CN108968140A - A kind of tobacco leaf additive and preparation method thereof - Google Patents
A kind of tobacco leaf additive and preparation method thereof Download PDFInfo
- Publication number
- CN108968140A CN108968140A CN201810622580.6A CN201810622580A CN108968140A CN 108968140 A CN108968140 A CN 108968140A CN 201810622580 A CN201810622580 A CN 201810622580A CN 108968140 A CN108968140 A CN 108968140A
- Authority
- CN
- China
- Prior art keywords
- parts
- lactate
- tobacco leaf
- preparation
- hyperbranched
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24B—MANUFACTURE OR PREPARATION OF TOBACCO FOR SMOKING OR CHEWING; TOBACCO; SNUFF
- A24B15/00—Chemical features or treatment of tobacco; Tobacco substitutes, e.g. in liquid form
- A24B15/18—Treatment of tobacco products or tobacco substitutes
- A24B15/28—Treatment of tobacco products or tobacco substitutes by chemical substances
- A24B15/42—Treatment of tobacco products or tobacco substitutes by chemical substances by organic and inorganic substances
Landscapes
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Manufacture Of Tobacco Products (AREA)
Abstract
The present invention provides a kind of tobacco leaf additive and preparation method thereof, the tobacco leaf additive is made of following weight fraction ratio component materials: 30 ~ 50 parts of modifying agent, 10 ~ 30 parts of adsorbent, 5 ~ 10 parts of phenylalanine, 2 ~ 5 parts of malto-oligosaccharide alcohol, 2 ~ 5 parts of potassium malate, the modifying agent is mixed with by modification dolomite powder and hyperbranched lactate and is obtained, the adsorbent is mixed with by hyperbranched lactate and chinese medicine material and is obtained, and can promote tobacco leaf burning and CO absorption, CO using plasma modification dolomite2With reduction coke tar cracking temperature, keep coke tar cracking complete by the catalytic action of alkali metal in dolomite, to achieve the effect that reduce cigarette CO and releasing content of coke tar.The present invention effectively improves the big problem of cigarette pollutant burst size, improves the fragrance and comfort level of cigarette, has good economic benefit.
Description
Technical field
The invention belongs to technical field of tobacco, in particular to a kind of tobacco leaf additive and preparation method thereof.
Background technique
Smoking is harmful to your health, what this was generally well known, endangers to reduce smoking to mankind's bring, world health group
Knit one of the three big main action targets that " back suction cigarette " is classified as to 21 century health field.In this context, international cigarette city
Also there is accelerating the trend developed to more low tar, low nicotine and low harmful components cigarette in field, and to harmful ingredients in flue gas into
Row analysis and research, reduce harmful components to the greatest extent, produce the cigarette products of low harmful safe healthcare.Therefore, external low-coke tar cigarette
The cigarette products in China will be threatened, directly affects the cigarette market in China.In order to preferably protect the health of consumer, China is
Including that the fields such as leaf tobacco production, processing and reducing tar and reducing harm technology are increasing research dynamics, develop including modern biotechnology,
The reducing tar and reducing harms such as new material technology new technology simultaneously successfully applies in production of cigarettes.
Patent of invention CN200910139721.X, it is a kind of to reduce releasing content of coke tar in cigarette using perilla leaf, folium artemisiae argyi, Du Jingye
Method, the water that 5 times of weight are added after herbal raw material perilla leaf, folium artemisiae argyi, leaf of negundo chastetree (weight ratio 1:1:1) are pulverized and mixed decoct 2
Hour, it is repeated twice, is centrifugated out aqueous, merge, 2 times of raw material weight are concentrated into, by 40% ~ 95% ethyl alcohol of water extract
After dilution, uniformly it is sprayed on the pipe tobacco that weight is 100 ~ 200 times of extract, routinely cigarette process is made with obvious tar reduction
The cigarette of effect.This method raw material is cheap and easy to get, simple process, can reduce releasing content of coke tar in cigarette 10%~20%, has good
Good industrial applications prospect.
Patent of invention CN201510257588.3, the preparation method of a kind of black powder cigarette additive of cocoa and its in recombination cigarette
Application in cigar, it is first to carry out biofermentation processing to the black powder of natural cocoa with biological complex enzyme, then by fermentation liquid
As natural nitrogen source, maillard flavouring is carried out with honey and is reacted, comprising the following steps: 1) is added by weight into the black powder of natural cocoa
The biological complex enzyme for entering 0.1~0.5%, stirring incubates 4~24 hours in the water that pH is 8~11, temperature is 40~60 DEG C,
8000~10000rpm centrifugation, takes supernatant, is the black powder enzyme fermentation liquid of cocoa；2) bee is added into the black powder enzyme fermentation liquid of cocoa
Honey, the additional amount of the honey are the 0.5~5% of the black powder weight of natural cocoa, are mixed, stirring, and adjusting pH is 9~11, heating
Reflux carries out mailland reaction 3~8 hours, after reaction, reaction solution is concentrated into the black that relative density is 1.1~1.2
Medicinal extract, obtains the black powder cigarette additive of cocoa, and the biological complex enzyme is alkali protease, alkali cellulose enzyme, alkaline pectin
Enzyme and alkali starch enzyme, the alkali protease, alkali cellulose enzyme, alkaline pectase and alkali starch enzyme weight ratio be=
1: 0.5~2: 0.5~2:0.5~2.The black powder cigarette additive of cocoa of invention preparation can be used for the blending of recombination tobacco leaf cigarette
And dyeing, it can be not only used in recombination tobacco leaf, it can also be used in cigarette paper.
