CN109020701A - A kind of high-performance bio bacterial manure - Google Patents

A kind of high-performance bio bacterial manure Download PDF

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Publication number
CN109020701A
CN109020701A CN201811057069.2A CN201811057069A CN109020701A CN 109020701 A CN109020701 A CN 109020701A CN 201811057069 A CN201811057069 A CN 201811057069A CN 109020701 A CN109020701 A CN 109020701A
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CN
China
Prior art keywords
bacterial manure
phosphoric acid
performance bio
weight
base carrier
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CN201811057069.2A
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Chinese (zh)
Inventor
胡剑锋
胡娟红
俞冬冬
沈学锋
郑锋
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ZHEJIANG SHIJIA TECHNOLOGY CO LTD
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ZHEJIANG SHIJIA TECHNOLOGY CO LTD
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Priority to CN201811057069.2A priority Critical patent/CN109020701A/en
Publication of CN109020701A publication Critical patent/CN109020701A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B3/00Fertilisers based essentially on di-calcium phosphate
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity

Abstract

The present invention relates to technical field of fertilizers.The invention discloses a kind of high-performance bio bacterial manure, it is made by arbuscular mycorrhiza preparation, phosphorus base carrier, the sustained release raw materials such as potassium nitrogen powder and organic matter material, wherein phosphorus base carrier is made by phosphoric acid solution, milk of lime and polyvinyl alcohol microparticles, sustained release potassium nitrogen powder is made by potash fertilizer, nitrogenous fertilizer, water and alginate, and organic matter material after rubbish from cooking drying and crushing by being made.By high-performance bio bacterial manure produced by the present invention, performance is stablized, and function is extensive, has no toxic side effect, and has good application prospect in terms of vegetable cultivation, can promote the absorption of nutritional ingredient in soil, improves yield of vegetables;And antibiont can be secreted, inhibits soil-borne disease former, prevents pest and disease damage.

Description

A kind of high-performance bio bacterial manure
Technical field
The present invention relates to technical field of fertilizers, more particularly, to a kind of high-performance bio bacterial manure.
Background technique
Since middle 1960s, basic change is had occurred in the fertilizer structure in China, and the application of chemical fertilizer is big Width increases, and organic fertilizer accounts for the specific gravity of the total dosage of fertilizer and 100% dropped to current 50% or so by 1949.Largely answer With chemical fertilizer, although having played huge production-increasing function on China's agricultural history, chemical fertilizer only decades are used The drawbacks of just exposing it time: very big, and contaminated soil is destroyed to farmland quality not to the utmost, makes soil hardening, causes soil The decline of earth fertility, quality of agricultural product reduce.
Bio-feritlizer is a kind of with efficient, nontoxic, pollution-free and non-harmful new-type fertilizer, both can satisfy crop increasing The requirement of production also can solve people for chemical fertilizer bring worry is excessively used, but existing bio-feritlizer is playing it There are still certain defects, such as addition foreign carrier to change soil texture when effect, and nutritional ingredient cannot achieve sustained release etc. and ask Topic.
Summary of the invention
It is supported to solve the above problems, can be fully utilized the present invention provides a kind of carrier and give soil with equilibrium The high-performance bio bacterial manure divided.
To achieve the above object, The technical solution adopted by the invention is as follows:
A kind of high-performance bio bacterial manure, consists of the following components in percentage by weight:
Arbuscular mycorrhiza 4~9wt% of preparation, phosphorus 20~35wt% of base carrier, are sustained potassium nitrogen 25~30wt% of powder, and surplus is organic Matter raw material;
Phosphorus base carrier is made by phosphoric acid solution, milk of lime and polyvinyl alcohol microparticles, sustained release potassium nitrogen powder by potash fertilizer, nitrogenous fertilizer, water and Alginate is made, and organic matter material after rubbish from cooking drying and crushing by being made.
