CN102057937A - Insecticidal composition of thiacloprid and emamectin benzoate - Google Patents
Insecticidal composition of thiacloprid and emamectin benzoate Download PDFInfo
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- CN102057937A CN102057937A CN2011100249720A CN201110024972A CN102057937A CN 102057937 A CN102057937 A CN 102057937A CN 2011100249720 A CN2011100249720 A CN 2011100249720A CN 201110024972 A CN201110024972 A CN 201110024972A CN 102057937 A CN102057937 A CN 102057937A
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- thiophene worm
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- worm quinoline
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Abstract
The invention discloses an insecticidal composition of thiacloprid and emamectin benzoate. The combination of the thiacloprid and the emamectin benzoate can ensure that the probability of the drug resistance generated in the pests is greatly reduced and the cost is reduced while the drug effect is improved. The weight ratio of the thiacloprid to the emamectin benzoate is 20:1-1:20. Through indoor tests, all weight ratios of the emamectin benzoate to the thiacloprid, such as 1:5, 1:10, 1:20, 5:1, 10:1, 20:1, all show the summation action, and the effect of the thiacloprid and the emamectin benzoate after compounded is superior to the thiacloprid preparation and the emamectin benzoate preparation. Through field tests, the ratio of the thiacloprid to the emamectin benzoate is 1:1, the concentration of the thiacloprid and the emamectin benzoate is respectively 2 percent, 10 percent, 20 percent and 40 percent, the insecticidal effect after the thiacloprid and the emamectin benzoate are compounded is superior to the thiacloprid preparation and the emamectin benzoate preparation.
Description
Technical field the present invention relates to a kind of agricultural insecticide, is the Pesticidal combination of a kind of thiophene worm quinoline and emamectin-benzoate specifically.
Background technology thiophene worm quinoline (thiacloprid) belongs to anabasine insecticide, and interior absorption is stronger, have tag, stomach poison function, insecticidal spectrum is wide.
(Emamectin benzoate (B1a/B1b) is an Avermectin B1 structure modified outcome to emamectin-benzoate, and the insecticidal activity that compares the lepidoptera pest larva with the parent Avermectin is significantly improved, and toxicity but reduces greatly.Prove through the test of pesticide effectiveness repeatedly, first dimension salt pair resistant bollworm and diamond-back moth special efficacy, active in the parent Avermectin, be better than conventional dose simultaneously.First dimension salt has used for many years, and pesticide resistance is in various degree also arranged, and two kinds of compositions are mixed and can increase the drug effect of product, make insect be difficult for developing immunity to drugs.
300 yuan/kg of the former medicine of thiophene worm quinoline in addition, 900 yuan/kg of the first dimension former medicine of salt, two kinds of compositions synthesize under the prerequisite that guarantees drug effect and can reduce cost.
Summary of the invention the object of the present invention is to provide the Pesticidal combination of a kind of thiophene worm quinoline and emamectin-benzoate, and the probability that two kinds of drug regimens can make insect develop immunity to drugs greatly reduces, and reduces cost when improving drug effect.
Technical scheme of the present invention is as follows:
The active ingredient of this Pesticidal combination is thiophene worm quinoline and emamectin-benzoate, and the weight ratio of thiophene worm quinoline and emamectin-benzoate is: 20: 1～1: 20.
The weight percentage that above-mentioned thiophene worm quinoline and emamectin-benzoate account for total preparation is 2%～40%, and surplus is an auxiliary agent.
The concrete formulation of above-mentioned insecticide is aqua, missible oil, suspending agent, wetting powder, granule, microemulsion.
The invention has the advantages that: 1, through laboratory test, methylamino dimension rhzomorph benzoate and thiophene worm quinoline be with 1: 5,1: 10,1: 20,5: 1,10: 1, each proportioning all showed summation action in 20: 1, and the back insecticidal effect that is mixed all is better than list agent of thiophene worm quinoline and the agent of methylamino dimension rhzomorph benzoate list.Through field trial, thiophene worm quinoline and methylamino dimension rhzomorph benzoate is with 1: 1 proportioning, concentration respectively 2%, 10%, 20%, 40%, and the back insecticidal effect that is mixed all is better than list agent of thiophene worm quinoline and the agent of methylamino dimension rhzomorph benzoate list.2, both are mixed and can reduce the pesticide resistance of crop pests.3, because of thiophene worm quinoline cost is low, the effective but cost height of methylamino dimension rhzomorph benzoate pesticide, both applied in any combination had both improved drug effect, reduced cost again.