Patent of invention CN201710003564.4, a kind of preparation method and applications of recombination tobacco leaf additive, preparation side
Method includes the following steps: Step 1: preparing valerian root extract；Step 2: by step 1 preparation valerian root extract and
Other raw material components are uniformly mixed by weight percent: valerian root extract 4 ~ 8%, Prunus salicina Lindl. Extract 2 ~ 9%, Radix Glycyrrhizae reactant
2 ~ 6%, coffee medicinal extract 1 ~ 4%, 3% fenugreck lactone 1 ~ 5%, benzyl carbinol 0.2 ~ 2%, 10%2,3,5- trimethylpyrazine 0.1 ~
3%, 10% ethylmaltol 0.1 ~ 6%, 10% methyl cyclopentenyl ketone 0.1 ~ 4%, 10% vanillic aldehyde 0.1 ~ 2%, 10%2-
Acetyl furan 0.1-2%, fructose 5 ~ 15%, propylene glycol 5 ~ 20%, water 6 ~ 77.3%.The invention can effectively cover recombination tobacco leaf
Various miscellaneous gas, improve this perfume of tobacco, to propose aesthetic quality and the availability of recombination tobacco leaf.
Summary of the invention
Aiming at the problem that existing cigarette CO and tar content seriously affect smoker's health more, the present invention provides a kind of reduction
Cigarette CO and the tobacco leaf additive of releasing content of coke tar and preparation method thereof.
The present invention is achieved by the following technical solutions:
A kind of tobacco leaf additive is mainly made of following weight fraction ratio component materials: 30 ~ 50 parts of modifying agent, adsorbent
10 ~ 30 parts, 5 ~ 10 parts of phenylalanine, 2 ~ 5 parts of malto-oligosaccharide alcohol, 2 ~ 5 parts of potassium malate；
The modifying agent is by modification dolomite powder and hyperbranched lactate according to mass ratio 1:(0.2 ~ 0.5) be mixed with and
?；
The adsorbent is by hyperbranched lactate and chinese medicine material according to mass ratio 1:(2 ~ 5) mixing after be prepared；
The tobacco leaf additive additional amount is the 20% ~ 40% of quality of tobacco.
As a further improvement of the present invention, the chinese medicine material is Kiwi extract, tea polyphenols, Radix Astragali, plate indigo plant
One of root.
As a further improvement of the present invention, the additive tobacco leaf be in 50 ~ 60 DEG C of temperature, relative humidity 40% ~
It is added under the conditions of 50%.
By dolomite powder in NaNO3After impregnating in solution, dolomite surface carries alkali metallic sodium ion, passes through plasma
After body processing, calcium carbonate and magnesium carbonate in alkali metallic sodium and dolomite, at nano-component, are improved catalysis and are lived by arc through
Property, in cigarette combustion, alkali metallic sodium, which can adsorb and be catalyzed the burning of CO gas, generates CO2Gas, then by dolomite
Calcium carbonate and magnesium carbonate are to CO2Gas is adsorbed, to reduce the release of pernicious gas CO；On the other hand, dolomite surface
The NaNO of melting3It is Mg with lactate2+、Ca2+Diffusion provides ionic liquid channel, promotes ion diffusion, facilitates tobacco leaf
Completely burned reduces the cracking temperature of tar, improves the transformation efficiency of tar to reduce tar content in cigarette burst size；
Lactate can remove the acid of result of combustion of tobacco generation, while can improve the humectation of pipe tobacco, so that flue gas lubrication is tasty and refreshing,
Improve the comfort of flue gas；By lactate it is hyperbranched after, lactate can be promoted to be scattered in pipe tobacco so that in lactate alkali gold
Belong to sodium, potassium and lithium energy overall diffusion in pipe tobacco, in pipe tobacco burning, cooperates with and activate the cracking of dolomite catalytic tar, thus
Reach reduce coke tar cracking and CO absorption, CO2The effect of gas.
A large amount of active function groups that lactate has after hyperbranched are in conjunction with chinese medicine material, when can improve cigarette combustion
Wettability, organic acid is improved to the improvement result of flue gas suction quality, so that the tar in flue gas is cut by dissaving polymer
It stays, becomes more to lubricate tasty and refreshing after acting on using organic acid, improve flue gas comfort level.