Preferably, high-performance bio bacterial manure is made by following methods:
It is stirred 1~2 hour after arbuscular mycorrhiza preparation is mixed with phosphorus base carrier with the revolving speed of 5~10rpm, then adds sustained release Potassium nitrogen powder continues stirring 30~40 minutes, and organic matter material is then added and mixes up to high-performance bio bacterial manure.
Preferably, phosphorus base carrier is made by following raw material, the milk of lime that relative density is 1~1.1, relative density is 1.2~1.3 phosphoric acid solution, wherein the molar ratio of calcium hydroxide and phosphoric acid is 1:1, polyvinyl alcohol in milk of lime and phosphoric acid solution The additive amount of microballoon is the 30~55wt% of the sum of phosphoric acid solution and milk of lime weight.
Preferably, the partial size of polyethylene microballoon is 1~4 micron.
Preferably, phosphorus base carrier is made by following methods, by polyvinyl alcohol microparticles and polyvinylalcohol microsphere ball weight 0.05 ~0.08 times of phosphate coupling agent is added in phosphoric acid solution after evenly mixing, then under with the stirring of 60~90rpm revolving speed Milk of lime is added, temperature is controlled at 50~55 DEG C, and complete post curing 1~1.5 hour is added, then washs at 10~15 DEG C Filtering, and filter cake is dried at 30~40 DEG C;It is ground into Dicalcium Phosphate after drying, obtained Dicalcium Phosphate is added to It handles in 60~70 DEG C of dehydrated alcohol 1~1.5 hour, is then cleaned simultaneously by 70~80wt% ethanol water at room temperature Phosphorus base carrier is made after drying.
Preferably, sustained release potassium nitrogen powder is made by following raw material, mole of potassium element and nitrogen in nitrogenous fertilizer in potash fertilizer Than for 1:0.4~0.6, the weight of alginate is the 10~15wt% of the sum of potash fertilizer and nitrogenous fertilizer total weight, the weight of water is sea 2~4.5 times of alginates weight.
Preferably, sustained release potassium nitrogen powder is made by following methods, first potash fertilizer and nitrogenous fertilizer are dispersed in water, 20~ Alginate is added under the mixing speed of 30rpm, then proceedes to stir 30~40 minutes with the revolving speed of 10~15rpm, finally do It is dry and crush.
The carrier of bio-bacterial manure selects special porous calcium phosphate hydrogen calcium in the present invention, and porous calcium phosphate hydrogen calcium can be made in early period For the presence of arbuscular mycorrhiza preparations carrier, can be merged well without failing with the other components in fertilizer, while phosphorus Sour hydrogen calcium is a kind of phosphate fertilizer for being slightly soluble in water, and can gradually be dissolved in rainwater in the later period will not have an impact soil, and due to It, which can be used as phosphate fertilizer, can promote the fertility of soil;Use polyvinyl alcohol for template in the preparation process of porous calcium phosphate hydrogen calcium Agent is synthesized in water phase using milk of lime and phosphoric acid, and polyvinyl alcohol is a kind of organic polymer for being dissolved in water at high temperature, It can be stable in the presence of in water at low temperature;Using ethanol water in the base for not damaging calcium monohydrogen phosphate after calcium monohydrogen phosphate synthesis Polyvinyl alcohol is removed on plinth, the calcium monohydrogen phosphate with porous structure is made.In addition, for the nitrogenous fertilizer and potassium that are added in the present invention Fertilizer, the effect of sustained release is realized using the method for alginate cladding, and alginate here can select sodium alginate, alginic acid Potassium etc..
Therefore, the invention has the following advantages: by high-performance bio bacterial manure produced by the present invention, performance is stablized, function Extensively, it has no toxic side effect, there is good application prospect in terms of vegetable cultivation, the suction of nutritional ingredient in soil can be promoted It receives, improves yield of vegetables;And antibiont can be secreted, inhibits soil-borne disease former, prevents pest and disease damage.
Specific embodiment
Further description of the technical solution of the present invention With reference to embodiment.
