CN109006857A - It is a kind of to kill thrips composition containing emamectin benzoate and thiacloprid - Google Patents
It is a kind of to kill thrips composition containing emamectin benzoate and thiacloprid Download PDFInfo
- Publication number
- CN109006857A CN109006857A CN201810928557.XA CN201810928557A CN109006857A CN 109006857 A CN109006857 A CN 109006857A CN 201810928557 A CN201810928557 A CN 201810928557A CN 109006857 A CN109006857 A CN 109006857A
- Authority
- CN
- China
- Prior art keywords
- thiacloprid
- emamectin benzoate
- thrips
- composition
- weight ratio
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having a double or triple bond to nitrogen, e.g. cyanates, cyanamides
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to the fields of agriculture chemical compounding, and in particular to a kind of to kill thrips composition containing emamectin benzoate and thiacloprid.It is of the invention a kind of to kill thrips composition containing emamectin benzoate and thiacloprid, active constituent includes: emamectin benzoate, thiacloprid, the weight ratio of the emamectin benzoate and thiacloprid are as follows: 10:1 ~ 1:10, show synergistic effect, it is any one dosage form agriculturally allowed, including granule, water dispersible granules, wettable powder, suspending agent, dry suspending agent, dispersible oil-suspending agent, suspension seed-coating agent or fumicants that this, which kills thrips combination dosage form,.Controlling object is vegetables thrips, cotton thrips.Of the invention kills efficient thrips composition, low toxicity, environmental protection, and the composition can greatly improve control efficiency, reduces dosage, and delaying drug resistance generates.
Description
Technical field
The present invention relates to the fields of agriculture chemical compounding, and in particular to a kind of to kill thrips combination containing emamectin benzoate and thiacloprid
Object.
Background technique
Thrips is a kind of insect made a living by drawing water, belongs to Insecta Thysanoptera.Nymph is white, yellow,
Or orange, adult are then in brown or black, are laid eggs on blade, flower, stem tissue.It will cause the damage of leaf and flower when feed
Wound.Thrips is one of the important pests of danger to vegetables, rice, cotton etc. in recent years, early because its polypide is small and harm is hidden
Phase is not easy to be found, and just draws attention when often endangering serious, but late.
In recent years, thrips seriously endangers and medication is relatively simple, and resistance problem is increasingly prominent to be come out, and drug resistance is to shorten
The first cause of noval chemical compound life cycle, and noval chemical compound is studied, and long there are the R&D cycle, the high difficulty of Meteorological
Topic, therefore, filters out a compounds effective and is extremely not easy.In view of the above-mentioned problems, filtering out a reasonable compounding
Formula is necessary.
Emamectin benzoate (full name: emamectin-benzoate) is synthesized since tunning AVERMECTIN B1
A kind of new and effective semisynthetic antibiotics insecticide, it has ultra high efficiency, less toxic (preparation is closely nontoxic), and low-residual is nuisanceless etc.
The characteristics of biological pesticide, compared with avermectin, insecticidal activity improves 3 orders of magnitude first, to the larva of lepidopterous insects
It is high with the activity of other many pests, existing stomach poison function simultaneous action of contace poison again, in low-down dosage (0.084~2g/
Ha there is good effect under), and beneficial insect is not injured during pest control, be conducive to anti-to the synthesis of pest
It controls, in addition expands insecticidal spectrum, reduce the toxicity to people and animals.Emamectin benzoate can be enhanced neurotic such as glutamic acid and gamma-amino
The effect of butyric acid (GABA) makes cell dysfunction so that a large amount of chloride ions be made to enter nerve cell, upsets nerve conduction, children
Worm stops feed at once after contact, and irreversible paralysis occurs, highest lethality is reached in 3~4 days.Due to it and soil
Earth is tightly combined, not leaching, is not also accumulated in the environment, can be moved and be shifted by Translaminar, easily inhaled by crop
Epidermis is received and penetrated into, application crop is made to have long-term residual effect, occurred second desinsection lethality peak again at 10 days or more, simultaneously
Seldom influenced by environmental factor such as wind, rain etc..
