • C08J2203/142—Halogenated saturated hydrocarbons, e.g. H3C-CF3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/16—Unsaturated hydrocarbons
    • C08J2203/162—Halogenated unsaturated hydrocarbons, e.g. H2C=CF2
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/18—Binary blends of expanding agents
    • C08J2203/182—Binary blends of expanding agents of physical blowing agents, e.g. acetone and butane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/042—Nanopores, i.e. the average diameter being smaller than 0,1 micrometer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/044—Micropores, i.e. average diameter being between 0,1 micrometer and 0,1 millimeter
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2205/00—Foams characterised by their properties
    • C08J2205/04—Foams characterised by their properties characterised by the foam pores
    • C08J2205/052—Closed cells, i.e. more than 50% of the pores are closed
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2325/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2325/02—Homopolymers or copolymers of hydrocarbons
    • C08J2325/04—Homopolymers or copolymers of styrene
    • C08J2325/08—Copolymers of styrene
    • C08J2325/12—Copolymers of styrene with unsaturated nitriles
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/14—Applications used for foams

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
CN201780027495.9A 2016-05-06 2017-05-02 用于发泡包含聚苯乙烯的热塑性聚合物的Z-HFO-1336mzz发泡剂 Pending CN109071862A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN202510965567.0A CN120554701A (zh) 2016-05-06 2017-05-02 用于发泡包含聚苯乙烯的热塑性聚合物的Z-HFO-1336mzz发泡剂

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662332616P 2016-05-06 2016-05-06
US62/332616 2016-05-06
PCT/US2017/030587 WO2017192550A1 (en) 2016-05-06 2017-05-02 Z-HFO-1336mzz BLOWING AGENT FOR FOAMING THERMOPLASTIC POLYMER COMPRISING POLYSTYRENE

Related Child Applications (1)

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CN202510965567.0A Division CN120554701A (zh) 2016-05-06 2017-05-02 用于发泡包含聚苯乙烯的热塑性聚合物的Z-HFO-1336mzz发泡剂

Publications (1)

Publication Number Publication Date
CN109071862A true CN109071862A (zh) 2018-12-21

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CN201780027495.9A Pending CN109071862A (zh) 2016-05-06 2017-05-02 用于发泡包含聚苯乙烯的热塑性聚合物的Z-HFO-1336mzz发泡剂
CN202510965567.0A Pending CN120554701A (zh) 2016-05-06 2017-05-02 用于发泡包含聚苯乙烯的热塑性聚合物的Z-HFO-1336mzz发泡剂

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Country Status (8)

Country Link
US (1) US20190218358A1 (https=)
EP (1) EP3452538B1 (https=)
JP (1) JP2019515112A (https=)
CN (2) CN109071862A (https=)
ES (1) ES3004011T3 (https=)
MX (1) MX2018013275A (https=)
PL (1) PL3452538T3 (https=)
WO (1) WO2017192550A1 (https=)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114026160A (zh) * 2019-06-24 2022-02-08 科慕埃弗西有限公司 用于热塑性聚合物的发泡剂共混物

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019075040A1 (en) * 2017-10-10 2019-04-18 The Chemours Company Fc, Llc PROCESS FOR MANUFACTURING THERMOPLASTIC FOAM CONTAINING HFO-1336MZZ (Z) AND HFO-1336MZZ (E)
WO2020018332A1 (en) * 2018-07-16 2020-01-23 The Chemours Company Fc, Llc Blowing agent blends
JP7568650B2 (ja) * 2019-05-29 2024-10-16 ザ ケマーズ カンパニー エフシー リミテッド ライアビリティ カンパニー 熱可塑性ポリマーのための発泡剤ブレンド
JP7141983B2 (ja) * 2019-07-01 2022-09-26 旭有機材株式会社 フェノールフォーム製造用樹脂組成物並びにフェノールフォーム及びその製造方法
CN114945470B (zh) * 2020-01-16 2024-07-30 旭化成建材株式会社 酚醛树脂发泡体层叠板和复合板
JP7674081B2 (ja) * 2020-08-13 2025-05-09 ディーディーピー スペシャルティ エレクトロニック マテリアルズ ユーエス リミテッド ライアビリティ カンパニー 押出発泡法によるスチレン系樹脂発泡体の製造方法、及び製造される発泡体、並びに、製造方法に使用する発泡性樹脂組成物
US12054596B2 (en) 2020-11-30 2024-08-06 Honeywell International Inc. Azeotrope or azeotrope-like compositions of Z-1-chloro-2,3,3,3-tetrafluoropropene (HCFO-1224yd(Z))
CA3228702A1 (en) * 2021-08-16 2023-02-23 Hayim Abrevaya Foamable thermoplastic compositions, thermoplastic foams and methods of making same
JP7674229B2 (ja) * 2021-12-09 2025-05-09 株式会社ジェイエスピー ポリスチレン系樹脂押出発泡板の製造方法