Meanwhile the present invention provides the square the preparation method of tobacco leaf additive described in one kind, comprising the following steps:
One, the preparation of modification dolomite powder
(1) by ratio of weight and the number of copies, 10 ~ 15 parts of dolomite powder are weighed, NaNO is dissolved in3In be configured to solution, stirring 15 at 80 DEG C ~
20min, then the dry 2h at 120 DEG C, obtains compound dolomite powder；
The NaNO3It is (0.1 ~ 0.2) with dolomite powder mass ratio: 1；
(2) compound dolomite powder is handled into 1h in argon gas discharging plasma system, 6 each 10min, are changed altogether
Property dolomite powder；
The argon gas discharging plasma system is to pour argon gas after vacuumizing, and stablizes its pressure in 100 ~ 110Pa, then
It is passed through DC power supply, breakdown voltage 900V, burning voltage 600V, electric current are 9 ~ 11mA；
Two, the preparation of hyperbranched poly lactic acid
Score ratio by weight, by 50 ~ 70 parts of lactate, 10 ~ 20 parts of lactic acid, 1 ~ 5 part of glycerine, 3 ~ 5 parts of gluconic acid mixing, side
Stirring side is warming up to 120 ~ 165 DEG C, accelerates dehydration, removes after distillating moisture, continues to be decompressed to 1000 ~ 1300Pa, keep 170 ~
175 DEG C of 10 ~ 12h of isothermal reaction pour out reaction product, are ground into powder after cooling, after acetone solution, are added dropwise to dehydrated alcohol
Middle precipitating filters, and washing, 60 DEG C of vacuum drying 12h of filter cake obtain hyperbranched lactate；
The lactate is a kind of in sodium lactate, potassium lactate and lithium lactate；
Three, the preparation of modifying agent
Hyperbranched lactate is dissolved in 10 ~ 20 times of water, 30min is stirred at 30 ~ 35 DEG C dissolves it sufficiently, is then added and is modified
Dolomite powder continues stirring for 24 hours, obtains modifying agent；
The modification dolomite powder and hyperbranched lactate mass ratio 1:(0.2 ~ 0.5)；
Four, the preparation of adsorbent
The organic acid for taking hyperbranched lactate that its quality 2% ~ 8% is added is mixed, and obtains mixed liquor, mixing liquid is then added
The water of 10 ~ 20 times of product stirs 30min at 30 ~ 35 DEG C, and chinese medicine material is added, and after mixing 30 ~ 40min, obtains adsorbent；
The chinese medicine material and hyperbranched lactate mass ratio are (2 ~ 5): 1, it is added while stirring；
The organic acid is one of citric acid, malic acid；
Five, the preparation of tobacco leaf additive
By ratio of weight and the number of copies, 2 ~ 5 parts and 2 ~ 5 parts of potassium malate 5 ~ 10 parts of phenylalanine, malto-oligosaccharide alcohol mixing are taken, is heated to
After 40 ~ 50 DEG C, 30 ~ 50 parts of modifying agent, 10 ~ 30 parts of adsorbent is added, is cooled to room temperature after keeping the temperature 20 ~ 30min, cigarette can be obtained
Leaf additive.
As a further improvement of the present invention, the Kiwi extract the preparation method is as follows:
(1) take Kiwi berry, be put into juice extractor and be beaten broken, the mixing enzyme aqueous solution of equal quality is added, 36 DEG C of temperature ~
38 DEG C of progress constant temperature digest 2h, are warming up to 80 DEG C and keep 20 ~ 30min inactivation, obtain mixture；
The aqueous solution of the mixed enzyme be pectase, cellulase, carbohydrase, alpha-amylase and acid protease in mass ratio
2:1:1:1:2 is mixed to join in distilled water, and being prepared into mass fraction is 10% mixing enzyme aqueous solution；
(2) pH for adjusting the mixture after enzyme deactivation is 3.5 ~ 4.0, at 25 ~ 30 DEG C, carries out the Maillard reaction of 18h, is obtained anti-
Answer mixture；
(3) reaction mixture is distilled, collects fraction, obtain volatile fragrant component, distillation test residue volume
The ethanol water that score is 33 ~ 40% extracts, and supernatant is taken to be concentrated, and must dive fragrant component；
(4) head perfume (or spice) component and latent fragrant component are mixed according to 4 ︰ 1 of mass ratio, 2 ~ 4 DEG C carry out refrigeration 8h, take supernatant that can obtain Mi
Monkey peach extract.
As a further improvement of the present invention, the chinese medicine material Radix Astragali, Radix Isatidis material processing method are as follows:
Radix Astragali or Radix Isatidis are added in 2 ~ 5 times of water, after decoction to moisture content is 0.3 ~ 0.5 times of original volume, material is taken
It dries and crushes out, cross 50 ~ 100 meshes, obtain Radix Astragali, Radix Isatidis material.
Beneficial effects of the present invention:
1, the present invention improves dolomite as tobacco leaf additive using plasma, can effectively facilitate tobacco leaf efficiency of combustion, adsorbs
CO and CO2Gas, while coke tar cracking temperature is reduced, so that it is burnt just to utilize the alkali metal in dolomite to be catalyzed in tobacco leaf burning
Oil-breaking, to reduce releasing content of coke tar；
2, the present invention improves the combustibility of tobacco leaf using hyperbranched lactate and modification dolomite, can make alkali metal and white jade stone
It is completely dispersed and activates, improve tobacco leaf completely burned efficiency, reduce CO burst size, while hyperbranched lactate and organic acid improve
The crown_interception of tar, improves the comfort level of flue gas, increases the quality of cigarette.