Thiacloprid is a kind of novel chloro nicotinic insecticide, has special efficacy to pierce-suck type and pests with chewing mouthparts.Effect
Mechanism and other conventional pesticides are different, it mainly act on insect nerve engagement caudacoria, by with nicotinic acetycholine
Receptor combines, and interference insect nervous system normal conduction causes the obstruction of neural channel, causes a large amount of accumulation of acetylcholine,
To make insect exaltation, general spasticity, paralysis and it is dead.With it is stronger tag, stomach toxicity and systemic action, quick-acting and holding effect
Phase is long.
Summary of the invention
Thrips composition is killed it is an object of the present invention to provide a kind of efficient, less toxic, environmentally friendly prevention and treatment thrips, this kills thrips group
Closing object can reduce dosage, and delaying drug resistance generates.
In order to solve the above technical problems, the invention adopts the following technical scheme:
A kind of to kill thrips composition containing emamectin benzoate and thiacloprid, active constituent includes: emamectin benzoate, thiacloprid, described
The weight ratio of emamectin benzoate and thiacloprid are as follows: 10:1~1:10.
Preferably, the weight ratio of the emamectin benzoate and thiacloprid are as follows: 8:1~1:6.
Preferably, the weight ratio of the emamectin benzoate and thiacloprid are as follows: 5:1~1:5.
Preferably, the weight ratio of the emamectin benzoate and thiacloprid are as follows: 1:2~1:5.
Preferably, the weight ratio of the emamectin benzoate and thiacloprid are as follows: 1:2~1:3.
Preferably, the thrips combination dosage form of killing is any one dosage form agriculturally allowed, including granule, moisture
Shot agent, wettable powder, suspending agent, dispersible oil-suspending agent, dry suspending agent, suspension seed-coating agent or fumicants.
Preferably, the application of the present invention for killing thrips composition in prevention and treatment crop pest, the insect pest are vegetables Ji
Horse, cotton thrips.
Specific test method is as follows:
(1) present invention adds leaf dipping method to carry out Frankliniella occidentalis determination of activity to emamectin benzoate, thiacloprid compounding using filter paper medicine film.
1. emamectin benzoate, thiacloprid are used acetone solution respectively, diluted with 0.1% Tween 80 aqueous solution.6 series are set
Gradient concentration (is shown in Table 1), and the final content of organic solvent is no more than 2%.
2. diameter 9cm filter paper to be laid in the culture dish bottom of diameter 9cm, the 1ml medical fluid of respective concentration is drawn by filter paper
Wetting, to spare after natural drying.Kidney bean is cut into the segment of long 3cm, immerses naturally dry after the medical fluid 10s of respective concentration.
Test sets the processing without medicament and makees blank control, and every processing is no less than 3 repetitions.
3. taking age consistent Frankliniella occidentalis nymph, it is inoculated into the culture dish of respective concentration medical fluid processing, each culture
Ware is about inoculated with 30, is then placed in the kidney bean section of respective concentration medical fluid processing, sealed membrane and rubber band sealing, pricks hole and keeps saturating
Gas is placed in suitable condition insectary and cultivates.
4. after medicine for 24 hours, 48h count each handling dead borer population respectively, finally indicated with each processing corrected mortality, specific formula
It is as follows:
According to survey data, the corrected mortality of each processing is calculated.It is calculated by formula (1) (2), calculated result remains into
2 significant digits:
P=K/N*100 (1)
In formula:
The P- death rate, unit are percentage (%)；
K- indicates dead borer population, and unit is head；
N- indicates the total borer population of processing, and unit is head.
PI=(Pt-P0)/(1-P0)*100 (2)
In formula:
PICorrected mortality, unit are percentage (%)；
PtThe death rate is handled, unit is percentage (%)；
P0The blank control death rate, unit are percentage (%).