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CN101300296A (zh) * 2005-11-01 2008-11-05 纳幕尔杜邦公司 用于形成泡沫的包含不饱和氟碳化合物的发泡剂
CN101646724A (zh) * 2007-03-27 2010-02-10 陶氏环球技术公司 包含氟化链烯烃发泡剂的链烯基芳族聚合物泡沫体
CN101688013A (zh) * 2007-07-03 2010-03-31 陶氏环球技术公司 具有大的泡孔尺寸和高填料含量的闭孔泡沫体
CN102449100A (zh) * 2009-06-02 2012-05-09 纳幕尔杜邦公司 Z-1，1，1，4，4，4-六氟-2-丁烯的共沸和类共沸组合物
CN103172489A (zh) * 2013-03-14 2013-06-26 巨化集团技术中心 一种1,1,1,4,4,4-六氟-2-丁烯的合成方法
EP2706086A1 (de) * 2012-09-05 2014-03-12 Basf Se Verfahren zur Herstellung von Schaumstoffplatten niedriger Dichte durch Extrusion von Styrolpolymeren unter Verwendung von Hydrofluorolefinen als Treibmittel
WO2016007697A1 (en) * 2014-07-10 2016-01-14 Owens Corning Intellectual Capital, Llc Methods of manufacturing extruded polystyrene foams using carbon dioxide as a major blowing agent

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JPS597728B2 (ja) * 1976-03-23 1984-02-20 旭ダウ株式会社 スチレン系樹脂発泡体の製造方法
WO2008121776A1 (en) * 2007-03-29 2008-10-09 Arkema Inc. Hydrofluoropropene blowing agents for thermoplastics

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CN101300296A (zh) * 2005-11-01 2008-11-05 纳幕尔杜邦公司 用于形成泡沫的包含不饱和氟碳化合物的发泡剂
CN101646724A (zh) * 2007-03-27 2010-02-10 陶氏环球技术公司 包含氟化链烯烃发泡剂的链烯基芳族聚合物泡沫体
CN101688013A (zh) * 2007-07-03 2010-03-31 陶氏环球技术公司 具有大的泡孔尺寸和高填料含量的闭孔泡沫体
CN102449100A (zh) * 2009-06-02 2012-05-09 纳幕尔杜邦公司 Z-1，1，1，4，4，4-六氟-2-丁烯的共沸和类共沸组合物
EP2706086A1 (de) * 2012-09-05 2014-03-12 Basf Se Verfahren zur Herstellung von Schaumstoffplatten niedriger Dichte durch Extrusion von Styrolpolymeren unter Verwendung von Hydrofluorolefinen als Treibmittel
CN103172489A (zh) * 2013-03-14 2013-06-26 巨化集团技术中心 一种1,1,1,4,4,4-六氟-2-丁烯的合成方法
WO2016007697A1 (en) * 2014-07-10 2016-01-14 Owens Corning Intellectual Capital, Llc Methods of manufacturing extruded polystyrene foams using carbon dioxide as a major blowing agent

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114026160A (zh) * 2019-06-24 2022-02-08 科慕埃弗西有限公司 用于热塑性聚合物的发泡剂共混物

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EP3452538B1 (en) 2024-12-18
US20190218358A1 (en) 2019-07-18
JP2019515112A (ja) 2019-06-06
ES3004011T3 (en) 2025-03-11
WO2017192550A1 (en) 2017-11-09
MX2018013275A (es) 2019-03-28
CN120554701A (zh) 2025-08-29
EP3452538A1 (en) 2019-03-13
CA3021687A1 (en) 2017-11-09
PL3452538T3 (pl) 2025-04-14

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Application publication date: 20181221