Obviously, the described embodiments are merely a part of the embodiments of the present invention, instead of all the embodiments.Based on this Embodiment in invention, all other reality obtained by those of ordinary skill in the art without making creative efforts Example is applied, shall fall within the protection scope of the present invention.
In the present invention, if not refering in particular to, all equipment and raw material is commercially available or the industry is common, Method in following embodiments is unless otherwise instructed conventional method in that art.
Embodiment 1
A kind of high-performance bio bacterial manure, consists of the following components in percentage by weight:
Arbuscular mycorrhiza preparation 4wt%, phosphorus base carrier 20wt% are sustained potassium nitrogen powder 30wt%, organic matter material 46wt%;
Phosphorus base carrier is made by phosphoric acid solution, milk of lime and polyvinyl alcohol microparticles, and the relative density of milk of lime is 1, phosphoric acid solution Relative density be 1.2, wherein the molar ratio of calcium hydroxide and phosphoric acid is 1:1, polyvinylalcohol microsphere in milk of lime and phosphoric acid solution The additive amount of ball is the 30wt% of the sum of phosphoric acid solution and milk of lime weight, and the partial size of polyethylene microballoon is 1 micron;Phosphorus base carrier It is made by following methods, after evenly mixing with 0.05 times of polyvinylalcohol microsphere ball weight of phosphate coupling agent by polyvinyl alcohol microparticles It is added in phosphoric acid solution, then milk of lime is added under with the stirring of 60rpm revolving speed, temperature is controlled at 50 DEG C, is added complete Post curing 1 hour, filtering is then washed at 10 DEG C, and filter cake is dried at 30 DEG C;Dicalcium Phosphate is ground into after drying, Obtained Dicalcium Phosphate is added in 60 DEG C of dehydrated alcohol and is handled 1 hour, then passes through 70wt% ethyl alcohol at room temperature Phosphorus base carrier is simultaneously made after drying for aqueous cleaning;
Sustained release potassium nitrogen powder is made by potash fertilizer, nitrogenous fertilizer, water and alginate, mole of potassium element and nitrogen in nitrogenous fertilizer in potash fertilizer Than for 1:0.4, the weight of alginate is the 10wt% of the sum of potash fertilizer and nitrogenous fertilizer total weight, the weight of water is alginate weight 2 times;Sustained release potassium nitrogen powder is made by following methods, is first dispersed in water potash fertilizer and nitrogenous fertilizer, under the mixing speed of 20rpm Alginate is added, then proceedes to stir with the revolving speed of 10rpm 30 minutes, finally drying simultaneously crushes;
Organic matter material after rubbish from cooking drying and crushing by being made;
High-performance bio bacterial manure is made by following methods:
It is stirred 1 hour after arbuscular mycorrhiza preparation is mixed with phosphorus base carrier with the revolving speed of 5rpm, then adds sustained release potassium nitrogen powder Stirring 30 minutes is continued at end, and organic matter material is then added and mixes up to high-performance bio bacterial manure.