If compareing the death rate < 5%, without correction；The death rate is compareed between 5%~20%, school should be carried out by formula (2)
Just；The death rate > 20% is compareed, test need to reform.
5. using DPS or SPSS data processing software, virulence regression equation y=a+bx (the y representative of various medicaments is calculated
Corrected mortality probit value, x represent the common logarithm of pharmacy quality concentration), the lethal concentration of 50 (LC50) and its 95% confidence area
Between.
The results are shown in Table 1 to Frankliniella occidentalis lethality for the medicament of various concentration.
1 emamectin benzoate of table and thiacloprid are under various concentration to Frankliniella occidentalis determination of activity result
Lethal concentration of 50 conclusion (of pressure testing) such as table 2 of (2) two kinds of compounds to Frankliniella occidentalis.
2 emamectin benzoate of table, thiacloprid are to Frankliniella occidentalis lethal concentration of 50 conclusion
(3) formulation screening test
It is analyzed with softwares such as statistical analysis system (SAS), data processing systems (DPS), calculates the LC of each medicament50、b
It is worth (standard error) equivalence and its 95% confidence limit.
The co-toxicity coefficient (CTC value) of mixture is calculated by formula (3), formula (4), formula (5)；
ATI=S/M*100 (3)
In formula:
ATI --- mixture surveys toxicity index；
S --- the LC of standard pesticide agent50, unit is milligrams per liter (mg/L)；
The LC of M --- mixture50, unit is milligrams per liter (mg/L).
TTI=TIA*PA+TIB*PB (4)
In formula:
TTI --- mixtures theoretical toxicity index；
TIA--- A medicament toxicity index；
PA--- percentage composition of the A medicament in mixture, unit are percentage (%)；
TIB--- B medicament toxicity index；
PB--- percentage composition of the B medicament in mixture, unit are percentage (%).
CTC=ATI/TTI*100 (5)
In formula:
CTC --- co-toxicity coefficient；
ATI --- mixture surveys toxicity index；
TTI --- mixtures theoretical toxicity index.
The co-toxicity coefficient (CTC) >=120 of compounding agent shows as synergistic effect；CTC≤80 show as antagonism；80 <
CTC < 120 shows as summation action.
By a large amount of different ratio Stepwise Screenings is summed up to Frankliniella occidentalis active determination test following relatively good match
Side.Formula conclusion with synergistic effect is as shown in 3~table of table 4.
3 emamectin benzoate of table and thiacloprid have the formula of synergistic effect to Frankliniella occidentalis for 24 hours
4 emamectin benzoate of table and thiacloprid have the formula of synergistic effect to Frankliniella occidentalis 48h
The above test results show that emamectin benzoate: in thiacloprid (10:1~1:10) compound proportion, emamectin benzoate: thiacloprid=
8:1~1:6 co-toxicity coefficient is all larger than 130, and synergistic effect is obvious；Emamectin benzoate: thiacloprid=1:2~1:5 co-toxicity coefficient is all larger than
140, synergistic effect is more obvious；Emamectin benzoate: thiacloprid (1:2,1:3) synergistic effect is the most obvious, therefore is directed to emamectin benzoate: thiophene
Worm quinoline (1:2,1:3) further carries out compound synergic verification test, the results are shown in Table 5, table 6.
5 emamectin benzoate of table and thiacloprid have the formula of synergistic effect to Frankliniella occidentalis for 24 hours
6 emamectin benzoate of table and thiacloprid have the formula of synergistic effect to Frankliniella occidentalis 48h
In summary test result shows emamectin benzoate and thiacloprid compounding prevention and treatment Frankliniella occidentalis, matches in 10:1~1:10
Between when, the co-toxicity coefficient CTC of the series proportion of composition has synergistic effect 120 or more, and in emamectin benzoate: thiophene worm
When quinoline (1:2,1:3), co-toxicity coefficient CTC is maximum, is all larger than 190, synergistic effect is the most obvious.