Specific embodiment
Below with reference to embodiment, the present invention is further described.
Embodiment 1
One, the preparation of modification dolomite powder
(1) by ratio of weight and the number of copies, 10 parts of dolomite powder are weighed, according to NaNO3It is dissolved in dolomite powder mass ratio for 0.1:1
NaNO3In be configured to solution, 15min is stirred at 80 DEG C, then the dry 2h at 120 DEG C, obtains compound dolomite powder；
(2) compound dolomite powder is handled into 1h in argon gas discharging plasma system, 6 each 10min, are changed altogether
Property dolomite powder；
The argon gas discharging plasma system is to pour argon gas after vacuumizing, and stablizes its pressure in 100Pa, then passes to
DC power supply, breakdown voltage 900V, burning voltage 600V, electric current 9mA；
Two, the preparation of hyperbranched poly lactic acid
Score ratio by weight, by 50 parts of sodium lactate, 10 parts of lactic acid, 1 part of glycerine, 3 parts of gluconic acid mixing, warming while stirring
To 120 DEG C, accelerate dehydration, remove after distillating moisture, continue to be decompressed to 1000Pa, keep 170 DEG C of isothermal reaction 10h, pours out anti-
Product is answered, powder is ground into after cooling, after acetone solution, is added dropwise in dehydrated alcohol and precipitates, is filtered, washing, 60 DEG C of filter cake
Vacuum drying 12h obtains hyperbranched sodium lactate；
Three, the preparation of modifying agent
Hyperbranched sodium lactate is dissolved in 10 times of water, 30min is stirred at 30 DEG C dissolves it sufficiently, according to modification dolomite powder
Modification dolomite powder is added with hyperbranched lactate mass ratio 1:0.2, continues stirring for 24 hours, obtains modifying agent；
Four, the preparation of adsorbent
The citric acid for taking hyperbranched sodium lactate that its quality 2% is added is mixed, and obtains mixed liquor, mixeding liquid volume is then added
10 times of water stirs 30min at 30 DEG C, is 2:1 according to Kiwi extract and hyperbranched lactate mass ratio, while stirring
Kiwi extract is added, after mixing 30min, obtains adsorbent；
The Kiwi extract the preparation method is as follows:
(1) take Kiwi berry, be put into juice extractor and be beaten broken, the mixing enzyme aqueous solution of equal quality is added, 36 DEG C of temperature ~
38 DEG C of progress constant temperature digest 2h, are warming up to 80 DEG C and keep 20 ~ 30min inactivation, obtain mixture；
The aqueous solution of the mixed enzyme be pectase, cellulase, carbohydrase, alpha-amylase and acid protease in mass ratio
2:1:1:1:2 is mixed to join in distilled water, and being prepared into mass fraction is 10% mixing enzyme aqueous solution；
(2) pH for adjusting the mixture after enzyme deactivation is 3.5 ~ 4.0, at 25 ~ 30 DEG C, carries out the Maillard reaction of 18h, is obtained anti-
Answer mixture；
(3) reaction mixture is distilled, collects fraction, obtain volatile fragrant component, distillation test residue volume
The ethanol water that score is 33 ~ 40% extracts, and supernatant is taken to be concentrated, and must dive fragrant component；
(4) head perfume (or spice) component and latent fragrant component are mixed according to 4 ︰ 1 of mass ratio, 2 ~ 4 DEG C carry out refrigeration 8h, take supernatant that can obtain Mi
Monkey peach extract.
Five, the preparation of tobacco leaf additive
By ratio of weight and the number of copies, 5 parts of phenylalanine, 5 parts of malto-oligosaccharide alcohol and 2 parts of potassium malate mixing are taken, after being heated to 40 DEG C,
30 parts of modifying agent, 30 parts of adsorbent is added, is cooled to room temperature after keeping the temperature 20min, tobacco leaf additive can be obtained.
The tobacco leaf additive is added according to the 40% of quality of tobacco.