Embodiment
Embodiment:
Present composition insect killing effect test
Diamond-back moth is the insect of the difficult control of Lepidoptera, and in the insecticidal activity assay of pesticidal preparations, lepidopterous controlling object is representative with the diamond-back moth.
Thiophene worm quinoline emamectin-benzoate is to diamond-back moth indoor harmacological effect comparative trial
1.1 test medicine:
1.2 date of test:
14 days～September 15 August in 2009
1.3 pilot project:
The agent of thiophene worm quinoline list is measured the diamond-back moth indoor harmacological effect, respectively with concentration 1%, 5%, 10%, 15%, 20% test, the single agent of emamectin-benzoate (first dimension salt is called for short in the back) is measured the diamond-back moth indoor harmacological effect, respectively with concentration 1%, 5%, 10%, 15%, 20% test
Two of emamectin-benzoate and thiophene worm quinolines supply test agent to use the indoor joint toxicity measuring of totally 6 proportionings with
1.4 test proportioning
2.1 for trying object:
Diamond-back moth (plutella xylostella): 2 instar larvaes, the sensitive strain of indoor feeding.
2.2 test condition:
Temperature: 24～26 ℃
Humidity: RH60%
Illumination: L: D=14: 10
2.3 soup preparation
Accurately take by weighing reagent agent respectively with electronic analytical balance, replenish and add water to desired concn, be mixed with the desired concn mother liquor, be hybridly prepared into mixed solution, be diluted to the serial soup of tool finite concentration gradient with water by experimental scheme dosage respectively by the experimental scheme proportioning.
2.4 processing method
Handle and adopt the dipping feeding method.The cabbage leaves of greenhouse culture is fetched, made diameter 4cm leaf dish, standby.
The leaf dish is flooded 5s in soup, dry in the shade after the taking-up, put into the 9cm culture dish that is lined with filter paper.Handle blank earlier, repeat aforesaid operations by experimental scheme dosage order from low to high then, every processing repeats for 3 times.
Select the examination worm of neat and consistent and insert in the culture dish 10 in every ware.
2.5 investigation method
Examination worm after handling is placed in the observation ward routine observation examination worm response situation, dead, the borer population of living of 48h " Invest, Then Investigate ".
2.6 computational methods:
3 result of the tests and evaluation
3.1 result of the test:
Table 1 thiophene worm quinoline control diamond-back moth drug effect fruit
Table 2 first dimension salt control diamond-back moth drug effect fruit
Table 3: thiophene worm quinoline emamectin-benzoate is to the indoor associating evaluation of pesticide effectiveness of diamond-back moth result
3.2 evaluation of result:
In this test, methylamino dimension rhzomorph benzoate and thiophene worm quinoline were with 1: 5, and 1: 10,1: 20,5: 1,10: 1, each proportioning all showed summation action in 20: 1, and the back effect that is mixed all is better than list agent of thiophene worm quinoline and the agent of methylamino dimension rhzomorph benzoate list.Mixture preparation control diamond-back moth is adopted in suggestion.
The 2% first dimension thiophene worm quinoline soluble liquid control diamond-back moth test of pesticide effectiveness
1. test name: the 2% first dimension thiophene worm quinoline soluble liquid test of pesticide effectiveness
2. testing crew: Chifeng City flag of a commander in chief agricultural chemicals company
3. test site: Da Xiniu village, Wu San township
4. test period: 2009,07,11
5. testing program design:
5.1, test objective: 2% first dimension thiophene worm quinoline soluble liquid control diamond-back moth drug effect
5.2, materials and methods
5.2.1 test medicine (low content): 2% first dimension thiophene worm quinoline solubility liquid (SL); 1% first dimension salt SL;
1% thiophene worm quinoline SL;
5.2.2 trial crops: wild cabbage
5.2.3 test site: Da Xiniu village, Wu San township
5.2.4 sample plot condition stub: experiment about 1 mu of area (667 square metres)
Diamond-back moth (1-2 age) is not found ovum.