Beneficial effects of the present invention are, compared with single dose, the present invention screens and field medicine effect test in a large amount of indoor virulences
On the basis of, it is found that emamectin benzoate and thiacloprid compounding have obvious synergistic function thrips, dosage can be greatly reduced,
Keep desinsection more thorough, the duration is longer, improves control efficiency；And used emamectin benzoate, thiacloprid are free of objectionable impurities,
It is not likely to produce phytotoxicity；The mechanism of action of effective component is different in Pesticidal combination, is conducive to overcome thrips resistance and delay
The generation of drug resistance.
Specific embodiment
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
Art personnel every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
Embodiment 1
22% emamectin benzoate thiacloprid Granular formulations:
Emamectin benzoate 2%, thiacloprid 20%, alkylbenzene sulfonate 2%, lignosulfonates 3%, naphthalene sulfonate 3% are concave-convex
Stick soil 50%, kaolin 34%.
For preventing and treating cucumber thrips.
Embodiment 2
15% emamectin benzoate thiacloprid suspending agent formula:
Emamectin benzoate 5%, thiacloprid 10%, polycarboxylate 4%, aliphatic alcohol polyether 2%, propylene glycol 4%, organic silicon defoamer
0.4%, xanthan gum 0.1%, deionized water complements to 100%.
For preventing and treating sponge gourd thrips.
Embodiment 3
Oil-suspending agent formula can be dispersed in 18% emamectin benzoate thiacloprid:
Emamectin benzoate 3%, thiacloprid 15%, fatty alcohol polyoxyethylene ether 7%, Emulsifier LT-60M
5%, carboxylate 5%, organobentonite 2%, white carbon black 3%, turpentine oil 30% and methyl oleate 30%.
For preventing and treating cotton thrips.
Embodiment 4
25% emamectin benzoate thiacloprid water-dispersible grain agent prescription:
Emamectin benzoate 5%, thiacloprid 20%, white carbon black 8%, polycarboxylate 3%, alkylnaphthalene sulfonate 3%, ammonium sulfate
25%, precipitated calcium carbonate complements to 100%.
For preventing and treating cucumber thrips.
Embodiment 5
5.5% emamectin benzoate thiacloprid wettable powder agent prescription:
Emamectin benzoate 5%, thiacloprid 0.5%, white carbon black 8%, polycarboxylate 4%, alkylnaphthalene sulfonate 2%, ammonium sulfate
15%, precipitated calcium carbonate complements to 100%.
For preventing and treating cucumber thrips.
Embodiment 6
20% emamectin benzoate thiacloprid dry suspending agent formula:
Emamectin benzoate 5%, thiacloprid 15%, alkylbenzene sulfonate 4%, naphthalenesulfonate formaldehyde condensation compound 10%, sulfomethylated lignin
Hydrochlorate 20%, white carbon black 20%, organosilicon 2%, cornstarch 24%.
For preventing and treating cucumber thrips.
Embodiment 7
20% emamectin benzoate thiacloprid Smoke Agent:
Emamectin benzoate 4%, thiacloprid 16%, alkylbenzene sulfonate 5%, polycarboxylate 3%, potassium nitrate 25%, ammonium chloride
14%, nitrocellulose 12%, magnesium carbonate 11%.
For preventing and treating sponge gourd thrips.
Embodiment 8
14% emamectin benzoate thiacloprid suspended seed coating agent prescription:
Emamectin benzoate 2%, thiacloprid 12%, polyoxyethylene polyoxypropylene block copolymer 3%, alkyl phenol polyoxyethylene ether phosphorus
Acid esters 5%, polycarboxylate 5%, toner 3%, polyacrylate 5%, propylene glycol 5%, xanthan gum 0.3%, organosilicon 0.5%,
Kathon CG 0.6%, deionized water complements to 100%.
For preventing and treating cotton thrips.