Embodiment 2
One, the preparation of modification dolomite powder
(1) by ratio of weight and the number of copies, 15 parts of dolomite powder are weighed, according to NaNO3It is dissolved in dolomite powder mass ratio for 0.2:1
NaNO3In be configured to solution, 20min is stirred at 80 DEG C, then the dry 2h at 120 DEG C, obtains compound dolomite powder；
(2) compound dolomite powder is handled into 1h in argon gas discharging plasma system, 6 each 10min, are changed altogether
Property dolomite powder；
The argon gas discharging plasma system is to pour argon gas after vacuumizing, and stablizes its pressure in 110Pa, then passes to
DC power supply, breakdown voltage 900V, burning voltage 600V, electric current 11mA；
Two, the preparation of hyperbranched poly lactic acid
Score ratio by weight, by 70 parts of potassium lactate, 20 parts of lactic acid, 5 parts of glycerine, 5 parts of gluconic acid mixing, warming while stirring
To 165 DEG C, accelerate dehydration, remove after distillating moisture, continue to be decompressed to 1300Pa, keep 175 DEG C of isothermal reaction 12h, pours out anti-
Product is answered, powder is ground into after cooling, after acetone solution, is added dropwise in dehydrated alcohol and precipitates, is filtered, washing, 60 DEG C of filter cake
Vacuum drying 12h obtains hyperbranched potassium lactate；
Three, the preparation of modifying agent
Hyperbranched potassium lactate is dissolved in 20 times of water, 30min is stirred at 35 DEG C dissolves it sufficiently, according to modification dolomite powder
Modification dolomite powder is added with hyperbranched lactate mass ratio 1:0.5, continues stirring for 24 hours, obtains modifying agent；
Four, the preparation of adsorbent
The malic acid for taking hyperbranched potassium lactate that its quality 8% is added is mixed, and obtains mixed liquor, mixeding liquid volume is then added
20 times of water stirs 30min at 35 DEG C, is (2 ~ 5) according to Radix Astragali material and hyperbranched lactate mass ratio: 1, while stirring
Radix Astragali material is added, after mixing 40min, obtains adsorbent；The Radix Astragali material processing method is as follows:
Radix Astragali is added in 5 times of water, after decoction to moisture content is 0.5 times of original volume, material taking-up is dried and is crushed, mistake
100 meshes obtain Radix Astragali material；
Five, the preparation of tobacco leaf additive
By ratio of weight and the number of copies, 10 parts of phenylalanine, 2 parts of malto-oligosaccharide alcohol and 2 parts of potassium malate mixing are taken, are heated to 50 DEG C
Afterwards, 50 parts of modifying agent, 10 parts of adsorbent is added, is cooled to room temperature after keeping the temperature 30min, tobacco leaf additive can be obtained.
The tobacco leaf additive is added according to the 20% of quality of tobacco.
Embodiment 3
One, the preparation of modification dolomite powder
(1) by ratio of weight and the number of copies, 13 parts of dolomite powder are weighed, according to NaNO3It is dissolved in dolomite powder mass ratio for 0.2:1
NaNO3In be configured to solution, 20min is stirred at 80 DEG C, then the dry 2h at 120 DEG C, obtains compound dolomite powder；
(2) compound dolomite powder is handled into 1h in argon gas discharging plasma system, 6 each 10min, are changed altogether
Property dolomite powder；
The argon gas discharging plasma system is to pour argon gas after vacuumizing, and stablizes its pressure in 110Pa, then passes to
DC power supply, breakdown voltage 900V, burning voltage 600V, electric current 11mA；
Two, the preparation of hyperbranched poly lactic acid
Score ratio by weight, by 55 parts of lithium lactate, 15 parts of lactic acid, 2 parts of glycerine, 4 parts of gluconic acid mixing, warming while stirring
To 145 DEG C, accelerate dehydration, remove after distillating moisture, continue to be decompressed to 1200Pa, keep 175 DEG C of isothermal reaction 11h, pours out anti-
Product is answered, powder is ground into after cooling, after acetone solution, is added dropwise in dehydrated alcohol and precipitates, is filtered, washing, 60 DEG C of filter cake
Vacuum drying 12h obtains hyperbranched lithium lactate；
Three, the preparation of modifying agent
Hyperbranched lithium lactate is dissolved in 15 times of water, 30min is stirred at 33 DEG C dissolves it sufficiently, then according to modification dolomite
Modification dolomite powder is added in powder and hyperbranched lactate mass ratio 1:0.4, continues stirring for 24 hours, obtains modifying agent；
Four, the preparation of adsorbent
The malic acid for taking hyperbranched lithium lactate that its quality 6% is added is mixed, and obtains mixed liquor, mixeding liquid volume is then added
14 times of water stirs 30min at 33 DEG C, is (2 ~ 5) according to Radix Isatidis material and hyperbranched lactate mass ratio: 1, side stirring
Radix Isatidis material is added in side, after mixing 35min, obtains adsorbent；
The Radix Isatidis material processing method is as follows:
Radix Isatidis is added in 3 times of water, after decoction to moisture content is 0.4 times of original volume, material taking-up is dried and is crushed,
80 meshes are crossed, Radix Isatidis material is obtained；
Five, the preparation of tobacco leaf additive
By ratio of weight and the number of copies, 8 parts of phenylalanine, 4 parts of malto-oligosaccharide alcohol and 4 parts of potassium malate mixing are taken, are heated to 40 ~ 50 DEG C
Afterwards, 45 parts of modifying agent, 25 parts of adsorbent is added, is cooled to room temperature after keeping the temperature 28min, tobacco leaf additive can be obtained.
The tobacco leaf additive is added according to the 30% of quality of tobacco.
Experimental example
Conventional cigarette carries out conventional flue gas analysis experiment: according to GB/T 19609-2004, " cigarette is surveyed with conventional analysis with smoking machine
Determine total granules and tar " and GB/T 23356-2009 " the non-scatter infrared method of the measurement of carbonic oxide in components in cigarette smoke gas phase "
Measure smoke's total particulate matter (TPM), tar and carbon monoxide (CO) content.
