CN109070009A - 制造碳分子筛膜的改进方法 - Google Patents

制造碳分子筛膜的改进方法 Download PDF

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Publication number
CN109070009A
CN109070009A CN201780015488.7A CN201780015488A CN109070009A CN 109070009 A CN109070009 A CN 109070009A CN 201780015488 A CN201780015488 A CN 201780015488A CN 109070009 A CN109070009 A CN 109070009A
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CN
China
Prior art keywords
gas
molecular sieve
carbon molecular
sieve membrane
furnace
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201780015488.7A
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English (en)
Chinese (zh)
Inventor
J·赫斯勒
W·J·柯乐斯
徐立仁
M·K·布雷登
M·V·马丁内斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Georgia Tech Research Institute
Dow Global Technologies LLC
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Georgia Tech Research Institute
Dow Global Technologies LLC
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Filing date
Publication date
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Publication of CN109070009A publication Critical patent/CN109070009A/zh
Pending legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0067—Inorganic membrane manufacture by carbonisation or pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0083—Thermal after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08—Hollow fibre membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/021—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • B01D71/64—Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/10—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/12—Oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/22—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B01D2256/245—Methane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B01D2323/081—Heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B01D2323/082—Cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/50—Control of the membrane preparation process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/20—Specific permeability or cut-off range
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/28—Degradation or stability over time
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/20—Capture or disposal of greenhouse gases of methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
CN201780015488.7A 2016-03-21 2017-03-02 制造碳分子筛膜的改进方法 Pending CN109070009A (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662310836P 2016-03-21 2016-03-21
US62/310836 2016-03-21
PCT/US2017/020432 WO2017165098A1 (en) 2016-03-21 2017-03-02 Improved method of making carbon molecular sieve membranes

Publications (1)

Publication Number Publication Date
CN109070009A true CN109070009A (zh) 2018-12-21

Family

ID=58398259

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201780015488.7A Pending CN109070009A (zh) 2016-03-21 2017-03-02 制造碳分子筛膜的改进方法

Country Status (7)

Country Link
US (1) US11084000B2 (enExample)
EP (1) EP3433009A1 (enExample)
JP (1) JP6966464B2 (enExample)
KR (1) KR102339473B1 (enExample)
CN (1) CN109070009A (enExample)
BR (1) BR112018067665A2 (enExample)
WO (1) WO2017165098A1 (enExample)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110743389A (zh) * 2019-12-07 2020-02-04 中化泉州能源科技有限责任公司 一种碳分子筛膜及其制备方法
CN112044273A (zh) * 2019-06-05 2020-12-08 中国石油天然气股份有限公司 兼具改善的渗透率与选择性的碳分子筛膜及其制备方法和应用
CN112337320A (zh) * 2019-08-08 2021-02-09 中国石油天然气股份有限公司 一种碳分子筛膜的密封方法
CN115945079A (zh) * 2022-12-29 2023-04-11 太原理工大学 一种含氟可交联聚酰亚胺基碳分子筛膜的制备方法及应用

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112018011094B1 (pt) * 2015-12-17 2023-03-07 Dow Global Technologies Llc Método para fazer uma membrana de peneira molecular de carbono, e, processo para separar uma molécula de gás de uma alimentação de gás
CA3072472A1 (en) 2017-08-14 2019-02-21 Dow Global Technologies Llc Improved method to make carbon molecular sieve hollow fiber membranes
CN115888411A (zh) * 2017-10-30 2023-04-04 陶氏环球技术有限责任公司 含第13族金属的碳分子筛膜和其制造方法
DE102018216163A1 (de) 2018-09-21 2020-03-26 Forschungszentrum Jülich GmbH CMS-Membran, Verfahren zu ihrer Herstellung und ihre Verwendung
WO2020154146A1 (en) 2019-01-25 2020-07-30 Dow Global Technologies Llc A carbon molecular sieve membrane produced from a carbon forming polymer-polyvinylidene chloride copolymer blend
EP4204130A1 (en) * 2020-08-26 2023-07-05 King Abdullah University of Science and Technology Carbon molecular sieve membranes based on oxygen-free polymeric precursors
CN119680406B (zh) * 2024-12-17 2025-09-23 大连理工大学 一种具备高气体分离性能的含氟特罗格碱基炭分子筛膜制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102527259A (zh) * 2012-02-10 2012-07-04 南京工业大学 一种复合碳分子筛膜及其制备方法和应用
US20130305921A1 (en) * 2009-10-29 2013-11-21 Shell Oil Company Method for producing carbon molecular sieve membranes in controlled atmospheres
CN104125855A (zh) * 2011-12-20 2014-10-29 佐治亚科技研究公司 高性能碳分子筛中空纤维膜的多孔形态的稳定化
CN104254384A (zh) * 2012-05-01 2014-12-31 陶氏环球技术有限责任公司 中空纤维碳分子筛膜及其制备和用途
US20150182921A1 (en) * 2013-12-26 2015-07-02 L'air Liquide, Societe Anonyme Pour L'etude Et Exploitation Des Procedes Georges Claude Carbon molecular sieve membranes made from 6fda and detda-based precursor polymers
US20150290596A1 (en) * 2012-10-29 2015-10-15 Georgia Tech Research Corporation Carbon molecular sieve membranes for nitrogen/methane separation

