CN108957895A - 酸碱响应性电致变色薄膜、其制备方法和应用以及电致变色器件 - Google Patents
酸碱响应性电致变色薄膜、其制备方法和应用以及电致变色器件 Download PDFInfo
- Publication number
- CN108957895A CN108957895A CN201810659625.7A CN201810659625A CN108957895A CN 108957895 A CN108957895 A CN 108957895A CN 201810659625 A CN201810659625 A CN 201810659625A CN 108957895 A CN108957895 A CN 108957895A
- Authority
- CN
- China
- Prior art keywords
- acid
- weight
- parts
- response
- alkali
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 230000004044 response Effects 0.000 title claims abstract description 86
- 238000002360 preparation method Methods 0.000 title claims abstract description 42
- 239000003513 alkali Substances 0.000 claims abstract description 72
- 239000002253 acid Substances 0.000 claims abstract description 60
- 239000002585 base Substances 0.000 claims abstract description 44
- 239000003792 electrolyte Substances 0.000 claims abstract description 42
- 239000000975 dye Substances 0.000 claims abstract description 41
- 239000004014 plasticizer Substances 0.000 claims abstract description 40
- 229920003229 poly(methyl methacrylate) Polymers 0.000 claims abstract description 34
- 239000004926 polymethyl methacrylate Substances 0.000 claims abstract description 34
- 239000000463 material Substances 0.000 claims abstract description 23
- 150000002500 ions Chemical class 0.000 claims description 44
- 238000003860 storage Methods 0.000 claims description 38
- 238000000576 coating method Methods 0.000 claims description 24
- 239000011248 coating agent Substances 0.000 claims description 23
- 239000011521 glass Substances 0.000 claims description 13
- PYKYMHQGRFAEBM-UHFFFAOYSA-N anthraquinone Natural products CCC(=O)c1c(O)c2C(=O)C3C(C=CC=C3O)C(=O)c2cc1CC(=O)OC PYKYMHQGRFAEBM-UHFFFAOYSA-N 0.000 claims description 11
- 150000004056 anthraquinones Chemical class 0.000 claims description 11
- 230000005611 electricity Effects 0.000 claims description 10
- KJFMBFZCATUALV-UHFFFAOYSA-N phenolphthalein Chemical compound C1=CC(O)=CC=C1C1(C=2C=CC(O)=CC=2)C2=CC=CC=C2C(=O)O1 KJFMBFZCATUALV-UHFFFAOYSA-N 0.000 claims description 8
- FRPHFZCDPYBUAU-UHFFFAOYSA-N Bromocresolgreen Chemical compound CC1=C(Br)C(O)=C(Br)C=C1C1(C=2C(=C(Br)C(O)=C(Br)C=2)C)C2=CC=CC=C2S(=O)(=O)O1 FRPHFZCDPYBUAU-UHFFFAOYSA-N 0.000 claims description 7
- 150000004982 aromatic amines Chemical class 0.000 claims description 7
- -1 imidazole radicals benzoquinones Chemical class 0.000 claims description 7
- 150000003672 ureas Chemical class 0.000 claims description 7
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims description 6
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical class [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 6
- 150000004057 1,4-benzoquinones Chemical class 0.000 claims description 5
- SIXOAUAWLZKQKX-UHFFFAOYSA-N carbonic acid;prop-1-ene Chemical compound CC=C.OC(O)=O SIXOAUAWLZKQKX-UHFFFAOYSA-N 0.000 claims description 5
- 150000004989 p-phenylenediamines Chemical class 0.000 claims description 5
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 claims description 4
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 claims description 4
- 241001597008 Nomeidae Species 0.000 claims description 4
- 229910000040 hydrogen fluoride Inorganic materials 0.000 claims description 4