The tobacco leaf of the embodiment of the present invention 1 ~ 3 is prepared into cigarette and carries out conventional flue gas analysis experiment, according to GB/T 23356-
2009 " the non-scatter infrared methods of the measurement of carbon monoxide in components in cigarette smoke gas phase " measure carbon monoxide, GB/T 19609-2004 " volume
Cigarette conventional analysis measures total granules and tar with smoking machine " measurement smoke's total particulate matter (TPM) and tar, concrete outcome be shown in
Table 1.
1 cigarette smoke of table analyzes result
As shown in Table 1, releasing content of coke tar in cigarette, total granules and the CO burst size of 1 ~ 3 tobacco leaf of embodiment preparation are below routine
Cigarette, so as to improve the smoking mouthfeel of cigarette.
The cigarette of conventional cigarette and the preparation of 1 ~ 3 tobacco leaf of embodiment on the market is subjected to fume component analysis, concrete outcome
It is shown in Table 2.Wherein, the detection method of corresponding ingredient are as follows: the GB/T 23356-2009 " measurement of carbon monoxide in components in cigarette smoke gas phase
Non-scatter infrared method ", YC/T 253-2008 " the measurement continuous flow method of hydrogen cyanide in cigarette mainstream flue gas ", QJ/SY
JF10.4-2013 " the measurement of the peculiar N- nitrosamine of tobacco, ammonia Positive chemical ionization mode three in cigarette mainstream smoke total particulate matter
Weight quadrupole rod gas chromatography mass spectrometry method ", YC/T 377-2010 " the measurement chromatography of ions of ammonia of main stream smoke of cigarette ", GB/T
21130-2007 " measurement of benzo [a] pyrene in cigarette smoke condensates ", YC/T 254-2008 are " main in cigarette mainstream flue gas
Want the measurement high performance liquid chromatography of carbonyls ".
The analysis of 2 Chemical Components in Cigarette Smoke of table
As shown in Table 2,1 ~ 3 tobacco leaf of embodiment is prepared from the point of view of the risk assessment index of cigarette, hence it is evident that normal better than on the market
Cigarette is advised, it is significant for the removal effect of some high boiling substances (such as NNK, phenol and benzo [a] pyrene), moreover, being primarily present
The removal efficiency of ammonia in flue gas grain phase constituent is fairly good with the removal efficiency of higher boiling ingredient.
It randomly selects 10 smokeies, takes out after the cigarette prepared with the embodiment of the present invention 1 ~ 3 and conventional cigarette, fill in sense
Official's qualitative data such as table 3.
3 Sensory Quality of Cigarette data of table
As shown in Table 3, compared to conventional cigarette on the market, cigarette prepared by the present invention has suction experience well.
Above embodiments are only exemplary embodiment of the present invention, are not used in the limitation present invention, protection scope of the present invention
It is defined by the claims.Those skilled in the art can make various repair to the present invention within the spirit and scope of the present invention
Change or equivalent replacement, this modification or equivalent replacement also should be regarded as being within the scope of the present invention.
Claims (6)
1. a kind of tobacco leaf additive, which is characterized in that be mainly made of following weight fraction ratio component materials: modifying agent 30
~ 50 parts, 10 ~ 30 parts of adsorbent, 5 ~ 10 parts of phenylalanine, 2 ~ 5 parts of malto-oligosaccharide alcohol, 2 ~ 5 parts of potassium malate；
The modifying agent is by modification dolomite powder and hyperbranched lactate according to mass ratio 1:(0.2 ~ 0.5) be mixed with and
?；
The adsorbent is by hyperbranched lactate and chinese medicine material according to mass ratio 1:(2 ~ 5) mixing after be prepared；
The tobacco leaf additive additional amount is the 20% ~ 40% of quality of tobacco.
2. tobacco leaf additive according to claim 1, which is characterized in that the chinese medicine material is Kiwi berry extraction
One of object, tea polyphenols, Radix Astragali, Radix Isatidis.
3. tobacco leaf additive according to claim 1, which is characterized in that the additive is in temperature in tobacco leaf
50 ~ 60 DEG C, add under the conditions of relative humidity 40% ~ 50%.
