KR102339473B1 - 탄소 분자체 막의 개선된 제조 방법 - Google Patents

탄소 분자체 막의 개선된 제조 방법 Download PDF

Info

Publication number
KR102339473B1
KR102339473B1 KR1020187028432A KR20187028432A KR102339473B1 KR 102339473 B1 KR102339473 B1 KR 102339473B1 KR 1020187028432 A KR1020187028432 A KR 1020187028432A KR 20187028432 A KR20187028432 A KR 20187028432A KR 102339473 B1 KR102339473 B1 KR 102339473B1
Authority
KR
South Korea
Prior art keywords
gas
molecular sieve
delete delete
carbon molecular
pyrolysis
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
KR1020187028432A
Other languages
English (en)
Korean (ko)
Other versions
KR20190033464A (ko
Inventor
존 헤슬러
윌리엄 제이. 코로스
리렌 수
마크 케이. 브래이덴
마르코스 브이. 말티네즈
Original Assignee
다우 글로벌 테크놀로지스 엘엘씨
조지아 테크 리서치 코포레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 다우 글로벌 테크놀로지스 엘엘씨, 조지아 테크 리서치 코포레이션 filed Critical 다우 글로벌 테크놀로지스 엘엘씨
Publication of KR20190033464A publication Critical patent/KR20190033464A/ko
Application granted granted Critical
Publication of KR102339473B1 publication Critical patent/KR102339473B1/ko
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0067—Inorganic membrane manufacture by carbonisation or pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0083—Thermal after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08—Hollow fibre membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/021—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • B01D71/64—Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/10—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/12—Oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/22—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B01D2256/245—Methane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B01D2323/081—Heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B01D2323/082—Cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/50—Control of the membrane preparation process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/20—Specific permeability or cut-off range
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/28—Degradation or stability over time
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/20—Capture or disposal of greenhouse gases of methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
KR1020187028432A 2016-03-21 2017-03-02 탄소 분자체 막의 개선된 제조 방법 Active KR102339473B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662310836P 2016-03-21 2016-03-21
US62/310,836 2016-03-21
PCT/US2017/020432 WO2017165098A1 (en) 2016-03-21 2017-03-02 Improved method of making carbon molecular sieve membranes

Publications (2)

Publication Number Publication Date
KR20190033464A KR20190033464A (ko) 2019-03-29
KR102339473B1 true KR102339473B1 (ko) 2021-12-16

Family

ID=58398259

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1020187028432A Active KR102339473B1 (ko) 2016-03-21 2017-03-02 탄소 분자체 막의 개선된 제조 방법

Country Status (7)

Country Link
US (1) US11084000B2 (enExample)
EP (1) EP3433009A1 (enExample)
JP (1) JP6966464B2 (enExample)
KR (1) KR102339473B1 (enExample)
CN (1) CN109070009A (enExample)
BR (1) BR112018067665A2 (enExample)
WO (1) WO2017165098A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6924757B2 (ja) * 2015-12-17 2021-08-25 ダウ グローバル テクノロジーズ エルエルシー 炭素分子篩膜を作製する方法
JP2020530811A (ja) 2017-08-14 2020-10-29 ダウ グローバル テクノロジーズ エルエルシー 炭素分子篩中空繊維膜を作製するための改良された方法
EP3703847A1 (en) * 2017-10-30 2020-09-09 Dow Global Technologies LLC Carbon molecular sieve membranes containing a group 13 metal and method to make them
DE102018216163A1 (de) 2018-09-21 2020-03-26 Forschungszentrum Jülich GmbH CMS-Membran, Verfahren zu ihrer Herstellung und ihre Verwendung
US12036518B2 (en) 2019-01-25 2024-07-16 Dow Global Technologies Llc Carbon molecular sieve membrane produced from a carbon forming polymer-polyvinylidene chloride copolymer blend
CN112044273B (zh) * 2019-06-05 2023-04-25 中国石油天然气股份有限公司 兼具改善的渗透率与选择性的碳分子筛膜及其制备方法和应用
CN112337320A (zh) * 2019-08-08 2021-02-09 中国石油天然气股份有限公司 一种碳分子筛膜的密封方法
CN110743389B (zh) * 2019-12-07 2023-03-24 中化泉州能源科技有限责任公司 一种碳分子筛膜及其制备方法
WO2022043981A1 (en) * 2020-08-26 2022-03-03 King Abdullah University Of Science And Technology Carbon molecular sieve membranes based on oxygen-free polymeric precursors
CN115945079B (zh) * 2022-12-29 2025-10-10 太原理工大学 一种含氟可交联聚酰亚胺基碳分子筛膜的制备方法及应用
CN119680406B (zh) * 2024-12-17 2025-09-23 大连理工大学 一种具备高气体分离性能的含氟特罗格碱基炭分子筛膜制备方法