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07121344B2 (ja) * 1990-04-27 1995-12-25 宇部興産株式会社 非対称性中空糸炭素膜及びその製法
DE69102350T2 (de) 1990-04-27 1995-01-19 Ube Industries Asymmetrische Hohlfadenmembran aus Kohlenstoff und Verfahren zu deren Herstellung.
US5288304A (en) 1993-03-30 1994-02-22 The University Of Texas System Composite carbon fluid separation membranes
KR100263333B1 (ko) * 1997-12-31 2000-08-01 이영무 다공성 탄소분자체 분리막의 제조방법
JP4081956B2 (ja) * 1999-03-05 2008-04-30 宇部興産株式会社 部分炭素化された非対称性中空糸分離膜とその製法およびガス分離方法
US6299669B1 (en) 1999-11-10 2001-10-09 The University Of Texas System Process for CO2/natural gas separation
PT103453B (pt) * 2006-03-24 2008-05-28 Univ Do Porto Dispositivo de separação de olefinas de parafinas e de purificação de olefinas e sua utilização
SG181276A1 (en) * 2010-12-03 2012-06-28 Univ Singapore Method of fabricating a carbon molecular sieve membrane
WO2012148563A1 (en) 2011-03-07 2012-11-01 Georgia Tech Research Corporation Polyimide-based carbon molecular sieve membrane for ethylene/ethane separations
US8999037B2 (en) * 2012-05-30 2015-04-07 Georgia Tech Research Corporation Carbon molecular sieve membrane (CMSM) performance tuning by dual temperature secondary oxygen doping (DTSOD)
BR112018011094B1 (pt) 2015-12-17 2023-03-07 Dow Global Technologies Llc Método para fazer uma membrana de peneira molecular de carbono, e, processo para separar uma molécula de gás de uma alimentação de gás

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20130305921A1 (en) * 2009-10-29 2013-11-21 Shell Oil Company Method for producing carbon molecular sieve membranes in controlled atmospheres
CN104125855A (zh) * 2011-12-20 2014-10-29 佐治亚科技研究公司 高性能碳分子筛中空纤维膜的多孔形态的稳定化
CN102527259A (zh) * 2012-02-10 2012-07-04 南京工业大学 一种复合碳分子筛膜及其制备方法和应用
CN104254384A (zh) * 2012-05-01 2014-12-31 陶氏环球技术有限责任公司 中空纤维碳分子筛膜及其制备和用途
US20150290596A1 (en) * 2012-10-29 2015-10-15 Georgia Tech Research Corporation Carbon molecular sieve membranes for nitrogen/methane separation
US20150182921A1 (en) * 2013-12-26 2015-07-02 L'air Liquide, Societe Anonyme Pour L'etude Et Exploitation Des Procedes Georges Claude Carbon molecular sieve membranes made from 6fda and detda-based precursor polymers

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
J.N.BARSEMA,ET.AL: "Intermediate polymer to carbon gas separation membranes based on Matrimid PI", 《JOURNAL OF MEMBRANE SCIENCE》 *
XIAOLI MA,ET.AL: "Ultrathin carbon molecular sieve membrane for propylene/propane separation", 《AICHE JOURNAL》 *
时钧等: "《膜技术手册》", 31 January 2001, 北京：化学工业出版社 *
李砚硕等: "碳分子筛膜的制备及其气体分离性能研究", 《第18届全国分子筛学术大会论文集（下）》 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112044273A (zh) * 2019-06-05 2020-12-08 中国石油天然气股份有限公司 兼具改善的渗透率与选择性的碳分子筛膜及其制备方法和应用
CN112044273B (zh) * 2019-06-05 2023-04-25 中国石油天然气股份有限公司 兼具改善的渗透率与选择性的碳分子筛膜及其制备方法和应用
CN112337320A (zh) * 2019-08-08 2021-02-09 中国石油天然气股份有限公司 一种碳分子筛膜的密封方法
CN110743389A (zh) * 2019-12-07 2020-02-04 中化泉州能源科技有限责任公司 一种碳分子筛膜及其制备方法
CN110743389B (zh) * 2019-12-07 2023-03-24 中化泉州能源科技有限责任公司 一种碳分子筛膜及其制备方法
CN115945079A (zh) * 2022-12-29 2023-04-11 太原理工大学 一种含氟可交联聚酰亚胺基碳分子筛膜的制备方法及应用

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Publication number Publication date
KR20190033464A (ko) 2019-03-29
KR102339473B1 (ko) 2021-12-16
CA3018497A1 (en) 2017-09-28
BR112018067665A2 (pt) 2019-01-08
WO2017165098A1 (en) 2017-09-28
US11084000B2 (en) 2021-08-10
JP2019510624A (ja) 2019-04-18
EP3433009A1 (en) 2019-01-30
US20190099722A1 (en) 2019-04-04
JP6966464B2 (ja) 2021-11-17

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