Comparative example
3% emamectin benzoate micro-emulsion formulation:
Emamectin benzoate 3%, cyclohexanone 10%, phosphate 8%, alkyl phenol polyoxyethylene ether 2%, propylene glycol 4%, organosilicon disappears
Infusion 0.4%, complements to 100%, for preventing and treating cucumber, sponge gourd, cotton thrips.
Note: the percentage (%) of the embodiment and comparative example is mass volume ratio.
The medicament of Examples 1 to 8 and comparative example is shown in Table 7~table 9 to the preventive effect of thrips.
The preventive effect of 7 emamectin benzoate of table and thiacloprid compound drug to cucumber thrips
The preventive effect of 8 emamectin benzoate of table and thiacloprid compound drug to sponge gourd thrips
The preventive effect of 9 emamectin benzoate of table and thiacloprid compound drug to cotton thrips
Note: effective ingredient consumption is the total amount of emamectin benzoate and thiacloprid.
The foregoing is merely a prefered embodiment of the invention, the foregoing description of the disclosed embodiments, makes this field profession skill
Art personnel can be realized or using the present invention.Various modifications to these embodiments for those skilled in the art will
Be it will be apparent that the general principles defined herein can without departing from the spirit or scope of the present invention,
It is realized in other embodiments.Therefore, the present invention will not be limited to the embodiments shown herein, and is to fit to and this
Principle disclosed in text and the consistent widest scope of features of novelty.
Claims (9)
1. a kind of kill thrips composition containing emamectin benzoate and thiacloprid, which is characterized in that active constituent includes: emamectin benzoate, thiophene
Worm quinoline, the weight ratio of the emamectin benzoate and thiacloprid are as follows: 10:1 ~ 1:10.
A kind of thrips composition is killed containing emamectin benzoate and thiacloprid 2. according to claim 1, which is characterized in that described
The weight ratio of emamectin benzoate and thiacloprid are as follows: 8:1 ~ 1:6.
A kind of thrips composition is killed containing emamectin benzoate and thiacloprid 3. according to claim 2, which is characterized in that described
The weight ratio of emamectin benzoate and thiacloprid are as follows: 5:1 ~ 1:5.
A kind of thrips composition is killed containing emamectin benzoate and thiacloprid 4. according to claim 3, which is characterized in that described
The weight ratio of emamectin benzoate and thiacloprid are as follows: 1:2 ~ 1:5.
A kind of thrips composition is killed containing emamectin benzoate and thiacloprid 5. according to claim 4, which is characterized in that described
The weight ratio of emamectin benzoate and thiacloprid are as follows: 1:2 ~ 1:3.
6. according to claim 1-5 a kind of thrips composition, feature are killed containing emamectin benzoate and thiacloprid
It is, the Pesticidal combination dosage form is any one dosage form agriculturally allowed.
A kind of thrips composition is killed containing emamectin benzoate and thiacloprid 7. according to claim 6, which is characterized in that described
Pesticidal combination dosage form includes granule, water dispersible granules, wettable powder, suspending agent, dry suspending agent, dispersible oil suspension
Agent, suspension seed-coating agent or fumicants.
8. -5 or 7 described in any item a kind of killing thrips composition anti-containing emamectin benzoate and thiacloprid according to claim 1
Control the application in crop thrips.