5.2.5 test instrument: common knapsack sprayer
5.2.6 test is handled: this tests three medicaments, and concentration is 1000 times, four repetitions, and the clear water contrast:
1000 times of (1) 2% first dimension thiophene worm quinoline soluble liquids
(2) 1% first dimension salt SL1000 doubly
(3) 1% thiophene worm quinoline SL1000 doubly
5.2.6 content of the test: handle according to top test, water spray is converted in the dispenser in afternoon behind the secondary dilution.
5.2.7 experimental condition: fine 20 ℃-28 ℃ of July 11
Cloudy 18 ℃-28 ℃ of July 12
July 13, light rain was 19 ℃-27 ℃
Cloudy 28 ℃-34 ℃ of July 14
July 15, light rain was 20 ℃-35 ℃
Fine with occasional clouds 29 ℃-33 ℃ of July 16
Fine with occasional clouds 28 ℃-35 ℃ of July 17
5.2.8 control time and method:
Investigation diamond-back moth insect population radix before the medicine, investigation in 1 day, 3 days, 7 days after the dispenser, preventive effect.Adopt five point samplings, the borer population alive in the different length of times on the 20 strain wild cabbages is write down in each sub-district.Calculate insect population decrease rate and preventive effect.
Insect population borer population * 100 before rate (%)=(dispenser before borer population-dispenser after borer population)/dispenser of going down
Control efficiency (%)=(the treatment region insect population rate of going down-blank district insect population go down rate)/(100-blank district insect population go down rate) * 100
6. result of the test and analysis
Behind the table 4 spray medicine 1,3, three kinds of chemical control wild cabbages of 7d diamond-back moth test of pesticide effectiveness result
Annotate: 1 is 1000 times of 2% first dimension thiophene worm quinoline soluble liquids
2 is 1000 times of 1% first dimension salt soluble liquids
3 is 1000 times of 1% thiophene worm quinoline soluble liquids
By result of the test as can be seen, 1000 times of insecticidal effects of complex preparation 2% first dimension thiophene worm quinoline soluble liquid are 84.87%, obviously are better than 71.2% of first dimension salt list agent, more are better than 33.41% of thiophene worm quinoline list agent, be that low concentration thiophene worm quinoline is joined first dimension salt, control diamond-back moth drug effect improves very remarkable.Be worth promoting in practice, in non-environmental pollution control, use.
The 10% first dimension thiophene worm quinoline soluble liquid control diamond-back moth test of pesticide effectiveness
1. test name: the 10% first dimension thiophene worm quinoline soluble liquid test of pesticide effectiveness
2. testing crew: Chifeng City flag of a commander in chief agricultural chemicals company
3. test site: Cheng Zi township artist Gou Men village
4. test period: 2009.8.1～2009.8.8
5. testing program design:
5.1, test objective: 10% first dimension thiophene worm quinoline soluble liquid control diamond-back moth drug effect
5.2, materials and methods
5.2.1 test medicine: 10% first dimension thiophene worm quinoline soluble liquid (SL) (production of Chifeng flag of a commander in chief agricultural chemicals Co., Ltd);
5% first dimension salt SL (production of Chifeng flag of a commander in chief agricultural chemicals Co., Ltd);
5% thiophene worm quinoline SL (production of Chifeng flag of a commander in chief agricultural chemicals Co., Ltd);
5.2.2 trial crops: wild cabbage
5.2.3 test site: Cheng Zi township artist Gou Men village
5.2.4 sample plot condition stub: about 1 mu of experiment area, diamondback moth larvae phase.
5.2.5 test instrument: common knapsack sprayer
5.2.6 test is handled: this tests three medicaments, and concentration is 2000 times, four repetitions, and the clear water contrast:
2000 times of (1) 10% first dimension thiophene worm quinoline soluble liquids (methylamino dimension rhzomorph benzoate: thiophene worm quinoline is 1: 1)
(2) 5% first dimension salt SL2000 doubly
(3) 5% thiophene worm quinoline SL2000 doubly
5.2.6 content of the test: handle dispenser in the morning according to top test.
