CN103858899A - Pesticide composition containing spirotetramat and amide insecticide - Google Patents
Pesticide composition containing spirotetramat and amide insecticide Download PDFInfo
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- CN103858899A CN103858899A CN201210531402.5A CN201210531402A CN103858899A CN 103858899 A CN103858899 A CN 103858899A CN 201210531402 A CN201210531402 A CN 201210531402A CN 103858899 A CN103858899 A CN 103858899A
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- amide
- spiral shell
- ethyl ester
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Abstract
The invention relates to a pesticide insecticidal composition, the effective components of which contain (A) spirotetramat and (B), i.e. one of amide insecticides. Specifically, A and B are in a mass percentage of 1-80:80-1, and the content of A and B in the compound preparation is 1-80%. The compound pesticide composition prepared by the invention can be prepared into missible oil, suspending agents, wettable powder, water dispersible granules, emulsions in water and other dosage forms by methods well known to technicians in the field. The insecticidal composition provided by the invention is suitable for controlling piercing-sucking mouthpart pests in vegetables and fruits, and is especially suitable for controlling aphids, whiteflies, mealybugs, scale insects, plant hoppers, thrips, Empoasca pirisuga Matumura, as well as lepidoptera, coleoptera pests like diamondback moths, cotton bollworms and the like.
Description
Technical field
The present invention relates to a kind of agricultural insecticide composition with synergistic effect, active ingredient is spiral shell worm ethyl ester and be selected from one or more of amide-type insecticide.
Background technology
The suckings pest such as aphid, plant hopper, thrips, scale insect have short, the feature such as breeding amount is large, generation overlap is obvious of breeding cycle, are easy to develop immunity to drugs.Owing to using in a large number year after year, above-mentioned insect has produced serious resistance for the medicament such as Imidacloprid, Acetamiprid.
Spiral shell worm ethyl ester, English name Spirotetramat, is the tetronic acid insecticides of Bayer company research and development, belongs to similar compound with insecticidal/acaricidal agent spiral shell mite ester and Spiromesifen.Spiral shell worm ethyl ester has unique function Characteristics; there is good two-way interior suction conductive performance, can in whole plant corpus, upwards move down, arrive at blade face and bark; the interior absorption of this uniqueness can be protected newborn stem, leaf and root, prevents ovum and the larval growth of insect.Its another one feature is that the lasting period is long, and the effective control that reaches 8 weeks can be provided.Spiral shell worm ethyl ester can effectively be prevented and treated various suckings pest, as aphid, plant hopper, thrips, mealybug, aleyrodid and scale insect etc.Applicable chief crop comprises, tealeaves, soybean, oranges and tangerines, tropical fruit tree, nut, grape, lupulus, potato and vegetables etc.Research shows that it has good selectivity to important beneficial insect as ladybug, syrphus fly and parasitic wasp.But the long-term use separately of spiral shell worm ethyl ester is easily developed immunity to drugs, and cost accounting is higher.
Within 1998, Japanese agricultural chemicals company develops after first compound Flubendiamide that acts on target ryanodine receptor, and E.I.Du Pont Company on its basis, taking Flubendiamide as guide, successively develops a new class lead compound Rynaxypyr.Due to this two compounds structural similarity, the mechanism of action is identical, broad-spectrum high-efficiency and low-toxicity, Ge great research institution carries out ryanodine receptor insecticide research initiative, has formed this several insecticides: phthalic diamides, adjacent formamido benzamides, diamide, adjacent heterocycle benzamides agrochemical.
The amide-type insecticide that the present invention mentions is selected from one or more in Rynaxypyr, fipronil bisamide, thiophene insect amide, Flubendiamide, fluorine worm benzamide, chlorantraniliprole, cyanogen insect amide, Tolfenpyrad.
Summary of the invention
Based on above situation, the object of the present invention is to provide a kind of agricultural insecticide composition, this Pesticidal combination it is characterized in that taking (A) spiral shell worm ethyl ester and (B) one in amide-type insecticide carry out mixture as active ingredient, prevent the various pests of crops.
Pesticidal combination of the present invention is characterized in that, the mass ratio of effective constituents A and B is 1~80: 80~1.
Pesticidal combination of the present invention is characterized in that, tests through toxicity test, and the mass ratio of effective constituents A and B is preferably 1~50: 50~1.
The formulation that described Pesticidal combination of the present invention can be prepared according to the known method of those skilled in the art of the present technique be missible oil, aqueous emulsion, suspending agent, wetting powder, water dispersible granules, etc. formulation.
Pesticidal combination effective constituents A of the present invention and the B gross mass content in preparation is 1 ~ 80%, preferably 1% ~ 50%.All the other compositions are in agricultural chemicals, to allow to use and acceptable auxiliary element.
The auxiliary agent (auxiliary element) using in bactericidal composition of the present invention comprises solvent, wetting agent, dispersant, antifreezing agent, thickener, defoamer, disintegrant, filler etc., and other are of value to active ingredient stable known substance of bringing into play with drug effect (being composition conventional in agricultural chemicals or that permission is used) in preparation, concrete composition and consumption, according to formula requirement, determine by normal experiment.