Embodiment 2
A kind of high-performance bio bacterial manure, consists of the following components in percentage by weight:
Arbuscular mycorrhiza preparation 9wt%, phosphorus base carrier 35wt% are sustained potassium nitrogen powder 25wt%, organic matter material 31wt%;
Phosphorus base carrier is made by phosphoric acid solution, milk of lime and polyvinyl alcohol microparticles, and the relative density of milk of lime is 1.1, and phosphoric acid is molten The relative density of liquid is that the molar ratio of calcium hydroxide and phosphoric acid is 1:1, polyvinyl alcohol in 1.3, wherein milk of lime and phosphoric acid solution The additive amount of microballoon is the 55wt% of the sum of phosphoric acid solution and milk of lime weight, and the partial size of polyethylene microballoon is 4 microns;Phosphorus base load Body is made by following methods, and polyvinyl alcohol microparticles are uniformly mixed with 0.08 times of polyvinylalcohol microsphere ball weight of phosphate coupling agent After be added in phosphoric acid solution, then with 90rpm revolving speed stirring under milk of lime is added, temperature control at 55 DEG C, be added Full post curing 1.5 hours, filtering is then washed at 15 DEG C, and filter cake is dried at 40 DEG C;Calcium monohydrogen phosphate is ground into after drying Obtained Dicalcium Phosphate is added in 70 DEG C of dehydrated alcohol and handles 1.5 hours, then passes through at room temperature by powder Phosphorus base carrier is made after washing and drying in 80wt% ethanol water;
Sustained release potassium nitrogen powder is made by potash fertilizer, nitrogenous fertilizer, water and alginate, mole of potassium element and nitrogen in nitrogenous fertilizer in potash fertilizer Than for 1:0.6, the weight of alginate is the 15wt% of the sum of potash fertilizer and nitrogenous fertilizer total weight, the weight of water is alginate weight 4.5 times;Sustained release potassium nitrogen powder is made by following methods, is first dispersed in water potash fertilizer and nitrogenous fertilizer, in the mixing speed of 30rpm Lower addition alginate then proceedes to stir with the revolving speed of 15rpm 40 minutes, and finally drying simultaneously crushes;
Organic matter material after rubbish from cooking drying and crushing by being made;
High-performance bio bacterial manure is made by following methods:
It is stirred 2 hours after arbuscular mycorrhiza preparation is mixed with phosphorus base carrier with the revolving speed of 10rpm, then adds sustained release potassium nitrogen powder Stirring 40 minutes is continued at end, and organic matter material is then added and mixes up to high-performance bio bacterial manure.
Embodiment 3
A kind of high-performance bio bacterial manure, consists of the following components in percentage by weight:
Arbuscular mycorrhiza preparation 6wt%, phosphorus base carrier 25wt% are sustained potassium nitrogen powder 28wt%, organic matter material 41wt%;
Phosphorus base carrier is made by phosphoric acid solution, milk of lime and polyvinyl alcohol microparticles, and the relative density of milk of lime is 1.03, and phosphoric acid is molten The relative density of liquid is that the molar ratio of calcium hydroxide and phosphoric acid is 1:1, polyvinyl alcohol in 1.23, wherein milk of lime and phosphoric acid solution The additive amount of microballoon is the 35wt% of the sum of phosphoric acid solution and milk of lime weight, and the partial size of polyethylene microballoon is 2 microns;Phosphorus base load Body is made by following methods, and polyvinyl alcohol microparticles are uniformly mixed with 0.06 times of polyvinylalcohol microsphere ball weight of phosphate coupling agent After be added in phosphoric acid solution, then with 70rpm revolving speed stirring under milk of lime is added, temperature control at 52 DEG C, be added Full post curing 1.2 hours, filtering is then washed at 12 DEG C, and filter cake is dried at 33 DEG C;Calcium monohydrogen phosphate is ground into after drying Obtained Dicalcium Phosphate is added in 63 DEG C of dehydrated alcohol and handles 1.2 hours, then passes through at room temperature by powder Phosphorus base carrier is made after washing and drying in 72wt% ethanol water;
Sustained release potassium nitrogen powder is made by potash fertilizer, nitrogenous fertilizer, water and alginate, mole of potassium element and nitrogen in nitrogenous fertilizer in potash fertilizer Than for 1:0.43, the weight of alginate is the 12wt% of the sum of potash fertilizer and nitrogenous fertilizer total weight, the weight of water is alginate weight 3 times of amount;Sustained release potassium nitrogen powder is made by following methods, is first dispersed in water potash fertilizer and nitrogenous fertilizer, in the mixing speed of 25rpm Lower addition alginate then proceedes to stir with the revolving speed of 12rpm 35 minutes, and finally drying simultaneously crushes;
Organic matter material after rubbish from cooking drying and crushing by being made;
High-performance bio bacterial manure is made by following methods:
It is stirred 1.2 hours after arbuscular mycorrhiza preparation is mixed with phosphorus base carrier with the revolving speed of 7rpm, then adds sustained release potassium nitrogen Powder continues stirring 32 minutes, and organic matter material is then added and mixes up to high-performance bio bacterial manure.