5.2.7 experimental condition:
Fine 20 ℃-25 ℃ of August 1
Cloudy 19 ℃-24 ℃ of August 2
Fine 19 ℃-23 ℃ of August 3
Fine 18 ℃-31 ℃ of August 4
Fine 20 ℃-33 ℃ of August 5
Fine with occasional clouds 29 ℃-35 ℃ of August 6
Fine with occasional clouds 28 ℃-35 ℃ of August 7
Fine with occasional clouds 27 ℃-33 ℃ of August 8
5.2.8 control time and method:
Investigation diamond-back moth insect population radix before the medicine, investigation in 1 day, 3 days, 7 days after the dispenser, preventive effect.Adopt five point samplings, the borer population alive in the different length of times on the 20 strain wild cabbages is write down in each sub-district.Calculate insect population decrease rate and preventive effect.
Insect population borer population * 100 before rate (%)=(dispenser before borer population-dispenser after borer population)/dispenser of going down
Control efficiency (%)=(the treatment region insect population rate of going down-blank district insect population go down rate)/(100-blank district insect population go down rate) * 100
6. result of the test and analysis
Behind the table 5 spray medicine 1,3, three kinds of chemical control wild cabbages of 7d diamond-back moth test of pesticide effectiveness result
Annotate: 1 is 2000 times of 10% first dimension thiophene worm quinoline soluble liquids
2 is 2000 times of 5% first dimension salt soluble liquids
3 is 2000 times of 5% thiophene worm quinoline soluble liquids
By result of the test as can be seen, 2000 times of insecticidal effects of complex preparation 10% first dimension thiophene worm quinoline soluble liquid are better than the agent of first dimension salt list, more are better than the agent of thiophene worm quinoline list, are worth promoting in production practices.Delaying insect develops immunity to drugs.
The 20% first dimension thiophene worm quinoline soluble liquid control diamond-back moth test of pesticide effectiveness
1. test name: the 20% first dimension thiophene worm quinoline soluble liquid test of pesticide effectiveness
2 testing crews: Chifeng City flag of a commander in chief agricultural chemicals Co., Ltd
3. test site: Anqing Zhen Yuanmao Long Cun
4. test period: 2009.8.18～8.25
5. testing program design:
5.1, test objective: 20% first dimension thiophene worm quinoline soluble liquid control diamond-back moth drug effect
5.2, materials and methods
5.2.1 test medicine: 20% first dimension thiophene worm quinoline soluble liquid (SL) (methylamino dimension rhzomorph benzoate: thiophene worm quinoline is 1: 1, and Chifeng flag of a commander in chief agricultural chemicals Co., Ltd produces);
10% first dimension salt SL (production of Chifeng flag of a commander in chief agricultural chemicals Co., Ltd);
10% thiophene worm quinoline SL (production of Chifeng flag of a commander in chief agricultural chemicals Co., Ltd);
5.2.2 trial crops: wild cabbage
5.2.3 test site: Anqing Zhen Yuanmao Long Cun
5.2.4 sample plot condition stub: about 2 mu of experiment area.The diamondback moth larvae phase.
5.2.5 test instrument: workers and peasants' 16 type knapsack sprayers
5.2.6 test is handled: this tests three medicaments, and concentration is 2000 times, four repetitions, and the clear water contrast:
2000 times of (1) 20% first dimension thiophene worm quinoline soluble liquids
(2) 10% first dimension salt SL2000 doubly
(3) 10% thiophene worm quinoline SL2000 doubly
5.2.6 content of the test: handle dispenser in the morning according to top test.
