JP6966464B2 - 炭素分子篩膜を作製する改善された方法 - Google Patents

炭素分子篩膜を作製する改善された方法 Download PDF

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JP6966464B2
JP6966464B2 JP2018545916A JP2018545916A JP6966464B2 JP 6966464 B2 JP6966464 B2 JP 6966464B2 JP 2018545916 A JP2018545916 A JP 2018545916A JP 2018545916 A JP2018545916 A JP 2018545916A JP 6966464 B2 JP6966464 B2 JP 6966464B2
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gas
carbon molecular
membrane
furnace
pyrolysis temperature
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JP2019510624A5 (enExample
JP2019510624A (ja
Inventor
ジョン・ヘスラー
ウィリアム・ジェイ・コロス
リーレン・シュー
マーク・ケイ・ブライデン
マルコス・ヴイ・マルティネス
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Georgia Tech Research Corp
Dow Global Technologies LLC
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Dow Global Technologies LLC
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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0039—Inorganic membrane manufacture
    • B01D67/0067—Inorganic membrane manufacture by carbonisation or pyrolysis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/22—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion
    • B01D53/228—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by diffusion characterised by specific membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0002—Organic membrane manufacture
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D67/00—Processes specially adapted for manufacturing semi-permeable membranes for separation processes or apparatus
    • B01D67/0081—After-treatment of organic or inorganic membranes
    • B01D67/0083—Thermal after-treatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D69/00—Semi-permeable membranes for separation processes or apparatus characterised by their form, structure or properties; Manufacturing processes specially adapted therefor
    • B01D69/08—Hollow fibre membranes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/02—Inorganic material
    • B01D71/021—Carbon
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/58—Other polymers having nitrogen in the main chain, with or without oxygen or carbon only
    • B01D71/62—Polycondensates having nitrogen-containing heterocyclic rings in the main chain
    • B01D71/64—Polyimides; Polyamide-imides; Polyester-imides; Polyamide acids or similar polyimide precursors
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/10—Nitrogen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/12—Oxygen
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/22—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2256/00—Main component in the product gas stream after treatment
    • B01D2256/24—Hydrocarbons
    • B01D2256/245—Methane
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B01D2323/081—Heating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/08—Specific temperatures applied
    • B01D2323/082—Cooling
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2323/00—Details relating to membrane preparation
    • B01D2323/50—Control of the membrane preparation process
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/20—Specific permeability or cut-off range
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2325/00—Details relating to properties of membranes
    • B01D2325/28—Degradation or stability over time
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/20—Capture or disposal of greenhouse gases of methane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Silicates, Zeolites, And Molecular Sieves (AREA)
JP2018545916A 2016-03-21 2017-03-02 炭素分子篩膜を作製する改善された方法 Active JP6966464B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US201662310836P 2016-03-21 2016-03-21
US62/310,836 2016-03-21
PCT/US2017/020432 WO2017165098A1 (en) 2016-03-21 2017-03-02 Improved method of making carbon molecular sieve membranes

Publications (3)

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JP2019510624A JP2019510624A (ja) 2019-04-18
JP2019510624A5 JP2019510624A5 (enExample) 2019-06-20
JP6966464B2 true JP6966464B2 (ja) 2021-11-17

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JP2018545916A Active JP6966464B2 (ja) 2016-03-21 2017-03-02 炭素分子篩膜を作製する改善された方法