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 claims description 4
- MHCFAGZWMAWTNR-UHFFFAOYSA-M lithium perchlorate Chemical compound [Li+].[O-]Cl(=O)(=O)=O MHCFAGZWMAWTNR-UHFFFAOYSA-M 0.000 claims description 4
- 229910001486 lithium perchlorate Inorganic materials 0.000 claims description 4
- 229960005382 phenolphthalein Drugs 0.000 claims description 4
- KAIPKTYOBMEXRR-UHFFFAOYSA-N 1-butyl-3-methyl-2h-imidazole Chemical compound CCCCN1CN(C)C=C1 KAIPKTYOBMEXRR-UHFFFAOYSA-N 0.000 claims description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 claims description 3
- 150000004054 benzoquinones Chemical class 0.000 claims description 3
- 229910052744 lithium Inorganic materials 0.000 claims description 3
- 239000003471 mutagenic agent Substances 0.000 claims description 3
- 231100000707 mutagenic chemical Toxicity 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 claims description 3
- MFZQGVIVNYZZGI-UHFFFAOYSA-N 1,2-diethoxyanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(OCC)C(OCC)=CC=C3C(=O)C2=C1 MFZQGVIVNYZZGI-UHFFFAOYSA-N 0.000 claims description 2
- AMKRBKSZCGCEJK-UHFFFAOYSA-N 1,2-dimethoxyanthracene-9,10-dione Chemical compound C1=CC=C2C(=O)C3=C(OC)C(OC)=CC=C3C(=O)C2=C1 AMKRBKSZCGCEJK-UHFFFAOYSA-N 0.000 claims description 2
- 238000009825 accumulation Methods 0.000 claims description 2
- 238000000151 deposition Methods 0.000 claims description 2
- 230000008021 deposition Effects 0.000 claims description 2
- 238000010422 painting Methods 0.000 claims description 2
- 239000010408 film Substances 0.000 claims 19
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims 1
- 229910052794 bromium Inorganic materials 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- GNBHRKFJIUUOQI-UHFFFAOYSA-N fluorescein Chemical compound O1C(=O)C2=CC=CC=C2C21C1=CC=C(O)C=C1OC1=CC(O)=CC=C21 GNBHRKFJIUUOQI-UHFFFAOYSA-N 0.000 claims 1
- 238000000465 moulding Methods 0.000 claims 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims 1
- 150000004986 phenylenediamines Chemical class 0.000 claims 1
- 239000010409 thin film Substances 0.000 claims 1
- PRZSXZWFJHEZBJ-UHFFFAOYSA-N thymol blue Chemical compound C1=C(O)C(C(C)C)=CC(C2(C3=CC=CC=C3S(=O)(=O)O2)C=2C(=CC(O)=C(C(C)C)C=2)C)=C1C PRZSXZWFJHEZBJ-UHFFFAOYSA-N 0.000 claims 1
- 230000008859 change Effects 0.000 abstract description 11
- 230000002441 reversible effect Effects 0.000 abstract description 5
- 230000000694 effects Effects 0.000 abstract description 4
- 230000005684 electric field Effects 0.000 abstract description 4
- 238000002835 absorbance Methods 0.000 description 15
- 238000000034 method Methods 0.000 description 10
- 230000004043 responsiveness Effects 0.000 description 10
- 230000014759 maintenance of location Effects 0.000 description 9
- 239000000203 mixture Substances 0.000 description 7
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 6
- 238000007254 oxidation reaction Methods 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 238000010586 diagram Methods 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 238000005265 energy consumption Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- SMWDFEZZVXVKRB-UHFFFAOYSA-N Quinoline Chemical compound N1=CC=CC2=CC=CC=C21 SMWDFEZZVXVKRB-UHFFFAOYSA-N 0.000 description 2