Embodiment 4
A kind of high-performance bio bacterial manure, consists of the following components in percentage by weight:
Arbuscular mycorrhiza preparation 8wt%, phosphorus base carrier 30wt% are sustained potassium nitrogen powder 27wt%, organic matter material 35wt%;
Phosphorus base carrier is made by phosphoric acid solution, milk of lime and polyvinyl alcohol microparticles, and the relative density of milk of lime is 1.07, and phosphoric acid is molten The relative density of liquid is that the molar ratio of calcium hydroxide and phosphoric acid is 1:1, polyvinyl alcohol in 1.27, wherein milk of lime and phosphoric acid solution The additive amount of microballoon is the 45wt% of the sum of phosphoric acid solution and milk of lime weight, and the partial size of polyethylene microballoon is 3 microns;Phosphorus base load Body is made by following methods, and polyvinyl alcohol microparticles are uniformly mixed with 0.07 times of polyvinylalcohol microsphere ball weight of phosphate coupling agent After be added in phosphoric acid solution, then with 80rpm revolving speed stirring under milk of lime is added, temperature control at 53 DEG C, be added Full post curing 1.3 hours, filtering is then washed at 13 DEG C, and filter cake is dried at 37 DEG C;Calcium monohydrogen phosphate is ground into after drying Obtained Dicalcium Phosphate is added in 67 DEG C of dehydrated alcohol and handles 1.3 hours, then passes through at room temperature by powder Phosphorus base carrier is made after washing and drying in 78wt% ethanol water;
Sustained release potassium nitrogen powder is made by potash fertilizer, nitrogenous fertilizer, water and alginate, mole of potassium element and nitrogen in nitrogenous fertilizer in potash fertilizer Than for 1:0.57, the weight of alginate is the 13wt% of the sum of potash fertilizer and nitrogenous fertilizer total weight, the weight of water is alginate weight 3.5 times of amount;Sustained release potassium nitrogen powder is made by following methods, is first dispersed in water potash fertilizer and nitrogenous fertilizer, in the stirring speed of 25rpm Degree is lower to be added alginate, then proceedes to stir with the revolving speed of 13rpm 35 minutes, finally drying simultaneously crushes;
Organic matter material after rubbish from cooking drying and crushing by being made;
High-performance bio bacterial manure is made by following methods:
It is stirred 1.8 hours after arbuscular mycorrhiza preparation is mixed with phosphorus base carrier with the revolving speed of 8rpm, then adds sustained release potassium nitrogen Powder continues stirring 38 minutes, and organic matter material is then added and mixes up to high-performance bio bacterial manure.
Tomato applies effect of fertilizer test
With choosing 6 growing tomatoes, every planting site is 1 mu, is set as Examples 1 to 4 group and control group 1, control group 2.
Control group 1 only applies npk fertilizer by the prior art;
Control group 2 adds the group planting bush mycorrhiza agent of 5wt% on the basis of control group 1 applies npk fertilizer;
Examples 1 to 4 group applies 1~4 high-performance bio bacterial manure of the embodiment of the present invention.
Fertilizing method and daily maintenance management carry out according to a conventional method, finally compare each group tomato production and pest and disease damage Situation the results are shown in Table 1.
1 tomato production of table compares
Group Per mu yield (Kg/ mus) Mean fruit weight (g)
Control group 1 2035 194
Control group 2 2289 224
Example 1 group 2890 285
2 groups of embodiment 2970 295
3 groups of embodiment 3012 301
4 groups of embodiment 2960 297
It can be seen from upper table 1 compared with control group 1, the tomato per mu yield and single fruit weight of control group 2 increase, with Control group 2 is compared, Examples 1 to 4 group, i.e., by the tomato of the present invention resulting colleges and universities' bio-bacterial manure fertilising, per mu yield and average Single fruit weight is significantly increased, and shows that the resulting high-performance bio bacterial manure effect of the present invention is prominent and increases production and see disease pest with significant Evil effect.