4. a kind of the preparation method side of the tobacco leaf additive as described in claim 1 ~ 3 is any, which is characterized in that including following
Step:
One, the preparation of modification dolomite powder
(1) by ratio of weight and the number of copies, 10 ~ 15 parts of dolomite powder are weighed, NaNO is dissolved in3In be configured to solution, stirring 15 at 80 DEG C ~
20min, then the dry 2h at 120 DEG C, obtains compound dolomite powder；
The NaNO3It is (0.1 ~ 0.2) with dolomite powder mass ratio: 1；
(2) compound dolomite powder is handled into 1h in argon gas discharging plasma system, 6 each 10min, are changed altogether
Property dolomite powder；
The argon gas discharging plasma system is to pour argon gas after vacuumizing, and stablizes its pressure in 100 ~ 110Pa, then
It is passed through DC power supply, breakdown voltage 900V, burning voltage 600V, electric current are 9 ~ 11mA；
Two, the preparation of hyperbranched poly lactic acid
Score ratio by weight, by 50 ~ 70 parts of lactate, 10 ~ 20 parts of lactic acid, 1 ~ 5 part of glycerine, 3 ~ 5 parts of gluconic acid mixing, side
Stirring side is warming up to 120 ~ 165 DEG C, accelerates dehydration, removes after distillating moisture, continues to be decompressed to 1000 ~ 1300Pa, keep 170 ~
175 DEG C of 10 ~ 12h of isothermal reaction pour out reaction product, are ground into powder after cooling, after acetone solution, are added dropwise to dehydrated alcohol
Middle precipitating filters, and washing, 60 DEG C of vacuum drying 12h of filter cake obtain hyperbranched lactate；
The lactate is a kind of in sodium lactate, potassium lactate and lithium lactate；
Three, the preparation of modifying agent
Hyperbranched lactate is dissolved in 10 ~ 20 times of water, 30min is stirred at 30 ~ 35 DEG C dissolves it sufficiently, is then added and is modified
Dolomite powder continues stirring for 24 hours, obtains modifying agent；
The modification dolomite powder and hyperbranched lactate mass ratio 1:(0.2 ~ 0.5)；
Four, the preparation of adsorbent
The organic acid for taking hyperbranched lactate that its quality 2% ~ 8% is added is mixed, and obtains mixed liquor, mixing liquid is then added
The water of 10 ~ 20 times of product stirs 30min at 30 ~ 35 DEG C, and chinese medicine material is added, and after mixing 30 ~ 40min, obtains adsorbent；
The chinese medicine material and hyperbranched lactate mass ratio are (2 ~ 5): 1, it is added while stirring；
The organic acid is one of citric acid, malic acid；
Five, the preparation of tobacco leaf additive
By ratio of weight and the number of copies, 2 ~ 5 parts and 2 ~ 5 parts of potassium malate 5 ~ 10 parts of phenylalanine, malto-oligosaccharide alcohol mixing are taken, is heated to
After 40 ~ 50 DEG C, 30 ~ 50 parts of modifying agent, 10 ~ 30 parts of adsorbent is added, is cooled to room temperature after keeping the temperature 20 ~ 30min, cigarette can be obtained
Leaf additive.
5. the preparation method of tobacco leaf additive according to claim 4, which is characterized in that the Kiwi berry extracts
Object the preparation method is as follows:
(1) take Kiwi berry, be put into juice extractor and be beaten broken, the mixing enzyme aqueous solution of equal quality is added, 36 DEG C of temperature ~
38 DEG C of progress constant temperature digest 2h, are warming up to 80 DEG C and keep 20 ~ 30min inactivation, obtain mixture；
The aqueous solution of the mixed enzyme be pectase, cellulase, carbohydrase, alpha-amylase and acid protease in mass ratio
2:1:1:1:2 is mixed to join in distilled water, and being prepared into mass fraction is 10% mixing enzyme aqueous solution；
(2) pH for adjusting the mixture after inactivation is 3.5 ~ 4.0, at 25 ~ 30 DEG C, carries out the Maillard reaction of 18h, is obtained anti-
Answer mixture；
(3) reaction mixture is distilled, collects fraction, obtain volatile fragrant component, distillation test residue volume
The ethanol water that score is 33 ~ 40% extracts, and supernatant is taken to be concentrated, and must dive fragrant component；
(4) head perfume (or spice) component and latent fragrant component are mixed according to 4 ︰ 1 of mass ratio, 2 ~ 4 DEG C carry out refrigeration 8h, take supernatant that can obtain Mi
Monkey peach extract.