Described emulsifier is selected from any one or more mixtures with arbitrary proportion composition in calcium dodecyl benzene sulfonate and aliphatic acid polyethenoxy ether, alkylphenol polyoxyethylene sulfosuccinate, styrylphenol polyoxyethylene ether, polyoxyethylene nonylphenol ether, castor oil polyoxyethylene ether, aliphatic acid polyethenoxy base ester, polyoxyethylene aliphatic alcohol ether.
Described solvent is any one or more mixed solvents with arbitrary proportion composition in dimethylbenzene or biodiesel, toluene, diesel oil, methyl alcohol, ethanol, n-butanol, isopropyl alcohol, turpentine oil, solvent naphtha, dimethyl formamide, dimethyl sulfoxide (DMSO), water equal solvent.
Described dispersant is selected from one or more in polycarboxylate, lignosulfonates, alkylphenol polyoxyethylene formaldehyde condensation products sulphate, alkyl benzene sulfonate calcium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, alkylphenol polyoxyethylene, aliphatic amine polyoxyethylene ether, polyoxyethylene carboxylate, fatty acid glyceride APEO.
Described wetting agent is selected from: lauryl sodium sulfate, calcium dodecyl benzene sulfonate, Nekal BX., one or more in wetting and penetrating agent F, alkylnaphthalene sulfonate, polyoxyethylene triphenylethylene phosphenylic acid salt, spaonin powder, silkworm excrement, soapberry powder.
Described disintegrant is selected from: one or more in bentonite, urea, ammonium sulfate, aluminium chloride, citric acid, succinic acid, sodium bicarbonate.
Described thickener is selected from: one or more in xanthans, CMC, hydroxyethylcellulose, methylcellulose, Magnesiumaluminumsilicate, polyvinyl alcohol.
Described stabilizing agent is selected from: the one in sodium citrate, resorcinol.
Described antifreezing agent is selected from: one or more in ethylene glycol, propane diols, glycerine.
Described defoamer is selected from: silicone oil, silicone compound, C
10-20saturated fat acid compounds, C
8-10one or more in aliphatic alcohols compound.
Described filler is selected from: one or more in kaolin, diatomite, bentonite, attapulgite, white carbon, starch, precipitated calcium carbonate.
Pesticidal combination of the present invention has very significantly synergistic effect, can reduce effective ingredient consumption, delays the generation of pest resistance to insecticide, and can be used for the improvement of resistant insect.Be particularly suitable for sucking pest insect and Lepidoptera and Diptera pest for preventing and treating vegetables and fruit, be especially suitable for anti-eliminating aphis, aleyrodid, mealybug, scale insect, plant hopper, thrips, tea lesser leafhopper, diamond-back moth, prodenia litura etc.Pesticide dosage is low, is difficult for causing residual exceeding standard, and also has the feature that toxicity is low simultaneously, is conducive to environmental protection and produces non-polluted farm product.
Embodiment
Spiral shell worm ethyl ester proportioning co-toxicities different from amide-type insecticide
1.1 reagent agent
The former medicine of 95% spiral shell worm ethyl ester, the former medicine of 95.3% Rynaxypyr, above-mentioned former medicine provides by research and development centre of Qingdao Hailir Pesticides and Chemical Co., Ltd..
1.2 for examination worm source
Indoor potted plant cabbage seedling is raised the cabbage aphid three generations adult in 10 generations, temperature (25 ± 2) continuously
oc, relative moisture 50% ± 4%, periodicity of illumination 1 4/1 0 h (L/D).
1.3 single dose assay methods
Adopt dip method that two former medicines are all used to a small amount of acetone solution, then be diluted to into the solution of 5 concentration of equal difference with 0.1% Tween solution, be diluted in beaker with for subsequent use, and with clear water in contrast.Three generations's cabbage aphid adult of the same size is flooded to 5S in the liquid that soaks worm cage, be placed in the culture dish that diameter is 9 c m after sucking unnecessary liquid, in ware, be placed with fresh cabbage leaves and add a cover.Every concentration is processed 10, repeats 4 times.If blank.In (27 ± 1) DEG C illumination box, keep checking lethality after 24 h, it is dead touching polypide nonresponder by pulling needle.Lethality Abbott formula correction, then according to concentration logarithm---lethality probit value is analyzed (Bliss) method, obtains virulence regression equation and puts dead middle amount LC
50value.