It should be understood that those skilled in the art, can be improved or be become according to the above description It changes, and all these modifications and variations should all belong to the protection domain of appended claims of the present invention.

Claims (7)

1. a kind of high-performance bio bacterial manure, it is characterised in that consist of the following components in percentage by weight:
Arbuscular mycorrhiza 4~9wt% of preparation, phosphorus 20~35wt% of base carrier are sustained potassium nitrogen 25~30wt% of powder, and surplus is organic matter Raw material;
The phosphorus base carrier is made by phosphoric acid solution, milk of lime and polyvinyl alcohol microparticles, and the sustained release potassium nitrogen powder is by potassium Fertilizer, nitrogenous fertilizer, water and alginate are made, and the organic matter material after rubbish from cooking drying and crushing by being made.
2. a kind of high-performance bio bacterial manure according to claim 1, it is characterised in that it is made by following methods:
It is stirred 1~2 hour after arbuscular mycorrhiza preparation is mixed with phosphorus base carrier with the revolving speed of 5~10rpm, then adds sustained release Potassium nitrogen powder continues stirring 30~40 minutes, and organic matter material is then added and mixes up to high-performance bio bacterial manure.
3. a kind of high-performance bio bacterial manure according to claim 1, it is characterised in that:
The phosphorus base carrier is made by following raw material, the milk of lime that relative density is 1~1.1, and relative density is 1.2~1.3 Phosphoric acid solution, wherein the molar ratio of calcium hydroxide and phosphoric acid is 1:1 in milk of lime and phosphoric acid solution, and polyvinyl alcohol microparticles add Dosage is the 30~55wt% of the sum of phosphoric acid solution and milk of lime weight.
4. a kind of high-performance bio bacterial manure according to claim 1 or 3, it is characterised in that:
The partial size of the polyethylene microballoon is 1~4 micron.
5. a kind of high-performance bio bacterial manure according to claim 1 or 3, it is characterised in that:
The phosphorus base carrier is made by following methods, by polyvinyl alcohol microparticles and 0.05~0.08 times of polyvinylalcohol microsphere ball weight Phosphate coupling agent be added in phosphoric acid solution after evenly mixing, then by milk of lime under with the stirring of 60~90rpm revolving speed It being added, temperature is controlled at 50~55 DEG C, and complete post curing 1~1.5 hour is added, filtering is then washed at 10~15 DEG C, and Filter cake is dried at 30~40 DEG C;It is ground into Dicalcium Phosphate after drying, obtained Dicalcium Phosphate is added to 60~70 DEG C dehydrated alcohol in handle 1~1.5 hour, then at room temperature after 70~80wt% ethanol water washes and dries Phosphorus base carrier is made.
6. a kind of high-performance bio bacterial manure according to claim 1, it is characterised in that:
The sustained release potassium nitrogen powder is made by following raw material, and potassium element and the molar ratio of nitrogen in nitrogenous fertilizer are 1 in potash fertilizer: 0.4~0.6, the weight of alginate is the 10~15wt% of the sum of potash fertilizer and nitrogenous fertilizer total weight, and the weight of water is alginate weight 2~4.5 times of amount.
7. a kind of high-performance bio bacterial manure according to claim 1 or 6, it is characterised in that:
The sustained release potassium nitrogen powder is made by following methods, is first dispersed in water potash fertilizer and nitrogenous fertilizer, in stirring for 20~30rpm It mixes and alginate is added under speed, then proceed to stir with the revolving speed of 10~15rpm 30~40 minutes, finally drying simultaneously crushes.
CN201811057069.2A 2018-09-11 2018-09-11 A kind of high-performance bio bacterial manure Pending CN109020701A (en)

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Application publication date: 20181218

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