6. the preparation method of tobacco leaf additive according to claim 4, which is characterized in that the chinese medicine material is
When Radix Astragali or Radix Isatidis, processing method is as follows:
Radix Astragali or Radix Isatidis are added in 2 ~ 5 times of water, after decoction to moisture content is 0.3 ~ 0.5 times of original volume, material is taken
It dries and crushes out, cross 50 ~ 100 meshes, obtain Radix Astragali or Radix Isatidis material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810622580.6A CN108968140B (en) | 2018-06-15 | 2018-06-15 | Cigarette tobacco additive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810622580.6A CN108968140B (en) | 2018-06-15 | 2018-06-15 | Cigarette tobacco additive and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108968140A true CN108968140A (en) | 2018-12-11 |
| CN108968140B CN108968140B (en) | 2021-07-30 |
Family
ID=64541412
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810622580.6A Active CN108968140B (en) | 2018-06-15 | 2018-06-15 | Cigarette tobacco additive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108968140B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114468169A (en) * | 2022-04-01 | 2022-05-13 | 潍坊天普阳光饲料科技有限公司 | Feed additive for relieving pig stress and preparation method thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1355865A (en) * | 1970-07-30 | 1974-06-05 | Celanese Corp | Smoking materials |
| DE1900491B2 (en) * | 1968-01-10 | 1979-07-12 | Celanese Corp., New York, N.Y. (V.St.A.) | Tobacco replacement material - contg. starch, starch ethers or cellulose ethers |
| US4195645A (en) * | 1978-03-13 | 1980-04-01 | Celanese Corporation | Tobacco-substitute smoking material |
| US4233993A (en) * | 1978-03-17 | 1980-11-18 | Celanese Corporation | Smoking material |
| CN103371429A (en) * | 2012-04-22 | 2013-10-30 | 朱大恒 | Tobacco dechlorinating method, application of tobacco dechlorinating method and tobacco dechlorinating device |
| DE202018000336U1 (en) * | 2018-01-23 | 2018-03-02 | Ursula Boscheinen | Highly concentrated flavored and / or steam donating additive for water pipe tobacco and substitute |
-
2018
- 2018-06-15 CN CN201810622580.6A patent/CN108968140B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1900491B2 (en) * | 1968-01-10 | 1979-07-12 | Celanese Corp., New York, N.Y. (V.St.A.) | Tobacco replacement material - contg. starch, starch ethers or cellulose ethers |
| GB1355865A (en) * | 1970-07-30 | 1974-06-05 | Celanese Corp | Smoking materials |
| US4195645A (en) * | 1978-03-13 | 1980-04-01 | Celanese Corporation | Tobacco-substitute smoking material |
| US4233993A (en) * | 1978-03-17 | 1980-11-18 | Celanese Corporation | Smoking material |
| CN103371429A (en) * | 2012-04-22 | 2013-10-30 | 朱大恒 | Tobacco dechlorinating method, application of tobacco dechlorinating method and tobacco dechlorinating device |
| DE202018000336U1 (en) * | 2018-01-23 | 2018-03-02 | Ursula Boscheinen | Highly concentrated flavored and / or steam donating additive for water pipe tobacco and substitute |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114468169A (en) * | 2022-04-01 | 2022-05-13 | 潍坊天普阳光饲料科技有限公司 | Feed additive for relieving pig stress and preparation method thereof |
| CN114468169B (en) * | 2022-04-01 | 2022-06-10 | 潍坊天普阳光饲料科技有限公司 | Feed additive for relieving pig stress and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108968140B (en) | 2021-07-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101084798A (en) | Technology for manufacturing snuff | |
| CN101999753B (en) | Method for processing burley tobacco and application thereof to cigarette | |
| CN104223346B (en) | The method of functional type reconstituted tobacco prepared by Fructus Citri tangerinae grass | |
| CN107114821B (en) | A kind of device and method of hot trapping preparation smoke fragrance | |
| CN113876023A (en) | Method for preparing tobacco flavor by utilizing tobacco leaf residues and application of tobacco flavor | |
| CN112646661A (en) | Preparation method and application of smoked plum tobacco flavor | |
| CN102048238A (en) | Preparation method for liquid cigarette | |
| CN106675783A (en) | Preparation method of flavor having tobacco and coffee fragrance and used for thermal reaction tobacco, and application of flavor to cigarettes | |
| CN101623126A (en) | Preparation technology of traditional Chinese medicine detoxification smoke-quit perfuming annex solution for cigarette | |
| CN110982625A (en) | Licorice-flavored dried beads for cigarette filter tips and preparation method thereof | |
| CN108968140A (en) | A kind of tobacco leaf additive and preparation method thereof | |
| CN107874318B (en) | Herbal carbon composite particles, preparation method and application thereof in cigarettes | |
| CN103462213A (en) | Tobacco material preparing method for heated non-combustion tobacco products | |
| CN108887732B (en) | Preparation method of tobacco humectant | |
| CN106675782A (en) | Preparation method of thermal reaction tobacco flavor with fresh-sweetness aroma of tobacco as well as application of tobacco flavor in cigarettes | |
| CN106867667A (en) | The preparation and its application of a kind of essence spice for cigarette | |
| CN114052283B (en) | Abelmoschus manihot bead-blasting essence and preparation method and application thereof | |
| CN105029699A (en) | Mint glycerol triacetate extract and application thereof in cigarette | |
| CN105011368A (en) | Glycerol triacetate extract of momordica grosvenori and application thereof to cigarette | |
| CN101322581B (en) | Mineral ether-extracted Pu'er cooked tea extract and preparation and use thereof | |
| CN108936793A (en) | A method of reducing cigarette CO and releasing content of coke tar | |
| CN101342010B (en) | Petroleum ether extracted white tea extract, preparation and application thereof | |
| CN107802025A (en) | A kind of preparation method of ginkgo biloba p.e and its application in cigarette | |
| CN108991599A (en) | A kind of cigarette filter-tip additive agent and preparation method thereof | |
| CN102266117A (en) | Production method of liquid cigarette |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20221129 Address after: 538001 Building 5, north of Taohua Lake New Business Incubation Park, taozhong Road, Gangkou District, Fangchenggang City, Guangxi Zhuang Autonomous Region Patentee after: FANGCHENGGANG FENGHE QUCHEN AGRICULTURAL TECHNOLOGY CO.,LTD. Address before: 530000 No. 101, unit 2, building 38, No. 4, Anhu Road, Qingxiu District, Nanning City, Guangxi Zhuang Autonomous Region Patentee before: Zhang Shenman |