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140000454A1 (en) * 2012-05-30 2014-01-02 Georgia Tech Research Corporation Carbon Molecular Sieve Membrane (CMSM) Performance Tuning By Dual Temperature Secondary Oxygen Doping (DTSOD)
US20150290596A1 (en) 2012-10-29 2015-10-15 Georgia Tech Research Corporation Carbon molecular sieve membranes for nitrogen/methane separation

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE69102350T2 (de) 1990-04-27 1995-01-19 Ube Industries Asymmetrische Hohlfadenmembran aus Kohlenstoff und Verfahren zu deren Herstellung.
JPH07121344B2 (ja) * 1990-04-27 1995-12-25 宇部興産株式会社 非対称性中空糸炭素膜及びその製法
US5288304A (en) 1993-03-30 1994-02-22 The University Of Texas System Composite carbon fluid separation membranes
KR100263333B1 (ko) * 1997-12-31 2000-08-01 이영무 다공성 탄소분자체 분리막의 제조방법
JP4081956B2 (ja) * 1999-03-05 2008-04-30 宇部興産株式会社 部分炭素化された非対称性中空糸分離膜とその製法およびガス分離方法
US6299669B1 (en) 1999-11-10 2001-10-09 The University Of Texas System Process for CO2/natural gas separation
PT103453B (pt) * 2006-03-24 2008-05-28 Univ Do Porto Dispositivo de separação de olefinas de parafinas e de purificação de olefinas e sua utilização
US8486179B2 (en) 2009-10-29 2013-07-16 Georgia Tech Research Corporation Method for producing carbon molecular sieve membranes in controlled atmospheres
SG181276A1 (en) * 2010-12-03 2012-06-28 Univ Singapore Method of fabricating a carbon molecular sieve membrane
CN103347596A (zh) * 2011-03-07 2013-10-09 佐治亚科技研究公司 用于乙烯/乙烷分离的基于聚酰亚胺的碳分子筛膜
KR102062413B1 (ko) * 2011-12-20 2020-01-03 조지아 테크 리서치 코오포레이션 고성능 탄소 분자체 중공 섬유막의 다공성 형태의 안정화
CN102527259A (zh) * 2012-02-10 2012-07-04 南京工业大学 一种复合碳分子筛膜及其制备方法和应用
US9346011B2 (en) * 2012-05-01 2016-05-24 Dow Global Technologies Llc Hollow fiber carbon molecular sieve membrane and preparation and use thereof
WO2015100161A1 (en) * 2013-12-26 2015-07-02 L'air Liquide, Societe Anonyme Pour L'etude Et Exploitation Des Procedes Georges Claude Carbon molecular sieve membranes made from 6fda and detda-based precursor polymers
JP6924757B2 (ja) * 2015-12-17 2021-08-25 ダウ グローバル テクノロジーズ エルエルシー 炭素分子篩膜を作製する方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140000454A1 (en) * 2012-05-30 2014-01-02 Georgia Tech Research Corporation Carbon Molecular Sieve Membrane (CMSM) Performance Tuning By Dual Temperature Secondary Oxygen Doping (DTSOD)
US20150290596A1 (en) 2012-10-29 2015-10-15 Georgia Tech Research Corporation Carbon molecular sieve membranes for nitrogen/methane separation