- 230000005518 electrochemistry Effects 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 229920002521 macromolecule Polymers 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012856 packing Methods 0.000 description 2
- 238000006116 polymerization reaction Methods 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000010998 test method Methods 0.000 description 2
- 238000002371 ultraviolet--visible spectrum Methods 0.000 description 2
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- RLQZIECDMISZHS-UHFFFAOYSA-N 2-phenylcyclohexa-2,5-diene-1,4-dione Chemical class O=C1C=CC(=O)C(C=2C=CC=CC=2)=C1 RLQZIECDMISZHS-UHFFFAOYSA-N 0.000 description 1
- ZPLCXHWYPWVJDL-UHFFFAOYSA-N 4-[(4-hydroxyphenyl)methyl]-1,3-oxazolidin-2-one Chemical compound C1=CC(O)=CC=C1CC1NC(=O)OC1 ZPLCXHWYPWVJDL-UHFFFAOYSA-N 0.000 description 1
- 229910003893 H2WO4 Inorganic materials 0.000 description 1
- JLTDJTHDQAWBAV-UHFFFAOYSA-N N,N-dimethylaniline Chemical compound CN(C)C1=CC=CC=C1 JLTDJTHDQAWBAV-UHFFFAOYSA-N 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000008033 biological extinction Effects 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 125000005586 carbonic acid group Chemical group 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 125000001664 diethylamino group Chemical group [H]C([H])([H])C([H])([H])N(*)C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000001548 drop coating Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- DCYOBGZUOMKFPA-UHFFFAOYSA-N iron(2+);iron(3+);octadecacyanide Chemical compound [Fe+2].[Fe+2].[Fe+2].[Fe+3].[Fe+3].[Fe+3].[Fe+3].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-].N#[C-] DCYOBGZUOMKFPA-UHFFFAOYSA-N 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 150000002518 isoindoles Chemical class 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- IEQIEDJGQAUEQZ-UHFFFAOYSA-N phthalocyanine Chemical compound N1C(N=C2C3=CC=CC=C3C(N=C3C4=CC=CC=C4C(=N4)N3)=N2)=C(C=CC=C2)C2=C1N=C1C2=CC=CC=C2C4=N1 IEQIEDJGQAUEQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920000123 polythiophene Chemical class 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 229960003351 prussian blue Drugs 0.000 description 1
- 239000013225 prussian blue Substances 0.000 description 1
- BBNQQADTFFCFGB-UHFFFAOYSA-N purpurin Chemical compound C1=CC=C2C(=O)C3=C(O)C(O)=CC(O)=C3C(=O)C2=C1 BBNQQADTFFCFGB-UHFFFAOYSA-N 0.000 description 1
- 238000006479 redox reaction Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 238000004528 spin coating Methods 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000000638 stimulation Effects 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- CMPGARWFYBADJI-UHFFFAOYSA-L tungstic acid Chemical compound O[W](O)(=O)=O CMPGARWFYBADJI-UHFFFAOYSA-L 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/15—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect
- G02F1/1514—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material
- G02F1/1523—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material
- G02F1/1525—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on an electrochromic effect characterised by the electrochromic material, e.g. by the electrodeposited material comprising inorganic material characterised by a particular ion transporting layer, e.g. electrolyte