5.2.7 experimental condition:
Fine 19 ℃-26 ℃ of August 18
Cloudy 18 ℃-27 ℃ of August 19
Fine 19 ℃-29 ℃ of August 20
Fine 20 ℃-31 ℃ of August 21
Fine 20 ℃-32 ℃ of August 22
Cloudy 19 ℃-35 ℃ of August 23
Fine 22 ℃-35 ℃ of August 24
Cloudy 21 ℃-33 ℃ of August 25
5.2.8 control time and method:
Investigation diamond-back moth insect population radix before the medicine, investigation in 1 day, 3 days, 7 days after the dispenser, preventive effect.Adopt five point samplings, the borer population alive in the different length of times on the 20 strain wild cabbages is write down in each sub-district.Calculate insect population decrease rate and preventive effect.
Insect population borer population * 100 before rate (%)=(dispenser before borer population-dispenser after borer population)/dispenser of going down
Control efficiency (%)=(the treatment region insect population rate of going down-blank district insect population go down rate)/(100-blank district insect population go down rate) * 100
6. result of the test and analysis
Behind the table 6 spray medicine 1,3, three kinds of chemical control wild cabbages of 7d diamond-back moth test of pesticide effectiveness result
Annotate: 1 is 2000 times of 20% first dimension thiophene worm quinoline soluble liquids
2 is 2000 times of 10% first dimension salt soluble liquids
3 is 2000 times of 10% thiophene worm quinoline soluble liquids
By result of the test as can be seen, 2000 times of insecticidal effects of complex preparation 20% first dimension thiophene worm quinoline soluble liquid are better than the agent of first dimension salt list, more are better than the agent of thiophene worm quinoline list, and 7 days preventive effects reach 87.80 behind the medicine, are worth promoting in production practices, delay insect and develop immunity to drugs.
The 40% first dimension thiophene worm quinoline soluble liquid control diamond-back moth test of pesticide effectiveness
1. test name: the 40% first dimension thiophene worm quinoline soluble liquid test of pesticide effectiveness
2 testing crews: Chifeng City flag of a commander in chief agricultural chemicals Co., Ltd
3. test site: when Bei Dao village, floor file township
4. test period: 2009.8.10～8.17
5. testing program design:
5.1, test objective: 40% first dimension thiophene worm quinoline soluble liquid control diamond-back moth drug effect
5.2, materials and methods
5.2.1 test medicine: (methylamino dimension rhzomorph benzoate: thiophene worm quinoline is 1: 1 to 40% first dimension thiophene worm quinoline soluble liquid (SL); Chifeng City flag of a commander in chief agricultural chemicals Co., Ltd produces);
20% first dimension salt SL (production of Chifeng City flag of a commander in chief agricultural chemicals Co., Ltd);
20% thiophene worm quinoline SL (production of Chifeng City flag of a commander in chief agricultural chemicals Co., Ltd);
5.2.2 trial crops: wild cabbage
5.2.3 test site: when Bei Dao village, floor file township
5.2.4 sample plot condition stub: about 2 mu of experiment area.The diamondback moth larvae phase.Worm 2～3 ages of age
5.2.5 test instrument: workers and peasants' 16 type knapsack sprayers
5.2.6 test is handled: this tests three medicaments, and concentration is 3000 times, four repetitions, and the clear water contrast:
3000 times of (1) 40% first dimension thiophene worm quinoline soluble liquids
(2) 20% first dimension salt SL3000 doubly
(3) 20% thiophene worm quinoline SL3000 doubly
5.2.6 content of the test: handle dispenser in the morning according to top test.
5.2.7 experimental condition:
Fine 16 ℃-26 ℃ of August 10
Cloudy 19 ℃-26 ℃ of August 11
Fine 29 ℃-29 ℃ of August 12
Fine 20 ℃-31 ℃ of August 13
Fine 20 ℃-32 ℃ of August 14
Cloudy 19 ℃-35 ℃ of August 15
Fine 22 ℃-35 ℃ of August 16
Cloudy 21 ℃-33 ℃ of August 17
5.2.8 control time and method:
Investigation diamond-back moth insect population radix before the medicine, investigation in 1 day, 3 days, 7 days after the dispenser, preventive effect.Adopt five point samplings, the borer population alive in the different length of times on the 20 strain wild cabbages is write down in each sub-district.Calculate insect population decrease rate and preventive effect.