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US (1) US11084000B2 (enExample)
EP (1) EP3433009A1 (enExample)
JP (1) JP6966464B2 (enExample)
KR (1) KR102339473B1 (enExample)
CN (1) CN109070009A (enExample)
BR (1) BR112018067665A2 (enExample)
CA (1) CA3018497A1 (enExample)
WO (1) WO2017165098A1 (enExample)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
BR112018011094B1 (pt) * 2015-12-17 2023-03-07 Dow Global Technologies Llc Método para fazer uma membrana de peneira molecular de carbono, e, processo para separar uma molécula de gás de uma alimentação de gás
US11517857B2 (en) 2017-08-14 2022-12-06 Dow Global Technologies Llc Method to make carbon molecular sieve hollow fiber membranes
CN111225736B (zh) * 2017-10-30 2023-03-31 陶氏环球技术有限责任公司 含第13族金属的碳分子筛膜和其制造方法
DE102018216163A1 (de) 2018-09-21 2020-03-26 Forschungszentrum Jülich GmbH CMS-Membran, Verfahren zu ihrer Herstellung und ihre Verwendung
US12036518B2 (en) 2019-01-25 2024-07-16 Dow Global Technologies Llc Carbon molecular sieve membrane produced from a carbon forming polymer-polyvinylidene chloride copolymer blend
CN112044273B (zh) * 2019-06-05 2023-04-25 中国石油天然气股份有限公司 兼具改善的渗透率与选择性的碳分子筛膜及其制备方法和应用
CN112337320A (zh) * 2019-08-08 2021-02-09 中国石油天然气股份有限公司 一种碳分子筛膜的密封方法
CN110743389B (zh) * 2019-12-07 2023-03-24 中化泉州能源科技有限责任公司 一种碳分子筛膜及其制备方法
US20230311073A1 (en) * 2020-08-26 2023-10-05 King Abdullah University Of Science And Technology Carbon molecular sieve membranes based on oxygen-free polymeric precursors
CN115945079B (zh) * 2022-12-29 2025-10-10 太原理工大学 一种含氟可交联聚酰亚胺基碳分子筛膜的制备方法及应用
CN119680406B (zh) * 2024-12-17 2025-09-23 大连理工大学 一种具备高气体分离性能的含氟特罗格碱基炭分子筛膜制备方法

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DE69102350T2 (de) 1990-04-27 1995-01-19 Ube Industries Asymmetrische Hohlfadenmembran aus Kohlenstoff und Verfahren zu deren Herstellung.
JPH07121344B2 (ja) * 1990-04-27 1995-12-25 宇部興産株式会社 非対称性中空糸炭素膜及びその製法
US5288304A (en) 1993-03-30 1994-02-22 The University Of Texas System Composite carbon fluid separation membranes
KR100263333B1 (ko) * 1997-12-31 2000-08-01 이영무 다공성 탄소분자체 분리막의 제조방법
JP4081956B2 (ja) * 1999-03-05 2008-04-30 宇部興産株式会社 部分炭素化された非対称性中空糸分離膜とその製法およびガス分離方法
US6299669B1 (en) 1999-11-10 2001-10-09 The University Of Texas System Process for CO2/natural gas separation
PT103453B (pt) * 2006-03-24 2008-05-28 Univ Do Porto Dispositivo de separação de olefinas de parafinas e de purificação de olefinas e sua utilização
US8486179B2 (en) 2009-10-29 2013-07-16 Georgia Tech Research Corporation Method for producing carbon molecular sieve membranes in controlled atmospheres
SG181276A1 (en) * 2010-12-03 2012-06-28 Univ Singapore Method of fabricating a carbon molecular sieve membrane
EP2683473A1 (en) * 2011-03-07 2014-01-15 Georgia Tech Research Corporation Polyimide-based carbon molecular sieve membrane for ethylene/ethane separations
AU2012354175B2 (en) * 2011-12-20 2015-04-30 Air Liquide Advanced Technologies U.S., Llc Stabilization of porous morphologies for high performance carbon molecular sieve hollow fiber membranes
CN102527259A (zh) * 2012-02-10 2012-07-04 南京工业大学 一种复合碳分子筛膜及其制备方法和应用
EP2844368B1 (en) * 2012-05-01 2019-08-07 Dow Global Technologies LLC Use of a hollow fiber carbon molecular sieve membrane
US8999037B2 (en) * 2012-05-30 2015-04-07 Georgia Tech Research Corporation Carbon molecular sieve membrane (CMSM) performance tuning by dual temperature secondary oxygen doping (DTSOD)
EP2911769A4 (en) 2012-10-29 2016-06-15 Georgia Tech Res Inst CARBON MOLECULAR SIEVE MEMBRANES FOR NITROGEN / METHANE SEPARATION
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Publication number Publication date
US20190099722A1 (en) 2019-04-04
WO2017165098A1 (en) 2017-09-28
US11084000B2 (en) 2021-08-10
EP3433009A1 (en) 2019-01-30
CN109070009A (zh) 2018-12-21
KR20190033464A (ko) 2019-03-29
CA3018497A1 (en) 2017-09-28
BR112018067665A2 (pt) 2019-01-08
JP2019510624A (ja) 2019-04-18
KR102339473B1 (ko) 2021-12-16

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