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/18—Manufacture of films or sheets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/0427—Coating with only one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2333/12—Homopolymers or copolymers of methyl methacrylate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
- C08J2433/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C08J2433/10—Homopolymers or copolymers of methacrylic acid esters
- C08J2433/12—Homopolymers or copolymers of methyl methacrylate
Landscapes
- Chemical & Material Sciences (AREA)
- Physics & Mathematics (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Nonlinear Science (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- General Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Electrochromic Elements, Electrophoresis, Or Variable Reflection Or Absorption Elements (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810659625.7A CN108957895B (zh) | 2018-06-25 | 2018-06-25 | 酸碱响应性电致变色薄膜、其制备方法和应用以及电致变色器件 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201810659625.7A CN108957895B (zh) | 2018-06-25 | 2018-06-25 | 酸碱响应性电致变色薄膜、其制备方法和应用以及电致变色器件 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN108957895A true CN108957895A (zh) | 2018-12-07 |
CN108957895B CN108957895B (zh) | 2021-06-11 |
Family
ID=64486308
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201810659625.7A Active CN108957895B (zh) | 2018-06-25 | 2018-06-25 | 酸碱响应性电致变色薄膜、其制备方法和应用以及电致变色器件 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN108957895B (zh) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111505880A (zh) * | 2020-05-25 | 2020-08-07 | 哈尔滨工程大学 | 一种热响应电解质材料及其制备方法和应用 |
CN113238422A (zh) * | 2020-01-22 | 2021-08-10 | 北京开阳亮微科技有限公司 | 离子传输复合膜、包含所述复合膜的电致变色玻璃及其制备方法 |
CN113238423A (zh) * | 2020-01-22 | 2021-08-10 | 北京开阳亮微科技有限公司 | 离子传输纳米复合膜、包含所述复合膜的电致变色玻璃及其制备方法 |
CN113376916A (zh) * | 2021-06-25 | 2021-09-10 | 绍兴迪飞新材料有限公司 | 一种智能动态调光膜及其制备方法和应用 |
CN115073505A (zh) * | 2022-06-08 | 2022-09-20 | 吉林大学 | 一种电致变色材料、薄膜、器件及其应用 |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104518150A (zh) * | 2013-09-28 | 2015-04-15 | 海洋王照明科技股份有限公司 | 有机电致发光器件及其制备方法 |
CN105838350A (zh) * | 2016-04-16 | 2016-08-10 | 吉林大学 | 一类电致变色复合材料及制备电致变色器件 |
CN106117215A (zh) * | 2016-07-11 | 2016-11-16 | 复旦大学 | 一类含有二吡咯酮并苯的电致变色材料及其制备方法和应用 |
US9500926B2 (en) * | 2013-03-14 | 2016-11-22 | Ricoh Company, Ltd. | Electrochromic display element and image display device |
JP2017198966A (ja) * | 2016-04-22 | 2017-11-02 | 株式会社リコー | エレクトロクロミック素子 |
JP2018021113A (ja) * | 2016-08-02 | 2018-02-08 | 国立研究開発法人産業技術総合研究所 | エレクトロクロミック材料、これを用いた色可変電極及び素子 |
-
2018
- 2018-06-25 CN CN201810659625.7A patent/CN108957895B/zh active Active
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US9500926B2 (en) * | 2013-03-14 | 2016-11-22 | Ricoh Company, Ltd. | Electrochromic display element and image display device |
CN104518150A (zh) * | 2013-09-28 | 2015-04-15 | 海洋王照明科技股份有限公司 | 有机电致发光器件及其制备方法 |
CN105838350A (zh) * | 2016-04-16 | 2016-08-10 | 吉林大学 | 一类电致变色复合材料及制备电致变色器件 |
JP2017198966A (ja) * | 2016-04-22 | 2017-11-02 | 株式会社リコー | エレクトロクロミック素子 |
CN106117215A (zh) * | 2016-07-11 | 2016-11-16 | 复旦大学 | 一类含有二吡咯酮并苯的电致变色材料及其制备方法和应用 |