The joint toxicity measuring method of 1.4 different proportionings
According to the toxicity test result of single dose, be 10% quality than spiral shell worm ethyl ester by active ingredient: Rynaxypyr is respectively 9:1,7.5:2.5,5:5,2.5:7.5,9:1.Adopt above-mentioned 1.3 methods to carry out toxicity test, calculate LC
50, and press the abundant method of Sun Yun and calculate co-toxicity coefficient (CTC).Co-toxicity coefficient CTC, computing formula is as follows: (taking spiral shell worm ethyl ester as standard medicament, its toxicity index is 100):
The LC of toxicity index (TI)=spiral shell worm ethyl ester of Rynaxypyr
50the LC of/Rynaxypyr
50× 100
The LC of actual toxicity index (ATI)=spiral shell worm ethyl ester of M
50the LC of/M
50× 100
TI × P Rynaxypyr of TTI × P spiral shell worm ethyl ester+Rynaxypyr of theoretical toxicity index (TTI)=spiral shell worm ethyl ester of M
TTI × 100 of the ATI/M of co-toxicity coefficient (CTC)=M of M
In formula:
M be spiral shell worm ethyl ester from Rynaxypyr by the mixture of different proportionings
P Rynaxypyr is Rynaxypyr shared ratio in mixture
P spiral shell worm ethyl ester is spiral shell worm ethyl ester shared ratio in mixture
2.1 toxicity test results
table 1 spiral shell worm ethyl ester (A), the indoor measurement result of Rynaxypyr (B) to cabbage aphid
As can be seen from the table, in the mixture of different proportion, its co-toxicity coefficient is all greater than 120, shows certain synergistic effect, wherein spiral shell worm ethyl ester: the synergistic effect that Rynaxypyr is 5:5 is the most obvious, and co-toxicity coefficient is 198.69.Result of the test shows, under indoor conditions, spiral shell worm ethyl ester, two kinds of medicaments of Rynaxypyr all have higher activity to cabbage aphid, the result of the test of different proportion proportioning shows, by active ingredient spiral shell worm ethyl ester: when Rynaxypyr is 9:1,7.5:2.5,5:5,2.5:7.5,9:1, all show stronger synergistic effect, wherein taking spiral shell worm ethyl ester: Rynaxypyr is during as 5:5, and synergistic effect is best.
Claims (6)
1. one kind contains (A) spiral shell worm ethyl ester and (B) composition pesticide of amide-type insecticide.
2. amide-type insecticide of the present invention is selected from one or more in Rynaxypyr, fipronil bisamide, thiophene insect amide, Flubendiamide, fluorine worm benzamide, chlorantraniliprole, cyanogen insect amide, Tolfenpyrad.
3. Pesticidal combination according to claim 1, is characterized in that: the mass ratio of A and B is 1 ~ 80:80 ~ 1.
4. Pesticidal combination according to claim 1, is characterized in that: A is 1 ~ 50:50 ~ 1 with the quality optimization ratio of B.
5. Pesticidal combination according to claim 1, is characterized in that: effective constituents A and the B total mass ratio in composition is 1 ~ 80%, preferably than being 1 ~ 50%.
6. Pesticidal combination according to claim 1, is characterized in that: adopt the known technical scheme of those skilled in the art can be prepared into the formulations such as missible oil, suspending agent, wetting powder, water dispersible granules, aqueous emulsion.
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104407091A (en) * | 2014-12-30 | 2015-03-11 | 郭庆龙 | GC-NCI-MS method for measuring residual quantity of flubendiamide |
CN104502482A (en) * | 2014-12-30 | 2015-04-08 | 郭庆龙 | Detecting method for residual quantity of flubendiamide in fruits and vegetables |
CN109221204A (en) * | 2018-11-02 | 2019-01-18 | 陕西标正作物科学有限公司 | Pesticidal combination and application |
CN110150296A (en) * | 2019-06-06 | 2019-08-23 | 青岛润农化工有限公司 | A kind of Tolfenpyrad and the Pesticidal combination of spiral shell worm ethyl ester and the preparation method and application thereof |
CN115119837A (en) * | 2021-08-10 | 2022-09-30 | 永农生物科学有限公司 | Flonicamid-spirotetramat mixed preparation and application thereof |
-
2012
- 2012-12-12 CN CN201210531402.5A patent/CN103858899A/en active Pending
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104407091A (en) * | 2014-12-30 | 2015-03-11 | 郭庆龙 | GC-NCI-MS method for measuring residual quantity of flubendiamide |
CN104502482A (en) * | 2014-12-30 | 2015-04-08 | 郭庆龙 | Detecting method for residual quantity of flubendiamide in fruits and vegetables |
CN104407091B (en) * | 2014-12-30 | 2015-11-18 | 郭庆龙 | A kind of GC-NCI-MS assay method of fipronil bisamide residual quantity |
CN109221204A (en) * | 2018-11-02 | 2019-01-18 | 陕西标正作物科学有限公司 | Pesticidal combination and application |
CN110150296A (en) * | 2019-06-06 | 2019-08-23 | 青岛润农化工有限公司 | A kind of Tolfenpyrad and the Pesticidal combination of spiral shell worm ethyl ester and the preparation method and application thereof |
CN115119837A (en) * | 2021-08-10 | 2022-09-30 | 永农生物科学有限公司 | Flonicamid-spirotetramat mixed preparation and application thereof |
CN115119837B (en) * | 2021-08-10 | 2023-12-26 | 永农生物科学有限公司 | Flonicamid-spirotetramat mixed preparation and application thereof |
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Application publication date: 20140618 |