9. a kind of thrips composition that kills containing emamectin benzoate and thiacloprid according to claim 8 is preventing and treating crops vegetables Ji
Application in horse, cotton thrips.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810928557.XA CN109006857A (en) | 2018-08-15 | 2018-08-15 | It is a kind of to kill thrips composition containing emamectin benzoate and thiacloprid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810928557.XA CN109006857A (en) | 2018-08-15 | 2018-08-15 | It is a kind of to kill thrips composition containing emamectin benzoate and thiacloprid |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109006857A true CN109006857A (en) | 2018-12-18 |
Family
ID=64631376
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810928557.XA Pending CN109006857A (en) | 2018-08-15 | 2018-08-15 | It is a kind of to kill thrips composition containing emamectin benzoate and thiacloprid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109006857A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114600878A (en) * | 2022-04-11 | 2022-06-10 | 山东汤普乐作物科学有限公司 | Emamectin benzoate and thiacloprid suspending agent and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102057937A (en) * | 2011-01-21 | 2011-05-18 | 赤峰市帅旗农药有限责任公司 | Insecticidal composition of thiacloprid and emamectin benzoate |
| CN102273446A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Thiacloprid-containing ultralow-volume liquid |
| CN108024538A (en) * | 2015-08-11 | 2018-05-11 | 江苏龙灯化学有限公司 | Synergistic insecticidal composition |
-
2018
- 2018-08-15 CN CN201810928557.XA patent/CN109006857A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102057937A (en) * | 2011-01-21 | 2011-05-18 | 赤峰市帅旗农药有限责任公司 | Insecticidal composition of thiacloprid and emamectin benzoate |
| CN102273446A (en) * | 2011-09-13 | 2011-12-14 | 广西田园生化股份有限公司 | Thiacloprid-containing ultralow-volume liquid |
| CN108024538A (en) * | 2015-08-11 | 2018-05-11 | 江苏龙灯化学有限公司 | Synergistic insecticidal composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114600878A (en) * | 2022-04-11 | 2022-06-10 | 山东汤普乐作物科学有限公司 | Emamectin benzoate and thiacloprid suspending agent and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103734171A (en) | Pesticide composition containing imidacloprid | |
| CN105360166A (en) | Antibacterial insecticide for ecological agricultural and forest crops | |
| CN106342905A (en) | Agricultural insecticide composition containing phryma leptostachya extractive | |
| CN101984828B (en) | Compound pesticide | |
| CN101803605B (en) | Insecticidal composition of butene-fipronil and spinosad | |
| CN104255772B (en) | A kind of sanitary insect pest Pesticidal combination and application thereof containing Diacloden and Nylar | |
| CN109006857A (en) | It is a kind of to kill thrips composition containing emamectin benzoate and thiacloprid | |
| CN107372615A (en) | A kind of seed dressing and its preparation method and application | |
| CN103947647A (en) | Insecticidal composition | |
| CN105532680B (en) | A kind of highly efficiency compositional composition pesticide of pyrimidine containing trifluoro-benzene and cycloxaprid | |
| CN111418604B (en) | Bactericidal composition containing sodium selenite and thiophanate-methyl | |
| CN107279161A (en) | A kind of bactericidal composition containing folpet and fluopyram | |
| CN107372550A (en) | A kind of pesticide combination comprising folpet and benzo alkene fluorine bacterium azoles | |
| CN106900757B (en) | A kind of bitter pueraria root extract and the Pesticidal combination of Osthole and application thereof for preventing and treating agricultural pests | |
| CN1875718A (en) | Application of rhabditelliasis axei in white grub control | |
| CN115886007B (en) | Pesticide composition, application thereof and pesticide preparation containing pesticide composition | |
| CN108184903A (en) | A kind of chicken manure biogas slurry and bactericide compounded composition and the application in apple leaf diseases are prevented | |
| CN114794136B (en) | Pesticide composition for preventing and controlling orange leaf miner | |
| CN116806837B (en) | Use of tetrahydropyrimidine for reducing damage of insect pest to gramineous plants | |
| CN103004842A (en) | Pesticide compound composition comprising acetamiprid and flonicamid | |
| CN111436449B (en) | Compound composition of prothioconazole and osthole and application thereof | |
| CN108782576A (en) | Pesticide sterilizing composite containing captan and fluoxastrobin | |
| CN107771850A (en) | Seed treatment composition and its application | |
| CN106489994B (en) | Pesticidal combination containing Empedobacter brevis and dimehypo | |
| CN105248446A (en) | Complex synergism insecticide and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20181218 |