JP2018021113A (ja) * | 2016-08-02 | 2018-02-08 | 国立研究開発法人産業技術総合研究所 | エレクトロクロミック材料、これを用いた色可変電極及び素子 |
Non-Patent Citations (1)
Title |
---|
张宇模: "《电致酸/碱理论及其在有机电致变色材料中的应用》", 《中国博士学位论文全文数据库 工程科技I辑》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113238422A (zh) * | 2020-01-22 | 2021-08-10 | 北京开阳亮微科技有限公司 | 离子传输复合膜、包含所述复合膜的电致变色玻璃及其制备方法 |
CN113238423A (zh) * | 2020-01-22 | 2021-08-10 | 北京开阳亮微科技有限公司 | 离子传输纳米复合膜、包含所述复合膜的电致变色玻璃及其制备方法 |
CN111505880A (zh) * | 2020-05-25 | 2020-08-07 | 哈尔滨工程大学 | 一种热响应电解质材料及其制备方法和应用 |
CN113376916A (zh) * | 2021-06-25 | 2021-09-10 | 绍兴迪飞新材料有限公司 | 一种智能动态调光膜及其制备方法和应用 |
CN115073505A (zh) * | 2022-06-08 | 2022-09-20 | 吉林大学 | 一种电致变色材料、薄膜、器件及其应用 |
Also Published As
Publication number | Publication date |
---|---|
CN108957895B (zh) | 2021-06-11 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN108957895A (zh) | 酸碱响应性电致变色薄膜、其制备方法和应用以及电致变色器件 | |
CN108873537A (zh) | 一种电致变色薄膜、其制备方法和应用以及电致变色器件 | |
CN108873538A (zh) | 一种碱响应性电致变色薄膜及其制备方法和应用 | |
Lu et al. | Fabricating conducting polymer electrochromic devices using ionic liquids | |
Higuchi | Electrochromic organic–metallic hybrid polymers: fundamentals and device applications | |
MXPA03008458A (es) | Dispositivo de visualizacion electrocromico y composiciones utiles para hacer tales dispositivos. | |
CN108363255B (zh) | 一种电致变色膜材料及其制备的电致变色膜器件 | |
CN103172274B (zh) | 一种氧化镍/聚苯胺复合电致变色薄膜的制备方法 | |
CN107032637B (zh) | 一种复合电致变色薄膜的制备方法 | |
Jennings et al. | A redox-flow electrochromic window | |
CN107991819B (zh) | 一种提高普鲁士蓝电致变色薄膜在LiClO4/PC电解质中的循环稳定性的方法 | |
JP2023512976A (ja) | エレクトロクロミックデバイス、およびその変色方法 | |
CN108822297A (zh) | 一种多色电致变色聚合物及其在电致变色领域中的应用 | |
CN110791153B (zh) | 一种聚合物基导电油墨及其电致变色器件 | |
CN103232174A (zh) | 一种氧化镍/聚苯胺复合电致变色薄膜的制备方法 | |
CN111142301B (zh) | 一种高性能的电致变色器件及其制备方法 | |
Rozman | Multicolor Transparent‐Conductive‐Electrode Free Electronic Paper based on Steel Foil and Water Electrolyte with pH Indicator Dyes | |
JP2010204438A (ja) | 表示素子 | |
CN208737172U (zh) | 一种碱性电致变色器件 | |
CN208737170U (zh) | 一种电致变色器件 | |
JP2007047656A (ja) | エレクトロクロミック装置及びこれを用いた表示方法 | |
CN208737171U (zh) | 一种电致变色薄膜以及包含其的电致变色器件 | |
KR100214254B1 (ko) | 전기변색 고분자용액, 전기변색 고분자박막 및 전기변색소자와 이들의 제조 | |
CN115612146B (zh) | 一种高性能金属有机骨架材料与多金属氧酸盐电致变色复合薄膜及其应用 | |
JPS59217791A (ja) | エレクトロクロミツク材料 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
TR01 | Transfer of patent right |
Effective date of registration: 20210929 Address after: 201508 room 1005, 10th floor, No. 1000, Tingwei Road, Jinshan District, Shanghai Patentee after: Shanghai Dingyi Material Technology Co.,Ltd. Address before: 213000 Changyang Road, West Taihu Science and Technology Industrial Park, Wujin District, Changzhou City, Jiangsu Province Patentee before: CHANGZHOU YISHI PHOTOELECTRIC TECHNOLOGY Co.,Ltd. |
|
TR01 | Transfer of patent right | ||
TR01 | Transfer of patent right |
Effective date of registration: 20240301 Address after: 314000 No. 790 Huayan Road, Jiaxing Economic and Technological Development Zone, Zhejiang Province Patentee after: Zhejiang Caicheng Technology Co.,Ltd. Country or region after: China Address before: 201508 room 1005, 10th floor, No. 1000, Tingwei Road, Jinshan District, Shanghai Patentee before: Shanghai Dingyi Material Technology Co.,Ltd. Country or region before: China |
|
TR01 | Transfer of patent right |