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
AIChE Journal. 2015.8.31., Vol. 62, No. 2, 491~499*

Also Published As

Publication number Publication date
JP6966464B2 (ja) 2021-11-17
JP2019510624A (ja) 2019-04-18
KR20190033464A (ko) 2019-03-29
WO2017165098A1 (en) 2017-09-28
CN109070009A (zh) 2018-12-21
EP3433009A1 (en) 2019-01-30
US11084000B2 (en) 2021-08-10
CA3018497A1 (en) 2017-09-28
BR112018067665A2 (pt) 2019-01-08
US20190099722A1 (en) 2019-04-04

Similar Documents

Publication Publication Date Title
KR102339473B1 (ko) 탄소 분자체 막의 개선된 제조 방법
KR102718104B1 (ko) 탄소 분자체 막의 향상된 제조 방법
KR102648494B1 (ko) 탄소 분자체 막을 제조하는 방법
JP7262454B2 (ja) 第１３族金属を含有する炭素分子ふるい膜およびそれらを作製する方法
KR102339475B1 (ko) 개선된 전이금속을 포함하는 탄소 분자체 막들 및 그들의 제조 방법
KR20240037283A (ko) 중공 섬유 탄소 멤브레인의 제조 방법
KR102719972B1 (ko) 탄소 분자체 막의 향상된 제조 방법
CA3018497C (en) Improved method of making carbon molecular sieve membranes
KR20250138749A (ko) 역 선택적 탄소 막 및 이의 제조 방법

Legal Events

Date Code Title Description
PA0105 International application

Patent event date: 20181002

Patent event code: PA01051R01D

Comment text: International Patent Application

AMND Amendment
PG1501 Laying open of application
A201 Request for examination
AMND Amendment
PA0201 Request for examination

Patent event code: PA02012R01D

Patent event date: 20200217

Comment text: Request for Examination of Application

E902 Notification of reason for refusal
PE0902 Notice of grounds for rejection

Comment text: Notification of reason for refusal

Patent event date: 20210217

Patent event code: PE09021S01D

AMND Amendment
E601 Decision to refuse application
PE0601 Decision on rejection of patent

Patent event date: 20210821

Comment text: Decision to Refuse Application

Patent event code: PE06012S01D

Patent event date: 20210217

Comment text: Notification of reason for refusal

Patent event code: PE06011S01I

AMND Amendment
PX0901 Re-examination

Patent event code: PX09011S01I

Patent event date: 20210821

Comment text: Decision to Refuse Application

Patent event code: PX09012R01I

Patent event date: 20210416

Comment text: Amendment to Specification, etc.

Patent event code: PX09012R01I

Patent event date: 20200217

Comment text: Amendment to Specification, etc.

Patent event code: PX09012R01I

Patent event date: 20181025

Comment text: Amendment to Specification, etc.

PX0701 Decision of registration after re-examination

Patent event date: 20211025

Comment text: Decision to Grant Registration

Patent event code: PX07013S01D

Patent event date: 20210923

Comment text: Amendment to Specification, etc.

Patent event code: PX07012R01I

Patent event date: 20210821

Comment text: Decision to Refuse Application

Patent event code: PX07011S01I

Patent event date: 20210416

Comment text: Amendment to Specification, etc.

Patent event code: PX07012R01I

Patent event date: 20200217

Comment text: Amendment to Specification, etc.

Patent event code: PX07012R01I

Patent event date: 20181025

Comment text: Amendment to Specification, etc.

Patent event code: PX07012R01I

X701 Decision to grant (after re-examination)
PR0701 Registration of establishment

Comment text: Registration of Establishment

Patent event date: 20211210

Patent event code: PR07011E01D

PR1002 Payment of registration fee

Payment date: 20211213

End annual number: 3

Start annual number: 1

PG1601 Publication of registration
PR1001 Payment of annual fee

Payment date: 20241029

Start annual number: 4

End annual number: 4