Insect population borer population * 100 before rate (%)=(dispenser before borer population-dispenser after borer population)/dispenser of going down
Control efficiency (%)=(the treatment region insect population rate of going down-blank district insect population go down rate)/(100-blank district insect population go down rate) * 100
6. result of the test and analysis
Behind the table 7 spray medicine 1,3, three kinds of chemical control wild cabbages of 7d diamond-back moth test of pesticide effectiveness result
Annotate: 1 is 3000 times of 40% first dimension thiophene worm quinoline soluble liquids
2 is 3000 times of 20% first dimension salt soluble liquids
3 is 3000 times of 20% thiophene worm quinoline soluble liquids
By result of the test as can be seen, 3000 times of insecticidal effects of complex preparation 40% first dimension thiophene worm quinoline soluble liquid are better than single agent, and 7 days preventive effects reach 93.88% behind the medicine, can delay insect and develop immunity to drugs, and are worth promoting in production practices.
Claims (3)
1. the Pesticidal combination of thiophene worm quinoline and emamectin-benzoate, it is characterized in that: its active ingredient is thiophene worm quinoline and emamectin-benzoate, and the weight ratio of thiophene worm quinoline and emamectin-benzoate is: 20: 1～1: 20.
2. the Pesticidal combination of thiophene worm quinoline according to claim 1 and emamectin-benzoate is characterized in that: the weight percentage that thiophene worm quinoline and emamectin-benzoate account for total preparation is 2%～40%, and surplus is an auxiliary agent.
3. the Pesticidal combination of thiophene worm quinoline according to claim 1 and emamectin-benzoate is characterized in that: concrete formulation is aqua, missible oil, suspending agent, wetting powder, granule, microemulsion behind its interpolation auxiliary agent.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103960275A (en) * | 2013-01-31 | 2014-08-06 | 浙江农林大学 | Tree trunk injection liquid containing emamectin benzoate and thiacloprid, and preparation method thereof |
| CN108990642A (en) * | 2018-10-16 | 2018-12-14 | 南京林衡农业科技有限公司 | A kind of pine nematodiasis wood stump processing unit and control method |
| CN109006857A (en) * | 2018-08-15 | 2018-12-18 | 山东中农联合生物科技股份有限公司 | It is a kind of to kill thrips composition containing emamectin benzoate and thiacloprid |
| CN112075442A (en) * | 2020-09-17 | 2020-12-15 | 惠州市银农科技股份有限公司 | Water dispersible granule and preparation method thereof |
| CN114600878A (en) * | 2022-04-11 | 2022-06-10 | 山东汤普乐作物科学有限公司 | Emamectin benzoate and thiacloprid suspending agent and preparation method thereof |
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| CN101617688A (en) * | 2009-08-12 | 2010-01-06 | 深圳诺普信农化股份有限公司 | Pesticide composition containing thiacloprid |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103960275A (en) * | 2013-01-31 | 2014-08-06 | 浙江农林大学 | Tree trunk injection liquid containing emamectin benzoate and thiacloprid, and preparation method thereof |
| CN103960275B (en) * | 2013-01-31 | 2016-05-11 | 浙江农林大学 | Tie up trunk injection liquor of salt and thiacloprid and preparation method thereof containing first |
| CN109006857A (en) * | 2018-08-15 | 2018-12-18 | 山东中农联合生物科技股份有限公司 | It is a kind of to kill thrips composition containing emamectin benzoate and thiacloprid |
| CN108990642A (en) * | 2018-10-16 | 2018-12-14 | 南京林衡农业科技有限公司 | A kind of pine nematodiasis wood stump processing unit and control method |
| CN112075442A (en) * | 2020-09-17 | 2020-12-15 | 惠州市银农科技股份有限公司 | Water dispersible granule and preparation method thereof |
| CN112075442B (en) * | 2020-09-17 | 2022-05-10 | 惠州市银农科技股份有限公司 | Water dispersible granule and preparation method thereof |
| CN114600878A (en) * | 2022-04-11 | 2022-06-10 | 山东汤普乐作物科学有限公司 | Emamectin benzoate and thiacloprid suspending agent and preparation method thereof |
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Application publication date: 20110518 |